At the beginning of the twentieth century, engineers and technologists would have recognized the importance of adhesion in two main aspects: First, in the display of friction between surfaces - at the time a topic of growing importance to engineers; the second in crafts requiring the joining of materials - principally wood-to form engineering structures. While physical scientists would have admitted the adhesive properties of glues, gels, and certain pastes, they regarded them as materials of uncertain formulation, too impure to be amenable to precise experiment. Biological scientists were aware also of adhesive phenomena, but the science was supported by documentation rather than understanding. By the end of the century, adhesion and adhesives were playing a crucial and deliberate role in the formulation of materials, in the design and manufacture of engineering structures without weakening rivets or pins, and in the use of thin sections and intricate shapes. Miniaturization down to the micro- and now to the nano-level of mechanical, electrical, electronic, and optical devices relied heavily on the understanding and the technology of adhesion. For most of the century, physical scientists were aware that the states of matter, whether gas, liquid, or solid, were determined by the competition between thermal energy and int- molecular binding forces. Then the solid state had to be differentiated into crystals, amorphous glasses, metals, etc. , so the importance of the molecular attractions in determining stiffness and strength became clearer.

The two volumes "New Developments in Polymer Analytics" deal with recent progress in the characterization of polymers, mostly in solution but also at s- faces. Despite the fact that almost all of the described techniques are getting on in years, the contributions are expected to meet the readers interest because either the methods are newly applied to polymers or the instrumentation has achieved a major breakthrough leading to an enhanced utilizaton by polymer scientists. The first volume concentrates on separation techniques. H. Pasch summarizes the recent successes of multi-dimensional chromatography in the characteri- tion of copolymers. Both, chain length distribution and the compositional h- erogeneity of copolymers are accessible. Capillary electrophoresis is widely and successfully utilized for the characterization of biopolymers, particular of DNA. It is only recently that the technique has been applied to the characterization of water soluble synthetic macromolecules. This contributrion of Grosche and Engelhardt focuses on the analysis of polyelectrolytes by capillary electopho- sis. The last contribution of the first volume by Coelfen and Antonietti sum- rizes the achievements and pitfalls of field flow fractionation techniques. The major drawbacks in the instrumentation have been overcome in recent years and the"triple F techniques" are currently advancing to a powerful competitor to size exclusion chromatography.

The two volumes "New Developments in Polymer Analytics" deal with recent progress in the characterization of polymers, mostly in solution but also at sur faces. Despite the fact that almost all of the described techniques are getting on in years, the contributions are expected to meet the readers interest because either the methods are newly applied to polymers or the instrumentation has achieved a major breakthrough leading to an enhanced utilization by polymer scientists. The first volume concentrates on separation techniques. H. Pasch summarizes the recent successes of multi dimensional chromatography in the characteriza tion of copolymers. Both, chain length distribution and the compositional het erogeneity of copolymers are accessible. Capillary electrophoresis is widely and successfully utilized for the characterization of biopolymers, particular of DNA . It is only recently that the technique has been applied to the characterization of water soluble synthetic macromolecules. This contribution of Grosche and Engelhardt focuses on the analysis of polyelectrolytes by capillary electophore sis. The last contribution of the first volume by Coelfen and Antonietti summa rizes the achievements and pitfalls of field flow fractionation techniques .The major drawbacks in the instrumentation have been overcome in recent years and the "triple F techniques" are currently advancing to a powerful competitor to size exclusion chromatography.

A general and introductory survey of foams, emulsions and cellular materials. Foams and emulsions are illustrations of some fundamental concepts in statistical thermodynamics, rheology, elasticity and the physics and chemistry of divided media and interfaces. They also give rise to some of the most beautiful geometrical shapes and tilings, ordered or disordered. The chapters are grouped into sections having fairly loose boundaries. Each chapter is intelligible alone, but cross referencing means that the few concepts that may not be familiar to the reader can be found in other chapters in the book. Audience: Research students, researchers and teachers in physics, physical chemistry, materials science, mechanical engineering and geometry.

