This book deals with the electro-chemo-mechanical properties characteristic of and unique to solid electrode surfaces, covering interfacial electrochemistry and surface science. Electrochemical reactions such as electro-sorption, electro-deposition or film growth on a solid electrode induce changes in surface stress or film stress that lead to transformation of the surface phase or alteration of the surface film. The properties of solid electrode surfaces associated with the correlation between electrochemical and mechanical phenomena are named "electro-chemo-mechanical properties". The book first derives the surface thermodynamics of solid electrodes as fundamentals for understanding the electro-chemo-mechanical properties. It also explains the powerful techniques for investigating the electro-chemo-mechanical properties, and reviews the arguments for derivation of surface thermodynamics of solid electrodes. Further, based on current experimental findings and theories, it discusses the importance of the contribution of surface stress to the transformation of surface phases, such as surface reconstruction and underpotential deposition in addition to the stress evolution during film growth and film reduction. Moreover, the book describes the nano-mechanical properties of solid surfaces measured by nano-indentation in relation to the electro-chemo-mechanical properties. This book makes a significant contribution to the further development of numerous fields, including electrocatalysis, materials science and corrosion science.

This book systematically reviews the history of lead-free piezoelectric materials, including the latest research. It also addresses a number of important issues, such as new types of materials prepared in a multitude of sizes, structural and physical properties, and potential applications for high-performance devices. Further, it examines in detail the state of the art in lead-free piezoelectric materials, focusing on the pathways to modify different structures and achieve enhanced physical properties and new functional behavior. Lastly, it discusses the prospects for potential future developments in lead-free piezoelectric materials across disciplines and for multifunctional applications. Given its breadth of coverage, the book offers a comprehensive resource for graduate students, academic researchers, development scientists, materials producers, device designers and applications engineers who are working on or are interested in advanced lead-free piezoelectric materials.

The book reviews photosynthetic water oxidation and proton-coupled electron transfer in photosystem, focusing on the molecular vibrations of amino acid residues and water molecules. Photosynthetic water oxidation performed by plants and cyanobacteria is essential for the sustenance of life on Earth, not only as an electron source for synthesizing sugars from CO2, but also as an O2 source in the atmosphere. Water oxidation takes place at the Mn4CaO5 cluster in photosystem II, where a series of electron transfer reactions coupled with proton transfer occur using light energy. The author addresses the unresolved mechanisms of photosynthetic water oxidation and relevant proton-coupled electron transfer reactions using a combined approach of experimental and computational methods such as Fourier transform infrared difference spectroscopy and quantum chemical calculations. The results show that protonation and hydrogen-bond structures of water molecules and amino acid residues in the protein play important roles in regulation of the electron and proton transfer reactions. These findings and the methodology make a significant contribution to our understanding the molecular mechanism of photosynthetic water oxidation.

This significantly extended second edition addresses the important physical phenomenon of Surface Plasmon Resonance (SPR) or Surface Plasmon Polaritons (SPP) in thin metal films, a phenomenon which is exploited in the design of a large variety of physico-chemical optical sensors. In this treatment, crucial materials aspects for design and optimization of SPR sensors are investigated and described in detail. The text covers a selection of nanometer thin metal films, ranging from free-electron to the platinum-type conductors, along with their combination with a large variety of dielectric substrate materials, and associated individual layer and opto-geometric arrangements. Whereas the first edition treated solely the metal-liquid interface, the SP-resonance conditions considered here are expanded to cover the metal-gas interface in the angular and wavelength interrogation modes, localized and long-range SP's and the influence of native oxidic ad-layers in the case of non-noble metals. Furthermore, a selection of metal grating structures that allow SP excitation is presented, as are features of radiative SP's. Finally, this treatise includes as-yet hardly explored SPR features of selected metal-metal and metal-dielectric superlattices. An in-depth multilayer Fresnel evaluation provides the mathematical tool for this optical analysis, which otherwise relies solely on experimentally determined electro-optical materials parameters.

