Over the last fifteen years, space-based exploration of the solar system has increased dramatically, with more and more sophisticated orbiters and landers being sent to Mars. This intense period, rich in unprecedented scientific results, has led to immense progress in our perception of Mars and of its evolution over geological time. In parallel, advances in numerical simulations and laboratory experiments also shed new light on the geochemical evolution of the planet Mars. The ISSI-Europlanet Workshop entitled "Quantifying the Martian Geochemical Reservoirs" was held in Bern in April 2011 with the objective to create a diverse interdisciplinary forum composed of scientists directly involved in space-based exploration of the Martian surface, meteoriticists studying SNC meteorites, and planetary and/or Earth scientists simulating, numerically or experimentally, the physical and chemical processes occurring on or within Mars. The chapters of this book provide an overview of current knowledge of the past and present Martian geochemical reservoirs, from the accretionary history to the secondary alteration processes at the surface. In addition to the detailed description of data from Mars and the methods used to obtain them, the contributions also emphasize comparison with features on Earth, providing a perspective on the extent to which our knowledge of terrestrial systems influences interpretation of data from Mars. Areas that would benefit from future work and measurements are also identified, providing a view of the short-term and long-term future of the study of Mars. This collection of chapters constitutes a timely perspective on current knowledge and thinking concerning the geochemical evolution of Mars, providing context and a valuable reference point for even more exciting future discoveries. It is aimed at graduate students and researchers active in geochemistry and space science. Previously published in Space Science Reviews, Vol. 174/1-4, 2013.

This text outlines the fundamentals required to understand the science of thermodynamics and provides a comprehensive and balanced coverage of the application of thermodynamics in geochemistry.

There are several books on properties of chitin and associated biomolecules and their biochemical significance. However, the present volume deals with a wide variety of biogeochemical and organic geochemical aspects of this vital macromolecule written by leading authors and experts in the field. Each chapter is carefully peer reviewed and is an updated account of recent research in isotopic, nanostructural, biochemical, microstructural, geochemical, paleontological and experimental aspects of chitin formation, distribution and preservation in the environment and earth history.

This book details the analytical processes, and interpretation of the resulting data, needed in order to achieve a comprehensive source-rock evaluation of organic-rich shales. The authors employ case studies on Permian and Cretaceous shales from various Indian basins and other petroleum-bearing basins around the world to illustrate the key features of their organic-rich shale characterization methodology. These case studies may also help to identify potential zones within shale formations that could be exploited for commercial gas and/or oil production. Given its scope, the book will be of interest to all researchers working in the field of source-rock analysis. In addition, the source-rock evaluation techniques - and the various intricacies associated with them - discussed here offer valuable material for postgraduate geology courses.

This book offers the guidelines on long-term confinement of fine particulate waste products in a safe and environmentally acceptable location. It seeks to present the state of the art, drawing on combined experience from within the European Union (EU), on good international practice where relevant and on lessons learnt from recent untoward incidents. These guidelines have been developed in parallel with the development of the European Standard on Earthworks (prEN 16907) and the contents have been influenced by the well-publicised need for guidance to all stakeholders on both technical and regulatory aspects of the permitting, design and construction of extractive waste facilities in Europe. The Extractive Waste Directive (EWD) imposes a duty on all operators and regulators to ensure the competent design, operation and closure of such facilities. However, though some guidance has been published on a limited number of related technical elements, the relevance of these contributions has been diminished by the lack of an integrated approach. It is now evident to both regulatory bodies and operators alike that a unified and comprehensive document providing guidance to all stakeholders is required if the future of mining within the EU is to be assured and further untoward incidents avoided. These guidelines seek to address all technical stages of the development of a hydraulic fill project in the context of the EWD, with an emphasis on waste and facility characterisation and on the risk-based assessments which underwrite them. They are intended for use by all stakeholders involved in those European industries which involve the generation, transport and storage of fine particulate waste products requiring long-term confinement in a safe, stable and environmentally acceptable location.

