This book combines the contributions of experts in the field to describe the behavior of various materials, micromechanisms involved during processing, and the optimization of cold-spray technology. It spans production, characterization, and applications including wear resistance, fatigue, life improvement, thermal barriers, crack repair, and biological applications. Cold spray is an innovative coating technology based on the kinetic energy gained by particles sprayed at very high pressures. While the technique was developed in the 1990s, industrial and scientific interest in this technology has grown vastly in the last ten years. Recently, many interesting applications have been associated with cold-sprayed coatings, including wear resistance, fatigue life improvement, thermal barriers, biological applications, and crack repair. However, many fundamental aspects require clarification and description.

This book is focused on recent advances in the development of thin films for photovoltaic applications, TiO2/WO3 bi-layers for applications with enhanced photo-catalytic properties, nanometer oxide and hydroxide films for anticorrosive coatings, surface passivation in chemical industries, micro- and nanoelectronics, trilayers of metglas and lead free piezoelectrics for magnetic field sensors, current sensors, spintronics, microwave and read/write devices. Diluted ferromagnetic alloy films are also considered for superconducting spintronics based on superconducting spin-valves. Thermal properties of segmented nanowires are analyzed with respect to thermoelectric applications. Recent advances in template production of nanocomposites are also reviewed with particular focus on technologies for template assisted formation of metal nanotubes. Some elements related to abrasive flow machining (AFM), specifically state of the art elements of technological systems and construction of equipment are presented. The book is written for researchers in materials science, nanotechnologies, PhD students and graduate student.

This book covers various molecular, metal-organic, dynamic covalent, polymer and other gels, focusing on their driving interactions, structures and properties. It consists of six chapters demonstrating interesting examples of these gels, classified by the type of driving interaction, and also discusses the effect of these interactions on the gels' structures and properties. The book offers an interesting and useful guide for a broad readership in various fields of chemical and materials science.

Designed to sit alongside more conventional established condensed matter physics textbooks, this compact volume offers a concise presentation of the principles of solid state theory, ideal for advanced students and researchers requiring an overview or a quick refresher on a specific topic. The book starts from the one-electron theory of solid state physics, moving through electron-electron interaction and many-body approximation schemes, to lattice oscillations and their interactions with electrons. Subsequent chapters discuss transport theory and optical properties, phase transitions and some properties of low-dimensional semiconductors. This extensively expanded second edition includes new material on adiabatic perturbation theory, kinetic coefficients, the Nyquist theorem, Bose condensation, and the field-theoretical approach to non-relativistic quantum electrodynamics. Throughout the text, mathematical proofs are often only sketched, and the final chapter of the book reviews some of the key concepts and formulae used in theoretical physics. Aimed primarily at graduate and advanced undergraduate students taking courses on condensed matter theory, the book serves as a study guide to reinforce concepts learned through conventional solid state texts. Researchers and lecturers will also find it a useful resource as a concise set of notes on fundamental topics.

This new edition updates readers in three areas of NMR studies, namely, recent developments in high-Tc materials, heavy fermion systems and actinide oxides are presented. The NMR probe has yielded a vast array of data for solid state materials, corresponding to different compounds, ionic sites, and nuclear species, as well as to a wide variety of experimental conditions. The last two parts of the book are completely new in this edition, while the first part has seen major updates.This edition features the latest developments for high-Tc materials, especially the advances in the area of pseudogap studies are reviewed. An in depth overview of heavy fermion systems is presented in the second part, notably Kondo lattices, quantum critical points and unconventional superconductivity are areas of intense research recently and are covered extensively. Finally, valuable information from NMR studies with actinide oxides will be provided.Ongoing analysis and discussion of NMR data have resulted in a wealth of important insights into the physics of these exotic systems. The aims of this monograph are manyfold. First, it reviews NMR methodology as it has been applied to the different studies. This is addressed to NMR practitioners and to physics laypersons alike. Next, it presents a review of NMR measurements and the wide variety of phenomena which they represent. The third phase is to recount the theoretical model calculations and other proposals which have been put forward to account for these data.