This interdisciplinary work on condensed matter physics, the continuum mechanics of novel materials, and partial differential equations, discusses the mathematical theory of elasticity and hydrodynamics of quasicrystals, as well as its applications. By establishing new partial differential equations of higher order and their solutions under complicated boundary value and initial value conditions, the theories developed here dramatically simplify the solution of complex elasticity problems. Comprehensive and detailed mathematical derivations guide readers through the work. By combining theoretical analysis and experimental data, mathematical studies and practical applications, readers will gain a systematic, comprehensive and in-depth understanding of condensed matter physics, new continuum mechanics and applied mathematics. This new edition covers the latest developments in quasicrystal studies. In particular, it pays special attention to the hydrodynamics, soft-matter quasicrystals, and the Poisson bracket method and its application in deriving hydrodynamic equations. These new sections make the book an even more useful and comprehensive reference guide for researchers working in Condensed Matter Physics, Chemistry and Materials Science.

This book highlights a novel and holistic approach to multiscaled PVA bionanocomposite films used for electrical sensing, medical and packaging applications. With a combination of material characterization and modeling to understand the effect of nanoparticle size and shape, as well as 3D interphase properties and features such as interphase modulus and nanoscale dimensions, this book substantiates how excellent mechanical and thermal properties of these materials are achieved. Also it addresses the importance of using economical and ecofriendly bionanocomposites as potential green materials to support the goal of environmental sustainability with multifunctional properties.

This textbook explains the physics of phase transformation and associated constraints from a metallurgical or materials science point of view, based on many topics including crystallography, mass transport by diffusion, thermodynamics, heat transfer and related temperature gradients, thermal deformation, and even fracture mechanics. The work presented emphasizes solidification and related analytical models based on heat transfer. This corresponds with the most fundamental physical event of continuous evolution of latent heat of fusion for directional or non-directional liquid-to-solid phase transformation at a specific interface with a certain geometrical shape, such as planar or curved front. Dr. Perez introduces mathematical and engineering approximation schemes for describing the phase transformation, mainly during solidification of pure metals and alloys. Giving clear definitions and explanations of theoretical concepts and full detail of derivation of formulae, this interdisciplinary volume is ideal for graduate and upper-level undergraduate students in applied science, and professionals in the metal making and surface reconstruction industries.

Advancing the experimental study of superfluids relies on increasingly sophisticated techniques. We develop and demonstrate the loading of Bose-Einstein condensates (BECs) into nearly arbitrary trapping potentials, with a resolution improved by a factor of seven when compared to reported systems. These advanced control techniques have since been adopted by several cold atoms labs around the world. How this BEC system was used to study 2D superfluid dynamics is described. In particular, negative temperature vortex states in a two-dimensional quantum fluid were observed. These states were first predicted by Lars Onsager 70 years ago and have significance to 2D turbulence in quantum and classical fluids, long-range interacting systems, and defect dynamics in high-energy physics. These experiments have established dilute-gas BECs as the prototypical system for the experimental study of point vortices and their nonequilibrium dynamics. We also developed a new approach to superfluid circuitry based on classical acoustic circuits, demonstrating its conceptual and quantitative superiority over previous lumped-element models. This has established foundational principles of superfluid circuitry that will impact the design of future transport experiments and new generation quantum devices, such as atomtronics circuits and superfluid sensors.

This book introduces readers to experimental techniques of general utility that can be used to practically and reliably determine nucleation rates. It also covers the basics of gas hydrates, phase equilibria, nucleation theory, crystal growth, and interfacial gaseous states. Given its scope, the book will be of interest to graduate students and researchers in the field of hydrate nucleation. The formation of gas hydrates is a first-order phase transition that begins with nucleation. Understanding nucleation is of interest to many working in the chemical and petroleum industry, since nucleation, while beneficial in many chemical processes, is also a concern in terms of flow assurance for oil and natural gas pipelines. A primary difficulty in the investigation of gas hydrate nucleation has been researchers' inability to determine and compare the nucleation rates of gas hydrates across systems with different scales and levels of complexity, which in turn has limited their ability to study the nucleation process itself. This book introduces readers to experimental techniques that can be used to practically and reliably determine the nucleation rates of gas hydrate systems. It also covers the basics of gas hydrates, phase equilibria, nucleation theory, crystal growth, and interfacial gaseous states. Given its scope, the book will be of interest to graduate students and researchers in the field of hydrate nucleation.

This book is for engineers and students to solve issues concerning the fluidized bed systems. It presents an analysis that focuses directly on the problem of predicting the fluid dynamic behavior which empirical data is limited or unavailable. The second objective is to provide a treatment of computational fluidization dynamics that is readily accessible to the non-specialist. The approach adopted in this book, starting with the formulation of predictive expressions for the basic conservation equations for mass and momentum using kinetic theory of granular flow. The analyses presented in this book represent a body of simulations and experiments research that has appeared in numerous publications over the last 20 years. This material helps to form the basis for university course modules in engineering and applied science at undergraduate and graduate level, as well as focused, post-experienced courses for the process, and allied industries.