The investigative assault upon the enigmatic asphaltenes has recently resulted in sig nificant advances in many varied disciplines. Taken individually, each discipline exposes certain facets of asphaltenes, but each, alone, can never reveal asphaltenes from all van tages. Even seemingly narrowly focused issues such as the molecular structures of asphal tenes, or the colloidal structures of asphaltenes require a confluence of many lines of investigation to yield an understanding which differs from truth by diminishing uncer tainty. An holistic treatment of the asphaltenes is a powerful approach to evolve further their understanding. For example, examination of asphaltenes at the highest resolution yields molecular structure. A slight increase in scale probes asphaltene colloidal structure. Weaving together asphaltene studies performed at different length scales results in a fabric which envelops an encompassing vision of asphaltenes. At the same time, the interfaces of these hierarchical studies provide additional constraints on imagination, more than investi gations at individual length scales alone. These considerations shaped the timing, format, and the content of our book. The editors are very appreciative of the diligence and hard work manifest in each of the contributed chapters herein. We thank the contributing authors for making this project a success. Oliver C. Mullins Eric Y. Sheu vii CONTENTS I. Asphaltenes: Types and Sources ...................................... ."

This volume documents the scientific events of the NATO Advanced Research Workshop (ARW) on The Preparation of Nanoparticles in Solutions and in Solids. The ARW was held in the second largest city in Hungary, Szeged, truthfully referred to as "the city of sunshine," from March 8 to March 13, 1996. The seventy-seven participants, including seventeen students, came from twentyone different countries. Housing all participants together and arranging a number of social activities fostered lively discussions both inside and outside of formal sessions. Twenty-one key lectures were presented in five sessions. Each session was followed by a fortyfive minutes of general discussion. One evening was devoted to the presentation of fifty-five posters. Thirty-two contribution were submitted and accepted for publication in the present volume. The volume also contains the minutes of the discussions, and a summary of the conclusions of the working groups. The ARW was organized under the auspices and financial support of NATO, City of Szeged, European Research Office of the US Army, Hungarian Academy of Sciences, Hungarian National Committee for Technological Development (OMBF), International Association of Colloid and Interface Scientists IACIS, and National Science Foundation (NSF). Both the organizers and participants gratefully acknowledge the generous support of the agencies. The Editors also thank the high quality and creative contributions of the participants. It is they who made this volume a reality. Janos H. fendler Irnre Dekany ix Glossary of Some Names and Acronyms Advanced Materials Man-made materials having superior mechanical, thennal, electrical, optical, and other desirable properties.

Fine Particles Science and Technology deals with the preparation, characterization and technological applications of monodisperse particles in the micro to nano size range. A broad view of this frontier field is given, covering understanding the mechanisms by which uniform fine particles are formed and the search for new processes; the mechanism of the precipitation technique, requiring knowledge of the relationship between the complex solution chemistry and the products formed; the sequence of events leading to the formation of monodisperse colloids. The following topics are presented: microparticles, nanoparticles, applications in the preparation of materials, synthesis and properties, environmental applications, and many others.

During my professional career, I developed a strong interest in sol-gel technology, and worked on both xerogel and aerogel systems. My fascination with aerogels has driven me to explore their commercial potential, which is currently an important component of my company's business plan. Together with my co-workers, I have also worked on the preparation of controlled PZT and silica xerogels as well as thin film coatings of metals by the sol-gel technology, These experiences convinced me of the tremendous potentials of this technology. A conviction that is shared by many scientists, engineers, and business leaders around the globe. Many sol-gel derived products are already articles of commerce. However, to expand the commercial potential of sol-gel technology, two challenges must be met: (1) the quality of sol-gel derived products must continue to meet or exceed the quality of competing products, (2) the production cost of sol-gel products (specially aerogels) must continued to decline. A key to lowering the costs of sol-gel products is finding inexpensive precursors.

