This book focuses on molecular space chemistry, which is recognized as an important concept for the design of novel functional materials and catalysts. A wide variety of topics and ideas included in this book are based on that concept. The book showcases recent representative examples of molecular space design to create functional materials and catalysts possessing unique properties. This unique volume will be of great interest to chemists in a wide variety of research fields, including organic, inorganic, biological, polymer, and supramolecular chemistry. Readers will obtain new ideas and directions to create novel functional molecules, and those ideas will lead to innovative views of science.

This book suggests a new common approach to the study of resonance energy transport based on the recently developed concept of Limiting Phase Trajectories (LPTs), presenting applications of the approach to significant nonlinear problems from different fields of physics and mechanics. In order to highlight the novelty and perspectives of the developed approach, it places the LPT concept in the context of dynamical phenomena related to the energy transfer problems and applies the theory to numerous problems of practical importance. This approach leads to the conclusion that strongly nonstationary resonance processes in nonlinear oscillator arrays and nanostructures are characterized either by maximum possible energy exchange between the clusters of oscillators (coherence domains) or by maximum energy transfer from an external source of energy to the chain. The trajectories corresponding to these processes are referred to as LPTs. The development and the use of the LPTs concept a re motivated by the fact that non-stationary processes in a broad variety of finite-dimensional physical models are beyond the well-known paradigm of nonlinear normal modes (NNMs), which is fully justified either for stationary processes or for nonstationary non-resonance processes described exactly or approximately by the combinations of the non-resonant normal modes. Thus, the role of LPTs in understanding and analyzing of intense resonance energy transfer is similar to the role of NNMs for the stationary processes. The book is a valuable resource for engineers needing to deal effectively with the problems arising in the fields of mechanical and physical applications, when the natural physical model is quite complicated. At the same time, the mathematical analysis means that it is of interest to researchers working on the theory and numerical investigation of nonlinear oscillations.

This thesis combines advanced femtosecond laser micro/nanofabrication technologies and frontier bionic design principles to prepare diverse biomimetic micro/nanostructures to realize their functions. By studying the formation mechanism of the micro/nanostructures, the author identifies various artificial structural colors, three-dimensional micro/nanocage arrays, and fish-scale inspired microcone arrays in different processing environments. Multiple functions such as enhanced antireflection, hydrophobicity, and underwater superoleophobicity are achieved by precisely adjusting laser-machining parameters. This novel design and method have extensive potential applications in the context of new colorizing technologies, microfluidics, microsensors, and biomedicine.

The development of nanomaterials opens the possibility for new materials with outstanding properties compared to classical engineering materials. These materials can find applications in different fields such as medical treatment or structural mechanics.

This monograph focuses on two major groups of nanomaterials, i.e.nanoparticels and nanocomposites. Nanopartices, for example in the form of hollow particles, allow for new possibilities in drug delivery. Different aspects of nanoparticles ranging from manufacturing to modeling and simulation are covered. Nanocomposite materials are formed by mixing two or more dissimilar materials at the nanoscale in order to control and develop new and improved structures and properties. The properties of nanocomposites depend not only on the individual components used but also on the morphology and the interfacial characteristics. Nanocomposite coatings and materials are one of the most exciting and fastest growing areas of research and novel properties being continuously developed which are previously unknown in the constituent materials. Thus, the second part of this monograph gives an overview on the latest developments in the area of composites and coatings based on nanomaterials."

Nanotube Superfiber Materials refers to different forms of macroscale materials with unique properties constructed from carbon nanotubes. These materials include nanotube arrays, ribbons, scrolls, yarn, braid, and sheets. Nanotube materials are in the early stage of development and this is the first dedicated book on the subject. Transitioning from molecules to materials is a breakthrough that will positively impact almost all industries and areas of society.

Key properties of superfiber materials are high flexibility and fatigue resistance, high energy absorption, high strength, good electrical conductivity, high maximum current density, reduced skin and proximity effects, high thermal conductivity, lightweight, good field emission, piezoresistive, magnetoresistive, thermoelectric, and other properties. These properties will open up the door to dozens of applications including replacing copper wire for power conduction, EMI shielding, coax cable, carbon biofiber, bullet-proof vests, impact resistant glass, wearable antennas, biomedical microdevices, biosensors, self-sensing composites, supercapacitors, superinductors, hybrid superconductor, reinforced elastomers, nerve scaffolding, energy storage, and many others.

The scope of the book covers three main areas: Part I: Processing; Part II: Properties; and Part III: Applications. Processing involves nanotube synthesis and macro scale material formation methods. Properties covers the mechanical, electrical, chemical and other properties of nanotubes and macroscale materials. Different approaches to growing high quality long nanotubes and spinning the nanotubes into yarn are explained in detail. The best ideas are collected from all around the world including commercial approaches. Applications of nanotube superfiber cover a huge field and provides a broad survey of uses. The book gives a broad overview starting from bioelectronics to carbon industrial machines.
First book to explore the production and applications of macro-scale materials made from nano-scale particles.

