This thesis examines electrode materials such as mesoporous carbons, manganese oxides, iron oxides and their nanohybrids with graphene. It also explores several of the key scientific issues that act as the governing principles for future development of supercapacitors, which are a promising class of high-efficiency energy storage devices for tackling a key aspect of the energy crisis. However, critical technical issues, such as the low energy density and reliability, need to be addressed before they can be extended to a wide range of applications with much improved performance. Currently available material candidates for the electrodes all have their disadvantages, such as a low specific capacitance or poor conductivity for transition metal oxide/hydroxide-based materials. This thesis addresses these important issues, and develops a high-performance, flexible asymmetric supercapacitor with manganese oxides/reduced graphene oxide as the positive electrode and iron oxide/reduced graphene oxide as the anode, which delivers a high energy density of 0.056 Wh cm-3.

The NATO ARW "Molecular Self-Organization in Micro-, Nano-, and Macro- Dimensions: From Molecules to Water, to Nanoparticles, DNA and Proteins" to commemorate Professor Alexander S. Davydov was held in Kiev, Ukraine, on 8-12 June, 2008, at the Bogolyubov Institute for Theoretical Physics of the National Academy of Sciences of Ukraine. Theobjective ofthisNATOARWistounveilandformulatetheprincipalfeatures that govern myriads of the molecular self-organization processes in micro-, nano-, and macro-dimensions from the following key representatives such as liquid - ter and aqueous solutions, and molecular liquids, nanodots, nanoparticles including gold, solitons, biomolecules such as DNA and proteins, biopolymers and bios- sors, catalysis, molecular modeling, molecular devices, and thin ?lms, and to offer another, more advanced directions in computational, experimental, and technolo- cal areas of nano- and bioscience towards engineering novel and powerful molecular self-organized assemblies with tailored properties. Nanoscience is indeed one of the most important research and development fr- tiers in modern science. Simplistically, nanoscience is the science of small particles of materials of a size of nanometre. Molecular nanoscience and nanotechnology have brought to us the unprecedented experimental control of the structure of matter with novel extraordinary properties that open new horizons and new opportunities, and new ways to make things, particularly in our everyday life, to heal our bodies, and to care of the environment. Unfortunately, they have also brought unwelcome advances in weaponry and opened yet more ways to foul up the world on an en- mous scale.

This thesis presents the latest findings on macroscopic-scale nanowire thin films composed of integrated nanowires. It introduces readers to essential synthesis and assembly strategies for the design and fabrication of high-quality nanowire thin films, and discusses their underlying principles in detail. The book highlights examples specific to well-aligned nanowire systems, and explores the applications of nanowire systems, including memory devices, flexible transparent electrodes, etc. The book offers a valuable resource for researchers and graduate students working in materials science, especially in nanowire device fabrication.

Global experts provide an authoritative source of information on the use of electrochemical fuel cells, and in particular discuss the use of nanomaterials to enhance the performance of existing energy systems. The book covers the state of the art in the design, preparation, and engineering of nanoscale functional materials as effective catalysts for fuel cell chemistry, highlights recent progress in electrocatalysis at both fuel cell anode and cathode, and details perspectives and challenges in future research.

Nanoscale science and computing is becoming a major research area as today's scientists try to understand the processes of natural and biomolecular computing. The field is concerned with the architectures and design of molecular self-assembly, nanostructures and molecular devices, and with understanding and exploiting the computational processes of biomolecules in nature.

This book offers a unique and authoritative perspective on current research in nanoscale science, engineering and computing. Leading researchers cover the topics of DNA self-assembly in two-dimensional arrays and three-dimensional structures, molecular motors, DNA word design, molecular electronics, gene assembly, surface layer protein assembly, and membrane computing.

The book is suitable for academic and industrial scientists and engineers working in nanoscale science, in particular researchers engaged with the idea of computing at a molecular level.

