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Books > Science & Mathematics > Chemistry > Physical chemistry
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Metalloporphyrins Catalyzed Oxidations (Hardcover, 1994 ed.)
Loot Price: R1,735
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Metalloporphyrins Catalyzed Oxidations (Hardcover, 1994 ed.)
Series: Catalysis by Metal Complexes, 17
Expected to ship within 10 - 15 working days
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Oxidative catalysis by metalloporphyrin systems occupies a
prominent role in the current research in the fields of chemical
and biological catalysis. Our particular interest and approach has
been to collect in the same volume papers dealing with both the
chemical and biological aspects of the reactivity of heme systems
because of the realization that a better understanding of the
complementary discipline can be extremely useful for the
researchers from either field. The current progress of the research
on synthetic metalloporphyrin catalysts has led to the development
of several systems that are able to reproduce the heme-enzyme
mediated oxygenation and oxidation reactions, at least in terms of
reaction types, mechanisms and often rates. These achievements have
stimulated the of creating metalloporphyrin catalysts which are
both ambitious project efficient and stable enough to become
competitive for large-scale industrial processes. Although this
project is still far from being realized, the efforts in this
direction parallel those aimed at the application of heme enzymes
to chemical technologies, e. g. for the mild, selective oxidation
of organics or the detoxification of pollutants. Both the two
approaches will be advantageous because while the enzyme systems
can achieve selectivities which are probably unattainable by
synthetic catalysts, the latter can be active under experimental
conditions that would readily inactivate the enzymes.
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