The technologies of hydrogen's energetic utilization have been known for a long time. But aspects of system analysis, energy economics, and ecology that would come into play in introducing it into energy systems nave received much less attention. For those reasons, this book attempts to show the development path of a hydrogen economy, based on assured technological knowledge. One special concern has been to demonstrate, on one hand, how these developments would fit into existing energy supply structures, and, on the other, how they would contribute to further development of the energy system as a whole. With that goal in mind it is necessary to contrast the obvious advantages of hydrogen with the large efforts that would be required for its introduction. This total-systems approach led to a three-part organization of the book that also aids the reader in quickly identifying those parts that are of special interest to him. Section A essentially explains why it is necessary today to think about a new synthetic energy carrier. It also describes the irreplacable and growing role of hydrogen as a chemical raw material, and it explains technologies that al ready exist for its energetic use or that need further development. An attempt has also been made to prove that hydrogen's safety characteristics indeed per mit its handling and use as an energy carrier. Hopefully, all this will show that hydrogen, together with electricity, could be the universally employable energy carrier of a future non-fossil energy supply system."

In todaya (TM)s competitive world, industries are focusing on shorter lead times, improved quality, reduced cost, increased profit, improved productivity and better customer service. As ERP and other information management systems have been widely implemented, information growth poses new challenges to decision makers in areas ranging from shop floor control to supply chain management and design.

Frontiers in Computing Technologies for Manufacturing Applications presents an overview of the state-of-the-art intelligent computing in manufacturing. Modelling, data processing, algorithms and computational analysis of difficult problems found in advanced manufacturing are discussed. It is the first book to bring together combinatorial optimization, information systems and fault diagnosis and monitoring in a consistent manner. Techniques are presented in order to aid decision makers needing to consider multiple, conflicting objectives in their decision processes. In particular, the use of metaheuristic optimization techniques for multi-objective problems is discussed. Readers will learn about computational technologies that can improve the performance of manufacturing systems ranging from manufacturing equipment to supply chains.

Frontiers in Computing Technologies for Manufacturing Applications will be of interest to students in industrial and mechanical engineering as well as information engineers needing practical examples for the successful integration of information in manufacturing applications. The book will also appeal to technical decision makers involved in production planning, logistics, supply chain, industrial ecology, manufacturing information systems, faultdiagnosis and monitoring.

Adsorption processes have experienced a significant growth in the last decades. This growth was a result of scientific and technological advances which generated new adsorbents as well as new concepts for processing systems (UOP's "Sorbex" process and PSA cycles). The expectations for a continued development of adsorption are high since process engineering is deeply concerned with intensive processes using less energy. Adsorption processes are also relevant to the increasingly important area of biotechonology. The development of affinity processes is a creative synthesis of biochemistry, molecular biology and chemical engineering. This NATO Advanced Study Institute on "ADSORPTION: SCIENCE and TECHNOLOGY" had as a primary objective to provide an updated treatment of the fundamentals of adsorption and adsorption processes. The lectures presented at the Institute are collected in this volume together with a few papers presented by participants. The material is arranged in four sections.Part I deals with the characterization of adsorption and thermodynamics of adsorption, namely the correlation of equilibrium data.Part II covers the kinetics of adsorption and fixed-bed processes (equilibrium theory, design aspects, adsorptive reactors).Part III is an extensive coverage of cyclic processes (pressure swing adsorption and thermal swing adsorption) and simulated moving beds (modeling for process optimization and industrial applications).Finally Part IV deals with applications mainly in biotechnolo gy (con tin uous adsorption, affini ty chrom atography, gel permeation, chromatographic reactors, scale-up methods).

In determining the response of offshore structures, it is of utmost importance to determine, in the most correct manner, all factors which contribute to the total force acting on these structures. Applying the Morison formula (Morison et. al. , 1950) to calculate forces on offshore slender structures, uncertainties related to the understanding of the wave climate, the hydrodynamic force coefficients and the kinematics of ocean waves represent the most important contributions to the uncertainties in the prediction of the total forces on these structures (Haver and Gudmestad, 1992). Traditional calculation of forces on offshore structures involves the use of regular waves with the following non-linearities inco1porated use of regular wave theories inco1porating higher order terms use of Morison equation having a nonlinear drag term inclusion of the effect of the free surface by integrating all contributions to total forces and moments from the sea floor to the free surface of the waves In order to describe the sea more realistically, the ocean surface is to be described as an irregular sea surface represented by its energy spectrum. The associated decomposition of the sea surface is given as a linear sum of linear waves. The total force is found by integrating the contribution from all components in the wave spectrum to the free surface. The kinematics of each component must therefore be determined.

