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Books > Science & Mathematics > Physics > States of matter
Presents the state of the technology, from fundamentals to new materials and applications Today's electronic devices, computers, solar cells, printing, imaging, copying, and recording technology, to name a few, all owe a debt to our growing understanding of the photophysics and photochemistry of polymeric materials. This book draws together, analyzes, and presents our current understanding of polymer photochemistry and photophysics. In addition to exploring materials, mechanisms, processes, and properties, the handbook also highlights the latest applications in the field and points to new developments on the horizon. "Photochemistry and Photophysics of Polymer Materials" is divided into seventeen chapters, including: Optical and luminescent properties and applications of metal complex-based polymers Photoinitiators for free radical polymerization reactions Photovoltaic polymer materials Photoimaging and lithographic processes in polymers Photostabilization of polymer materials Photodegradation processes in polymeric materials Each chapter, written by one or more leading experts and pioneers in the field, incorporates all the latest findings and developments as well as the authors' own personal insights and perspectives. References guide readers to the literature for further investigation of individual topics. Together, the contributions represent a series of major developments in the polymer world in which light and its energy have been put to valuable use. Not only does this reference capture our current state of knowledge, but it also provides the foundation for new research and the development of new materials and new applications.
This is the second volume in a four-part series on fluid dynamics: Part 1. Classical Fluid Dynamics Part 2. Asymptotic Problems of Fluid Dynamics Part 3. Boundary Layers Part 4. Hydrodynamic Stability Theory The series is designed to give a comprehensive and coherent description of fluid dynamics, starting with chapters on classical theory suitable for an introductory undergraduate lecture course, and then progressing through more advanced material up to the level of modern research in the field. In Part 2 the reader is introduced to asymptotic methods, and their applications to fluid dynamics. Firstly, it discusses the mathematical aspects of the asymptotic theory. This is followed by an exposition of the results of inviscid flow theory, starting with subsonic flows past thin aerofoils. This includes unsteady flow theory and the analysis of separated flows. The authors then consider supersonic flow past a thin aerofoil, where the linear approximation leads to the Ackeret formula for the pressure. They also discuss the second order Buzemann approximation, and the flow behaviour at large distances from the aerofoil. Then the properties of transonic and hypersonic flows are examined in detail. Part 2 concludes with a discussion of viscous low-Reynolds-number flows. Two classical problems of the low-Reynolds-number flow theory are considered, the flow past a sphere and the flow past a circular cylinder. In both cases the flow analysis leads to a difficulty, known as Stokes paradox. The authors show that this paradox can be resolved using the formalism of matched asymptotic expansions.
This book is dedicated to recent advancements in theoretical and computational studies on the interactions of hydrogen and hydrogenated molecules with metal surfaces. These studies are driven by the development of high-performance computers, new experimental findings, and the extensive work of technological applications towards the realization of a sustainable hydrogen economy. Understanding of the elementary processes of physical and chemical reactions on the atomic scale is important in the discovery of new materials with high chemical reactivity and catalytic activity, as well as high stability and durability. From this point of view, the book focuses on the behavior of hydrogen and hydrogenated molecules on flat, stepped, and reconstructed metal surfaces. It also tackles the quantum mechanical properties of hydrogen and related adsorbates; namely, molecular orbital angular momentum (spin) and diffusion along the minimum potential energy landscape on metal surfaces. All of these profoundly influence the outcomes of (1) catalytic reactions that involve hydrogen; (2) hydrogen storage in metals; and (3) hydrogen purification membranes. Lastly, it surveys the current status of the technology, outlook, and challenges for the long-desired sustainable hydrogen economy in relation to the topics covered in the book.
This thesis makes significant advances to the understanding of bottlebrush polymers. While bottlebrushes have received much attention due to the recent discovery of their unprecedented properties, including supersoftness, ultra-low viscosity, and hyperelasticity, this thesis is the first fundamental investigation at the molecular level that comprises structure and dynamics. Neutron scattering experiments, detailed within, reveal spherical or cylindrical shapes, instead of a random coil conformation. Another highlight is the analysis of the fast dynamics at the sub nm-length scale. The combination of three neutron spectrometers and the development of a new analysis technique enabled the calculation of the mean-square displacement over seven orders of magnitude in time scale. This unprecedented result can be applied to a broad class of samples, including polymers and other materials. The thesis is accessible to scientists from other fields, provides the reader with easily understandable guidelines for applying this analysis to other materials, and has the potential to make a significant impact on the analysis of neutron scattering data.