Discover why olefin metathesis has asserted itself as a powerful strategy for obtaining fine chemicals, biologically active compounds, architecturally complex assemblies, new materials, and functionalized polymers. This volume compiles all the latest trends in olefin metathesis. In particular, you ll learn how olefin metathesis has growing potential for the development of sustainable technologies with many possible industrial applications.

Quantum dots as nanomaterials have been extensively investigated in the past several decades from growth to characterization to applications. As the basis of future developments in the field, this book collects a series of state-of-the-art chapters on the current status of quantum dot devices and how these devices take advantage of quantum features. Written by 56 leading experts from 14 countries, the chapters cover numerous quantum dot applications, including lasers, LEDs, detectors, amplifiers, switches, transistors, and solar cells. "Quantum Dot Devices" is appropriate for researchers of all levels of experience with an interest in epitaxial and/or colloidal quantum dots. It provides the beginner with the necessary overview of this exciting field and those more experienced with a comprehensive reference source."

This book discusses emerging nanotechnology-based tools that have the potential to dramatically impact cancer research, diagnostics, and treatment. Cancer is a complex, devastating, and debilitating disease and, although much progress has been made, novel, more effective diagnostic and treatment options are still needed, especially for advanced cancers. The ultimate goal is to detect cancer early and non-invasively and to provide efficacious and targeted precision treatments that cause fewer harmful side effects. This book explains how nanotechnology can exploit the size-, shape-, and composition-dependent properties of nanomaterials to provide novel tools for precision cancer medicine. It will be of interest to researchers and professionals working in the fields of chemistry, biology, materials science and engineering, and medicine who want to learn more about this fascinating and fast-paced area of research.

"Neutron Applications in Materials for Energy "collects results and conclusions of recent neutron-based investigations of materials that are important in the development of sustainable energy. Chapters are authored by leading scientists with hands-on experience in the field, providing overviews, recent highlights, and case-studies to illustrate the applicability of one or more neutron-based techniques of analysis. The theme follows energy production, storage, and use, but each chapter, or section, can also be read independently, with basic theory and instrumentation for neutron scattering being outlined in the introductory chapter.

Whilst neutron scattering is extensively used to understand properties of condensed matter, neutron techniques are exceptionally-well suited to studying how the transport and binding of energy and charge-carrying molecules and ions are related to their dynamics and the material s crystal structure. These studies extend to "in situ" and "in operando" in some cases. The species of interest in leading energy-technologies include H2, H+, and Li+ which have particularly favourable neutron-scattering properties that render these techniques of analysis ideal for such studies and consequently, neutron-based analysis is common-place for hydrogen storage, fuel-cell, catalysis, and battery materials. Similar research into the functionality of solar cell, nuclear, and CO2 capture/storage materials rely on other unique aspects of neutron scattering and again show how structure and dynamics provide an understanding of the material stability and the binding and mobility of species of interest within these materials.

Scientists and students looking for methods to help them understand the atomic-level mechanisms and behaviour underpinning the performance characteristics of energy materials will find "Neutron Applications in Materials for Energy "a valuable resource, whilst the wider audience of sustainable energy scientists, and newcomers to neutron scattering should find this a useful reference. "

Reviews in Plasmonics is a comprehensive collection of current trends and emerging hot topics in the field of Plasmonics and closely related disciplines. It summarizes the years progress in Plasmonics and its applications, with authoritative analytical reviews specialized enough to be attractive to professional researchers, yet also appealing to the wider audience of scientists in related disciplines of Plasmonics.

A valuable learning tool as well as a reference, this book provides students and researchers in surface science and nanoscience with the theoretical crystallographic foundations, which are necessary to understand local structure and symmetry of bulk crystals, including ideal and real single crystal surfaces. The author deals with the subject at an introductory level, providing numerous graphic examples to illustrate the mathematical formalism. The book brings together and logically connects many seemingly disparate structural issues and notations used frequently by surface scientists and nanoscientists. Numerous exercises of varying difficulty, ranging from simple questions to small research projects, are included to stimulate discussions about the different subjects. From the contents: Bulk Crystals, Three-Dimensional Lattices - Crystal Layers, Two-Dimensional Lattices, Symmetry - Ideal Single Crystal Surfaces - Real Crystal Surfaces - Adsorbate layers - Interference Lattices - Chiral Surfaces - Experimental Analysis of Real Crystal Surfaces - Nanoparticles and Crystallites - Quasicrystals - Nanotubes

