This volume records the lectures given at a NATO Advanced Study Institute on Methods in Computational Molecular Physics held in Bad Windsheim, Germany, from 22nd July until 2nd. August, 1991. This NATO Advanced Study Institute sought to bridge the quite considerable gap which exist between the presentation of molecular electronic structure theory found in contemporary monographs such as, for example, McWeeny's Methods 0/ Molecular Quantum Mechanics (Academic Press, London, 1989) or Wilson's Electron correlation in moleeules (Clarendon Press, Oxford, 1984) and the realization of the sophisticated computational algorithms required for their practical application. It sought to underline the relation between the electronic structure problem and the study of nuc1ear motion. Software for performing molecular electronic structure calculations is now being applied in an increasingly wide range of fields in both the academic and the commercial sectors. Numerous applications are reported in areas as diverse as catalysis and interstellar chernistry, drug design and environmental studies, molecular biology and solid state physics. The range of applications continues to increase as scientists recognize the importance of molecular structure studies to their research activities. Recent years have seen a growing dependence of these applications on program packages, which are often not in the public domain and which may have a somewhat lirnited range of applicability dicta ted by the particular interests and prejudices of the program author.

This volume contains the lectures and seminars on Coronas, Gas Discharges, Diagnostics, Plasma Chemistry, and Applications pre sented at the Advanced Study Institute on Breakdown and Discharges in Gases. The Institute was held in Les Arcs, France, during June 28 to July 10, 1981. The first volume has been devoted to the areas of Basic Discharge Processes, Kinetic Theory and Gas Break down. This collection is both tutorial and representative of the state of the field. We hope it will be useful both to beginners and experienced researchers. We are grateful to a number of organizations for providing financial assistance. The Scientific Affiars Division of NATO provided the major contribution for the Institute. The Office of Naval Research, the Naval Surface Weapons Center at Dahlgren, the Air Force Office of Scientific Research and the Air Force Weapons Laboratory provided additional support. The National Science Foun dation financed the travel of one student. We would like to acknowledge the many people who helped us organize and carry the Institute to its successful completion."

The aim of this book is to present highly accurate and extensive theoretical Atomic data and to give a survey of selected calculational methods for atomic physics, used to obtain these data. The book presents the results of calculations of cross sections and probabilities of a broad variety of atomic processes with participation of photons and electrons, namely on photoabsorption, electron scattering and accompanying effects. Included are data for photoabsorption and electron scattering cross-sections and probabilities of vacancy decay formed for a large number of atoms and ions. Attention is also given to photoionization and vacancy decay in endohedrals and to positron-atom scattering. The book is richly illustrated. The methods used are one-electron Hartree-Fock and the technique of Feynman diagrams that permits to include many-electron correlations. This is done in the frames of the Random Phase approximation with exchange and the many-body perturbation theory. Newly obtained and previously collected atomic data are presented. The atomic data are useful for investigating the electronic structure and physical processes in solids and liquids, molecules and clusters, astronomical objects, solar and planet atmospheres and atomic nucleus. Deep understanding of chemical reactions and processes is reached by deep and accurate knowledge of atomic structure and processes with participation of atoms. This book is useful for theorists performing research in different domains of contemporary physics, chemistry and biology, technologists working on production of new materials and for experimentalists performing research in the field of photon and electron interaction with atoms, molecules, solid bodies and liquids.

Prompt gamma activation analysis (PGAA) is a unique, non-destructive nuclear analytical method with multi-element capabilities. It is most effective if intense neutron beams (especially cold beams) of nuclear reactors are used to induce the prompt gamma radiation. Based largely on the authors' pioneering research in cold neutron PGAA, the handbook describes the methodology in self-contained manner and reviews recent applications. The library of prompt gamma ray data and spectra for all natural elements is a unique aid to the practitioner. The level is understandable by a broad audience, which facilitates teaching and training. The Handbook of Prompt Gamma Activation Analysis is a comprehensive handbook written for those practising the method, wanting to implement it at a reactor facility, or just looking for a powerful non-destructive method of element analysis. The book is also useful for nuclear physics, chemistry and engineering scientists, scholars and graduate students interested in neutron-induced gamma ray spectroscopy and nuclear analytical methods.

