This book systematically reviews the history of lead-free piezoelectric materials, including the latest research. It also addresses a number of important issues, such as new types of materials prepared in a multitude of sizes, structural and physical properties, and potential applications for high-performance devices. Further, it examines in detail the state of the art in lead-free piezoelectric materials, focusing on the pathways to modify different structures and achieve enhanced physical properties and new functional behavior. Lastly, it discusses the prospects for potential future developments in lead-free piezoelectric materials across disciplines and for multifunctional applications. Given its breadth of coverage, the book offers a comprehensive resource for graduate students, academic researchers, development scientists, materials producers, device designers and applications engineers who are working on or are interested in advanced lead-free piezoelectric materials.

This significantly extended second edition addresses the important physical phenomenon of Surface Plasmon Resonance (SPR) or Surface Plasmon Polaritons (SPP) in thin metal films, a phenomenon which is exploited in the design of a large variety of physico-chemical optical sensors. In this treatment, crucial materials aspects for design and optimization of SPR sensors are investigated and described in detail. The text covers a selection of nanometer thin metal films, ranging from free-electron to the platinum-type conductors, along with their combination with a large variety of dielectric substrate materials, and associated individual layer and opto-geometric arrangements. Whereas the first edition treated solely the metal-liquid interface, the SP-resonance conditions considered here are expanded to cover the metal-gas interface in the angular and wavelength interrogation modes, localized and long-range SP's and the influence of native oxidic ad-layers in the case of non-noble metals. Furthermore, a selection of metal grating structures that allow SP excitation is presented, as are features of radiative SP's. Finally, this treatise includes as-yet hardly explored SPR features of selected metal-metal and metal-dielectric superlattices. An in-depth multilayer Fresnel evaluation provides the mathematical tool for this optical analysis, which otherwise relies solely on experimentally determined electro-optical materials parameters.

This textbook explains the physics of phase transformation and associated constraints from a metallurgical or materials science point of view, based on many topics including crystallography, mass transport by diffusion, thermodynamics, heat transfer and related temperature gradients, thermal deformation, and even fracture mechanics. The work presented emphasizes solidification and related analytical models based on heat transfer. This corresponds with the most fundamental physical event of continuous evolution of latent heat of fusion for directional or non-directional liquid-to-solid phase transformation at a specific interface with a certain geometrical shape, such as planar or curved front. Dr. Perez introduces mathematical and engineering approximation schemes for describing the phase transformation, mainly during solidification of pure metals and alloys. Giving clear definitions and explanations of theoretical concepts and full detail of derivation of formulae, this interdisciplinary volume is ideal for graduate and upper-level undergraduate students in applied science, and professionals in the metal making and surface reconstruction industries.

This monograph presents an intuitive theory of trial wave functions for strongly interacting fermions in fractional quantum Hall states. The correlation functions for the proposed fermion interactions follow a novel algebraic approach that harnesses the classical theory of invariants and semi-invariants of binary forms. This approach can be viewed as a fitting and far-reaching generalization of Laughlin's approach to trial wave functions. Aesthetically viewed, it illustrates an attractive symbiosis between the theory of invariants and the theory of correlations. Early research into numerical diagonalization computations for small numbers of electrons shows strong agreement with the constructed trial wave functions.The monograph offers researchers and students of condensed matter physics an accessible discussion of this interesting area of research.

Advancing the experimental study of superfluids relies on increasingly sophisticated techniques. We develop and demonstrate the loading of Bose-Einstein condensates (BECs) into nearly arbitrary trapping potentials, with a resolution improved by a factor of seven when compared to reported systems. These advanced control techniques have since been adopted by several cold atoms labs around the world. How this BEC system was used to study 2D superfluid dynamics is described. In particular, negative temperature vortex states in a two-dimensional quantum fluid were observed. These states were first predicted by Lars Onsager 70 years ago and have significance to 2D turbulence in quantum and classical fluids, long-range interacting systems, and defect dynamics in high-energy physics. These experiments have established dilute-gas BECs as the prototypical system for the experimental study of point vortices and their nonequilibrium dynamics. We also developed a new approach to superfluid circuitry based on classical acoustic circuits, demonstrating its conceptual and quantitative superiority over previous lumped-element models. This has established foundational principles of superfluid circuitry that will impact the design of future transport experiments and new generation quantum devices, such as atomtronics circuits and superfluid sensors.

