This book examines the characteristics of Proton Exchange Membrane (PEM) Fuel Cells with a focus on deriving realistic finite element models. The book also explains in detail how to set up measuring systems, data analysis, and PEM Fuel Cells' static and dynamic characteristics. Covered in detail are design and operation principles such as polarization phenomenon, thermodynamic analysis, and overall voltage; failure modes and mechanisms such as permanent faults, membrane degradation, and water management; and modelling and numerical simulation including semi-empirical, one-dimensional, two-dimensional, and three-dimensional models. It is appropriate for graduate students, researchers, and engineers who work with the design and reliability of hydrogen fuel cells, in particular proton exchange membrane fuel cells.

Mobility Gradient of Polystyrene in Films Supported on Solid Substrates, by Yoshihisa Fujii, Hiroshi Morita, Atsushi Takahara and Keiji Tanaka Probing Properties of Polymers in Thin Films Via Dewetting, by Gunter Reiter Heterogeneous and Aging Dynamics in Single and Stacked Thin Polymer Films, by Koji Fukao, Takehide Terasawa, Kenji Nakamura, Daisuke Tahara Heterogeneous Dynamics of Polymer Thin Films as Studied by Neutron Scattering, by Rintaro Inoue and Toshiji Kanaya

Molecular- and Nano-Tubes summarizes recent advancements in the synthesis, fabrication and applications of tubular structures. An interdisciplinary overview of innovative science focused on tubular structures is provided. The reader is offered an overview of the different fields that molecular and nano tubes appear in, in order to learn the fundamental basics as well as the applications of these materials. This book also: Shows how nanotechnology creates novel materials by crossing the barriers between biology and material science, electronics and optics, medicine and more Demonstrates that tubes are a fundamental element in nature and used in disparate applications such as ion channels and carbon nanotubes Molecular- and Nano-Tubes is an ideal volume for researchers and engineers working in materials science and nanotechnology.

This book introduces the reader to latex, which is a colloidal dispersion of polymer particles in water, and explains how useful products are made from it.

The primary focus is the process by which wet latex can be transformed into coatings, adhesives, and composites in the process known as film formation. The book reviews the main experimental techniques used to study the film formation process. It then presents the fundamental concepts for each of the three main stages of the process: evaporation of water, particle deformation, and polymer diffusion. The latest experimental observations are presented along with theoretical descriptions and models. Later chapters consider the effects of surfactant on film properties and describe films made from nanocomposite particles and from blends of latex with nanoparticles, such as clays or carbon nanotubes. The book concludes with a chapter considering the remaining technical challenges and highlighting a few exciting future directions. Throughout the presentation, fundamental concepts are emphasised. Relevant models are explained in an accessible way that does not assume prior knowledge.

This book will serve as a state-of-the art reference for scientists working in industrial R&D and also for researchers in diverse academic subjects, including chemistry, physics, engineering, and materials science.

This book gives a state-of-the-art view by recognized researchers of the nanotechnologies required for future integrated systems leading to innovations in energy, the environment, and biotechnologies. Nanostructures that would be difficult to form using the current semiconductor technology will be realized using a combination of bottom-up and top-down processes, including hybrid nanostructures made of inorganic and organic/biological materials. Bio-sensing, imaging, and cell or molecular manipulation are discussed in Chapters 2-7. The acquisition of basic knowledge on the cellular level will lead to curing serious diseases. Also, nanofabrication technologies, discussed in Chapters 8-15, will lead to next-generation solar cells, secondary batteries, and advanced electronic circuits using nanostructured materials, thus providing solutions for serious energy and environment issues. Prospective readers of this book include graduate students as well as researchers and engineers working in this field.

This text provides an introduction, at the level of an advanced student in engineering or physics, to the field of nanomechanics and nanomechanical devices. It provides a unified discussion of solid mechanics, transducer applications, and sources of noise and nonlinearity in such devices. Demonstrated applications of these devices, as well as an introduction to fabrication techniques, are also discussed. The text concludes with an overview of future technologies, including the potential use of carbon nanotubes and other molecular assemblies.

