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Manipulation of Matrix-Isolated Molecules and Molecular Clusters with Electrostatic Fields (Paperback, 1st ed. 2020)
Loot Price: R1,471
Discovery Miles 14 710
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Manipulation of Matrix-Isolated Molecules and Molecular Clusters with Electrostatic Fields (Paperback, 1st ed. 2020)
Series: Springer Theses
Expected to ship within 10 - 15 working days
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This book describes the manipulation of molecular properties, such
as orientation, structure, and dynamics, of small molecules and
molecular clusters isolated in cold inert matrices by using
unprecedentedly strong external electrostatic fields. Manipulation
of molecules with controllable external forces is a dream of
chemists. Molecules are inherently quantum-mechanical systems,
control of which potentially can lead to quantum technology, such
as quantum sensing and computing. This book demonstrates a
combination of the ice film nanocapacitor method and the matrix
isolation technique enabled the application of intense external dc
electric fields across the isolated molecules and molecular
clusters. Changes in molecular states induced by fields were
monitored by means of vibrational spectroscopy. Also, the book
presents manipulations of the inversion tunneling dynamics of
ammonia molecule and the dislocation of acidic proton in hydrogen
chloride-water complex. The book shows that the vibrational
spectroscopy with the aid of unprecedentedly strong dc electric
field can provide rich information on the electrostatic behaviors
of molecules and molecular clusters, which underlie the
understanding of intermolecular processes and molecular
manipulation.
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