This thesis reports a rare combination of experiment and theory on the role of geometry in materials science. It is built on two significant findings: that curvature can be used to guide crack paths in a predictive way, and that protected topological order can exist in amorphous materials. In each, the underlying geometry controls the elastic behavior of quasi-2D materials, enabling the control of crack propagation in elastic sheets and the control of unidirectional waves traveling at the boundary of metamaterials. The thesis examines the consequences of this geometric control in a range of materials spanning many orders of magnitude in length scale, from amorphous macroscopic networks and elastic continua to nanoscale lattices.

The book presents pedagogical reviews of important topics on high energy physics to the students and researchers in particle physics. The book also discusses topics on the Quark-Gluon plasma, thermal field theory, perturbative quantum chromodynamics, anomalies and cosmology. Students of particle physics need to be well-equipped with basic understanding of many concepts underlying the standard models of particle physics and cosmology. This is particularly true today when experimental results from colliders, such as large hadron collider (LHC) and relativistic heavy ion collider (RHIC), as well as inferences from cosmological observations, are expected to further expand our understanding of particle physics at high energies. This volume is the second in the Surveys in Theoretical High Energy Physics Series (SThEP). Topics covered in this book are based on lectures delivered at the SERC Schools in Theoretical High Energy Physics at the Physical Research Laboratory, Ahmedabad, and the University of Hyderabad.

This book focuses on the study of the interfacial water using molecular dynamics simulation and experimental sum frequency generation spectroscopy. It proposes a new definition of the free O-H groups at water-air interface and presents research on the structure and dynamics of these groups. Furthermore, it discusses the exponential decay nature of the orientation distribution of the free O-H groups of interfacial water and ascribes the origin of the down pointing free O-H groups to the presence of capillary waves on the surface. It also describes how, based on this new definition, a maximum surface H-bond density of around 200 K at ice surface was found, as the maximum results from two competing effects. Lastly, the book discusses the absorption of water molecules at the water-TiO2 interface. Providing insights into the combination of molecular dynamics simulation and experimental sum frequency generation spectroscopy, it is a valuable resource for researchers in the field.

This practical, comprehensive book introduces both semiconductors and integrated optics at a fundamental level, and provides in-depth derivations and analysis of key integrated optical components for more advanced study. Written from an engineer's point of view, the book emphasizes practical application; the author develops and explains the concepts and techniques needed to solve real-world problems and to understand the engineering issues involved. The book first discusses semiconductor optical material systems and then addresses the waveguide in depth. Next, it covers active devices such as lasers, modulators and detectors. Finally, there is a survey of integration and hybridization, plus the development of photonic integrated circuits. With its clear explanations and design examples, the book provides both experienced and budding engineers with the information necessary to design both the structure and fabrication process of a semiconductor integrated optical device.

For upper-level undergraduate students, and first-year graduate students in materials science, metallurgy, electrical engineering, and applied physics.;This Third Edition is the result of a thorough re-examination of the entire text, incorporating suggestions and corrections by students and professors who have used the text. Explanations and descriptions have been expanded, and additional information has beeen added on high Tc, superconductors, diamond films, "buckminsterfullerene", and thin magnetic materials. Adopted by more than 20 colleges and universities, this text has proven to be a solid introduction to the electrical, optical, and magnetic properties of materials.;It contains comprehensive coverage of electronic properties in metals, semiconductors, and insulators at a fundamental level; stresses the use of wave properties as an integrating theme for the discussion of phonons, photons, and electrons; includes a complete set of illustrative problems along with exercises and answers; and features a careful indication of both Gaussian and SI unit systems.

This thesis introduces a unique approach of applying atomic force microscopy to study the nanoelectromechanical properties of 2D materials, providing high-resolution computer-generated imagery (CGI) and diagrams to aid readers' understanding and visualization. The isolation of graphene and, shortly after, a host of other 2D materials has attracted a great deal of interest in the scientific community for both their range of extremely desirable and their record-breaking properties. Amongst these properties are some of the highest elastic moduli and tensile strengths ever observed in nature. The work, which was undertaken at Lancaster University's Physics department in conjunction with the University of Manchester and the National Physical Laboratory, offers a new approach to understanding the nanomechanical and nanoelectromechanical properties of 2D materials by utilising the nanoscale and nanosecond resolution of ultrasonic force and heterodyne force microscopy (UFM and HFM) - both contact mode atomic force microscopy (AFM) techniques. Using this approach and developing several other new techniques the authors succeeded in probing samples' subsurface and mechanical properties, which would otherwise remain hidden. Lastly, by using a new technique, coined electrostatic heterodyne force microscopy (E-HFM), the authors were able to observe nanoscale electromechanical vibrations with a nanometre and nanosecond resolution, in addition to probing the local electrostatic environment of devices fabricated from 2D materials.