THE CURRENT STATE OF THE ART of waterborne polymers, paints, coatings, inks and printing processes is presented in this volume. This is the third volume in the series on waterborne coating and printing technology. It documents several invited papers and the proceedings of the International Symposium on Surface Phenomena and Latexes in Waterborne Coatings and printing Technology sponsored by the Fine Particle Society (FPS). The FPS meeting was held in Las Vegas, Nevada, July 13-17, 1992. The volume deals with various basic and applied aspects of research on waterborne coating printing technology. Major topics discussed involve waterborne polymers and polymer blends, pigment grinding, millbases, paint formulation, and characterization of coating films. This edition includes sixteen selected papers related to recent developments in waterborne technology. These papers are divided in three broad categories: (1) Waterborne Polymers and pigment Dispersions, (2) Latex Film, Wetting Phenomena and Printing Gloss, (3) Surfactants and Polymers in Aqueous Coating printing Systems. This volume includes discussions of various waterborne polymers in coating printing systems. The editors hope that this volume will serve its intended objective of reflecting the current understanding of formulation and process problems related to waterborne coatings, paints and inks. In addition, it will be a valuable reference source for both novices as well as experts in the field of waterborne technology. It will also help the readers to understand underlying surface phenomena and will enhance the reader's potential for solving critical formulation, evaluation and process problems.

The author integrates discussions of fractal geometry, surface modeling techniques, and applications to real world problems to provide a comprehensive, accessible overview of the field. His work will equip researchers with the basic tools for measurement and interpretation of data, stimulating more work on these problems and, perhaps, leading to an understanding of the reasons that Nature has adopted this geometry to shape much of our world.

When we see a jumbo jet at the airport, we sometimes wonder how such a huge, heavy plane can fly high in the sky. To the extent that we think in a static way, it is certainly not understandable. In such a manner, dynamics yields behavior quite different from statics. When we want to prepare an iron nitride, for example, one of the most orthodox ways is to put iron in a nitrogen atmosphere under pressures higher than the dissociation pressure of the iron nitride at temperatures sufficiently high to let the nitrogen penetrate into the bulk iron. This is the way thermodynamics tells us to proceed, which requires an elaborate, expensive high-pressure apparatus, sophisticated techniques, and great efforts. However, if we flow ammonia over the iron, even under low pressures, we can easily prepare the nitride-provided the hydrogen pressure is sufficiently low. Since the nitrogen desorption rate is the determining step of the ammonia decomposition on the iron surface, the virtual pressure of nitrogen at the surface can reach an extremely high level (as is generally accepted) because, in such a dynamic system, the driving force of the ammonia decomposition reaction pushes the nitrogen into the bulk iron to form the nitride. Thus, dynamics is an approach considerably different from statics.

This book documents the proceedings of the Third Symposium on Particles in Gases and Liquids: Detection, Characterization and Control held as a part of the 22nd Annual Meeting of the Fine Particle Society in San Jose, California, July 29-August 2, 1991. This series of symposia was initiated in 1987 in light of the growing importance to eliminate particles from process gases and liquids. As pointed out in the Preface to antecedent volumes in this series that particles in process gases and liquids could cause significant yield losses in precision manufacturing and concomitantly there has been heightened interest in understanding the behavior of particles in gases and liquids and devising ways to eliminate, or at least reduce substantially, these particles. The concern about particles in gases and liquids has been there for qui.te some time in the microelectronics arena, but there are other areas also where particles are of significant concern, e.g. in operation theatres in hospitals, food and beverage industry, and pharmaceutical manufacturing. This symposium basically had the same objectives as its predecessors, but to provide an update on the R&D activity taking place in the arena of particle detection, characterization and control. The printed program comprised a total of 28 papers dealing with variegated aspects of particles in gases and liquids. There were brisk and lively discussions and the attendees offered many positive comments, which goes to show that it was a well-received and needed symposium.