This book, based on the lectures and contributions of the NATO ASIon Functional Properties of Nanostructured Materials, gives a broadoverview on this topic, as it combines basic theoretical articles, papersdealing with experimental techniques, and contributions on advancedand up-to-date applications in fields such as microelectronics, optoelectronics, electrochemistry, sensorics, and biotechnology. Inaddition, it presents an interdisciplinary approach since the authorscame from such different fields as physics, chemistry, engineering, materials science and biology. Some emphasis is given to the field ofnanostructured/nanoscaled thin films, again stretching from basictheoretical over experimental (including both fabrication andcharacterization) to application oriented topic

This book covers the state-of-the-art technologies for positioning with nanometer resolutions and accuracies, particularly those based on piezoelectric actuators and MEMS actuators. The latest advances are described, including the design of nanopositioning devices, sensing and actuation technologies and control methods for nanopositioning. This is an ideal book for mechanical and electrical engineering students and researchers; micro and nanotechnology researchers and graduate students; as well as those working in the precision instrumentation or semiconductor industries.

-Effects of Electric Fields on Block Copolymer Nanostructures By H. G. Schoberth, V. Olszowka, K. Schmidt, and A. Boeker -Nanopattern Evolution in Block Copolymer Films: Experiment, Simulations and Challenges By L. Tsarkova, G.J. Agur Sevink, and G. Krausch -Controlled Wrinkling as a Novel Method for the Fabrication of Patterned Surfaces By A. Schweikart, A. Horn, A. Boeker, and A. Fery -Layered Systems Under Shear Flow By D. Svensek and H. R. Brand -Thermal Diffusion in Polymer Blends: Criticality and Pattern Formation By W. Koehler, A. Krekhov, and W. Zimmermann -Foaming of Microstructured and Nanostructured Polymer Blends By H. Ruckdaschel, P. Gutmann, V. Altstadt, H. Schmalz, and A.H.E. Muller

The volumes VIII, IX and X examine the physical and technical foundation for recent progress in applied scanning probe techniques. This is the first book to summarize the state-of-the-art of this technique. The field is progressing so fast that there is a need for a set of volumes every 12 to 18 months to capture latest developments. These volumes constitute a timely comprehensive overview of SPM applications.

Intensive investigations on nanoscale magnetism have promoted remarkable progressintechnologicalapplicationsofmagnetisminvariousareas.Thete- nical progress of recent years in the preparations of multilayer thin ?lms and nanowires led to the discovery of Giant Magnetoresistance (GMR), imp- ing an extraordinary change in the resistivity of the material by varying the applied external magnetic ?eld. The Nobel Prize for Physics in 2007 was awardedtoAlbertFertandPeterGrun ] bergfortheirdiscoveryofGMR.App- cations of this phenomenon have revolutionizedtechniques for retrieving data fromharddisks.Thediscoveryalsoplaysamajorroleinvariousmagnetics- sors as well as the development of a new generation of electronics. The use of GMRcanberegardedasoneofthe?rstmajorapplicationsofnanotechnology. The GMR materials have already found applications as sensors of low magnetic ?eld, a key component of computer hard disk heads, magnetores- tive RAM chips etc. The "read" heads for magnetic hard disk drives have allowed us to increase the storage density on a disk drive from 1 to 20 Gbit per square inch, merely by the incorporation of the new GMR materials. On the other hand, recently discovered giant magneto-impedance (GMI) mate- als look very promising in the development of a new generation of microwave band electronic devices (such as switches, attenuators, and antennas) which could be managed electrically."

