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One-Dimensional Organometallic Materials - An Analysis of Electronic Structure Effects (Paperback, Softcover reprint of the original 1st ed. 1987)
Loot Price: R2,853
Discovery Miles 28 530
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One-Dimensional Organometallic Materials - An Analysis of Electronic Structure Effects (Paperback, Softcover reprint of the original 1st ed. 1987)
Series: Lecture Notes in Chemistry, 45
Expected to ship within 10 - 15 working days
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This lecture note gives an analysis of electronic structure effects
for a new class of molecular solids, i. e. one-dimensional
organometal lic systems formed by transition-met. l atoms that are
embedded in a matrix of macrocyclic organic ligands. These systems
as well as orga nic metals have focused considerable interest due
to the potential formation of high-mobility charge carriers. For
the present author it is difficult to participate in this
restriction on a single physical property (i. e. high electronic
conductivities, technical applications, etc. ). The lecture note is
hopefully a small contribution to enhance the general understanding
of certain electronic properties in organo metallic polymers. Those
problems have been considered in the first place that seem to form
a theoretical deficit in one specific field of solid-state
chemistry. For the reader it will become evident that this
contribution is a compromise always guided and limited by
boundaries: i) An attempt to present problems to a .chemical.
audience which have their roots in solid-state physics. ii) The
model calculations are limited by the currently available
computational facilities. This .boundary. implies that the compu
tational data a e subject to severe theoretical approximations.
iii) Theorists have often a strong tendency to identify their
numeri cal results and models with physical effects. Also this
lecture note is not free of this almost universal trend.
Nevertheless the author hopes that this text leads to some insight
into a rather modern research field. M. e. B6hm I."
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