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Conducting and Magnetic Organometallic Molecular Materials (Hardcover, 2009 ed.)
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Conducting and Magnetic Organometallic Molecular Materials (Hardcover, 2009 ed.)
Series: Topics in Organometallic Chemistry, 27
Expected to ship within 10 - 15 working days
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For several years, the two parallel worlds of Molecular Conductors
in one hand and Molecular Magnetism in the other have grown side by
side, the former essentially based on radical organic molecules,
the latter essentially based on the high spin properties of metal
complexes. Over the last few years however, organometallic
derivatives have started to play an increasingly important role in
both worlds, and have in many ways contributed to open several
passages between these two worlds. This volume recognizes this
important emerging evolution of both research areas. It is not
intended to give a comprehensive view of all possible
organometallic materials, and polymers for example were not
considered here. Rather we present a selection of the most recent
research topics where organometallic derivatives were shown to play
a crucial role in the setting of conducting and/or magnetic
properties in crystalline materials. First, the role of
organometallic anions in tet- thiafulvalenium-based molecular
conductors is highlighted by Schlueter, while Kubo and Kato
describe very recent ortho-metalated chelating ligands appended to
the TTF core and their conducting salts. The combination of
conducting and magnetic properties and the search for p-d
interactions are analyzed in two comp- mentary contributions by
Myazaki and Ouahab, while Valade focuses on the only class of metal
bis(dithiolene) complexes to give rise to superconductive molecular
materials, in association with organic as well as organometallic
cations.
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