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On Exciton-Vibration and Exciton-Photon Interactions in Organic Semiconductors (Paperback, 1st ed. 2021)
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On Exciton-Vibration and Exciton-Photon Interactions in Organic Semiconductors (Paperback, 1st ed. 2021)
Series: Springer Theses
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What are the physical mechanisms that underlie the efficient
generation and transfer of energy at the nanoscale? Nature seems to
know the answer to this question, having optimised the process of
photosynthesis in plants over millions of years of evolution. It is
conceivable that humans could mimic this process using synthetic
materials, and organic semiconductors have attracted a lot of
attention in this respect. Once an organic semiconductor absorbs
light, bound pairs of electrons with positively charged holes,
termed `excitons', are formed. Excitons behave as fundamental
energy carriers, hence understanding the physics behind their
efficient generation and transfer is critical to realising the
potential of organic semiconductors for light-harvesting and other
applications, such as LEDs and transistors. However, this problem
is extremely challenging since excitons can interact very strongly
with photons. Moreover, simultaneously with the exciton motion,
organic molecules can vibrate in hundreds of possible ways, having
a very strong effect on energy transfer. The description of these
complex phenomena is often beyond the reach of standard quantum
mechanical methods which rely on the assumption of weak
interactions between excitons, photons and vibrations. In this
thesis, Antonios Alvertis addresses this problem through the
development and application of a variety of different theoretical
methods to the description of these strong interactions, providing
pedagogical explanations of the underlying physics. A comprehensive
introduction to organic semiconductors is followed by a review of
the background theory that is employed to approach the relevant
research questions, and the theoretical results are presented in
close connection with experiment, yielding valuable insights for
experimentalists and theoreticians alike.
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