This is a revision of the highly successful electronic manufacturing guide, ESD Program Management: A Realistic Approach to Continuous Measurable Improvement in Static Control. This revision is comprehensive and explains how to develop, implement and manage an ESD control program, and includes up-to-date data, many new chapters, new case studies, and much more. New to this edition: Extensive changes and additions to auditing techniques, cost benefits data, and materials evaluation. Six new chapters on common myths, issues related to smaller companies, process controls, ISO 9000, material characterization, and training. New case studies on field-induced failures in the factory, long-distance central office system upsets, and automation-caused failures. Expanded coverage of the needs of smaller companies including discussion of common problems and cost-effective solutions. A training breakthrough is presented. Previously invisible ESD events can now be easily displayed for students at all levels - Seeing is believing ' Inclusion of new testing instruments such as the event detector and resistance probe. The 12 critical factors in an ESD program have been updated to reflect changes and refinements in program management. The author has also included the latest information on handling procedures and requirements from the Lucent ESD Control Handbook. ESD Program Management: A Realistic Approach to Continuous Measurable Improvement in Static Control, Second Edition, is a refreshingly unbiased guide for electronic manufacturing and quality control professionals.

TheI&ECSYMPOSIUMfromwhichthisvolumewasderivedfeatured519presen- tationsat88technicalsessionsduringathree-daymeetingonSeptember17-20, 1996in Birmingham,Alabamawith580registrants. Thefinalselectionsforthechaptersincluded hereinwerebasedonpeerreview,scientificmerit,theeditors'perceptionsoflastingvalue orinnovativefeatures, andthegeneralapplicabilityofeitherthetechnologyitselforthe scientificmethodsandscholarlydetailsprovidedbytheauthors. Thevolume isacontinuationofathemeinitiatedin 1990. Itspredecessors,Emerg- ing Technologies in Hazardous Waste Management, ACS Symposium Series No. 422 (1990), EmergingTechnologiesinHazardous WasteManagementII,ACSSymposiumSe- ries No. 468 (1991), Emerging Technologies in Hazardous WasteManagement III, ACS SymposiumSeriesNo. 518(1993), EmergingTechnologiesinHazardous WasteManage- mentIV, ACSSymposium Series No. 554 (1994),Emerging Technologies in Hazardous WasteManagement V. ACSSymposiumSeriesNo. 607(1995), andEmergingTechnolo- gies in Hazardous Waste Management VI, American AcademyofEnvironmental Engi- neersPublication (1996), arerelatedcontributionsonhazardouswastemanagement,but eachvolumeisessentiallydifferent. Byinspection,thereadermayquicklyrecognizethis diversity,andalsoconcludethatnosinglevolumecandojusticetothebreadthanddepth oftechnologiesbeingdevelopedandappliedinpractice. Thecontributionspresented in thisvolumearedivided intofourseparatebutcom- plementary sections, including: (1) Chemical and Thermal Treatment; (2) Biochemical Treatment;(3)SeparationTechnologies;and(4)RadioactiveWasteTreatment. D. WilliamTedder FrederickG. Pohland GeorgiaInstituteofTechnology UniversityofPittsburgh Atlanta, Georgia30332-0100 Pittsburgh,Pennsylvania15261-2294 v ACKNOWLEDGMENTS The Industrial & Engineering Chemistry (I&EC) Division ofACS organized and sponsored the symposium. ACS Corporate Associates was a majorfinancial cosponsor; theAmericanInstituteofChemicalEngineers(AIChE)EnvironmentalSciencesDivision, theAIChECenterforWasteReductionTechnologies,theAmericanAcademyofEnviron- mental Engineers,andtheJointAssociationfor theAdvancementsofSupercriticalFluid Technologywerenominalcosponsors;andEnviroExpocositedanexhibition. Thisgener- osity was essential to the overall successofthe symposium and is gratefully acknow- ledged. vii CONTENTS I. EmergingTechnologiesinHazardousWasteManagementVII:AnOverview...FrederickG. PohlandandD. WilliamTedder ChemicalandThermalMethods 2. GranularIronOxideasaCatalystinChemicalOxidationofOrganic Contaminants...9 MiratD. Gurol,Shu-SungLin,andNileshBhat 3. AnElectronBeamGeneratedPlasmaReactorforDecompositionof HalogenatedVOCs 23 S. A. Vitale, K. Hadidi,D. R. Cohn, L. Bromberg,andP. Falkos 4. IncinerationandThermalTreatmentofChemicalAgentsandChemicalWeapons 33 F. C. GouldinandE. M. Fisher 5. PredictingStabilityConstantsofVariousChelatingAgentsUsingQSAR Technology 49 R. W. Okey,S. Lin,andP. K. A. Hong 6. MineralizationofHazardousChemicalsbyHemeReaction ...69 GuyoungKang,JimoJung,KapsongPark,andDavidK. Stevens BiochemicalTreatment 7. AnaerobicTransformationsofCarbonTetrachloride:CombinedBacterialand AbioticProcesses 81 FlynnW. Picardal,SanggooKim,AnnaRadue,andDeberaBackhus 8. BiorecoveryofMetalsfromAcidMineDrainage...91 RakeshGovind,UmaKumar,RamaPuligadda,JimmyAntia,and HenryTabak ix x Contents 9. BiotreatmentofMinewater-ContainingCyanidesbyUsingImmobilizedCell Technology 103 Onguri K. Vijaya,G. R. V. Babu,JackAdams,JamesH. Wolfram,and KiritD. Chapatwala 10. Augmentationofin-SituSubsoilRemediationUsingColloidalGasDispersions 113 P. G. Chaphalkar,K. T. Valsaraj,D. Roy, W. D. Constant,andP. Lee 11. EffectofSorptionontheMicrobialReductiveDechlorinationofSoil-Bound Chloroalkenes 127 SpyrosG. PavlostathisandPingZhuang SeparationTechnologies 12. TheRemovalofVOCsfromExhaustAirandVapourCondensatesby MembraneProcesses ...

