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Techniques in Inorganic Chemistry (Paperback)
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Techniques in Inorganic Chemistry (Paperback)
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Inorganic chemistry continues to generate much current interest due
to its array of applications, ranging from materials to biology and
medicine. Techniques in Inorganic Chemistry assembles a collection
of articles from international experts who describe modern methods
used by research students and chemists for studying the properties
and structures of inorganic chemicals. Crystallography and
diffraction methods The book begins by examining developments in
small-molecule x-ray crystallography. It identifies some of the
major advances, discusses current attitudes toward crystallography
and its uses, and considers challenges and future prospects. It
then examines how ab initio x-ray powder diffraction (XRPD) methods
are used to determine structure, with discussions on metal
pyrazolates, metal imidazolates, and metal pyrimidinolates. This is
followed by a description of single crystal neutron diffraction, a
powerful structural technique. The text highlights what can
presently be achieved in neutron diffraction and discusses future
applications of neutron scattering. Quantum chemistry Reflecting
the popularity of density functional calculations, the book
includes a chapter that focuses on quantum chemistry. It examines
the latest computational techniques and describes how these
techniques can be applied to solve a wide range of real-world
problems encountered in the realm of inorganic chemistry and
particularly in transition metal chemistry. It also explains the
intelligent use of quantum chemical methods for the determination
of molecular structure, reactivity, and spectra of coordination and
organometallic compounds. Spectroscopy Lastly, the text explores
important spectroscopic approaches. It first describes
intermolecular nuclear Overhauser effect (NOE) NMR experiments and
diffusion experiments, offering examples that demonstrate
theoretical aspects of the methodology. The final chapter
summarizes recent experimental and theoretical work on pressure
effects on the d-d and luminescence spectra of transition metal
complexes. Derived from select articles in Comments on Inorganic
Chemistry, this volume provides a solid background in the array of
techniques available in the researcher's toolkit.
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