The extended and revised edition of this textbook provides essential information for a comprehensive upper-level graduate course on the crystalline growth of semiconductor heterostructures. Heteroepitaxy is the basis of today's advanced electronic and optoelectronic devices, and it is considered one of the most important fields in materials research and nanotechnology. The book discusses the structural and electronic properties of strained epitaxial layers, the thermodynamics and kinetics of layer growth, and it describes the major growth techniques: metalorganic vapor-phase epitaxy, molecular-beam epitaxy, and liquid-phase epitaxy. It also examines in detail cubic and hexagonal semiconductors, strain relaxation by misfit dislocations, strain and confinement effects on electronic states, surface structures, and processes during nucleation and growth. Requiring only minimal knowledge of solid-state physics, it provides natural sciences, materials science and electrical engineering students and their lecturers elementary introductions to the theory and practice of epitaxial growth, supported by references and over 300 detailed illustrations. In this second edition, many topics have been extended and treated in more detail, e.g. in situ growth monitoring, application of surfactants, properties of dislocations and defects in organic crystals, and special growth techniques like vapor-liquid-solid growth of nanowires and selective-area epitaxy.

This book puts forward a modern classification theory for superconducting gap nodes, whose structures can be observed by experiments and are essential for understanding unconventional superconductivity. In the first part of the book, the classification method, based on group theory and K theory, is introduced in a step-by-step, pedagogical way. In turn, the latter part presents comprehensive classification tables, which include various nontrivial gap (node) structures, which are not predicted by the Sigrist-Ueda method, but are by the new method. The results obtained here show that crystal symmetry and/or angular momentum impose critical constraints on the superconducting gap structures. Lastly, the book lists a range of candidate superconductors for the nontrivial gap nodes. The classification methods and tables presented here offer an essential basis for further investigations into unconventional superconductivity. They indicate that previous experimental studies should be reinterpreted, while future experiments should reflect the new excitation spectrum.

This book presents the basics and methods of nanoscale analytical techniques for tribology field. It gives guidance to the application of mechanical, microstructural, chemical characterization methods and topography analysis of materials. It provides an overview of the of state-of-the-art for researchers and practitioners in the field of tribology. It shows different examples to the application of mechanical, microstructural, chemical characterization methods and topography analysis of materials. Friction and Wear phenomena are governed by complexe processes at the interface of sliding surfaces. For a detailed understanding of these phenomena many surface sensitive techniques have become available in recent years. The applied methods are atom probe tomography, in situ TEM, SERS, NEXAFS, in situ XPS, nanoindentation and in situ Raman spectroscopy. A survey of new related numerical calculations completes this book. This concerns ab-initio coupling, numerical calculations for mechanical aspects and density functional theory (DFT) to study chemical reactivity.

This book explores several key issues in beam phase space dynamics in plasma-based wakefield accelerators. It reveals the phase space dynamics of ionization-based injection methods by identifying two key phase mixing processes. Subsequently, the book proposes a two-color laser ionization injection scheme for generating high-quality beams, and assesses it using particle-in-cell (PIC) simulations. To eliminate emittance growth when the beam propagates between plasma accelerators and traditional accelerator components, a method using longitudinally tailored plasma structures as phase space matching components is proposed. Based on the aspects above, a preliminary design study on X-ray free-electron lasers driven by plasma accelerators is presented. Lastly, an important type of numerical noise-the numerical Cherenkov instabilities in particle-in-cell codes-is systematically studied.