This thesis focuses on the energy band engineering of graphene. It presents pioneering findings on the controlled growth of graphene and graphene-based heterostructures, as well as scanning tunneling microscopy/scanning tunneling spectroscopy (STM/STS) studies on their electronic structures. The thesis primarily investigates two classes of graphene-based systems: (i) twisted bilayer graphene, which was synthesized on Rh substrates and manifests van Hove singularities near Fermi Level, and (ii) in-plane h-BN-G heterostructures, which were controllably synthesized in an ultrahigh vacuum chamber and demonstrate intriguing electronic properties on the interface. In short, the thesis offers revealing insights into the energy band engineering of graphene-based nanomaterials, which will greatly facilitate future graphene applications.

This thesis describes pioneering research on the extension of plasmonics schemes to the regime of high-intensity lasers. By presenting a rich and balanced mix of experimentation, theory and simulation, it provides a comprehensive overview of the emerging field of high field plasmonics, including open issues and perspectives for future research. Combining specially designed targets and innovative materials with ultrashort, high-contrast laser pulses, the author experimentally demonstrates the effects of plasmon excitation on electron and ion emission. Lastly, the work investigates possible further developments with the help of numerical simulations, revealing the potential of plasmonics effects in the relativistic regime for advances in laser-driven sources of radiation, and for the manipulation of extreme light at the sub-micron scale.

This book aims to introduce the reader to basic concepts concerning matter physics, describing how fundamental properties of atoms, molecules and condensed matter are affected by properties of electrons and by their interaction with electromagnetic waves.As an introductory text on basic properties of matter, the contents are designed for undergraduate students in electrical engineering. It is based on the lectures given by the author for over a decade on Matter Physics and Solid State Physics. It focuses on electronic properties to discuss the structure, electrical and optical properties of matter, and is organized into six chapters.The first chapter is a short review of the basic properties of electromagnetic waves, giving the basic concepts related to wave propagation to be handled easily to understand the subsequent topics. The next chapter on quantum mechanics helps to understand the quantum properties of matter using the simplest formalizations. Chapter 3 introduces the core of the book by using quantum mechanics to describe the electronic properties of the atom. Then, after atomic bonding, molecules and condensed matter are discussed before approaching the structural properties of crystal and soft matter. The following chapters (4 and 5) are then devoted to electrical properties and optical properties and address the main topics related to solid state and semiconductor physics as well as light-matter interaction. The final chapter 6, deals with the basic properties of lasers, due to the relevance of light sources in everyday life, and their widespread use in all branches of engineering.

This book introduces the ideas and concepts of nonlinear dielectric spectroscopy, outlines its history, and provides insight into the present state of the art of the experimental technology and understanding of nonlinear dielectric effects. Emphasis is on what can be learned from nonlinear experiments that could not be derived from the linear counterparts. The book explains that nonlinear dielectric spectroscopy can be used as a tool to measure structural recovery or physical aging, as well as connections between dynamics and thermodynamic variables such as enthalpy and entropy. Supercooled liquids in their viscous regime are ideal candidates for investigating nonlinear effects, because they are particularly sensitive to changes in temperature, and thus also to changes in the electric field. Other interesting materials covered are plastic crystals and complex liquids near criticality. The book also points out that, compared with other techniques such as mechanical shear experiments, the nonlinear regime of dielectric spectroscopy is special in the sense that the energies involved always remain small compared with thermal energies. To demonstrate this, nonlinear features of mechanical experiments are discussed. Theoretical approaches to nonlinear effects are particularly complicated because the tools available for the linear regime no longer apply. As a result, there is no single generally accepted theory to nonlinear dielectric responses of real liquids. Various approaches to nonlinear dielectric features have been reported, and the different aspects are communicated in several chapters. The book communicates recent progress most effectively through individual contributions from specialists in their respective fields.Chapter 'Third and Fifth Harmonic Responses in Viscous Liquids' is available open access under a Creative Commons Attribution 4.0 International License via link.springer.com.

