This book offers the guidelines on long-term confinement of fine particulate waste products in a safe and environmentally acceptable location. It seeks to present the state of the art, drawing on combined experience from within the European Union (EU), on good international practice where relevant and on lessons learnt from recent untoward incidents. These guidelines have been developed in parallel with the development of the European Standard on Earthworks (prEN 16907) and the contents have been influenced by the well-publicised need for guidance to all stakeholders on both technical and regulatory aspects of the permitting, design and construction of extractive waste facilities in Europe. The Extractive Waste Directive (EWD) imposes a duty on all operators and regulators to ensure the competent design, operation and closure of such facilities. However, though some guidance has been published on a limited number of related technical elements, the relevance of these contributions has been diminished by the lack of an integrated approach. It is now evident to both regulatory bodies and operators alike that a unified and comprehensive document providing guidance to all stakeholders is required if the future of mining within the EU is to be assured and further untoward incidents avoided. These guidelines seek to address all technical stages of the development of a hydraulic fill project in the context of the EWD, with an emphasis on waste and facility characterisation and on the risk-based assessments which underwrite them. They are intended for use by all stakeholders involved in those European industries which involve the generation, transport and storage of fine particulate waste products requiring long-term confinement in a safe, stable and environmentally acceptable location.

Over the last fifteen years, space-based exploration of the solar system has increased dramatically, with more and more sophisticated orbiters and landers being sent to Mars. This intense period, rich in unprecedented scientific results, has led to immense progress in our perception of Mars and of its evolution over geological time. In parallel, advances in numerical simulations and laboratory experiments also shed new light on the geochemical evolution of the planet Mars. The ISSI-Europlanet Workshop entitled "Quantifying the Martian Geochemical Reservoirs" was held in Bern in April 2011 with the objective to create a diverse interdisciplinary forum composed of scientists directly involved in space-based exploration of the Martian surface, meteoriticists studying SNC meteorites, and planetary and/or Earth scientists simulating, numerically or experimentally, the physical and chemical processes occurring on or within Mars. The chapters of this book provide an overview of current knowledge of the past and present Martian geochemical reservoirs, from the accretionary history to the secondary alteration processes at the surface. In addition to the detailed description of data from Mars and the methods used to obtain them, the contributions also emphasize comparison with features on Earth, providing a perspective on the extent to which our knowledge of terrestrial systems influences interpretation of data from Mars. Areas that would benefit from future work and measurements are also identified, providing a view of the short-term and long-term future of the study of Mars. This collection of chapters constitutes a timely perspective on current knowledge and thinking concerning the geochemical evolution of Mars, providing context and a valuable reference point for even more exciting future discoveries. It is aimed at graduate students and researchers active in geochemistry and space science. Previously published in Space Science Reviews, Vol. 174/1-4, 2013.

1000 DegreesC) and low pressures (< 2 kb) and typically results in the formation of "burnt" and fused rocks termed buchites, paralavas, clinkers and fulgarites. It is typically associated with shallow basaltic intrusions (contact aureoles, xenoliths,) combustion of carbonaceous matter, lightning strikes, and is also found in meteorites. During pyrometamorphism, the sequence of heating and cooling is greatly condensed favouring the preservation of a variety of stranded reaction microstructures that reflect disequilibrium reaction kinetics with metastable and mineral crystallisation. This second edition includes the latest developments in the study of pyrometamorphism derived from over 60 new references and accompanied with over 20 new illustrations.

This book brings together contributions from groundwater researchers and scientists on underground water resources in Egypt's deserts. The aquifers' quantity and quality are evaluated in many regions of the Egyptian deserts using established methods that can be effectively employed to investigate the potential for sustainable development in Egypt and similarly arid countries. The water resources in Egypt's deserts are subject to deterioration, mainly by land salinization and water deficiency. This book presents the best management practices, water quantity and quality, and optimal and sustainable usage of available groundwater. The book offers a unique guide for all readers interested in groundwater, modeling, and assessment for sustainable development in Egypt and countries with similar weather and water conditions.