This volume presents the characterization methods involved with carbon nanotubes and carbon nanotube-based composites, with a more detailed look at computational mechanics approaches, namely the finite element method. Special emphasis is placed on studies that consider the extent to which imperfections in the structure of the nanomaterials affect their mechanical properties. These defects may include random distribution of fibers in the composite structure, as well as atom vacancies, perturbation and doping in the structure of individual carbon nanotubes.

ZnO has been the central theme of research in the past decade due to its various applications in band gap engineering, and textile and biomedical industries. In nanostructured form, it offers ample opportunities to realize tunable optical and optoelectronic properties and it was also termed as a potential material to realize room temperature ferromagnetism. This book presents 17 high-quality contributory chapters on ZnO related systems written by experts in this field. These chapters will help researchers to understand and explore the varied physical properties to envisage device applications of ZnO in thin film, heterostructure and nanostructure forms.

The volumes VIII, IX and X examine the physical and technical foundation for recent progress in applied scanning probe techniques. This is the first book to summarize the state-of-the-art of this technique. The field is progressing so fast that there is a need for a set of volumes every 12 to 18 months to capture latest developments. These volumes constitute a timely and comprehensive overview of SPM applications.

This thesis outlines the first synthesis of a new complex branched polymer architecture that aims to combine the benefits of dendrimers with the simplicity of conventional polymerisation. There is no other available literature on these remarkable materials, dubbed hyperbranched polydendrons, due to their novelty. The new materials were shown to have very high molecular weights (>1,000,000 g/mol), exceptional self-assembly and encapsulation behaviour and unparalleled functionalisation capabilities, and were studied pharmacologically to determine their potential as oral nanomedicine candidates. The detailed investigation of the chemical variables involved in synthesising hyperbranched polydendrons has shown that their self-assembly and pharmacological behaviour can be turned on and off and fine-tuned by altering the composition of the materials. The permeation of the self-assembled particles through model gut epithelium suggests the potential for oral dosing of drug loaded nanomedicines that result in circulating nanoparticles - a research goal that is currently being pursued by several groups around the globe.

Written by leading international experts, this book summarizes the advances in sample preparation, design and construction of dangling bond atomic scale wires and logic gate circuits at the surface of a passivated semi-conductor. Individual chapters cover different aspects of the sample fabrication from research and development point of view, present design and construction as well as microscopic and spectroscopic characteristics of single dangling atomic wires and logic gates, and discuss the tools for design of large atomic scale circuit on a surface.This edited volume includes selected contributions from the "International Workshop on Atomic Wires" held in Krakow in September 2014 completed and updated with most current results up to mid-2016, and offers for the first time an overview of up-to-date knowledge in the burgeoning field of atomic scale circuits. The book will appeal to researchers and scholars interested in nanoscience and its various sub-fields including, in particular, molecular electronics, atomic scale electronics and nanoelectronics.

The intersection of nanotechnology with biology has given rise to numerous ideas for new ways to use nanotechnology for biological applications. Nanomaterials possess unique size- and material-dependent properties which make them attractive for improving regular biomedical fields, such as drug delivery, imaging, therapy, and diagnostics. Divided into three convenient sections, Nanomaterial Interfaces in Biology: Methods and Protocols covers protocols describing synthesis, fabrication, and construction of bio-nanomaterial interfaces, characterization protocols of bio-nanomaterial interfaces, and applications which utilize the bio-nanomaterial interfaces. Written in the highly successful Methods in Molecular Biology series format, chapters contain introductions to their respective topics, lists of the necessary materials and reagents, step-by-step, readily reproducible laboratory protocols, and notes on troubleshooting and avoiding known pitfalls. Authoritative and accessible Nanomaterial Interfaces in Biology: Methods and Protocols will serve the new and emerging scientific community, enabling new capabilities and technologies that were not previously possible in medicine and biology.