There is considerable interest, both fundamental and technological, in the way atoms and molecules interact with solid surfaces. Thus the description of heterogeneous catalysis and other surface reactions requires a detailed understand ing of molecule-surface interactions. The primary aim of this volume is to provide fairly broad coverage of atoms and molecules in interaction with a variety of solid surfaces at a level suitable for graduate students and research workers in condensed matter physics, chemical physics, and materials science. The book is intended for experimental workers with interests in basic theory and concepts and had its origins in a Spring College held at the International Centre for Theoretical Physics, Miramare, Trieste. Valuable background reading can be found in the graduate-Ievel introduction to the physics of solid surfaces by ZangwilI(1) and in the earlier works by Garcia Moliner and F1ores(2) and Somorjai.(3) For specifically molecule-surface interac tions, additional background can be found in Rhodin and Ertl(4) and March.(S) V. Bortolani N. H. March M. P. Tosi References 1. A. Zangwill, Physics at Surfaces, Cambridge University Press, Cambridge (1988). 2. F. Garcia-Moliner and F. Flores, Introduction to the Theory of Solid Surfaces, Cambridge University Press, Cambridge (1979). 3. G. A. Somorjai, Chemistry in Two Dimensions: Surfaces, Cornell University Press, Ithaca, New York (1981). 4. T. N. Rhodin and G. Erd, The Nature of the Surface Chemical Bond, North-Holland, Amsterdam (1979). 5. N. H. March, Chemical Bonds outside Metal Surfaces, Plenum Press, New York (1986)."

This collection of articles contains a systematic outline of original experimental and theoretical research on photoproduction of neutral pions at protons and at a strongly bound system of a few nucleons, i.e., the helium nucleus. Spark chambers and their use as spectrometers for photons and electrons are described in detail. The articles of the collection include information on a novel method of determining the efficiency of recording apparatus by generating monochromatic photons. The articles de- scribe original theoretical research on the optical anisotropy of nuclei. Problems encountered in experimental studies of operating the synchrotron as a storage-type accelerator of electrons and positrons receive particular attention. The results of this research work are listed, and the problems of oppositely directed electron-positron beams in the 250-MeV synchrotron are considered. The articles should be of interest to physicists, including research workers, teachers, engineers, graduate students, and students in advanced undergraduate courses. v CONTENTS Photoproduction of Neutral Pions at Nucleons and Nuclei B. B. Govorkov, S. P. Denisov, and E. V. Minarik 0 Photoproduction of 1r Mesons at Helium and at Photon Energies of 71 160-240 MeV ...

Protein NMR for the Millennium is the third volume in a special thematic series devoted to the latest developments in protein NMR under the Biological Magnetic Resonance umbrella. This book is divided into three major sections dealing with significant recent advances in the study of large proteins in solution and solid state, structure refinement, and screening of bioactive ligands. Key Features: * TROSY, * Segmental isotope labeling of proteins, * Hydrogen bond scalar couplings, * Structure refinement based on residual dipolar couplings, * Written by the world's foremost experts who have provided broad leadership in advancing the protein NMR field.

Volume 17 is the second in a special topic series devoted to modern techniques in protein NMR, under the Biological Magnetic Resonance series. Volume 16, with the subtitle Modern Techniques in Protein NMR , is the first in this series. These two volumes present some of the recent, significant advances in the biomolecular NMR field with emphasis on developments during the last five years. We are honored to have brought together in these volume some of the world s foremost experts who have provided broad leadership in advancing this field. Volume 16 contains - vances in two broad categories: I. Large Proteins, Complexes, and Membrane Proteins and II. Pulse Methods. Volume 17 contains major advances in: I. Com- tational Methods and II. Structure and Dynamics. The opening chapter of volume 17 starts with a consideration of some important aspects of modeling from spectroscopic and diffraction data by Wilfred van Gunsteren and his colleagues. The next two chapters deal with combined automated assignments and protein structure determination, an area of intense research in many laboratories since the traditional manual methods are often inadequate or laborious in handling large volumes of NMR data on large proteins. First, Werner Braun and his associates describe their experience with the NOAH/DIAMOD protocol developed in their laboratory.