Presently, there is an intense race throughout the world to develop good enough thermoelectric materials which can be used in wide scale applications. This book focuses comprehensively on very recent up-to-date breakthroughs in thermoelectrics utilizing nanomaterials and methods based in nanoscience. Importantly, it provides the readers with methodology and concepts utilizing atomic scale and nanoscale materials design (such as superlattice structuring, atomic network structuring and properties control, electron correlation design, low dimensionality, nanostructuring, etc.). Furthermore, also indicates the applications of thermoelectrics expected for the large emerging energy market. This book has a wide appeal and application value for anyone being interested in state-of-the-art thermoelectrics and/or actual viable applications in nanotechnology.

This book describes 200 bio-polymers, including the most recent and advanced nanotechnology applications. The applications of various bio-medical and other future potential uses are covered and examined in depth. Systematic discussion of current leading natural polymers is also included.

This thesis consists of an in-depth study of investigating microstructure-property relationships in bulk metallic glasses using a novel quantitative approach by which influence of the second phase features on mechanical properties can be independently and systematically analyzed. The author evaluates and optimizes the elastic and plastic deformation, as well as the overall toughness of cellular honeycombs under in-plane compression and porous heterostructures under uniaxial tension. The study reveals three major deformation zones in cellular metallic glass structures, where deformation changes from collective buckling showing non-linear elasticity to localized failure exhibiting a brittle-like deformation, and finally to global sudden failure with negligible plasticity as the length to thickness ratio of the ligaments increases. The author found that spacing and size of the pores, the pore configuration within the matrix, and the overall width of the sample determines the extent of deformation, where the optimized values are attained for pore diameter to spacing ratio of one with AB type pore stacking.

Currently, nanotechnology is exposing the properties of DNA in unprecedented detail leading to new insights on the biological behavior and function of DNA. With the structural perfection of a self-assembling DNA nano-object, such as a DNA origami, it is clear how complex DNA is as a molecule, leading researchers to wonder how many different constructs could be designed and realized. "DNA Nanotechnology: Methods and Protocols" shows the procedures to follow in order to repeat methods that lead to such constructs or to the mastering of the characterization techniques used to study them. The chapters of this book are roughly divided into two parts: some cover the methods for preparing the nanostructures, from the rationale of the operations to the techniques for their handling, while other chapters deal more directly with advanced instrumental techniques that can manipulate and characterize molecules and nanostructures. Written in the highly successful "Methods in Molecular Biology " series format, chapters contain introductions to their respective topics, lists of the necessary materials and reagents, step-by-step, readily reproducible laboratory protocols, and notes on troubleshooting and avoiding known pitfalls.

Authoritative and accessible, "DNA Nanotechnology: Methods and Protocols "serves as an ideal guide to scientists of all backgrounds and aims to ignite interest and spur activity in this young and rapidly growing research field.

Includes cutting-edge methods and protocols

Provides step-by-step detail essential for reproducible results

Contains key notes and implementation advice from the experts"

General routes to the development of innovative, multi functional nanosystems are described by experts in the field. The systems described are based on fullerenes, nanotubes, metals (Au, Ag, Pt, etc.) and semiconductors (Si, CdS, CdTe, metal oxides), nanocrystals and polymer / biopolymer assembly systems. The book also discusses the realization and characterization of the fundamental properties of nanosystems, defined by nano-size effects, as well as the application of such systems in electronics, optics, magnetoelectronics, spintronics, biomedicine, pharmaceutical biocomplexes, and biosensors.

This book provides a new direction in electronics research with the invention of a new material tuPOY, which changes our perception of developing electronics. Evolving on a relatively underplayed phenomenon of static electricity in scientific exploration and application, tuPOY upholds the potential to rival both silicon and metals as electronics of the future. Devices made of tuPOY present a new emblem to the technological world, where we could envision our electronic paraphernalia from a completely different perspective. A computer the size of a big wall, which could be neatly folded and kept in our pockets when not in use and laundered on a regular basis, can be imagined possible with this invention. The concept, manufacturing process, physics and uses of tuPOY as the next generation material of electronics is described in this book. The book covers the production process of tuPOY and goes on to conceptual advancement from manipulating the sensing, radiating and processing properties of tuPOY. Theoretical modelling of tuPOY is characterized by steady-state equations exploiting interchanges based on the lattice kinetics, which mathematizes an Interchange Phenomenon in tuPOY. The numerical manifestations calibrate mathematically, tuPOY's response to any external physical impetus such as charge, heat or energy flow. The book validates the sensing properties and theoretical model by designing a tuPOY sensor which can be used in a plethora of applications. A novel microstrip antenna is designed by amalgamation of tuPOY, raw silk and polynylon composites to experimentally verify the radiation properties of the new material. The conduction properties are verified by drawing fibres of tuPOY and using them as wires and connectors in electronics. A Power Generating Unit (PGU) is designed with tuPOY as its primary element. This is a first of its kind PGU that scavenges power from thermal energy presenting a new dimension in operational power dynamics. Overall this book should be of interest to a wide range of readers ranging from researchers, scientists, developers, manufacturers, engineers, graduate students and anyone who has satiety to think differently.