Microbial Nanobionics: Volume 2, Basic Research Applications continues the important discussion of microbial nanoparticle synthesis with a focus on the mechanistic approach of biosynthesis towards nanobionics. This volume also explores the toxicity of nanomaterials in microbes and their effect on human health and the environment. Special Emphasis is given to the use of polymeric nanomaterials in smart packing for the food industry and agricultural sector. The future of nanomaterials for detection of soil microbes and their interactions and tools for environmental remedies is also comprehensively covered. The rich biodiversity of microbes make them excellent candidates for potential nanoparticle synthesis biofactories. Through a better understanding of the biochemical and molecular mechanisms of the microbial biosynthesis of metal nanoparticles, the rate of synthesis can be better developed and the monodispersity of the product can be enhanced. The characteristics of nanoparticles can be controlled via optimization of important parameters, such as temperature, pH, concentration and pressure, which regulate microbe growth conditions and cellular and enzymatic activities. Large scale microbial synthesis of nanoparticles is a sustainable method due to the non-hazardous, non-toxic and economical nature of these processes. The applications of microbial synthesis of nanoparticles are wide and varied, spanning the industrial, biomedical and environmental fields. Biomedical applications include improved and more targeted antimicrobials, biosensing, imaging and drug delivery. In the environmental fields, nanoparticles are used for bioremediation of diverse contaminants, water treatment, catalysis and production of clean energy. With the expected growth of microbial nanotechnology, this volume will serve as a comprehensive and timely reference.

This volume continues the tradition formed in Nanotechnology in Catalysis 1 and 2. As with those books, this one is based upon an ACS symposium. Some of the most illustrious names in heterogeneous catalysis are among the contributors. The book covers: Design, synthesis, and control of catalysts at nanoscale; understanding of catalytic reaction at nanometer scale; characterization of nanomaterials as catalysts; nanoparticle metal or metal oxides catalysts; nanomaterials as catalyst supports; new catalytic applications of nanomaterials.

Metallic nanoparticles display fascinating properties that are quite different from those of individual atoms, surfaces or bulk rmaterials. They are a focus of interest for fundamental science and, because of their huge potential in nanotechnology, they are the subject of intense research effort in a range of disciplines. Applications, or potential applications, are diverse and interdisciplinary. They include, for example, use in biochemistry, in catalysis and as chemical and biological sensors, as systems for nanoelectronics and nanostructured magnetism (e.g. data storage devices), where the drive for further miniaturization provides tremendous technological challenges and, in medicine, there is interest in their potential as agents for drug delivery.
The book describes the structure of metallic nanoparticles, the experimental and theoretical techniques by which this is determined, and the models employed to facilitate understanding. The various methods for the production of nanoparticles are outlined. It surveys the properties of clusters and the methods of characterisation, such as photoionization, optical spectroscopy, chemical reactivity and magnetic behaviour, and discusses element-specific information that can be extracted by synchrotron-based techniques such as EXAFS, XMCD and XMLD. The properties of clusters can vary depending on whether they are free, deposited on a surface or embedded in a matrix of another material; these issues are explored. Clusters on a surface can be formed by the diffusion and aggregation of atoms; ways of modelling these processes are described. Finally we look at nanotechnology and examine the science behind the potential of metallic nanoparticles in chemical synthesis, catalysis, the magnetic separation of biomolecules, the detection of DNA, the controlled release of molecules and their relevance to data storage.
The book addresses a wide audience. There was a huge development of the subject beginning in the mid-1980s where researchers began to study the properties of free nanoparticle and models were developed to describe the observations. The newcomer is introduced to the established models and techniques of the field without the need to refer to other sources to make the material accessible. It then takes the reader through to the latest research and provides a comprehensive list of references for those who wish to pursue particular aspects in more detail. It will also be an invaluable handbook for the expert in a particular aspect of nanoscale research who wishes to acquire knowledge of other areas.
The authors are specialists in different aspects of the subject with expertise in physics and chemistry, experimental techniques and computational modelling, and in interdisciplinary research. They have collaborated in research. They have also collaborated in writing this book, with the aim from the outset of making it is a coherent whole rather than a series of independent loosely connected articles.
* Appeals to a wide audience
* Provides an introduction to established models and techniques in the field
* Comprehensive list of references