Unlike previous volumes in the series for colloid and surface scientists, revolves generally around two topics: surfactants and polymers. The six papers discuss micelles of block and graft copolymers in solutions, surfactant association in nonaqueous media, a study of the boundary viscosity of organ

'IHE CURRENT STATE OF 'IHE AID' of several aspects of water-based coatings and printing processes is presented in this voltnne. It documents the proceedings of the Intemationl Syrrposium on Surface RJ. enornena and Fine Particles in Water-Based Coatings and Printing Teclmology sponsored by the Fine Particle Society (FPS). '!his meeting was held in Boston, Massachusetts, August 21-25, 1989. '!he syrrp:>sium upon which this voltnne is based was organized in six sessions errphasizing various basic and applied areas of research on water-based technology. Major topics discussed involve surface phenomena in coatings, printing defects and their remedies, surface tension effects in water-based coatings and printing inks, surface energies of polymer substrates, wettability, aqueous polymeric film coating of pharmaceuticals, flexographic and gravure printing processes, characterization of coating materials, pigment dispersion, wax emulsions for surface modifications, and the role of polymer in particle/surface deposition. '!his edition includes the twenty four selected papers presented in the syrrp:>sium. '!hese papers are divided in three broad categories: (1) Water-Based Inks and Coatings, (2) Emulsions and Adhesion in Coatings, and (3) Characterization of Coating and Printing Materials. Several types of coating and printing on different substrates using water-based fonnulations with special reference to surface phenomena and particle technology are described in these sections. This proceedings vo1tnne includes discussions of various processes occuring at llIOlecular, microscopic, and macroscopic levels in water-based coatings and printing processes.

The purpose of this book is to stimulate thinking among corrosion scientists and engineers to examine corrosion mechanisms and corro sion control from another perspective. While the presence of corro sion films in electrochemical corrosion has been recognized for over a century, the contribution of these films to all facets of corrosion has not been explored to a significant degree. Rather the role of films in certain mechanisms (i.e., stress corrosion cracking) has been empha sized, yet almost ignored for other corrosion mechanisms. This is viewed by the author as solely attributable to the lack of investigation into, and an understanding of, the contribution of films to these mech anisms or forms of attack. The lack of emphasis and study of corrosion films and their contribution to all forms of corrosion attack are probably the result of current university instruction that utilizes two popular corrosion texts (Uhlig and Fontana and Greene) for teaching. These texts provide an excellent understanding at the undergraduate level of corrosion funda mentals; however, the major implicit premise in these texts is that bulk properties of an alloy or metal control the corrosion resistance in a particular environment. For many applications and for a simple under standing of corrosion mechanics, this approach is sufficient. Yet, research on corrosion films indicate these films often have an entirely different composition than the bulk metal (ratio of alloying elements)."

Monomolecular assemblies on substrates, now termed Langmuir-Blodgett (LB) films, have been studied for over half a century. Their development can be viewed in three stages. Following the pioneering work of Irving Langmuir and Katharine Blodgett in the late 1930s there was a brief flurry of activity just before and just after the Second World War. Many years later Hans Kuhn published his stimulating work on energy transfer. This German contribution to the field, made in the mid-1960s, can be regarded as laying the foundation for studies of artificial systems of cooperat ing molecules on solid substrates. However, the resurgence of activity in academic and industrial laboratories, which has resulted in four large international con ferences, would not have occurred but for British and French groups highlighting the possible applications of LB films in thefield of electronics. Many academic and industrial establishments involved in high technology are now active in or maintaining a watching brief on the field. Nevertheless this impor tant area of solid state science is still perhaps largely unfamiliar to many involved in materials or electronic device research. The richness of the variety of organic molecular materials suitable for LB film deposition offers enormous scope for those interested in their basic properties or their practical applications. LB films are now an integral part of the field of molecular electronics. It seems inevitable that they will play some role in replacing inorganic materials in certain areas of application."