This book discusses non-equilibrium quantum many-body dynamics, recently explored in an analog quantum simulator of strongly correlated ultracold atoms. The first part presents a field-theoretical analysis of the experimental observability of the Higgs amplitude mode that emerges as a relativistic collective excitation near a quantum phase transition of superfluid Bose gases in an optical lattice potential. The author presents the dynamical susceptibilities to external driving of the microscopic parameters, taking into account a leading-order perturbative correction from quantum and thermal fluctuations and shows clear signatures of the Higgs mode in these observables. This is the first result that strongly supports the stability of the Higgs mode in three-dimensional optical lattices even in the presence of a spatially inhomogeneous confinement potential and paves the way for desktop observations of the Higgs mode. In the second part, the author applies the semi-classical truncated-Wigner approximation (TWA) to far-from-equilibrium quantum dynamics. Specifically, he considers the recent experiments on quantum-quench dynamics in a Bose-Hubbard quantum simulator. A direct comparison shows remarkable agreement between the numerical results from TWA and the experimental data. This result clearly indicates the potential of such a semi-classical approach in reliably simulating many-body systems using classical computers. The book also includes several chapters providing comprehensive reviews of the recent studies on cold-atomic quantum simulation and various theoretical methods, including the Schwinger-boson approach in strongly correlated systems and the phase-space semi-classical method for far-from-equilibrium quantum dynamics. These chapters are highly recommended to students and young researchers who are interested in semi-classical approaches in non-equilibrium quantum dynamics.

This monograph presents an intuitive theory of trial wave functions for strongly interacting fermions in fractional quantum Hall states. The correlation functions for the proposed fermion interactions follow a novel algebraic approach that harnesses the classical theory of invariants and semi-invariants of binary forms. This approach can be viewed as a fitting and far-reaching generalization of Laughlin's approach to trial wave functions. Aesthetically viewed, it illustrates an attractive symbiosis between the theory of invariants and the theory of correlations. Early research into numerical diagonalization computations for small numbers of electrons shows strong agreement with the constructed trial wave functions.The monograph offers researchers and students of condensed matter physics an accessible discussion of this interesting area of research.

This book, written by key researchers in the field, provides a comprehensive analysis and overview of the state of the art of plasma-based cancer therapy. Recent progress in atmospheric plasmas has led to non-thermal or cold atmospheric plasma (CAP) devices with ion temperatures close to room temperature. In contrast to many existing anti-cancer approaches, CAP is a selective anti-cancer modality which has demonstrated significant potential in cancer therapy.Written by a global, cross-disciplinary group of leading researchers, this book covers basic theory, generation, diagnostics, and simulation of cold atmospheric plasma, as well as their clinical application in cancer therapy, immunotherapy, and future outlook, giving a complete picture of the field. It is meant for a broad audience, from students to engineers and scientists, who are interested in the emerging world of plasma medical applications. It presents recent advances, primary challenges, and future directions of this exciting, cutting-edge field.

This volume is the third edition of the first-ever elementary book on the Langevin equation method for the solution of problems involving the translational and rotational Brownian motion of particles and spins in a potential highlighting modern applications in physics, chemistry, electrical engineering, and so on. In order to improve the presentation, to accommodate all the new developments, and to appeal to the specialized interests of the various communities involved, the book has been extensively rewritten and a very large amount of new material has been added. This has been done in order to present a comprehensive overview of the subject emphasizing via a synergetic approach that seemingly unrelated physical problems involving random noise may be described using virtually identical mathematical methods in the spirit of the founders of the subject, viz., Einstein, Langevin, Smoluchowski, Kramers, etc. The book has been written in such a way that all the material should be accessible both to an advanced researcher and a beginning graduate student. It draws together, in a coherent fashion, a variety of results which have hitherto been available only in the form of scattered research papers and review articles.

On the 40th anniversary of the Beresinskii-Kosterlitz-Thouless Theory (BKT), this informative volume looks back at some of the developments and achievements and varied physics applications which ensued from the beautiful BKT vortex-unbinding seminal idea. During the last four decades, BKT theory, which is undeniably one of the most important developments in condensed matter and theoretical physics of the second half of the twentieth century, has expanded widely. It has been used and extended from many different theoretical and experimental perspectives. New and unexpected features have been uncovered from the BKT theory. Since its inception, apart from applications in condensed matter physics, the theory has been actively applied in other branches of physics, such as high energy physics, atomic physics, nuclear physics, statistical physics, nonlinear systems, etc. This makes the theory an indispensable topic for all who are involved in physics. An international team of experts, each of whom has left his mark on the developments of this remarkable theory and experimental applications, contribute both historical essays and more detailed current technical and experimental accounts to this volume. These articles highlight the new discoveries from the respective authors' perspectives. This unique volume celebrates the impact over four decades of the BKT theory on modern physics. In addition to the historical perspective provided by Kosterlitz and Thouless's overview, the volume provides a comprehensive description of experimental and theoretical applications and extensions of the BKT theory.