This book addresses the behavior of inorganic material in combustion systems. The past decade has seen unprecedented improvements in understanding the rates and mecha nisms of inorganic transformations and in developing analytical tools to predict them. These tools range from improved fuel analysis procedures to predictive computer codes. While this progress has been met with great enthusiasm within the research community, the practices of the industrial community remain largely unchanged. The papers in this book were selected from those presented at an Engineering Foundation Conference of the same title. All have been peer reviewed. The intent of the conference was to illustrate the application of advanced technology to ash-related problems in boilers and, by so doing, engage the research and industrial communities in more productive dialog. Those attending the conference generally felt that we were successful on these counts. We also engaged the industrial community to a greater extent than ever before in the conference discussion and presentation. We hope these proceedings will facilitate a continued and improved interaction between industrial and research communities. Behavior of inorganic material has long been recognized as one of the major considerations affecting the design and operation of boilers that burn ash-producing fuels. The practical problems associated with the behavior are sometimes catastrophic and spec tacular, ranging from major slag falls that damage the bottom of furnaces to complete plugging of convection passes."

The ninth International Cryogenic Materials Conference (ICMC) was held on the campus of the University of Alabama at Huntsville (UAH) in collaboration with the Cryogenic Engineering Conference (CEC) on June 11-14, 1991. The continuing bond between these two major conferences in the field of cryogenics is indicative of the extreme interdependence of their subject matter. The major purpose of the conference is sharing of the latest advances in low temperature materials science and technology. However, the many side benefits which accrue when this many experts gather, such as identification of new research areas, formation of new collaborations which often cross the boundaries of both scientific discipline and politics, and a chance for those new to the field to meet the old-timers, may override the stated purpose. This 1991 ICMC was chaired by F. R. Fickett of the National Institute of Standards and Technology. K. T. Hartwig, of Texas A&M served as Program Chairman with the assistance of eleven other Program Committee members. We especially appreciate the contributions of the CEC board and its Conference Chairman, J. Hendricks of Alabama Cryogenic Engineering, to the organization. of this joint conference. UAH hosted the conference. The local arrangements and management, under the watchful eye of Ann Yelle and Mary Beth Magathan of the UAH conference staff, were excellent. Participation in the CEC/ICMC continues to exceed expectations with 650 registrants for the combined conference.

