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Topology of Polymers (Paperback, 1st ed. 2019)
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Topology of Polymers (Paperback, 1st ed. 2019)
Series: SpringerBriefs in the Mathematics of Materials, 4
Expected to ship within 10 - 15 working days
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Plastics, films, and synthetic fibers are among typical examples of
polymer materials fabricated industrially in massive quantities as
the basis of modern social life. By comparison, polymers from
biological resources, including proteins, DNAs, and cotton fibers,
are essential in various processes in living systems. Such polymers
are molecular substances, constituted by the linking of hundreds to
tens of thousands of small chemical unit (monomer) components.
Thus, the form of polymer molecules is frequently expressed by line
geometries, and their linear and non-linear forms are believed to
constitute the fundamental basis for their properties and
functions. In the field of polymer chemistry and polymer materials
science, the choice of macromolecules has continuously been
extended from linear or randomly branched forms toward a variety of
precisely controlled topologies by the introduction of intriguing
synthetic techniques. Moreover, during the first decade of this
century, a number of impressive breakthroughs have been achieved to
produce an important class of polymers having a variety of cyclic
and multicyclic topologies. These developments now offer unique
opportunities in polymer materials design to create unique
properties and functions based on the form, i.e., topology, of
polymer molecules. The introduction and application of topological
geometry (soft geometry) to polymer molecules is a crucial
requirement to account for the basic geometrical properties of
polymer chains uniquely flexible in nature, in contrast to small
chemical compounds conceived upon Euclidian geometry (hard
geometry) principles. Topological geometry and graph theory are
introduced for the systematic classification and notation of the
non-linear constructions of polymer molecules, including not only
branched but also single cyclic and multicyclic polymer topologies.
On that basis, the geometrical-topological relationship between
different polymers having distinctive constructions is discussed. A
unique conception of topological isomerism is thus formed, which
contrasts with that of conventional constitutional and
stereoisomerism occurring in small chemical compounds. Through the
close collaboration of topology experts Shimokawa and Ishihara and
the polymer chemist Tezuka, this monograph covers the fundamentals
and selected current topics of topology applied in polymers and
topological polymer chemistry. In particular, the aim is to provide
novel insights jointly revealed through a unique interaction
between mathematics (topology) and polymer materials science.
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