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Flexible Polymer Chains in Elongational Flow - Theory and Experiment (Hardcover, 1999 ed.)
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Flexible Polymer Chains in Elongational Flow - Theory and Experiment (Hardcover, 1999 ed.)
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The behavior of polymer solutions in simple shear flows has been
the subject of considerable research in the past. On the other
hand, reports on polymers in elongational flow have appeared
comparatively recently in the literature. Elongational flow with an
inherent low vorticity is known to be more effective in extending
polymer chains than simple shear flow and thus is more interesting
from the point of view of basic (molecular chain dynamics at high
deformation) and applied polymer science (rheology, fiber
extrusion, drag reduction, flow through porous media). Undoubtly,
one landmark in the field of polymer dynamics in elongational flow
was the notion of critical strain-rate for chain extension,
initially put forward by A. Peterlin (1966) and later refined into
the "coil-stretching" transition by P. G. de Gennes and H. Hinch
(1974). In the two decades which followed, significant progress in
the understanding of chain conformation in "strong" flow has been
accomplished through a combination of advances in instrumentation,
computation techniques and theoretical studies. As a result of the
multidisciplinary nature of the field, information on polymer
chains in "strong" flow is accessible only from reviews and
research papers scattered in disparate scientific journals. An
important objective of this book is to remedy that situation by
providing the reader with up-to-date knowledge in a single volume.
The editors therefore invited leading specialists to provide both
fundamental and applied information on the multiple facets of chain
deformation in elongational flow.
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