This book is for engineers and students to solve issues concerning the fluidized bed systems. It presents an analysis that focuses directly on the problem of predicting the fluid dynamic behavior which empirical data is limited or unavailable. The second objective is to provide a treatment of computational fluidization dynamics that is readily accessible to the non-specialist. The approach adopted in this book, starting with the formulation of predictive expressions for the basic conservation equations for mass and momentum using kinetic theory of granular flow. The analyses presented in this book represent a body of simulations and experiments research that has appeared in numerous publications over the last 20 years. This material helps to form the basis for university course modules in engineering and applied science at undergraduate and graduate level, as well as focused, post-experienced courses for the process, and allied industries.

The extended and revised edition of this textbook provides essential information for a comprehensive upper-level graduate course on the crystalline growth of semiconductor heterostructures. Heteroepitaxy is the basis of today's advanced electronic and optoelectronic devices, and it is considered one of the most important fields in materials research and nanotechnology. The book discusses the structural and electronic properties of strained epitaxial layers, the thermodynamics and kinetics of layer growth, and it describes the major growth techniques: metalorganic vapor-phase epitaxy, molecular-beam epitaxy, and liquid-phase epitaxy. It also examines in detail cubic and hexagonal semiconductors, strain relaxation by misfit dislocations, strain and confinement effects on electronic states, surface structures, and processes during nucleation and growth. Requiring only minimal knowledge of solid-state physics, it provides natural sciences, materials science and electrical engineering students and their lecturers elementary introductions to the theory and practice of epitaxial growth, supported by references and over 300 detailed illustrations. In this second edition, many topics have been extended and treated in more detail, e.g. in situ growth monitoring, application of surfactants, properties of dislocations and defects in organic crystals, and special growth techniques like vapor-liquid-solid growth of nanowires and selective-area epitaxy.

This volume is the third edition of the first-ever elementary book on the Langevin equation method for the solution of problems involving the translational and rotational Brownian motion of particles and spins in a potential highlighting modern applications in physics, chemistry, electrical engineering, and so on. In order to improve the presentation, to accommodate all the new developments, and to appeal to the specialized interests of the various communities involved, the book has been extensively rewritten and a very large amount of new material has been added. This has been done in order to present a comprehensive overview of the subject emphasizing via a synergetic approach that seemingly unrelated physical problems involving random noise may be described using virtually identical mathematical methods in the spirit of the founders of the subject, viz., Einstein, Langevin, Smoluchowski, Kramers, etc. The book has been written in such a way that all the material should be accessible both to an advanced researcher and a beginning graduate student. It draws together, in a coherent fashion, a variety of results which have hitherto been available only in the form of scattered research papers and review articles.

This book puts forward a modern classification theory for superconducting gap nodes, whose structures can be observed by experiments and are essential for understanding unconventional superconductivity. In the first part of the book, the classification method, based on group theory and K theory, is introduced in a step-by-step, pedagogical way. In turn, the latter part presents comprehensive classification tables, which include various nontrivial gap (node) structures, which are not predicted by the Sigrist-Ueda method, but are by the new method. The results obtained here show that crystal symmetry and/or angular momentum impose critical constraints on the superconducting gap structures. Lastly, the book lists a range of candidate superconductors for the nontrivial gap nodes. The classification methods and tables presented here offer an essential basis for further investigations into unconventional superconductivity. They indicate that previous experimental studies should be reinterpreted, while future experiments should reflect the new excitation spectrum.