This book presents a comprehensive overview of state-of-the-art quantum dot photodetectors, including device fabrication technologies, optical engineering/manipulation strategies, and emerging photodetectors with building blocks of novel quantum dots (e.g. perovskite) as well as their hybrid structured (e.g. 0D/2D) materials. Semiconductor quantum dots have attracted much attention due to their unique quantum confinement effect, which allows for the facile tuning of optical properties that are promising for next-generation optoelectronic applications. Among these remarkable properties are large absorption coefficient, high photosensitivity, and tunable optical spectrum from ultraviolet/visible to infrared region, all of which are very attractive and favorable for photodetection applications. The book covers both fundamental and frontier research in order to stimulate readers' interests in developing novel ideas for semiconductor photodetectors at the center of future developments in materials science, nanofabrication technology and device commercialization. The book provides a knowledge sharing platform and can be used as a reference for researchers working in the fields of photonics, materials science, and nanodevices.
Working Guide to Vapor-Liquid Phase Equilibria Calculations offers a practical guide for calculations of vapor-phase equilibria. The book begins by introducing basic concepts such as vapor pressure, vapor pressure charts, equilibrium ratios, and flash calculations. It then presents methods for predicting the equilibrium ratios of hydrocarbon mixtures: Wilson's correlation, Standing's correlation, convergence pressure method, and Whitson and Torp correlation. The book describes techniques to determine equilibrium ratios of the plus fraction, including Campbell's method, Winn's method, and Katz's method. The remaining chapters cover the solution of phase equilibrium problems in reservoir and process engineering; developments in the field of empirical cubic equations of state (EOS) and their applications in petroleum engineering; and the splitting of the plus fraction for EOS calculations.
This book presents new approaches that offer a better characterization of the interrelationship between crystalline and amorphous phases. In recent years, the use of dielectric spectroscopy has significantly improved our understanding of crystallization. The combination of modern scattering methods, using either synchrotron light or neutrons and infrared spectroscopy with dielectrics, is now helping to reveal modifications of both crystalline and amorphous phases. In turn, this yields insights into the underlying physics of the crystallization process in various materials, e.g. polymers, liquid crystals and diverse liquids. The book offers an excellent introduction to a valuable application of dielectric spectroscopy, and a helpful guide for every scientist who wants to study crystallization processes by means of dielectric spectroscopy.
This thesis presents the first ever measurement of the noise emitted by magnetic monopoles and the development of an exquisitely sensitive magnetic-field-noise spectrometer based on a superconducting quantum interference device (SQUID) that enabled it. Magnetic monopoles are highly elusive elementary particles exhibiting quantized magnetic charge. The prospects for studying them brightened recently with the theoretical discovery that the thermally excited states in certain classes of magnetic insulators exhibit all the characteristics of magnetic monopoles. Furthermore, in 2018, it was predicted that the random motion of magnetic monopoles inside would generate a very specific kind of magnetization noise. In this thesis, the author describes a new experimental technique, so-called spin noise spectroscopy, and the subsequent discovery of virtually all of the predicted features of the magnetic noise expected from a dense fluid of magnetic monopoles in crystals of Dy2Ti2O7. Remarkably, because this magnetic monopole noise occurs in the frequency range below 20kHz, when amplified by the SQUID it is actually audible to humans.
Light scattering from particles in the nanometric and micrometric size range is relevant in several research fields, such as aerosol science and nanotechnology. In many applications, the description of the optical properties of non-spherical, inhomogeneous particles is still inadequate or requires demanding numerical calculations. Lorenz-Mie scattering and effective medium approximations represent currently the main theoretical tools to model such particles, but their effectiveness has been recently called into question. This work examines how the morphology of a particle affects its scattering parameters from an experimental standpoint, supporting findings with extensive simulations. The dust content of Antarctic, Greenlandic, and Alpine ice cores is analysed with a particle-by-particle approach. Moreover, a study on colloidal aggregates shows that correlations among the fields radiated by primary particles are responsible for the poor agreement of effective medium approximations with experimental results. On the theoretical side, an interpretation in terms of the structure factor is given, which satisfactorily describes the data. The insights of this thesis are relevant for quantifying the contribution of mineral dust to the radiative energy balance of the Earth.