The contributions in this volume were presented at a NATO Advanced Study Institute held in Erice, Italy, 4-19 July 2013. Many aspects of important research into nanophotonics, plasmonics, semiconductor materials and devices, instrumentation for bio sensing to name just a few, are covered in depth in this volume. The growing connection between optics and electronics, due to the increasing important role plaid by semiconductor materials and devices, find their expression in the term photonics, which also reflects the importance of the photon aspect of light in the description of the performance of several optical systems. Nano-structures have unique capabilities that allow the enhanced performance of processes of interest in optical and photonic devices. In particular these structures permit the nanoscale manipulation of photons, electrons and atoms; they represent a very hot topic of research and are relevant to many devices and applications.
The various subjects bridge over the disciplines of physics, biology and chemistry, making this volume of interest to people working in these fields. The emphasis is on the principles behind each technique and on examining the full potential of each technique."

This book presents in a concise way the Mie theory and its current applications. It begins with an overview of current theories, computational methods, experimental techniques, and applications of optics of small particles. There is also some biographic information on Gustav Mie, who published his famous paper on the colour of Gold colloids in 1908. The Mie solution for the light scattering of small spherical particles set the basis for more advanced scattering theories and today there are many methods to calculate light scattering and absorption for practically any shape and composition of particles. The optics of small particles is of interest in industrial, atmospheric, astronomic and other research. The book covers the latest developments in divers fields in scattering theory such as plasmon resonance, multiple scattering and optical force.

This thesis describes a new approach to the construction of "solar cells." Following nature's example, this approach has the goal to find a biomimetic self-assembling dye, whose aggregates can mimic the natural light-harvesting system of special photosynthetic active bacteria. The thesis investigates methods to control the self-assembly such that suitable dye aggregates are formed with high internal order and size-confinement. The dye aggregates can be implemented into a new type of "solar cells," designed to combine the advantages of "hybrid solar cells" and "solid-state dye-sensitized solar cells" (ss-DSSCs): dye aggregate solar cells (DASCs). This book describes the construction and first tests of a prototype for DASCs on the basis of the investigated dye aggregates. The described approach has the advantage that it will enable to build up a light-harvesting system fully synthetically in large scale in order to realize low-cost, light-weight and environmentally friendly solar cells - a worthwhile goal towards the exploitation of clean energy from sunlight.

This book collects selected lectures from the Third Workshop of the Croucher Advanced Study Institute on Nano Science and Technology, and showcases contributions from world-renowned researchers. The book presents in-depth articles on the latest developments in nanomaterials and nanotechnology, and provides a cross-disciplinary perspective covering physics and biophysics, chemistry, materials science, and engineering.

This book discusses the effects, modeling, latest results, and nanotechnology applications of rainbows that appear during channeling of charged particles in crystals and nanotubes. The authors begin with a brief review of the optical and particle rainbow effects followed by a detailed description of crystal rainbows, which appear in ion channeling in crystals, and their modeling using catastrophe theory. The effects of spatial and angular focusing of channeled ions are described, with special attention given to the applications of the former effect to subatomic microscopy. The results of a thorough study of the recent high-resolution channeling experiments performed with protons of energies between 2.0 and 0.7 MeV and a 55 nm thick silicon crystal are also provided. This study opens up the potential for accurate analysis of very thin crystals. Also presented are recent results related to rainbows occurring in proton transmission through carbon nanotubes, and a detailed quantum consideration of the transmission of positrons of an energy of 1 MeV through very short carbon nanotubes. This process is determined by the rainbow effect. The initial positron beam is represented as an ensemble of non-interacting Gaussian wave packets, and the principal and supernumerary primary rainbows appearing in the spatial and angular distributions of transmitted positrons are clearly identified. They are explained by the effects of wrinkling, concentration and coordination of the wave packets.

