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Paramagnetic Complexes in High Resolution NMR Spectroscopy (Hardcover)
Loot Price: R5,838
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Paramagnetic Complexes in High Resolution NMR Spectroscopy (Hardcover)
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The monograph covers theoretical aspects of the method based on the
analysis of NMR spectra transformed by electron-nuclear or
hyperfine coupling, and provides examples of its practical
application for the solution of different tasks related to
structure and intramolecular dynamics of multi-electron systems.
The fundamentals of NMR theory in paramagnetic systems were
formulated by Blombergen, McConnell, Solomon, Berkheyn and other
researchers. However, wide application of HFC specifics for the
solution of diverse chemical tasks was triggered later, after the
development of a method for analysis of NMR spectra transformed by
additives of paramagnetic complexes. The book consists of three
chapters. Chapter 1 discloses the fundamentals of high resolution
NMR spectra transformed by hyperfine coupling. The two other
chapters illustrate fruitfulness and prospects of the application
of NMR phenomenon in paramagnetic systems for studying molecular
structure. Examples of specific spectra, analyzed in the monograph,
are selected in such a way that they could help a reader understand
a circle of possible problems which are solved using peculiarities
of the NMR phenomenon in paramagnetic systems. The same examples
also illustrate the techniques which can be employed for obtaining
information on the molecular structure of both ligands and
complexes using their NMR spectra transformed by hyperfine
coupling.
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