This book presents photoelectron spectroscopy as a valuable method for studying the electronic structures of various solid materials in the bulk state, on surfaces, and at buried interfaces. This second edition introduces the advanced technique of high-resolution and high-efficiency spin- and momentum-resolved photoelectron spectroscopy using a novel momentum microscope, enabling high-precision measurements down to a length scale of some tens of nanometers. The book also deals with fundamental concepts and approaches to applying this and other complementary techniques, such as inverse photoemission, photoelectron diffraction, scanning tunneling spectroscopy, as well as photon spectroscopy based on (soft) x-ray absorption and resonance inelastic (soft) x-ray scattering. This book is the ideal tool to expand readers' understanding of this marvelously versatile experimental method, as well as the electronic structures of metals and insulators.
This thesis focuses on experimental studies on collective motion using swimming bacteria as model active-matter systems. It offers comprehensive reviews of state-of-the-art theories and experiments on collective motion from the viewpoint of nonequilibrium statistical physics. The author presents his experimental studies on two major classes of collective motion that had been well studied theoretically. Firstly, swimming filamentous bacteria in a thin fluid layer are shown to exhibit true, long-range orientational order and anomalously strong giant density fluctuations, which are considered universal and landmark signatures of collective motion by many numerical and theoretical works but have never been observed in real systems. Secondly, chaotic bacterial turbulence in a three-dimensional dense suspension without any long-range order as described in the first half is demonstrated to be capable of achieving antiferromagnetic vortex order by imposing a small number of constraints with appropriate periodicity. The experimental results presented significantly advance our fundamental understanding of order and fluctuations in collective motion of motile elements and their future applications.
This book introduces the concepts of more electric aircraft and aviation electrical appliances, as well as the aviation experimental platform of vacuum switches, the interruption characteristics, frequency characteristics and post-arc breakdown characteristics of intermediate frequency vacuum switches, etc. It is the first monograph on protection electrical appliances, vacuum interrupter in aviation variable frequency power system. This book includes a lot of experimental process and chart analysis for readers to understand and provides references for practical engineering problems. This book could be used as references for engineers and technicians working on electric power systems in aircrafts.
This book covers a diverse cross section of this interdisciplinary research field, with contributions grouped into four categories: laser-induced filamentation; atoms and molecules in a laser field; interaction of solid materials with a coherent light field; and ion acceleration and ionization of atoms in super intense laser fields. This book series presents up-to-date reviews of advances in this interdisciplinary research field, spanning atomic and molecular physics, as well as molecular and optical science, which have been stimulated by the recent developments in ultrafast laser technologies. Each book compiles peer-reviewed articles by researchers at the forefront of their particular subfields. All the chapters include an overview to allow graduate students and researchers unfamiliar with the subfield to grasp the importance and attractions of the topic covered, followed by reports of cutting-edge discoveries.
This book addresses the fabrication of responsive functional nanomaterials and their use in sustainable energy and environmental applications. Responsive functional nanomaterials can change their physiochemical properties to adapt to their environment. Accordingly, these novel materials are playing an increasingly important role in a diverse range of applications, such as sensors and actuators, self-healing materials, separation, drug delivery, diagnostics, tissue engineering, functional coatings and textiles. This book reports on the latest advances in responsive functional nanomaterials in a wide range of applications and will appeal to a broad readership across the fields of materials, chemistry, sustainable energy, environmental science and nanotechnology.
This book presents different thermodynamic approaches in the area of constitutive theory: thermodynamics of irreversible processes, rational thermodynamics, and extended thermodynamics. These different approaches are analyzed with respect to their presuppositions, as well as to their results, and each method is applied to several important examples. In many cases these examples are archetypes for numerous technologically important materials; i.e. complex materials having an internal structure. Some of the examples dealt with in this book are liquid crystals, colloid suspensions, ans fiber suspensions. The book well serves students and researchers who have basic knowledge in continuum mechanics and thermodynamics. It provides a systematic overview of the vast field of thermodynamic constitutive theory, beginning from a historical perspective and concluding with outstanding questions in recent research.