Sets out the processes for producing macro-scale materials from carbon nanotubes, and describes the unique properties of these materials

Potential applications for CNT fiber/yarn include replacing copper wire for power conduction, EMI shielding, coax cable, carbon biofiber, bullet-proof vests, impact resistant glass, wearable antennas, biomedical microdevices, biosensors, self-sensing composites, supercapacitors, superinductors, hybrid superconductor, reinforced elastomers, nerve scaffolding, energy storage, and many others.

This expanded and updated edition of the 2007 version introduces readers from various backgrounds to the rapidly growing interface between biology and nanotechnology. It intellectually integrates concepts, applications, and outlooks from these major scientific fields and presents them to readers from diverse backgrounds in a comprehensive and didactic manner.Written by two leading nanobiologists actively involved at the forefront of the field both as researchers and educators, this book takes the reader from the fundamentals of nanobiology to the most advanced applications.The book fulfils a unique niche: to address not only students, but also scientists who are eager (and nowadays obliged) to learn about other state-of-the-art disciplines. The book is written in such a way as to be accessible to biologists, chemists, and physicists with no background in nanotechnology (for example biologists who are interested in inorganic nanostructures or physicists who would like to learn about biological assemblies and applications thereof). It is reader-friendly and will appeal to a wide audience not only in academia but also in the industry and anyone interested in learning more about nanobiotechnology.

"Applied Nanotechnology "takes an integrated approach to the scientific, commercial and social aspects of nanotechnology, exploring: The relationship between nanotechnology and innovationThe changing economics and business models required to commercialize innovations in nanotechnology Product design case studies Applications in various sectors, including information technology, composite materials, energy, and agriculture The role of government in promoting nanotechnology The potential future of molecular self-assembly in industrial production

In this 2e, new chapters have been added on energy applications and the role of nanotechnology in sustainability. The section on the safety of nanoproducts has also been updated, and material on funding and commercialization has been updated and expanded, with new case studies illustrating the experience of new startups in a challenging economic environment.
A route map for the commercialization of nanotechnology researchDiscusses product design challenges, regulatory issues, and ethical and social implications of nanotechnologyFeatures new case studies on nanotechnology startups in challenging economic times

The thesis covers a broad range of electronic, optical and opto-electronic devices and various predicted physical effects. In particular, it examines the quantum interference transistor effect in graphene nanorings; tunable spin-filtering and spin-dependent negative differential resistance in composite heterostructures based on graphene and ferromagnetic materials; optical and novel electro-optical bistability and hysteresis in compound systems and the real-time control of radiation patterns of optical nanoantennas. The direction of the main radiation lobe of a regular plasmonic array can be changed abruptly by small variations in external control parameters. This optical effect, apart from its relevance for applications, is a revealing example of the Umklapp process and, thus, is a visual manifestation of one of the most fundamental laws of solid state physics: the conservation of the quasi-momentum to within a reciprocal lattice vector. The thesis analyzes not only results for particular device designs but also a variety of advanced numerical methods which are extended by the author and described in detail. These methods can be used as a sound starting point for further research.

This book demonstrates how to use the Synopsys Sentaurus TCAD 2014 version for the design and simulation of 3D CMOS (complementary metal-oxide-semiconductor) semiconductor nanoelectronic devices, while also providing selected source codes (Technology Computer-Aided Design, TCAD). Instead of the built-in examples of Sentaurus TCAD 2014, the practical cases presented here, based on years of teaching and research experience, are used to interpret and analyze simulation results of the physical and electrical properties of designed 3D CMOSFET (metal-oxide-semiconductor field-effect transistor) nanoelectronic devices. The book also addresses in detail the fundamental theory of advanced semiconductor device design for the further simulation and analysis of electric and physical properties of semiconductor devices. The design and simulation technologies for nano-semiconductor devices explored here are more practical in nature and representative of the semiconductor industry, and as such can promote the development of pioneering semiconductor devices, semiconductor device physics, and more practically-oriented approaches to teaching and learning semiconductor engineering. The book can be used for graduate and senior undergraduate students alike, while also offering a reference guide for engineers and experts in the semiconductor industry. Readers are expected to have some preliminary knowledge of the field.

This book describes the n and p-channel Silicon Nanowire Transistor (SNT) designs with single and dual-work functions, emphasizing low static and dynamic power consumption. The authors describe a process flow for fabrication and generate SPICE models for building various digital and analog circuits. These include an SRAM, a baseband spread spectrum transmitter, a neuron cell and a Field Programmable Gate Array (FPGA) platform in the digital domain, as well as high bandwidth single-stage and operational amplifiers, RF communication circuits in the analog domain, in order to show this technology's true potential for the next generation VLSI.

