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Specific Intermolecular Interactions of Organic Compounds (Paperback, 2012 ed.)
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Specific Intermolecular Interactions of Organic Compounds (Paperback, 2012 ed.)
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Prof. Baev presents in his book the development of the
thermodynamic theory of specific intermolecular interactions for a
wide spectrum of organic compounds: ethers, ketones, alcohols,
carboxylic acids, and hydrocarbons. The fundamentals of an
unconventional approach to the theory of H-bonding and specific
interactions are formulated based on a concept of pentacoordinate
carbon atoms. New types of hydrogen bonds and specific interactions
are substantiated and on the basis of the developed methodology
their energies are determined. The system of interconnected
quantitative characteristics of the stability of specific
intermolecular interactions is presented. The laws of their
transformations are discussed and summarized. The new concept of
the extra stabilizing effect of isomeric methyl groups on the
structure and stability of organic molecules is introduced and the
destabilization action on specific interactions is outlined.
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