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An Ordering Concept on the Basis of Alternative Principles in Chemistry - Design of Chemicals and Chemical Reactions by Differentiation and Compensation (Paperback, Softcover reprint of the original 1st ed. 1990)
Loot Price: R2,780
Discovery Miles 27 800
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An Ordering Concept on the Basis of Alternative Principles in Chemistry - Design of Chemicals and Chemical Reactions by Differentiation and Compensation (Paperback, Softcover reprint of the original 1st ed. 1990)
Series: Reactivity and Structure: Concepts in Organic Chemistry, 28
Expected to ship within 10 - 15 working days
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Considering aspects of symmetry rules in chemistry, one is faced
with con tradictory terms as for example, "90 % concertedness"
sometimes being used in literature. To accept conservation of
orbital symmetry to be as controlled as inversion by alternative
principles seems far more promising. The intention of this book is
aimed at introducing a qualitative understanding of phase rela
tions in electromagnetic interactions. Avoiding one-sided dogmatism
we tried to demonstrate the importance of alternative principles as
guidelines to the evolution of alternative order in chemical
systems. Passing through the jungle of information it became
extremly important to control again and again our insights into the
ordering phenomena by experi ments under conditions as coherent as
possible. We became more aware of the fact that chemistry - the
science of "becoming" in complex systems - can not be understood by
mechanistic details, i. e. THROUGHPUT-studies alone, because the
mechanism is only true for the special system under inves tigation
and does not offer a tool for the evolution of opposite order. We
had to accept chemistry as a mediator between molecular physics and
general epistemology. This quite unusual combination was directed
by excel lent teachers and the realizations were made possible by
enthusiastic, open minded coworkers (see references). The next
target we will strive for on this journey will be to quantify the
alternative principles, that means obtaining the order parameters
of H. Haken (e. g. in asymmetric synthesis).
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