The purpose of this text is to introduce engineering and science students to the basic underlying physics and chemistry concepts that form the foundation of plasma science and engineering. It is an accessible primer directed primarily at those students who, like the general public, simply do not understand exactly what a plasma or gas discharge is nor do they even necessarily have the fundamental background in statistical thermodynamics, gas dynamics, fluid dynamics, or solid state physics to effectively understand many plasma and gas discharge principles. At the conclusion of this text, the reader should understand what an ion is, how they move, the equations we use to describe these basic concepts, and how they link to the aforementioned topics of plasmas and gas discharges. This book is focused on specific concepts that are important to non-equilibrium, low temperature gas discharges. These discharges fi nd wide applicability today and are of significant interest to the scientifi c and engineering communities.

The thesis provides the necessary experimental and analytical tools to unambiguously observe the atomically resolved chemical reactions. A great challenge of modern science has been to directly observe atomic motions during structural transitions, and while this was first achieved through a major advance in electron source brightness, the information content was still limited and new methods for image reconstruction using femtosecond electron diffraction methods were needed. One particular challenge lay in reconciling the innumerable possible nuclear configurations with the observation of chemical reaction mechanisms that reproducibly give the same kind of chemistry for large classes of molecules. The author shows that there is a simple solution that occurs during barrier crossing in which the highly anharmonic potential at that point in nuclear rearrangements couples high- and low-frequency vibrational modes to give highly localized nuclear motions, reducing hundreds of potential degrees of freedom to just a few key modes. Specific examples are given in this thesis, including two photoinduced phase transitions in an organic system, a ring closure reaction, and two direct observations of nuclear reorganization driven by spin transitions. The emerging field of structural dynamics promises to change the way we think about the physics of chemistry and this thesis provides tools to make it happen.

This volume summarises recent developments and highlights new techniques which will define possible future directions for small molecule X-ray crystallography. It provides an insight into how specific aspects of crystallography are developing and shows how they may interact or integrate with other areas of science. The development of more sophisticated equipment and the massive rise in computing power has made it possible to solve the three-dimensional structure of an organic molecule within hours if not minutes. This successful trajectory has resulted in the ability to study ever more complex molecules and use smaller and smaller crystals. The structural parameters for over a million organic and organometallic compounds are now archived in the most commonly used database and this wealth of information creates a new set of problems for future generations of scientists. The volume provides some insight into how users of crystallographic structural data banks can navigate their way through a world where "big data" has become the norm. The coupling of crystallography to quantum chemical calculations provides detailed information about electron distributions in crystals affording a much more detailed analysis of bonding than has been possible previously. In quantum crystallography, quantum mechanical wavefunctions are used to extract information about bonding and properties from the measured X-ray structure factors. The advent of quantum crystallography has resulted in form and structure factors derived from quantum mechanics which have been used in advanced refinement and wavefunction fitting. This volume describes how quantum mechanically derived atomic form factors and structure factors are constructed to allow the improved description of the diffraction experiment. It further discusses recent developments in this field and illustrates their applications with a wide range of examples. This volume will be of interest to chemists and crystallographers with an interest in the synthesis, characterisation and physical and catalytic properties of solid-state materials. It will also be relevant for the community of computational chemists who study chemical systems. Postgraduate students entering the field will benefit from a historical introduction to the way in which scientists have used the data derived from crystallography to develop new structural and bonding models.

This book is a monograph on chaos in dissipative systems written for those working in the physical sciences. Emphasis is on symbolic description of the dynamics and various characteristics of the attractors, and written from the view-point of practical applications without going into formal mathematical rigour. The author used elementary mathematics and calculus, and relied on physical intuition whenever possible. Substantial attention is paid to numerical techniques in the study of chaos. Part of the book is based on the publications of Chinese researchers, including those of the author's collaborators.