The 1995 International Cryogenic Materials Conference (lCMC) was held at the Greater Columbus Convention Center in Columbus, Ohio, in conjunction with the Cryogenic Engineering Conference (CEC) on July 17-21. The interdependent subjects of the two conferences attracted more than eight hundred participants, who came to share the latest advances in low-temperature materials science and technology. They also came for the important by products of the conferences: identification of new research areas, of collaborative research possibilities, and the establishment and renewal of exploration professional relationships. Ted Collings (Ohio State University), as Chairmen of the 1995 ICMC; Ted Hartwig (Texas A&M University), as Program Chairman; and twenty-one other Program Committee members expertly arranged the ICMC technical sessions and related activities. The contributions of the CEC board and its Conference Chairman James B. Peeples of CVI, Inc., were central to the success of the eleventh CEC/ICMC. Jeff Bergen of Lake Shore Cryogenics served as Exhibits Chairman. Local arrangements and conference management were expertly handled under the guidance of Centennial Conferences, Inc. Skillful assistance with editing and preparation ofthese proceedings was provided by Ms. Vicky Bardos ofSynchrony, Inc.

Innovative technologies provide opportunities for making manufacturing and logistics operations cleaner and more resource-efficient. New technologies focus on lifecycle engineering and lifecycle management. This book will be valuable to both academics and practitioners who wish to deepen their knowledge of technology management. The book will cover technical, organizational, financial and social issues connected to the implementation of more sustainable technologies.

This major reference book is divided into two sections; the first deals with the practical, hands-on understanding of individual areas of tape casting and the other targets the understanding of the overall system. Readers can quickly address current problems with tried and true fixes and their relation to the overall process. The book handles the problem diagnosis separately from the standard production of quick-fixes. Tape Casting will benefit technicians, engineers, and engineering managers, as well as professors and students.

Carbon gasification reactions form the basis of many important industrial processes, such as the combustion of coal and the produc tion of synthesis gas, fuel gases and activated carbons. They are also involved in metallurgical processes and in the regeneration of coked catalysts. Thus, understanding the fundamentals of carbon gasification is of vital importance for further technological development. Moreover, the subject is of interdisciplinary nature, involving chemistry, ma terials science and chemical engineering. Therefore, it was thought that an Advanced Study Institute would be fruitful in establishing the state of the art, in bringing together experts from the various sectors involved and in identifying areas of required research and industrial development. Such a meeting was held at Alvor, Portugal, from the 20th to the 31st May 1985, and the lectures presented the reof are collected in this volume. The present volume is organized in seven chapters. The Intro duction presents the carbon gasification reactions an their rele vance for particular processes and industrial uses. In the second chapter, the structures of carbon and coal are reviewed, together with methods of structural, chemical and textural characterization."

Most catalysts used in the chemical and petrochemical indus tries are strongly affected by one or another form of deactivation, leading to poor performances and reduced life. The increasing num ber of scientific communications devoted to the subject in recent years, and culminating with an International Symposium held in Antwerp in October 1980, is a measure of the interest it arouses in both the industrial and academic communities. A stage has been reached whereby it was thought that a NATO Advanced Study Institute on "Catalyst Deactivation" might be fruit ful in establishing the state of the art and in stimulating a more systematic research on the phenomenon. Such a meeting was held n Lagos, Portugal, from 18 to 29 May 1981. The purpose of the Institute was to present and discuss in a didatic and systematic way the various processes that lead to cata lyst deactivation, namely coking, poisoning and solid state trans formations, and at the same time to promote the exchange of ideas and experiences among the participants, drawn from industry and uni versity. The lectures presented at the Institute are collected in this volume with the exception of Dr. L.L.Hegedus "Catalyst Poisoning," which has been previously published (Catalysis Reviews, Science md Engineering, 23, 377-476, 1981)."