In this thesis, Andrew Logsdail demonstrates that computational chemistry is a powerful tool in contemporary nanoscience, complementing experimental observations and helping guide future experiments. The aim of this particular PhD is to further our understanding of structural and compositional preferences in gold nanoparticles, as well as the compositional and chemical ordering preferences in bimetallic nanoalloys formed with other noble metals, such as palladium and platinum. Highlights include: calculations of the structural preferences and optical-response of gold nanoparticles and gold-containing nanoalloys; the design and implementation of novel numerical algorithms for the structural characterisation of gold nanoparticles from electron microscopy images; and electronic structure calculations investigating the interaction of gold nanoparticles with graphene and graphite substrates.The results presented here have significant implications for future research on the chemical and physical properties of gold-based nanoparticles and are of interest to many researchers working on experimental and theoretical aspects of nanoscience.

This book brings together reviews from international experts who are exploring the biological activities of nanomaterials for medical applications or to better understand nanotoxicity. Topics include but are not limited to the following: 1) mechanistic understanding of nanostructure-bioactivity relationships; 2) the regulation of nanoparticles' bioactivity by means of chemical modification; 3) the new methodologies and standard methods used to assess nanoparticles' bioactivity; 4) the mechanisms involved in nanoparticle-biomolecule interactions and nanoparticle-cell interactions; and 5) biomedical applications of nanotechnology. The book will be a valuable resource for a broad readership in various subfields of chemical science, engineering, biology, environment, and medicine.

This book introduces readers to the cutting-edge topic of nanophotonic photochemical reactions and their applications. From among the various innovations in optical technology achieved by means of the non-uniform optical near field, it focuses on photochemical reactions at the nanoscale. Optical near fields are the elementary surface excitations of nanometric particles with non-uniform field distributions. After reviewing the unique properties of the non-uniform optical field, the book presents a range of applications of near-field assisted photochemical reactions, including near-field etching, visible water splitting, carbon dioxide reduction and reactions in solar cells.

This thesis reports the discovery of metal nanoparticles having new structures that do not exist in bulk state and that exhibit hydrogen storage ability or CO oxidation activity. Research into the reaction of hydrogen with metals has attracted much attention because of potential applications as effective hydrogen storage materials, as permeable films, or as catalysts for hydrogenation. Also, CO oxidation catalysts have been extensively developed because of their importance to CO removal from car exhaust or fuel-cell systems. At the same time, atomic-level (solid solution) alloying has the advantage of being able to continuously control chemical and physical properties of elements by changing compositions and/or combinations of constituent elements. This thesis provides a novel strategy for the basis of inter-elemental fusion to create highly efficient functional materials for energy and material conversions.

This book covers the state of the art of laser micro- and nanotechnology. The physical fundamentals of different processes and the application are presented. The book deals with different materials like phase change and memory alloys, thin films, polymers etc. New phenomena and mechanisms of laser-matter interaction in nano-domains are explained. This book is helpful for students, postgraduates, engineers and researches working not only in the field of laser microtechnology but also in high-tech industry, like photonics, microelectronics, information technology.

This thesis combines highly accurate optical spectroscopy data on the recently discovered iron-based high-temperature superconductors with an incisive theoretical analysis. Three outstanding results are reported: (1) The superconductivity-induced modification of the far-infrared conductivity of an iron arsenide with minimal chemical disorder is quantitatively described by means of a strong-coupling theory for spin fluctuation mediated Cooper pairing. The formalism developed in this thesis also describes prior spectroscopic data on more disordered compounds. (2) The same materials exhibit a sharp superconductivity-induced anomaly for photon energies around 2.5 eV, two orders of magnitude larger than the superconducting energy gap. The author provides a qualitative interpretation of this unprecedented observation, which is based on the multiband nature of the superconducting state. (3) The thesis also develops a comprehensive description of a superconducting, yet optically transparent iron chalcogenide compound. The author shows that this highly unusual behavior can be explained as a result of the nanoscopic coexistence of insulating and superconducting phases, and he uses a combination of two complementary experimental methods - scanning near-field optical microscopy and low-energy muon spin rotation - to directly image the phase coexistence and quantitatively determine the phase composition. These data have important implications for the interpretation of data from other experimental probes.

This volume of Modern Aspects of Electrochemistry has contributions from significant individuals in electrochemistry. This 7 chapter book discusses electrodeposition and the characterization of alloys and composite materials, the mechanistic aspects of lead electrodeposition, electrophoretic deposition of ceramic materials onto metal surfaces and the fundamentals of metal oxides for energy conversion and storage technologies. This volume also has a chapter devoted to the anodization of aluminum, electrochemical aspects of chemical and mechanical polishing, and surface treatments prior to metallization of semiconductors, ceramics, and polymers. This volume of Modern Aspects of Electrochemistry is ideal for scientists, researchers, engineers, and students interested in the latest findings in the field of electrodeposition and surface finishing.