On the 40th anniversary of the Beresinskii-Kosterlitz-Thouless Theory (BKT), this informative volume looks back at some of the developments and achievements and varied physics applications which ensued from the beautiful BKT vortex-unbinding seminal idea. During the last four decades, BKT theory, which is undeniably one of the most important developments in condensed matter and theoretical physics of the second half of the twentieth century, has expanded widely. It has been used and extended from many different theoretical and experimental perspectives. New and unexpected features have been uncovered from the BKT theory. Since its inception, apart from applications in condensed matter physics, the theory has been actively applied in other branches of physics, such as high energy physics, atomic physics, nuclear physics, statistical physics, nonlinear systems, etc. This makes the theory an indispensable topic for all who are involved in physics. An international team of experts, each of whom has left his mark on the developments of this remarkable theory and experimental applications, contribute both historical essays and more detailed current technical and experimental accounts to this volume. These articles highlight the new discoveries from the respective authors' perspectives. This unique volume celebrates the impact over four decades of the BKT theory on modern physics. In addition to the historical perspective provided by Kosterlitz and Thouless's overview, the volume provides a comprehensive description of experimental and theoretical applications and extensions of the BKT theory.

This book covers newly emerging two-dimensional nanomaterials which have been recently used for the purpose of water purification. It focuses on the synthesis methods of 2D materials and answers how scientists/engineers/nanotechnologist/environmentalists could use these materials for fabricating new separation membranes and most probably making commercially feasible technology. The chapters are written by a collection of international experts ensuring a broad view of each topic. The book will be of interest to experienced researchers as well as young scientists looking for an introduction into 2D materials-based cross-disciplinary research.

This book presents the most important advances in the class of topological materials and discusses the topological characterization, modeling and metrology of materials. Further, it addresses currently emerging characterization techniques such as optical and acoustic, vibrational spectroscopy (Brillouin, infrared, Raman), electronic, magnetic, fluorescence correlation imaging, laser lithography, small angle X-ray and neutron scattering and other techniques, including site-selective nanoprobes. The book analyzes the topological aspects to identify and quantify these effects in terms of topology metrics. The topological materials are ubiquitous and range from (i) de novo nanoscale allotropes of carbons in various forms such as nanotubes, nanorings, nanohorns, nanowalls, peapods, graphene, etc. to (ii) metallo-organic frameworks, (iii) helical gold nanotubes, (iv) Moebius conjugated polymers, (v) block co-polymers, (vi) supramolecular assemblies, to (vii) a variety of biological and soft-matter systems, e.g. foams and cellular materials, vesicles of different shapes and genera, biomimetic membranes, and filaments, (viii) topological insulators and topological superconductors, (ix) a variety of Dirac materials including Dirac and Weyl semimetals, as well as (x) knots and network structures. Topological databases and algorithms to model such materials have been also established in this book. In order to understand and properly characterize these important emergent materials, it is necessary to go far beyond the traditional paradigm of microscopic structure-property-function relationships to a paradigm that explicitly incorporates topological aspects from the outset to characterize and/or predict the physical properties and currently untapped functionalities of these advanced materials. Simulation and modeling tools including quantum chemistry, molecular dynamics, 3D visualization and tomography are also indispensable. These concepts have found applications in condensed matter physics, materials science and engineering, physical chemistry and biophysics, and the various topics covered in the book have potential applications in connection with novel synthesis techniques, sensing and catalysis. As such, the book offers a unique resource for graduate students and researchers alike.

This new edition provides a state-of-the-art survey of ellipsometric methods used to study organic films and surfaces, from laboratory to synchrotron applications, with a special focus on in-situ use in processing environments and at solid-liquid interfaces. Thanks to the development of functional organic, meta- and hybrid materials for new optical, electronic, sensing and biotechnological devices, the ellipsometric analysis of optical and material properties has made tremendous strides over the past few years. The second edition has been updated to reflect the latest advances in ellipsometric methods. The new content focuses on the study of anisotropic materials, conjugated polymers, polarons, self-assembled monolayers, industrial membranes, adsorption of proteins, enzymes and RGD-peptides, as well as the correlation of ellipsometric spectra to structure and molecular interactions.

This book, written by key researchers in the field, provides a comprehensive analysis and overview of the state of the art of plasma-based cancer therapy. Recent progress in atmospheric plasmas has led to non-thermal or cold atmospheric plasma (CAP) devices with ion temperatures close to room temperature. In contrast to many existing anti-cancer approaches, CAP is a selective anti-cancer modality which has demonstrated significant potential in cancer therapy.Written by a global, cross-disciplinary group of leading researchers, this book covers basic theory, generation, diagnostics, and simulation of cold atmospheric plasma, as well as their clinical application in cancer therapy, immunotherapy, and future outlook, giving a complete picture of the field. It is meant for a broad audience, from students to engineers and scientists, who are interested in the emerging world of plasma medical applications. It presents recent advances, primary challenges, and future directions of this exciting, cutting-edge field.