Intelligent Manufacturing is a new disciplinary field which applies computer science, artificial intelligence, mechanical engineering and systems science to industrial manufacturing processes. This book presents a new integration architecture for implementing real-time distributed intelligent manufacturing systems.

Mathematical Methods in Chemical Engineering

The world of microelectronics is filled with cusses measurement systems, manufacturing many success stories. From the use of semi control techniques, test, diagnostics, and fail ure analysis. It discusses methods for modeling conductors for powerful desktop computers to their use in maintaining optimum engine per and reducing defects, and for preventing de formance in modem automobiles, they have fects in the first place. The approach described, clearly improved our daily lives. The broad while geared to the microelectronics world, has useability of the technology is enabled, how applicability to any manufacturing process of similar complexity. The authors comprise some ever, only by the progress made in reducing their cost and improving their reliability. De of the best scientific minds in the world, and fect reduction receives a significant focus in our are practitioners of the art. The information modem manufacturing world, and high-quality captured here is world class. I know you will diagnostics is the key step in that process. find the material to be an excellent reference in of product failures enables step func Analysis your application. tion improvements in yield and reliability. which works to reduce cost and open up new Dr. Paul R. Low applications and technologies. IBM Vice President and This book describes the process ofdefect re of Technology Products General Manager duction in the microelectronics world."

The assembly sector is one of the least automated in the manufacturing industry. Automation is essential if industrial companies are to be competitive in the future. In assembly, an integrated and flexible approach is needed because 75% of the applications are produced in small and medium batches. The methodologies developed in this book deal with the integration of the assembly process from the initial design of the product to its production. In such an integrated system, assembly planning is one of the most important features. A well-chosen assembly plan will reduce both the number of tool changes and the fixtures within the assembly cell. It will prevent the handling of unstable subassemblies, simplify the design of the robot grippers and reduce production costs. An automatic generator of assembly sequences can be an efficient aid to the designer. Whenever he or she modifies features of the product, the influence of these modifications can immediately be checked on the sequences. For small batch production, the automatic generation of assembly sequences is faster, more reliable and more cost-effective than manual generation. By using this latter method interesting sequences could be missed because of the combinatorial explosion of solutions. The main subjects treated in this book are as follows. 1. Presentation and classification of existing systems of automatic generation of assembly sequences. Automatic assembly planning is, indeed, a very recent research area and, in my experience, no systematic study has been carried out up to now.

CIM (computer integrated manufacturing) is an acronym that has become fairly well known in recent years in manufacturing and related engineering circles. The purpose of the CIM Project at IIASA is to close the widening gap between the pace of technological, economic, and social events, on the one hand, and the progress of understanding those events, on the other. The IIASA study has attempted, first, to define the existing world situation with regard to the underlying technologies of CIM, and the degrees to which technologies such as NC/CNC machine tools, robotics, and CAD/CAM are currently being used in metal products manufacturing. The methodology adopted in the study is eclectic. It is multiperspective and multidisciplinary, as well as multinational. It incorporates elements of both "bottom-up" and "top-down" approaches. Finally, it incorporates both historical analysis and "model" forecasts of the future, together with scenarios analyses. This first volume is a summary volume and describes the outputs of the bottom-up part of the study.

CIM (computer integrated manufacturing) is an acronym that has become fairly well known in recent years in manufacturing and related engineering circles. The purpose of the CIM Project at IIASA is to close the widening gap between the pace of technological, economic, and social events, on the one hand, and the progress of understanding those events, on the other. The IIASA study has attempted, first, to define the existing world situation with regard to the underlying technologies of CIM, and the degrees to which technologies such as NC/CNC machine tools, robotics, and CAD/CAM are currently being used in metal products manufacturing. The methodology adopted in the study is eclectic. It is multiperspective and multidisciplinary, as well as multinational. It incorporates elements of both "bottom-up" and "top-down" approaches. Finally, it incorporates both historical analysis and "model" forecasts of the future, together with scenarios analyses. This fourth volume in the series focuses on the effects of CIM on society and the economy in both quantitative and qualitative terms.