The current state of the art of various aspects of micro emulsion systems is reflected in this volume. Major topics discussed include: general background on solubilized systems, phase diagrams and phase equi- libria, bicontinuous microemulsions, Winsor's phases, theories and models of complex self association structures, cry tical behaviour, phase tran- sitions in lyotropic liquid crystals. I hope that this book will serve its intended objective of reflecting our current understanding of microemulsions both in theory and practice, and that it will be useful to researchers, both novices as well as experts, as a valuable reference source. I feel indebted to the people of the Ettore Majorana Centre: the friendly atmosphere of the Erice centre provided a very effective environ- ment to enjoy the company of colleagues and friends during breaks and after sessions, and to discuss problems of mutual interest. The courtesy, efficiency and devotion of the secretarial and technical staff was also appreciated, and greatly contributed to make the Workshop a smoothly run- ning one. The Scientific Secretary Donatella Senatra Department of Physics University of Florence (Italy) v INTRODUCTION The decision to publish. in a more permanent form than heretofore. the Proceedings of the Workshop on "Progress in Microemulsion" of the Inter- national School of Quantum Electronics. which was held in Erice (Italy) from October 26 to November 1st. 1985. under the auspices of the "Ettore Majorana" Centre for Scientific Culture. will prove to be a sound one.

This book has its origins in the 1982 Spring College held at the Interna tional Centre for Theoretical Physics, Miramare, Trieste. The primary aim is to give a broad coverage of liquids and amorphous solids, at a level suitable for graduate students and research workers in condensed-matter physics, physical chemistry, and materials science. The book is intended for experimental workers with interests in the basic theory. While the topics covered are many, it was planned to place special emphasis on both static structure and dynamics, including electronic transport. This emphasis is evident from the rather complete coverage of the determination of static structure from both diffraction experiments and, for amorphous solids especially, from model building. The theory of the structure of liquids and liquid mixtures is then dealt with from the standpoint of, first, basic statistical mechanics and, subsequently, pair potentials constructed from the electron theory of simple metals and their alloys. The discussion of static structure is completed in two chapters with rather different emphases on liquid surfaces and interfaces. The first deals with the basic statistical mechanics of neutral and charged interfaces, while the second is concerned with solvation and double-layer effects. Dynamic structure is introduced by a comprehensive discussion of single-particle motion in liquids. This is followed by the structure and dynamics of charged fluids, where again much basic statistical mechanics is developed."

From blood to milk, pumice to gelatine, most scientists interact with colloids on a daily basis without any real knowledge of their nature. Building on the success of the first edition, "Colloids and Interfaces with Surfactants and Polymers Second Edition" is a user-friendly, non-technical introduction to colloids and interfaces.

Includes: Many practical examples of colloid and interface scienceAn enhanced section on fluorescence microscopy, a widely used technique in biological systems for the optical imaging of cellular structuresA new section on phenomenology (the principle of time/temperature superposition), which enables the experimentalist to extend the frequency range of their rheological instrumentsNew information on sedimentation and strategies for the control of sedimentation, which is critical in many dispersions of commercial importanceFresh treatments of traditional theoretical topics like the electrical double-layer, colloidal interactions, wetting behavior and light scattering, as well as more recent advances in polymer science, statistical mechanics and the use of neutronsIn-depth discussions of widely used techniques with mathematics used in a straight-forward way so quantitative descriptions of colloid and interface properties can be derived

"Colloids and Interfaces with Surfactants and Polymers Second Edition" explains all the fundamental concepts of colloids and interfaces as well as detailing some of the more advanced aspects which might be useful in specific applications. Intended for undergraduate and graduate courses in colloids and soft materials, the book is also relevant to those in the chemical, coatings, cosmetics, ceramics, food, pharmaceutical and oil industries.

For Powerpoint slides of all the figures in the book, please see the Instructor Companion website at http: //bcs.wiley.com/he-bcs/Books?action=index&bcsId=5121&itemId=0470518804

This volume presents the acomplishments of over 85 internationlly renowned scientists whose work was influenced by Professor Wasan's groundbreaking research on interfacial phenomena at The Illinois Institute of Technology, Chicago.