This textbook presents all the mathematical and physical concepts needed to visualize and understand representation surfaces, providing readers with a reliable and intuitive understanding of the behavior and properties of anisotropic materials, and a sound grasp of the directionality of material properties. They will learn how to extract quantitative information from representation surfaces, which encode tremendous amounts of information in a very concise way, making them especially useful in understanding higher order tensorial material properties (piezoelectric moduli, elastic compliance and rigidity, etc.) and in the design of applications based on these materials. Readers will also learn from scratch concepts on crystallography, symmetry and Cartesian tensors, which are essential for understanding anisotropic materials, their design and application. The book describes how to apply representation surfaces to a diverse range of material properties, making it a valuable resource for material scientists, mechanical engineers, and solid state physicists, as well as advanced undergraduates in Materials Science, Solid State Physics, Electronics, Optics, Mechanical Engineering, Composites and Polymer Science. Moreover, the book includes a wealth of worked-out examples, problems and exercises to help further understanding.

This book addresses problems in three main developments in modern condensed matter physics- namely topological superconductivity, many-body localization and strongly interacting condensates/superfluids-by employing fruitful analogies from classical mechanics. This strategy has led to tangible results, firstly in superconducting nanowires: the density of states, a smoking gun for the long sought Majorana zero mode is calculated effortlessly by mapping the problem to a textbook-level classical point particle problem. Secondly, in localization theory even the simplest toy models that exhibit many-body localization are mathematically cumbersome and results rely on simulations that are limited by computational power. In this book an alternative viewpoint is developed by describing many-body localization in terms of quantum rotors that have incommensurate rotation frequencies, an exactly solvable system. Finally, the fluctuations in a strongly interacting Bose condensate and superfluid, a notoriously difficult system to analyze from first principles, are shown to mimic stochastic fluctuations of space-time due to quantum fields. This analogy not only allows for the computation of physical properties of the fluctuations in an elegant way, it sheds light on the nature of space-time. The book will be a valuable contribution for its unifying style that illuminates conceptually challenging developments in condensed matter physics and its use of elegant mathematical models in addition to producing new and concrete results.

Superfluid helium is a quantum liquid that exhibits a range of counter-intuitive phenomena such as frictionless flow. Quantized vortices are a particularly important feature of superfluid helium, and all superfluids, characterized by a circulation that can only take prescribed integer values. However, the strong interactions between atoms in superfluid helium prohibit quantitative theory of vortex behaviour. Experiments have similarly not been able to observe coherent vortex dynamics. This thesis resolves this challenge, bringing microphotonic techniques to bear on two-dimensional superfluid helium, observing coherent vortex dynamics for the first time, and achieving this on a silicon chip. This represents a major scientific contribution, as it opens the door not only to providing a better understanding of this esoteric quantum state of matter, but also to building new quantum technologies based upon it, and to understanding the dynamics of astrophysical superfluids such as those thought to exist in the core of neutron stars.

This thesis presents the application of non-perturbative, or functional, renormalization group to study the physics of critical stationary states in systems out-of-equilibrium. Two different systems are thereby studied. The first system is the diffusive epidemic process, a stochastic process which models the propagation of an epidemic within a population. This model exhibits a phase transition peculiar to out-of-equilibrium, between a stationary state where the epidemic is extinct and one where it survives. The present study helps to clarify subtle issues about the underlying symmetries of this process and the possible universality classes of its phase transition. The second system is fully developed homogeneous isotropic and incompressible turbulence. The stationary state of this driven-dissipative system shows an energy cascade whose phenomenology is complex, with partial scale-invariance, intertwined with what is called intermittency. In this work, analytical expressions for the space-time dependence of multi-point correlation functions of the turbulent state in 2- and 3-D are derived. This result is noteworthy in that it does not rely on phenomenological input except from the Navier-Stokes equation and that it becomes exact in the physically relevant limit of large wave-numbers. The obtained correlation functions show how scale invariance is broken in a subtle way, related to intermittency corrections.