This textbook presents all the mathematical and physical concepts needed to visualize and understand representation surfaces, providing readers with a reliable and intuitive understanding of the behavior and properties of anisotropic materials, and a sound grasp of the directionality of material properties. They will learn how to extract quantitative information from representation surfaces, which encode tremendous amounts of information in a very concise way, making them especially useful in understanding higher order tensorial material properties (piezoelectric moduli, elastic compliance and rigidity, etc.) and in the design of applications based on these materials. Readers will also learn from scratch concepts on crystallography, symmetry and Cartesian tensors, which are essential for understanding anisotropic materials, their design and application. The book describes how to apply representation surfaces to a diverse range of material properties, making it a valuable resource for material scientists, mechanical engineers, and solid state physicists, as well as advanced undergraduates in Materials Science, Solid State Physics, Electronics, Optics, Mechanical Engineering, Composites and Polymer Science. Moreover, the book includes a wealth of worked-out examples, problems and exercises to help further understanding.

This book addresses problems in three main developments in modern condensed matter physics- namely topological superconductivity, many-body localization and strongly interacting condensates/superfluids-by employing fruitful analogies from classical mechanics. This strategy has led to tangible results, firstly in superconducting nanowires: the density of states, a smoking gun for the long sought Majorana zero mode is calculated effortlessly by mapping the problem to a textbook-level classical point particle problem. Secondly, in localization theory even the simplest toy models that exhibit many-body localization are mathematically cumbersome and results rely on simulations that are limited by computational power. In this book an alternative viewpoint is developed by describing many-body localization in terms of quantum rotors that have incommensurate rotation frequencies, an exactly solvable system. Finally, the fluctuations in a strongly interacting Bose condensate and superfluid, a notoriously difficult system to analyze from first principles, are shown to mimic stochastic fluctuations of space-time due to quantum fields. This analogy not only allows for the computation of physical properties of the fluctuations in an elegant way, it sheds light on the nature of space-time. The book will be a valuable contribution for its unifying style that illuminates conceptually challenging developments in condensed matter physics and its use of elegant mathematical models in addition to producing new and concrete results.

This thesis presents the application of non-perturbative, or functional, renormalization group to study the physics of critical stationary states in systems out-of-equilibrium. Two different systems are thereby studied. The first system is the diffusive epidemic process, a stochastic process which models the propagation of an epidemic within a population. This model exhibits a phase transition peculiar to out-of-equilibrium, between a stationary state where the epidemic is extinct and one where it survives. The present study helps to clarify subtle issues about the underlying symmetries of this process and the possible universality classes of its phase transition. The second system is fully developed homogeneous isotropic and incompressible turbulence. The stationary state of this driven-dissipative system shows an energy cascade whose phenomenology is complex, with partial scale-invariance, intertwined with what is called intermittency. In this work, analytical expressions for the space-time dependence of multi-point correlation functions of the turbulent state in 2- and 3-D are derived. This result is noteworthy in that it does not rely on phenomenological input except from the Navier-Stokes equation and that it becomes exact in the physically relevant limit of large wave-numbers. The obtained correlation functions show how scale invariance is broken in a subtle way, related to intermittency corrections.

This book advances understanding of light-induced phase transitions and nonequilibrium orders that occur in a broken-symmetry system. Upon excitation with an intense laser pulse, materials can undergo a nonthermal transition through pathways different from those in equilibrium. The mechanism underlying these photoinduced phase transitions has long been researched, but many details in this ultrafast, non-adiabatic regime still remain to be clarified. The work in this book reveals new insights into this phenomena via investigation of photoinduced melting and recovery of charge density waves (CDWs). Using several time-resolved diffraction and spectroscopic techniques, the author shows that the light-induced melting of a CDW is characterized by dynamical slowing-down, while the restoration of the symmetry-breaking order features two distinct timescales: A fast recovery of the CDW amplitude is followed by a slower re-establishment of phase coherence, the latter of which is dictated by the presence of topological defects in the CDW. Furthermore, after the suppression of the original CDW by photoexcitation, a different, competing CDW transiently emerges, illustrating how a hidden order in equilibrium can be unleashed by a laser pulse. These insights into CDW systems may be carried over to other broken-symmetry states, such as superconductivity and magnetic ordering, bringing us one step closer towards manipulating phases of matter using a laser pulse.