This book reveals unique transport phenomena and functionalities in topological insulators coupled with magnetism and superconductivity. Topological insulators are a recently discovered class of materials that possess a spin-momentum-locked surface state. Their exotic spin texture makes them an exciting platform for investigating emergent phenomena, especially when coupled with magnetism or superconductivity. Focusing on the strong correlation between electricity and magnetism in magnetic topological insulators, the author presents original findings on current-direction-dependent nonreciprocal resistance, current-induced magnetization reversal and chiral edge conduction at the domain wall. In addition, he demonstrates how the coupling between superconductivity and topological surface state leads to substantial nonreciprocal resistance. The author also elucidates the origins of these phenomena and deepens readers' understanding of the topologically nontrivial electronic state. The book includes several works which are published in top journals and were selected for the President's Award by the University of Tokyo and for the Ikushi Prize, awarded to distinguished Ph.D. students in Japan.
This book summarizes and records the recent notable advances in diverse topics in organic crystal chemistry, which has made substantial progress along with the rapid development of a variety of analysis and measurement techniques for solid organic materials. This review book is one of the volumes that are published periodically on this theme. The previous volume, published in 2015, systematically summarized the remarkable progress in assorted topics of organic crystal chemistry using organic solids and organic-inorganic hybrid materials during the previous 5 years, and it has been widely read. The present volume also shows the progress of organic solid chemistry in the last 5 years, with contributions mainly by invited members of the Division of Organic Crystal Chemistry of the Chemical Society of Japan (CSJ), together with prominent invited authors from countries other than Japan.
This book highlights a series of new itinerant electron models proposed based on the experimental results of electron spectra obtained since 1970. Although conventional magnetic ordering models were established before 1960, many problems remain to be solved. The new models in this book include an O 2p itinerant electron model for magnetic oxides, a new itinerant electron model for magnetic metals, and a Weiss electron pair model for the origin of magnetic ordering energy of magnetic metals and oxides. With these models, the book explains typical magnetic ordering phenomena including those that cannot be explained using conventional models. These new models are easier to understand than the conventional magnetic ordering models.
This book highlights the latest advances in bioMEMS for biosensing applications. It comprehensively reviews different detection methods, including colorimetric, fluorescence, luminescence, bioluminescence, chemiluminescence, biochemiluminescence, and electrochemiluminescence, and presents various bioMEMS for each, together with recent examples. The book also offers an overview of the history of BioMEMS and the design and manufacture of the first bioMEMS-based devices.
Effects of many-body interactions and superconducting correlations have become central questions in the quantum transport community. While most previous works investigating current fluctuations in nanodevices have been restricted to the stationary regime, Seoane's thesis extends these studies to the time domain. It provides relevant information about the time onset of electronic correlations mediated by interactions and superconductivity. This knowledge is essential for the development of fast electronic devices, as well as novel applications requiring fast manipulations, such as quantum information processing. In addition, the thesis establishes contact with issues of broad current interest such as non-equilibrium quantum phase transitions.
This book presents the basics of superconductivity and applications of superconducting magnets. It explains the phenomenon of superconductivity, describes theories of superconductivity, and discusses type II and high-temperature cuprate superconductors. The main focus of the book is the application of superconducting magnets in accelerators, fusion reactors and other advanced applications such as nuclear magnetic resonance (NMR), magnetic resonance imaging (MRI), high-gradient magnetic separation (HGMS), and superconducting magnetic energy storage (SMES). This new and significantly extended second edition covers the state of the art in the development of novel superconductors for advanced magnet applications, as well as the production of practical superconducting wires, tapes, and ultra high current cables used for high-field magnets. It includes two new chapters each devoted to MgB2 and Fe-based superconductors, and discusses the recently developed and world record-setting 45.5-Tesla magnetic field generated by a combination of conventional and high-temperature cuprate superconducting magnets. In addition, it discusses the status and outlook of all current and future nuclear fusion reactors worldwide. The chapter on accelerators includes the ongoing efforts to build high luminosity LHC (HL-LHC), the high-energy 28 TeV LHC (HE-LHC), the future circular collider (FCC) at CERN, and the just launched electro-ion collider (EIC) at Brookhaven National Laboratory. The book is based on the long-standing experience of the author in studying superconducting materials, building magnets and delivering numerous lectures to research scholars and students. The book provides comprehensive and fundamental knowledge in the field of applied superconductivity, greatly benefiting researchers and graduate students wishing to learn more about the various aspects of superconductivity and advanced magnet applications. |
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