This book can be looked upon in more ways than one. On the one hand, it describes strikingly interesting and lucid hydrodynamic experiments done in the style of the "good old days" when the physicist needed little more than a piece of string and some sealing wax. On the other hand, it demonstrates how a profound physical analogy can help to get a synoptic view on a broad range of nonlinear phenomena involving self-organization of vortical structures in planetary atmo spheres and oceans, in galaxies and in plasmas. In particular, this approach has elucidated the nature and the mechanism of such grand phenomena as the Great of galaxies. A number of our Red Spot vortex on Jupiter and the spiral arms predictions concerning the dynamics of spiral galaxies are now being confirmed by astronomical observations stimulated by our experiments. This book is based on the material most of which was accumulated during 1981-88 in close cooperation with our colleagues, experimenters from the Plasma Physics Department of the Kurchatov Atomic Energy Institute (S. V. Antipov, A. S. Trubnikov, AYu. Rylov, AV. Khutoretsky) and astrophysics theoreticians from the Astronomical Council of the USSR Academy of Sciences (AM. Frid man) and from the Volgograd State University (AG. Morozov). To all of them we wish to express our gratitude. Whenever we speak of "our experiments," the participation of the entire team is implied."

The Imager for Magnetopause-to-Aurora Global Exploration (IMAGE) is a NASA Explorer mission that is the first space mission dedicated to imaging of the Earth's magnetosphere. IMAGE was launched from Vandenberg AFB into an elliptical polar orbit by a Delta II launch vehicle on March 25, 2000. The two-year prime sci entific mission of IMAGE began on May 25, 2000 after instrument commissioning was successfully completed. IMAGE has now been approved for operation until October 1,2005, and an additional two-year extension is now being considered by NASA. The papers in this volume represent many of the scientific results obtained dur ing the IMAGE prime mission and include some of the early correlative research with ground-based measurements, measurements from other spacecraft such as Cluster II, and relevant theory and modeling programs. All of the reported work is related to the overall IMAGE science objective: How does the magnetosphere respond globally to the changing conditions in the solar wind? IMAGE addresses this question with multi-spectral imaging of most of the important plasma pop ulations of the inner magnetosphere, combined with radio sounding of gradients of total plasma content. The new experimental techniques fall into the following areas: neutral atom imaging (NAI) over an energy range from 10 eV to 500 keY for detection of ionospheric outflow, the plasma sheet, and the ring current; far ultraviolet (FUV) imaging at 121-190 nm for detection of precipitating protons and the global aurora; extreme ultraviolet (EUV) imaging at 30.

Inelastic scattering of X-rays with very high energy resolution has finally become possible thanks to a new generation of high-intensity X-ray sources. This development marks the end to the traditional belief that low energy excitations like lattice vibrations cannot be resolved directly with X-rays: Inelastic scattering experiments allow to observe directly the small energy shifts of the photons. Studies of lattice vibrations, of excitations in molecular crystals, of collective excitations in liquids and electronic excitations in crystals demonstrating the broad applicability and power of this new technology are discussed in this book. The progress in this field opens up fantastic new research areas not only in physics but also in other disciplines such as materials science, biology and chemistry.

Photoproduction of pions from complex nuclei has become an investigative tool for (1) the detailed form of the elementary photopion amplitude, (2) the pion-nucleus optical potential, (3) nuclear structure, and (4) off-shell and medium effects on the elementary amplitude in nuclear processes. In this book, all these aspects are considered in detail. With improved experimental accuracy and beam tech- nology the study of nuclear pion photoproduction will break new ground and become an even more powerful investigative tool. This monograph is intended as an introductory guide as well as a reference manual for grad- uate students and researchers working in this important area of physics.

This book gives a detailed overview on this new and exciting field at the boundary of physics and chemistry. Laser-induced ultrafast molecuar dynamics is presented for many textbook-like examples of model molecules and clusters. Experimental results on phenomena like wave packet propagation, ultrafast photodissociation and femtosecond structural redistribution are presented and described theoretically.