This book advances understanding of light-induced phase transitions and nonequilibrium orders that occur in a broken-symmetry system. Upon excitation with an intense laser pulse, materials can undergo a nonthermal transition through pathways different from those in equilibrium. The mechanism underlying these photoinduced phase transitions has long been researched, but many details in this ultrafast, non-adiabatic regime still remain to be clarified. The work in this book reveals new insights into this phenomena via investigation of photoinduced melting and recovery of charge density waves (CDWs). Using several time-resolved diffraction and spectroscopic techniques, the author shows that the light-induced melting of a CDW is characterized by dynamical slowing-down, while the restoration of the symmetry-breaking order features two distinct timescales: A fast recovery of the CDW amplitude is followed by a slower re-establishment of phase coherence, the latter of which is dictated by the presence of topological defects in the CDW. Furthermore, after the suppression of the original CDW by photoexcitation, a different, competing CDW transiently emerges, illustrating how a hidden order in equilibrium can be unleashed by a laser pulse. These insights into CDW systems may be carried over to other broken-symmetry states, such as superconductivity and magnetic ordering, bringing us one step closer towards manipulating phases of matter using a laser pulse.

The book addresses several aspects of thermodynamics and correlations in the strongly-interacting regime of one-dimensional bosons, a topic at the forefront of current theoretical and experimental studies. Strongly correlated systems of one-dimensional bosons have a long history of theoretical study. Their experimental realisation in ultracold atom experiments is the subject of current research, which took off in the early 2000s. Yet these experiments raise new theoretical questions, just begging to be answered. Correlation functions are readily available for experimental measurements. In this book, they are tackled by means of sophisticated theoretical methods developed in condensed matter physics and mathematical physics, such as bosonization, the Bethe Ansatz and conformal field theory. Readers are introduced to these techniques, which are subsequently used to investigate many-body static and dynamical correlation functions.

The book helps to answer the following questions: How far have the understanding and mesoscale modeling advanced in recent decades, what are the key open questions that require further research and what are the mathematical and physical requirements for a mesoscale model intended to provide either insight or a predictive engineering tool? It is addressed to young researchers including doctoral students, postdocs and early career faculty,

Plants offer some of the most elegant applications of soft matter principles in Nature. Understanding the interplay between chemistry, physics, biology, and fluid mechanics is critical to forecast plant behaviour, which is necessary for agriculture and disease management. It also provides inspiration for novel engineering applications. Starting with fundamental concepts around plant biology, physics of soft matter and viscous fluids, readers of this book will be given a cross-disciplinary and expert grounding to the field. The book covers local scale aspects, such as cell and tissue mechanics, to regional scale matters covering movement, tropism, roots, through to global scale topics around fluid transport. Focussed chapters on water stress, networks, and biomimetics provide the user with a concise and complete introduction. Edited by internationally recognised leading experts in this field with contributions from key investigators worldwide, this book is the first introduction to the subject matter and will be suitable for both physical and life science readers.

This book offers a comprehensive overview of thermodynamics. It is divided into four parts, the first of which equips readers with a deeper understanding of the fundamental principles of thermodynamics of equilibrium states and of their evolution. The second part applies these principles to a series of generalized situations, presenting applications that are of interest both in their own right and in terms of demonstrating how thermodynamics, as a theory of principle, relates to different fields. In turn, the third part focuses on non-equilibrium configurations and the dynamics of natural processes. It discusses both discontinuous and continuous systems, highlighting the interference among non-equilibrium processes, and the nature of stationary states and of fluctuations in isolated systems. Lastly, part four introduces the relation between physics and information theory, which constitutes a new frontier in fundamental research. The book includes step-by-step exercises, with solutions, to help readers to gain a fuller understanding of the subjects, and also features a series of appendices providing useful mathematical formulae. Reflecting the content of modern university courses on thermodynamics, it is a valuable resource for students and young scientists in the fields of physics, chemistry, and engineering.