This book includes a collection of chapters illustrating the application of geochemical methods to investigate the interactions between geological materials and fluids with humans. Examples include the incorporation and human health effects of inhaling lithogenic materials, the reactivity of biological fluids with geological materials, and the impact on nascent biomineral formation. Biomineralization is investigated in terms of mineralogy, morphology, bone chemistry, and pathological significance with a focus on the health impacts of "foreign" geological/environmental trace element incorporation. One of the contribution is devoted to particulate matter, the presence of metals and metalloids in the environment, and the possibility of using human hair as a biomarker between environmental/geological exposure and human bioincorporation. Other chapters focus on the last advances on the analytical methods and instrumentational approaches to investigating the chemistry of biological fluids and tissues.

There are several books on properties of chitin and associated biomolecules and their biochemical significance. However, the present volume deals with a wide variety of biogeochemical and organic geochemical aspects of this vital macromolecule written by leading authors and experts in the field. Each chapter is carefully peer reviewed and is an updated account of recent research in isotopic, nanostructural, biochemical, microstructural, geochemical, paleontological and experimental aspects of chitin formation, distribution and preservation in the environment and earth history.

Chemical additives are used to enhance the properties of many industrial products. Since their release into the environment is a potential risk for man and nature, their fate and behavior have been investigated in the framework of the European Union-funded project RISKCYCLE. The results are presented in two volumes, Global Risk-Based Management of Chemical Additives I: Production, Usage and Environmental Occurrence and Global Risk-Based Management of Chemical Additives II: Risk-Based Assessment and Management Strategies. This book is the second of the two volumes and features two main parts. In the first part, experts in the field discuss different models related to the assessment of the potential risks posed by chemical additives and analyze their benefits and drawbacks. In the second part, specific case studies in which the models have been applied are presented and the reliability of the models is evaluated. This volume is an invaluable source of information for scientists and governmental agencies dealing with the risk assessment of chemicals on a global scale.

When did life first appear on Earth and what form did it take? The answer to this intriguing and fundamentally important question lies somewhere within the early Archean rock record. The young Earth was, however, a very different place to that we know today and numerous pitfalls await our interpretation of these most ancient rocks.

The first half of this practical guide equips the reader with the background knowledge to successfully evaluate new potentially biological finds from the Archean rock record. Successive steps are covered, from locating promising samples in the field, through standard petrography and evaluation of antiquity and biogenicity criteria, to the latest state of the art geochemical techniques. The second half of the guide uniquely brings together all the materials that have been claimed to comprise the earliest fossil record into an easily accessible, fully illustrated format.

This will be a handbook that every Archean geologist, palaeobiologist and astrobiologist will wish to have in their backpack or on their lab-bench.

The book starts with an introduction on silicon isotopes and related analytical methods, and explains the mechanisms of silicon isotope fractionation. Silicon isotope distributions in lithosphere, hydrosphere and biosphere are shown based on results from field studies, and silicon isotope relevance for applications are presented.

Minerals respond texturally and compositionally to changing magmatic environments and preserve a wealth of information regarding magmatic processes and compositions in their crystal-growth stratigraphy. This book reports the detailed petrography and in-situ geochemistry of the clinopyroxene phenocrysts of the mafic dykes in the Jiaodong Peninsula, southeastern North China Craton, including in-situ determinations of major elements, trace elements, Sr isotopic compositions, and H2O contents with further constraints on the petrogenesis and geodynamics of the mafic dykes. Systematic analyses of mineralogical, major, and trace elements, Sr-Nd isotopes, and in-situ S isotopes on the pyrite of the main gold-bearing mineral assemblages and visible gold were conducted, aiming to explore the source of ore-forming materials and the process of Au element migration and deposition. The geodynamic setting of mineralization in the studied region is also summarized.