This volume presents five pedagogical articles spanning frontier developments in contemporary nuclear physics ranging from the physics of a single nucleon to nucleosynthesis in the Big Bang. Although the objectives of Advances in Nuclear Physics have been and will continue to be quite distinct from those of conventional conference proceedings, the articles in this volume are carefully edited and expanded manuscripts based on an outstanding series of lectures delivered at the VI J. A. Swieca Summer School in Brazil. Starting at the smallest scale, the first article by Dan Olof Riska addresses realistic chiral symmetric models of the nucleon. Since the analytic tools are not yet developed to solve nonperturbative QCD directly, significant effort has been devoted in recent years to the development of models which incorporate and are constrained by the approximate chiral symmetry manifested in QCD. This article provides a clear introduction to chiral symmetry and the Skyrme model, and discusses the Skyrme model's relation to the chiral bag model, its extensions, and its application to nucleons and hyperons.

The 1979 Cargese Summer Institute on Quarks and Leptons was organized by the Universite Pierre et Marie Curie, Paris (M. LEVY and J.-L. BASDEVANT), CERN (M. JACOB), the Universite Catholi~ue de Louvain (D. SPEISER and J. WEYERS), and the Katholieke Universiteit te Leuven (R. GASTMANS), who, like in 1975 and 1977, had joined their efforts and worked in common. It was the 20th Summer Institute held at Cargese and the 5th one organized by the two institutes of theoretical physics at Leuven and Louvain-la- Neuve. This time, the school was dominated by the impressive advances which were made in the field of perturbative ~uantum chromodyna- mics and its applications to high energy phenomena involving strongly interacting particles. The unification of weak and electromagnetic interactions being well established, a new picture in particle physics emerges wherein a possible unification of weak, electromagnetic, and strong forces is put forward. Its conse~uences were also discussed in detail. Finally, to complete the picture of the present status of high energy physics, experi- mentalists from the major laboratories around the world reported on the latest developments in electron-positron scattering, neutrino induced reactions, and hadron collisions. We owe many thanks to all those who have made this Summer Institute possible! Thanks are due to the Scientific Committee of NATO and its President for a generous grant and especially to the head of the Scientific Affairs Division, Dr. M. DI LULLO for his constant help and encouragements.

Stochastic Energetics by now commonly designates the emerging field that bridges the gap between stochastic dynamical processes and thermodynamics. Triggered by the vast improvements in spatio-temporal resolution in nanotechnology, stochastic energetics develops a framework for quantifying individual realizations of a stochastic process on the mesoscopic scale of thermal fluctuations. This is needed to answer such novel questions as: Can one cool a drop of water by agitating an immersed nano-particle? How does heat flow if a Brownian particle pulls a polymer chain? Can one measure the free-energy of a system through a single realization of the associated stochastic process? This book will take the reader gradually from the basics to the applications: Part I provides the necessary background from stochastic dynamics (Langevin, master equation), Part II introduces how stochastic energetics describes such basic notions as heat and work on the mesoscopic scale, Part III details several applications, such as control and detection processes, as well as free-energy transducers. It aims in particular at researchers and graduate students working in the fields of nanoscience and technology.

The decade of the 1990s offers a chance to build a new and better international order. What policy choices will this decade pose for the United States? This wide-ranging volume of essays imaginatively addresses these crucial issues. The peaceful revolutions of 1989-1990 in the Soviet Union and Eastern Europe have swept away the foundations of the Cold War. The Eastern European nations are free; Europe is no longer divided; Germany is united. The Soviet threat to Western Europe is ending with the collapse of the Warsaw Pact and the withdrawals and asymmetrical cuts of Soviet forces. And U.S.-Soviet rivalry in the Third World is giving way to cooperation in handling conflicts, as in Iraq and elsewhere. Much, of course, remains uncertain and unsettled. What sort of Soviet Union will emerge from the ongoing turmoil, with what political and economic system and what state structure? How far and how soon will the Eastern Euro pean states succeed in developing pluralist democracies and market economies? Are the changes irreversible? Certainly there will be turmoil, backsliding, and failures, but a return to the Cold War hardly seems likely."

