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Surface Tension and Related Thermodynamic Quantities of Aqueous Electrolyte Solutions (Paperback)
Loot Price: R1,873
Discovery Miles 18 730
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Surface Tension and Related Thermodynamic Quantities of Aqueous Electrolyte Solutions (Paperback)
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Total price: R1,893
Discovery Miles: 18 930
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Surface tension provides a thermodynamic avenue for analyzing
systems in equilibrium and formulating phenomenological
explanations for the behavior of constituent molecules in the
surface region. While there are extensive experimental observations
and established ideas regarding desorption of ions from the
surfaces of aqueous salt solutions, a more successful discussion of
the theory has recently emerged, which allows the quantitative
calculation of the distribution of ions in the surface region.
Surface Tension and Related Thermodynamic Quantities of Aqueous
Electrolyte Solutions provides a detailed and systematic analysis
of the properties of ions at the air/water interface. Unifying
older and newer theories and measurements, this book emphasizes the
contributions of simple ions to surface tension behavior, and the
practical consequences. It begins with a general discussion on
Gibbs surface thermodynamics, offering a guide to his theoretical
insight and formulation of the boundary between fluids. The text
then discusses the thermodynamic formulae that are useful for
practical experimental work in the analysis of fluid/fluid
interfaces. Chapters cover surface tension of pure water at
air/water and air/oil interfaces, surface tension of solutions and
the thermodynamic quantities associated with the adsorption and
desorption of solutes, and surface tension of simple salt
solutions. They also address adsorption of ions at the air/water
interface, surface tension of solutions and the effect of
temperature, adsorption from mixed electrolyte solutions, and
thermodynamic properties of zwitterionic amino acids in the surface
region. Focusing on the thermodynamic properties of ions at
air/fluid interfaces, this book gives scientists a quantitative,
rigorous, and objectively experimental methodology they can employ
in their research.
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