This book is written for researchers and students interested in the function and role of chemical elements in biological or environmental systems. Experts have long known that the Periodic System of Elements (PSE) provides only an inadequate chemical description of elements of biological, environmental or medicinal importance. This book explores the notion of a Biological System of the Elements (BSE) established on accurate and precise multi-element data, including evolutionary aspects, representative sampling procedures, inter-element relationships, the physiological function of elements and uptake mechanisms. The book further explores the concept Stoichiometric Network Analysis (SNA) to analyze the biological roles of chemical species. Also discussed is the idea of ecotoxicological identity cards which give a first-hand description of properties relevant for biological and toxicological features of a certain chemical element and its geo biochemically plausible speciation form. The focus of this book goes beyond both classical bioinorganic chemistry and toxicology.

This book provides two state-of-the-art quantitative techniques to determine ultra-trace rare earth elements (REEs) in natural carbonates using solution nebulization-inductively coupled plasma mass spectrometry (SN-ICPMS) and laser ablation-inductively coupled plasma mass spectrometry (LA-ICPMS) with respective applications were presented in this dissertation. These techniques were applied to natural carbonates, including corals and stalagmites, to understand volcano eruptions and the impacts on modern biosystem and paleoclimate regimes. In the first SN-ICPMS protocol, direct measurements for femtogram quantity carbonate samples without chemical separation steps can offer accurate and high-precision analysis (+/-1.9-6.5%, 2 ) with a high sample throughput of 8-10 samples/hr routinely. Application to modern Porites corals collected from South China Sea region, the anomalies of REE contents and Al/Ca ratios associated with micro-domain images, register modern coral reefs could be exacerbated by volcanic eruptions. In the second protocol, a high-sensitivity quantitative open-cell LA-ICPMS technique has been established to allow direct sampling on stalagmite surface in the atmospheric air. This technique improved limits of detection down to sub-ng/g range and promises analyses of carbonate REE profiles at the single digit parts-per-billion (ppb) levels. Application to a 15-cm stalagmite collected from East Timor reveals two peaks of REE contents by at least one order of magnitude, possibly due to volcanic ash preserved in stalagmite. Both improved SN-ICPMS and LA-ICPMS techniques highlight the high-sensitivity and high-temporal-resolution carbonate REE analyses for corals and stalagmites, with great potential to other natural carbonates such as travertine, tufa, and flowstone, benefit our understanding of paleoclimatic and paleoenvironmental dynamics.

This book provides an overview of the fundamentals and reference values for Ca stable isotope research, as well as current analytical methodologies including detailed instructions for sample preparation and isotope analysis. As such, it introduces readers to the different fields of application, including low-temperature mineral precipitation and biomineralisation, Earth surface processes and global cycling, high-temperature processes and cosmochemistry, and lastly human studies and biomedical applications. The current state of the art in these major areas is discussed, and open questions and possible future directions are identified. In terms of its depth and coverage, the current work extends and complements the previous reviews of Ca stable isotope geochemistry, addressing the needs of graduate students and advanced researchers who want to familiarize themselves with Ca stable isotope research.

The first volume in this new text book series covers comprehensively relevant aspects related to the appearance and characterisation of fossil matter in the geosphere such as kerogen, oil, shales and coals. As organic geochemistry is a modern scientific subject characterized by a high transdisciplinarity and located at the edge of chemistry, environmental sciences, geology and biology, there clearly is a need for a flexible offer of appropriate academic teaching material on an undergraduat level addressed to the variety of students coming originally from different study disciplines. For such a flexible usage this textbook series' consists of different volumes with clear defined aspects and with manageable length.

This book presents an overview of recent advances in our understanding of the genesis of diamonds and the associated phases. It is divided into three main parts, starting with an introduction to the analysis of diamond inclusions to infer the formation processes. In turn, the second part of the book presents high-pressure experimental studies in mantle diamond-parental mineral systems with representative multicomponent boundary compositions. The experimental syngenesis phase diagrams provided reveal the physicochemical mechanisms of diamond nucleation and substantiate the mantle-carbonatite concept of the genesis of diamonds and associated phases. Lastly, the book describes the genetic classification of diamond-hosted mineral inclusions and experimentally determined RE "mineral-parental melt" partition coefficients. The physicochemical experimental evidence presented shows the driving forces behind the fractional evolution of the mantle magmas and diamond-parental melts. Given the depth and breadth of its coverage, the book offers researchers essential new insights into the ways diamonds and associated minerals and rocks are naturally created.