In Cellular and Subcellular Nanotechnology: Methods and Protocols expert researchers in the field detail the most recent advances which have been made in utilizing the enormous potential of nanotechnology for probing, imaging and manipulating life on a cellular and subcellular level. Written in the highly successful Methods in Molecular Biology (TM) series format, chapters include introductions to their respective topics, lists of the necessary materials and reagents, step-by-step, readily reproducible laboratory protocols, and key tips on troubleshooting and avoiding known pitfalls. Authoritative and Practical, Cellular and Subcellular Nanotechnology: Methods and Protocols seeks to aid scientists in the further study of applying nanotechnology to all areas of biomedical sciences.

This book addresses the use of MEMS and micromachined devices for the investigation of nanoscience and technology, as well as biotechnology. Such micromachined tools for nanotechnology can enhance the sensitivity, spatial resolution, dexterity, selectivity, and parallel processing capability in measuring and manipulating nano-objects. The book covers state-of-the-art MEMS and NEMS devices for DNA molecular handling and analysis, cell handling and culture on a chip, chemical lab-on-a-chip, multi-probes for vacuum tunneling microscopy and AFM, and characterization of quantum semiconductor structures. Readers will gain deep insight into such developments and students will learn about the emerging field of MEMS and nanotechnology.

Controlled radical polymerization techniques for molecular imprinting, by Mark E. Byrne From bulk polymers to nanoparticles, by Lei Ye Post-imprinting and in-cavity functionalization, by Toshifumi Takeuchi Characterization of MIPs (affinity, selectivity, site heterogeneity...), by Richard Ansell Theoretical aspects and computer modelling, by Ian Nicholls MIPs in aqueous environments, by Bin Lu MIPs for binding macromolecules, by Kenneth J. Shea Solid phase extraction, by Ecevit Yilmaz Sensors, by Sergey A. Piletsky MIPs for catalysis and synthesis, by Marina Resmini Wastewater treatment, by Bo Mattiasson MIPs as tools for bioassays, biotransformation and drug delivery, by Meiping Zhao

Waste Energy Harvesting overviews the latest progress in waste energy harvesting technologies, with specific focusing on waste thermal mechanical energies. Thermal energy harvesting technologies include thermoelectric effect, storage through phase change materials and pyroelectric effect. Waste mechanical energy harvesting technologies include piezoelectric (ferroelectric) effect with ferroelectric materials and nanogenerators. The book aims to strengthen the syllabus in energy, materials and physics and is well suitable for students and professionals in the fields.

This outstanding thesis provides a wide-ranging overview of the growth of titanium dioxide thin films and its use in photo-electrochemicals such as water splitting. The context for water splitting is introduced with the theory of semiconductor-liquid junctions, which are dealt with in detail. In particular plasmonic enhancement of TiO2 by the addition of gold nanoparticles is considered in depth, including a thorough and critical review of the literature, which discusses the possible mechanisms that may be at work. Plasmonic enhancement is demonstrated with gold nanoparticles on Nb-doped TiO2. Finally, the use of temperature and pressure to control the phase and morphology of thin films grown by pulsed laser deposition is presented.

This research monograph presents the latest results related to the characterization of low dimensional systems. Low-angle polarized neutron scattering and X-ray scattering at grazing incidence are used as the two main techniques to explore various physical phenomena of these systems. Special focus is put on systems like thin film transition metal and rare-earth layers, oxide heterostructures, hybrid systems, self-assembled nanostructures and self-diffusion. Readers will gain in-depth knowledge about the usage of specular scattering and off-specular scattering techniques. Investigation of in-plane and out-of-plane structures and magnetism with vector magnetometric information is illustrated comprehensively. The book caters to a wide audience working in the field of nano-dimensional magnetic systems and the neutron and X-ray reflectometry community in particular.