This thesis addresses two very different but equally important topics in the very broad fields of astrophysics and cosmology: (I) the generation of cosmological magnetic fields and (II) gravitational fragmentation of the Cosmic Web. All mathematical developments are completed by illuminating physical interpretations, and the thesis, which is guided by existing observations, is purely theoretical. In part I, the author further develops a magnetogenesis model proposed in the literature, providing an unprecedented level of physical understanding. He demonstrates that the physics of photoionisation is very likely to have premagnetised, at a relevant level, the entire Universe at the early epoch of the formation of the first luminous sources. In part II, the author adapts the tools of plasma spectral theory to the context of gravitational instability of the baryonic gas within the stratified structures of the Cosmic Web. He skillfully derives the wave equation governing the growth of perturbations and explores various equilibrium configurations, in planar and cylindrical geometries characteristic of cosmic walls and filaments, for isothermal and polytropic conditions, with or without an external gravitational background. Clearly structured and written in pedagogical style, this outstanding thesis puts the results into perspective and highlights the merits and limitations of the various approaches explored.

This book offers a review of the use of extended ablation plasmas as nonlinear media for HHG of high-order harmonic generation (HHG). The book describes the different experimental approaches, shows the advantages and limitations regarding HHG efficiency and discusses the particular processes that take place at longer interaction lengths, including propagation and quasi-phase matching effects. It describes the most recent approaches to harmonic generation in the extreme ultraviolet (XUV) range with the use of extended plasma plumes, and how these differ from more commonly-used gas-jet sources. The main focus is on studies using extended plasmas, but some new findings from HHG experiments in narrow plasma plumes are also discussed. It also describes how quasi-phase-matching in modulated plasmas, as demonstrated in recent studies, has revealed different means of tuning enhanced harmonic groups in the XUV region. After an introduction to the fundamental theoretical and experimental aspects of HHG, a review of the most important results of HHG in narrow plasmas is presented, including recent studies of small-sized plasma plumes as emitters of high-order harmonics. In Chapter 2, various findings in the application of extended plasmas for harmonic generation are analyzed. One of the most important applications of extended plasmas, the quasi-phase-matching of generated harmonics, is demonstrated in Chapter 3, including various approaches to the modification of perforated plasma plumes. Chapter 4 depicts the nonlinear optical features of extended plasmas produced on the surfaces of different non-metal materials. Chapter 5 is dedicated to the analysis of new opportunities for extended plasma induced HHG. The advantages of the application of long plasma plumes for HHG, such as resonance enhancement and double-pulse method, are discussed in Chapter 6. Finally, a summary section brings together all of these findings and discuss the perspectives of extended plasma formations for efficient HHG and nonlinear optical plasma spectroscopy. The book will be useful for students and scholars working in this highly multidisciplinary domain involving material science, nonlinear optics and laser spectroscopy. It brings the new researcher to the very frontier of the physics of the interaction between laser and extended plasma; for the expert it will serve as an essential guide and indicate directions for future research.

This thesis experimentally demonstrates the much discussed electronic charge-glass states in solids. It focuses on quasi-two-dimensional organic conductors of the -(BEDT-TTF)2X family, which form anisotropic triangular lattices, and examines their electronic properties using various measurements: resistivity, time-resolved electric transport, X-ray diffraction analysis, and nuclear magnetic resonance spectroscopy. The hallmark of the charge glass caused by geometrical frustration of lattice structure for those materials is successfully observed for the first time. The thesis provides new insights into the exotic properties of matter driven by strong electron correlations and crystalline frustration. The introduction enables beginners to understand fundamentals of the charge-glass states and the organic-conductor family -(BEDT-TTF)2X. The comprehensive and detailed descriptions of the experimental demonstration make this a valuable resource.

This carefully researched book presents facts and arguments showing, beyond a doubt, that nuclear fusion power will not be technically feasible in time to satisfy the world's urgent need for climate-neutral energy. The author describes the 70-year history of nuclear fusion; the vain attempts to construct an energy-generating nuclear fusion power reactor, and shows that even in the most optimistic scenario nuclear fusion, in spite of the claims of its proponents, will not be able to make a sizable contribution to the energy mix in this century, whatever the outcome of ITER. This implies that fusion power will not be a factor in combating climate change, and that the race to save the climate with carbon-free energy will have been won or lost long before the first nuclear fusion power station comes on line. Aimed at the general public as well as those whose decisions directly affect energy policy, this book will be a valuable resource for informing future debates.