"Distribution and Transformation of Nutrients and Eutrophication in Large-scale Lakes and Reservoirs: The Three Gorges Reservoir" presents key findings on early eutrophication in large-scale lakes and reservoirs, providing readers with an overview of lake management problems and the tools that can be applied to solve them. The broad spectrum of available tools is presented in detail, including environmental technological methods, ecotechnological methods and the application of models to determine the best management strategy.

The book is intended for environmental engineers and researchers in the fields of environmental science and ecological chemistry.

Professor Zhenyao Shen, Professor Junfeng Niu and Associate Professor Ying Wang work at the School of Environment, Beijing Normal University, China. Dr. Hongyuan Wang works at Chinese Academy of Agricultural Sciences, China. Dr. Xin Zhao works at Changjiang River Scientific Research Institute, China.

This book provides a comprehensive summary of research to date in the field of stable iron isotope geochemistry. Since research began in this field 20 years ago, the field has grown to become one of the major research fields in "non-traditional" stable isotope geochemistry. This book reviews all aspects of the field, from low-temperature to high-temperature processes, biological processes, and cosmochemical processes. It provides a detailed history and state-of-the art summary about analytical methods to determine Fe-isotope ratios and discusses analytical and sample prospects.

This book is both a review and a look to the future, highlighting challenges for better predicting quantitatively the impact of diagenesis on reservoir rocks. Classical diagenesis studies make use of a wide range of descriptive analytical techniques to explain specific, relatively time-framed fluid-rock interaction processes, and deduce their impacts on reservoir rocks. Future operational workflows will consist of constructing a conceptual diagenesis model, quantifying the related diagenetic phases, and modelling the diagenetic processes. Innovative approaches are emerging for applied quantitative diagenesis, providing numerical data that can be used by reservoir engineers as entry (input) data, and for validating results of numerical simulations. Geometry-based, geostatistical and geochemical modelling do not necessarily mimic natural processes, they rather provide reasonable solutions to specific problems.

Most of the world s mountains are rich in water and, as such, play a pivotal role in the global water cycle. They provide water for diverse human uses and ecosystems. Growing water demands as well as climate change will lead to ever-increasing pressure on mountain waters. Overcoming water-use conflicts and maintaining the ecological functioning of mountain waters presents a highly challenging task and is indispensable for sustainable development.
This book extensively portrays the highly diverse attributes of mountain waters and demonstrates their paramount importance for ecological and societal development. The extensive summaries on the scientific basics of mountain waters are supplemented with considerations on the diverse water uses, needs for management actions, and challenges regarding sustainable water management. This overview concerns not only the mountain areas themselves but also downriver reaches and their surrounding lowlands, and, therefore, the relationship between mountain and lowland water issues."

This book presents recent research into developing and applying computational tools to estimate the performance and safety of hydraulic structures from the planning and construction stage to the service period. Based on the results of a close collaboration between the author and his colleagues, friends, students and field engineers, it shows how to achieve a good correlation between numerical computation and the actual in situ behavior of hydraulic structures. The book's heuristic and visualized style disseminates the philosophy and road map as well as the findings of the research. The chapters reflect the various aspects of the three typical and practical methods (the finite element method, the block element method, the composite element method) that the author has been working on and made essential contributions to since the 1980s. This book is an advanced continuation of Hydraulic Structures by the same author, published by Springer in 2015.

