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Books > Science & Mathematics > Physics > Electricity, magnetism & electromagnetism
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Multifunctional Molecular Magnets Based on Octacyanidometalates (Hardcover, 1st ed. 2017)
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Multifunctional Molecular Magnets Based on Octacyanidometalates (Hardcover, 1st ed. 2017)
Series: Springer Theses
Expected to ship within 18 - 22 working days
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This thesis demonstrates the novel magnetic functionalities in
cyanido-bridged metal assemblies, and as such appeals to readers in
the field of materials science. The utilization of
octacyanidometalates as building blocks enables the observation of
(i) photo-induced magnetization due to a light-induced
spin-crossover in an iron octacyanidoniobate-based assembly, (ii)
photo-induced magnetization with a two-step spin-crossover behavior
in an iron octacyanidoniobate-based material, and (iii) the
coexistence of super-ionic conductivity and metamagnetism in a
manganese-octacyanoniobate system. These multi-functionalities are
achieved by incorporating a spin-crossover moiety or a
hydrogen-bonding network into a cyanido-bridged network structure
with a strong magnetic interaction. In particular, in light-induced
spin-crossover magnets, a magnetically non-ordered state can be
altered to a magnetically ordered state by photo-irradiation, which
is one of the attractive mechanisms for novel optical switching
devices.
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