This book introduces readers to fundamental information on phosphor and quantum dots. It comprehensively reviews the latest research advances in and applications of fluoride phosphors, oxide phosphors, nitridosilicate phosphors and various quantum dot materials. Phosphors and phosphor-based quantum dot materials have recently gained considerable scientific interest due to their wide range of applications in lighting, displays, medical and telecommunication technologies. This work will be of great interest to researchers and graduate students in materials sciences and chemistry who wish to learn more about the principles, synthesis and analysis of phosphors and quantum dot materials.

This thesis focuses on the transport and magneto-transport properties of graphene p-n-p junctions, such as the pronounced quantum Hall effect, a well-defined plateau-plateau transition point, and scaling behavior. In addition, it demonstrates persistent photoconductivity (PPC) in the monolayer MoS2 devices, an effect that can be attributed to random localized potential fluctuations in the devices. Further, it studies scaling behavior at zeroth Landau level and high performance of fractional values of quantum Hall plateaus in these graphene p-n-p devices. Moreover, it demonstrates a unique and efficient means of controlling the PPC effect in monolayer MoS2. This PPC effect may offer novel functionalities for MoS2-based optoelectronic applications in the future.

This book presents a new system of solar cells. Colloidal nanocrystals possess many physical and chemical properties which can be manipulated by advanced control over structural features like the particle size. One application field is photovoltaics where colloidal semiconductor nanocrystals are explored as components of photo-active layers which can be produced from liquid media, often in combination with conductive polymers. The further development of this interdisciplinary field of research requires a deep understanding of the physics and chemistry of colloidal nanocrystals, conducting polymers and photovoltaic devices. This book aims at bridging gaps between the involved scientific disciplines and presents important fundamentals and the current state of research of relevant materials and different types of nanoparticle-based solar cells. The book will be of interest to researchers and PhD students. Moreover, it may also serve to accompany specialized lectures in related areas.

This book introduces the fascinating world of plasmonics and physics at the nanoscale, with a focus on simulations and the theoretical aspects of optics and nanotechnology. A research field with numerous applications, plasmonics bridges the gap between the micrometer length scale of light and the secrets of the nanoworld. This is achieved by binding light to charge density oscillations of metallic nanostructures, so-called surface plasmons, which allow electromagnetic radiation to be focussed down to spots as small as a few nanometers. The book is a snapshot of recent and ongoing research and at the same time outlines our present understanding of the optical properties of metallic nanoparticles, ranging from the tunability of plasmonic resonances to the ultrafast dynamics of light-matter interaction. Beginning with a gentle introduction that highlights the basics of plasmonic interactions and plasmon imaging, the author then presents a suitable theoretical framework for the description of metallic nanostructures. This model based on this framework is first solved analytically for simple systems, and subsequently through numerical simulations for more general cases where, for example, surface roughness, nonlinear and nonlocal effects or metamaterials are investigated.

Nanoelectronics are a diverse set of materials and devices that are so small that quantum mechanics need to be applied to their function. The possibilities these devices present outweigh the difficulties associated with their development, as biosensors and similar devices have the potential to vastly improve our technological reach. The Handbook of Research on Nanoelectronic Sensor Modeling and Applications begins with an introduction of the fundamental concepts of nanoelectronic sensors, then proceeds to outline in great detail the concepts of nanoscale device modeling and nanoquantum fundamentals. Recent advances in the field such as graphene technology are discussed at length in this comprehensive handbook, ideal for electrical engineers, advanced engineering students, researchers, and academics.

This book presents a detailed history of chemical warfare development during the First World War and discusses design approaches to gas masks and the performance of new filter materials that decontaminate chemical warfare agents (CWA) when applied in the vapor phase. It describes multifunctional nanocomposites containing zinc and zirconium (hydr)oxides, graphite oxide and silver or gold nanoparticles as reactive adsorbents for the degradation of the CWAs vapors. In addition it examines in detail the surface properties that are most important in the mineralization performance.

This book provides an overview of essential research on and developments in the electrohydrodynamic (EHD) direct-writing technique and its applications. Firstly, it presents mechano- and helix electrospinning methods to achieve direct writing of straight/serpentine micro/nano fibers in high resolution. Secondly, it examines functional inks and multi nozzle arrays for EHD printing, which are used to efficientlyform patterns and devices. Thirdly, the book discusses the various control methods adopted in the context of EHD to improve the controllability of the electrospun fibers. Lastly, it addresses the equipment used in EHD printing and its applications, while also outlining challenges for the field's future development. Combining academic and industrial viewpoints, the book provides in-depth information for experienced researchers, as well as a valuable guide for those just entering the field.