Following release to the environment, synthetic chemicals may be degraded by biotic and abiotic processes. The degradation of the chemical can follow a plethora of pathways and a range of other substances can be formed via thesedifferentpathways(e.g.[1]).Anumberoftermshavebeenusedforthese substances including metabolites, degradates and transformation products - in this book we use the term transformation products. While we often know a lot about the environmental properties and effects of the parent synthetic chemical, we know much less about the transformationproducts. Transformationproductscanbehave very differently fromtheparent c- pound (e.g. [2]). For example, selected transformation products are much more persistent than their associated parent compound in soils, waters and sediments andsomemaybetransported aroundthelocal,regionalandglobal environmentstoadifferentextentthantheparentcompound.Transformation products can also have very different toxicities than the parent compound (e.g. [3]) and in some cases transformation products can be orders of mag- tude more toxic than their parent compound; although this situation is rare. The environmental risks of transformation products can therefore be very different than the risks of the parent compound. Thepotentialenvironmentalimpactsoftransformationproductsarerec- nised by many regulatory assessment schemes. For example, in the EU, pes- cideproducersarenotonlyrequiredtoassessthefateandeffectsoftheparent pesticide but are also required to assess the potential adverse effects of major metabolitesandminor metabolitesthat aredeemed tobeofconcern[4]. S- ilar requirements also exist for new human and veterinary pharmaceuticals and biocides (e.g. [5]). However, for many older substances and many other substance classes (e.g. industrial chemicals), data on the environmental risks of transformationproductscan be limited or non-existent.

Written by two of the best US researchers in the field, this text investigates issues of astrobiological relevance in the context of cold aqueous planetary geochemistry. At the core of the technical chapters is the FREZCHEM model, initially developed over many years by one of the authors to quantify aqueous electrolyte properties and chemical thermodynamics at subzero temperatures. FREZCHEM is of huge relevance to scientists in a number of fields, including biogeochemists.

This book is aimed at generalizing the modern ideas of both biogeochemical and environmental risk assessment that have been developed in recent years. Only a few books are available for readers in this interdisciplinary area, since most books deal mainly with various technical aspects of ERA description and calculations. This text aims at supplementing the existing books by providing a modern understanding of mechanisms that are responsible for ecological risks for human beings and ecosystems. The book is to a certain extent a summary of both scientific results of various authors and of classes in biogeochemistry and ERA, taught by the author in recent years to students in the USA, in particular at Cornell, and in different universities in Moscow, Pushchino, Seoul, and Bangkok.

South America is a unique place where a number of past climate archives are ava- able from tropical to high latitude regions. It thus offers a unique opportunity to explore past climate variability along a latitudinal transect from the Equator to Polar regions and to study climate teleconnections. Most climate records from tropical and subtropical South America for the past 20,000 years have been interpreted as local responses to shift in the mean position and intensity of the InterTropical Conv- gence Zone due to tropical and extratropical forcings or to changes in the South American Summer Monsoon. Further South, the role of the Southern Hemisphere westerly winds on global climate has been highly investigated with both paleodata and coupled climate models. However the regional response over South America during the last 20,000 years is much more variable from place to place than pre- ously thought. The factors that govern the spatial patterns of variability on millennial scale resolution are still to be understood. The question of past natural rates and ranges of climate conditions over South America is therefore of special relevance in this context since today millions of people live under climates where any changes in monsoon rainfall can lead to catastrophic consequences.

These proceedings comprise the peer-reviewed contributions submitted to the 11th International Congress for Applied Mineralogy (ICAM) held July 5-10, 2013, at the Southwest University of Science and Technology (SWUST) in Mianyang, China. The biennial ICAM is the most important gathering of applied mineralogists, organized every other year by the ICAM-Council. The multidisciplinary research presented in this book will be of interest to scientists and professionals dealing with topics like environmental and medical mineralogy; industrial minerals; bio-minerals and biomaterials; advanced materials; process mineralogy; mining and metallurgy; cultural heritage; the interaction of minerals with microorganisms; and solid waste treatment and recycling, including genetic mineralogy. "The field of applied mineralogy has been able to match society's pace by continuously reinventing itself, quickly adopting new technologies and instrumentation as they became available and putting them to work for the service of mankind living in a world that heavily relies on minerals. Over the past few decades, applied mineralogy has evolved into a cutting- edge discipline that leads the way for science, engineering and research and development to benefit society. Contrary to popular belief, mineral resources are limited, and we have an obligation to our heirs to use them responsibly." Dr. Maarten A.T.M. Broekmans Post-President ICAM Council