Smart materials are of significant interest and this is the first textbook to provide a comprehensive graduate level view of topics that relate to this field. Fundamentals of Smart Materials consists of a workbook and solutions manual covering the basics of different functional material systems aimed at advanced undergraduate and postgraduate students. Topics include piezoelectric materials, magnetostrictive materials, shape memory alloys, mechanochromic materials, thermochromic materials, chemomechanical polymers and self-healing materials. Each chapter provides an introduction to the material, its applications and uses with example problems, fabrication and manufacturing techniques, conclusions, homework problems and a bibliography. Edited by a leading researcher in smart materials, the textbook can be adopted by teachers in materials science and engineering, chemistry, physics and chemical engineering.

The book describes the new advances in the science and technology of hydrocolloids which are used in food and related systems. The focus is on the technofunctionality and the biofunctionality of hydrocolloids, giving an appropriate emphasis to the manipulative skills of the food scientist and recognising the special part hydrocolloids can play in supporting human health. Gums and Stabilisers for the Food Industry 15 captures the latest research findings of leading scientists which were presented at the Gums and Stabilisers for the Food Industry Conference at the Glyndwr University, Wrexham, UK in June 2009. The areas covered are: - Structure and characterisation - Technofunctionality - Mixed hydrocolloid systems - Food applications - Hydrocolloids and health - Hydrogels for medical applications This book will be a useful information source to researchers and other professionals in industry and academia, particularly those involved with food science.

From reviews of the first edition: "Very well written and brings a focus and a perspective that are not currently available in one convenient volume, especially one that is suitable for self-study or as a teaching tool." —Colloid and Interface Science "A revolutionary approach [to] writing an up-to-date text on ‘The Colloidal Domain’ and its origin in and impact on physics, chemistry, biology, and technology." —Advanced Materials "The authors should be congratulated for producing such a well-written text that is full of illustrations and formulas." —Chemistry and Industry This new edition of Evans and Wennerström’s critically acclaimed text provides students and professionals with a comprehensive and up-to-date treatment of colloid science theory, methods, and applications. Emphasizing the molecular interactions that determine the properties of colloidal systems, the authors provide an authoritative account of critical developments in colloid science that have occurred over the past several decades. Combining all of the best features of a professional reference and a student text, The Colloidal Domain, Second Edition features:

• Concept maps preceding each chapter that put subject matter into perspective
• Numerous worked examples—many new to this edition—illustrating key concepts
• More than 250 high-quality illustrations that help clarify processes described
• A new chapter that integrates the development of colloid science and technology in the twentieth century with challenges facing the field today

Highlighting recent developments as well as future challenges, this series of volumes covers such topics as emulsions, nano-emulsions, nano-dispersions and novel techniques for their investigation. It also considers the fundamental approach in areas such as controlled release, drug delivery and various applications of nanotechnology.

From blood to milk, pumice to gelatine, most scientists interact with colloids on a daily basis without any real knowledge of their nature. Building on the success of the first edition, "Colloids and Interfaces with Surfactants and Polymers Second Edition" is a user-friendly, non-technical introduction to colloids and interfaces.

Includes: Many practical examples of colloid and interface scienceAn enhanced section on fluorescence microscopy, a widely used technique in biological systems for the optical imaging of cellular structuresA new section on phenomenology (the principle of time/temperature superposition), which enables the experimentalist to extend the frequency range of their rheological instrumentsNew information on sedimentation and strategies for the control of sedimentation, which is critical in many dispersions of commercial importanceFresh treatments of traditional theoretical topics like the electrical double-layer, colloidal interactions, wetting behavior and light scattering, as well as more recent advances in polymer science, statistical mechanics and the use of neutronsIn-depth discussions of widely used techniques with mathematics used in a straight-forward way so quantitative descriptions of colloid and interface properties can be derived

"Colloids and Interfaces with Surfactants and Polymers Second Edition" explains all the fundamental concepts of colloids and interfaces as well as detailing some of the more advanced aspects which might be useful in specific applications. Intended for undergraduate and graduate courses in colloids and soft materials, the book is also relevant to those in the chemical, coatings, cosmetics, ceramics, food, pharmaceutical and oil industries.

For Powerpoint slides of all the figures in the book, please see the Instructor Companion website at http: //bcs.wiley.com/he-bcs/Books?action=index&bcsId=5121&itemId=0470518804