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Material Designs and New Physical Properties in MX- and MMX-Chain Compounds (Hardcover, 2013 ed.) Loot Price: R3,051
Discovery Miles 30 510
Material Designs and New Physical Properties in MX- and MMX-Chain Compounds (Hardcover, 2013 ed.): Masahiro Yamashita, Hiroshi...

Material Designs and New Physical Properties in MX- and MMX-Chain Compounds (Hardcover, 2013 ed.)

Masahiro Yamashita, Hiroshi Okamoto

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Loot Price R3,051 Discovery Miles 30 510 | Repayment Terms: R286 pm x 12*

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This is the first book to comprehensively address the recent developments in both the experimental and theoretical aspects of quasi-one-dimensional halogen-bridged mono- (MX) and binuclear metal (MMX) chain complexes of Pt, Pd and Ni. These complexes have one-dimensional electronic structures, which cause the various physical properties as well as electronic structures. In most MX-chain complexes, the Pt and Pd units are in M(II)-M(IV) mixed valence or charge density wave (CDW) states due to electron-phonon interactions, and Ni compounds are in Ni(III) averaged valence or Mott-Hubbard states due to the on-site Coulomb repulsion. More recently, Pd(III) Mott-Hubbard (MH) states have been realized in the ground state by using the chemical pressure. Pt and Pd chain complexes undergo photo-induced phase transitions from CDW to MH or metal states, and Ni chain complexes undergo photo-induced phase transitions from MH to metal states. Ni chain complexes with strong electron correlations show tremendous third-order optical nonlinearity and nonlinear electrical conductivities. They can be explained theoretically by using the extended Peierls-Hubbard model. For MMX-chain complexes, averaged valence, CDW, charge polarization, and alternating charge polarization states have been realized by using chemical modification and external stimuli, such as temperature, photo-irradiation, pressure, and water vapor. All of the electronic structures and phase transitions can be explained theoretically.

General

Imprint: Springer-Verlag
Country of origin: Austria
Release date: December 2012
First published: 2013
Editors: Masahiro Yamashita • Hiroshi Okamoto
Dimensions: 235 x 155 x 20mm (L x W x T)
Format: Hardcover
Pages: 270
Edition: 2013 ed.
ISBN-13: 978-3-7091-1316-5
Categories: Books > Science & Mathematics > Chemistry > Inorganic chemistry > General
Books > Science & Mathematics > Chemistry > Organic chemistry > Organometallic chemistry
Books > Science & Mathematics > Biology, life sciences > Biochemistry > General
Books > Professional & Technical > Electronics & communications engineering > Electronics engineering > Electronic devices & materials > General
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LSN: 3-7091-1316-4
Barcode: 9783709113165

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