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Automobile Catalytic Converters (Paperback, Softcover reprint of the original 1st ed. 1984)
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Automobile Catalytic Converters (Paperback, Softcover reprint of the original 1st ed. 1984)
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The use of catalytic converters for the purification of automotive
exhaust gases is a relatively new technology which was brought into
existence by social pressures for the preservation of acceptable
environmental conditions. The majority of catalytic practitioners
have been able to watch the growth of this technology from its
inception to its current state of sophistication. Automotive
catalytic converter technology is now in a mature state, and this
chapter from Vol. 5 Catalysis: Science and Technology by Dr. K. C.
Taylor provides a review which covers both the process chemistry
and the most important converter design factors. Contents 1.
Introduction. . . . . . . . . . . . . . 2. Emission Regulations in
the United States. 3. Exhaust Emission Characteristics. . 3 4. 1981
Emission Control Technology. 5 A. Converters. . . 5 B. Control
System. 7 8 ~. Catalyst Screening . 6. Laboratory Testing. .10 7.
The Chemical Reactions 13 8. Composition of Three-Way Catalysts. 16
A. Rhodium 17 21 B. Platinum. C. Palladium 22 D. Iridium . 22 23 E.
Ruthenium and Nickel. F. Cerium Oxide ..... 23 G. Search for
Alternatives to Nohle Metals 24 9. Catalyst Supports . 25 A.
Pellets .... 26 B. Monoliths . . 26 10. The Transient Behavior of
Three-Way Catalysts 27 II. Deterioration of Three-Way Catalysts. 35
A. Thermal Effects. . . . 35 B. Phosphorus Poisoning. . . 37 C.
Lead Poisoning. . . . . . * 38 D. Catalyst Poisoning by Sulfur * 40
12. The 0.4 NO,; Research Objective. * 41 13. Control of Diesel
Particulate Emissions.
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