The investigation of scattering phenomena is a major theme of modern physics. A scattered particle provides a dynamical probe of the target system. The practical problem of interest here is the scattering of a low energy electron by an N-electron atom. It has been difficult in this area of study to achieve theoretical results that are even qualitatively correct, yet quantitative accuracy is often needed as an adjunct to experiment. The present book describes a quantitative theoretical method, or class of methods, that has been applied effectively to this problem. Quantum mechanical theory relevant to the scattering of an electron by an N-electron atom, which may gain or lose energy in the process, is summarized in Chapter 1. The variational theory itself is presented in Chapter 2, both as currently used and in forms that may facilitate future applications. The theory of multichannel resonance and threshold effects, which provide a rich structure to observed electron-atom scattering data, is presented in Chapter 3. Practical details of the computational implementation of the variational theory are given in Chapter 4. Chapters 5 and 6 summarize recent appli cations of the variational theory to problems of experimental interest, with many examples of the successful interpretation of complex structural fea tures observed in scattering experiments, and of the quantitative prediction of details of electron-atom scattering phenomena."

This volume contains two papers that review certain theoretical problems that have been studied in the Laboratory of Plasma Accelerators and Plasma Physics of the P. N. Lebedev Physics Institute of the Academy of Sciences of the USSR. The review of R. R. Kikvidze and A. A. Rukhadze, "Theory of oscillations and stability of a semiconductor plasma with low carrier density in a strong electric field," is devoted to a solid-state plasma. The main attention is devoted to the fact that in such a plasma electro magnetic waves are effectively generated if there is a negative current-voltage characteristic in the carrier current; this effect can compete in importance with the well-known Gunn effect. In their fundamental review paper "Nonlinear theory of the interaction of waves in a plasma," V. V. Pustovalov and V. P. SHin set forth the fundamentals of the theory of nonlinear interaction of waves in a hot rarefied plasma. Besides a systematic exposition of the pro cedure for deriving the equations that describe the nonlinear interaction of waves in an iso tropic or an anisotropic (magnetized) plasma, they study many concrete examples relating to the interaction of definite types of waves under different conditions."

Atomic and nuclear physics are two flourishing but distinct branches of physics; the subject of isotope shifts in atomic spectra is one of the few that links these two branches. It is a subject that has been studied for well over fifty years, but interest in the subject, far from flagging, has been stimulated in recent years. Fast computers have enabled theoreticians to evaluate the properties of many-electron atoms, and laser spectroscopy has made it possible to measure isotope shifts in the previously unmeasurable areas of very rare isotopes, short-lived radioactive isotopes, weak transitions, and transitions involving high-lying atomic levels. Isotope shifts can now be measured with greater accuracy than before in both optical transitions and x-ray transitions of muonic atoms; this improved accuracy is revealing new facets of the subject. I am very grateful to Dr. H. G. Kuhn, F. R. S. , for having introduced me to the subject in the 1950s, and for supervising my efforts to measure isotope shifts in the spectrum of ruthenium. I thus approach the subject as an experimental atomic spectroscopist. This bias is obviously apparent in my use of the spectroscopist's notation of lower-upper for a transition, rather than the nuclear physicist's upper-lower. My reasons are given in Section 1. 3 and I hope that nuclear physicists will forgive me for using this notation even for muonic x-ray transitions.

This volume is composed of papers (invited and contributed) presented at the International Conference on Coherence and Quantum Optics held at the University of Hyderabad January 5-January 10, 1991. It has been organized by Professor Girish Agarwal and his colleagues at the School of Physics, University of Hyderabad, Hyder abad, India under partial support from the Department of Science and Technology, Government of India, International Center for Theoretical Physics, Trieste, Italy and the National Science Foundation, USA. Without the untiring efforts of Prof. Girish Agarwal and the members of his quantum office group, the Conference and the present volume would not have been possible. Some extraordinary circumstances resulted in a delay of the publication of the present volume. Our sincere apologies to all the authors. We deeply regret the inconvenience caused due to the delay. A debt of gratitude is due to Ms. Kim Bella for the excellent typing job of the different versions and the final version of the manuscript. It is a pleasure to acknowl edge the efforts of Ms. Pat Vann, Mr. Greg Safford and Mr. Eric Katz of the Plenum Publishing, without whose interest and persistence this volume would not have been possible. v CONTENTS QUANTUM OPTICS: THEORY The Quantum Mechanics of Particles in Time-Dependent Quadrupole Fields Roy J. Glauber . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 Localization of Photons in Random and Quasiperiodic Media S. Dutta Gupta . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15 Enhanced Fundamental Linewidth of a Laser Due to Outcoupling W. A. Hamel, M. P. van Exter, and J. P. Woerdman . . . . . . . . . . . . . . . . . . . . . . . ."