This book includes a collection of chapters illustrating the application of geochemical methods to investigate the interactions between geological materials and fluids with humans. Examples include the incorporation and human health effects of inhaling lithogenic materials, the reactivity of biological fluids with geological materials, and the impact on nascent biomineral formation. Biomineralization is investigated in terms of mineralogy, morphology, bone chemistry, and pathological significance with a focus on the health impacts of "foreign" geological/environmental trace element incorporation. One of the contribution is devoted to particulate matter, the presence of metals and metalloids in the environment, and the possibility of using human hair as a biomarker between environmental/geological exposure and human bioincorporation. Other chapters focus on the last advances on the analytical methods and instrumentational approaches to investigating the chemistry of biological fluids and tissues.

The book will include chapters which will span from the role of geochemistry in the environment in general to the specific investigations on site characterization (dealing with sampling strategy, analytical procedures and problems). Specific articles will deal with health problems related to environment pollution, waste disposal, data base management, and illustration of specific case histories for characterization and remediation of brownfield sites.
* Comprehensive analysis providing background information on geochemistry in general through to specific investigations
* Provides practical insight through case study material
* Informs and updates students and practitioners on hot topics, latest trends and developments

Chemical additives are used to enhance the properties of many industrial products. Since their release into the environment is a potential risk for man and nature, their fate and behavior have been investigated in the framework of the European Union-funded project RISKCYCLE. The results are presented in two volumes, Global Risk-Based Management of Chemical Additives I: Production, Usage and Environmental Occurrence and Global Risk-Based Management of Chemical Additives II: Risk-Based Assessment and Management Strategies. This book is the second of the two volumes and features two main parts. In the first part, experts in the field discuss different models related to the assessment of the potential risks posed by chemical additives and analyze their benefits and drawbacks. In the second part, specific case studies in which the models have been applied are presented and the reliability of the models is evaluated. This volume is an invaluable source of information for scientists and governmental agencies dealing with the risk assessment of chemicals on a global scale.

When did life first appear on Earth and what form did it take? The answer to this intriguing and fundamentally important question lies somewhere within the early Archean rock record. The young Earth was, however, a very different place to that we know today and numerous pitfalls await our interpretation of these most ancient rocks.

The first half of this practical guide equips the reader with the background knowledge to successfully evaluate new potentially biological finds from the Archean rock record. Successive steps are covered, from locating promising samples in the field, through standard petrography and evaluation of antiquity and biogenicity criteria, to the latest state of the art geochemical techniques. The second half of the guide uniquely brings together all the materials that have been claimed to comprise the earliest fossil record into an easily accessible, fully illustrated format.

This will be a handbook that every Archean geologist, palaeobiologist and astrobiologist will wish to have in their backpack or on their lab-bench.

This volume is for environmental researchers and government policy makers who are required to monitor environmental quality for their environmental investigators and remediation plans. It uses concepts and applications to aid in the exchange of scientific information across all the environmental science disciplines ranging from geochemistry to hydrogeology and ecology to biotechnology. Focusing on issues such as metals, organics and nutrient contamination of water and soils, and interactions between soil-water-plants-chemicals, the book synthesizes the latest findings in this rapidly-developing, multi-disciplinary field. Cutting-edge environmental analytical methods are also presented, making this a must-have for professionals tasked with monitoring environmental quality. These concepts and applications help in decision making and problem solving in a single resource.
*Integrative approach promotes the exchange of scientific information among difference disciplines
*New concepts and case studies make the text unique among existing resources
*Tremendous practical value in the fields of environmental quality and remediation with an emphasis on human health and ecological risk assessment

The book starts with an introduction on silicon isotopes and related analytical methods, and explains the mechanisms of silicon isotope fractionation. Silicon isotope distributions in lithosphere, hydrosphere and biosphere are shown based on results from field studies, and silicon isotope relevance for applications are presented.

This book is written for researchers and students interested in the function and role of chemical elements in biological or environmental systems. Experts have long known that the Periodic System of Elements (PSE) provides only an inadequate chemical description of elements of biological, environmental or medicinal importance. This book explores the notion of a Biological System of the Elements (BSE) established on accurate and precise multi-element data, including evolutionary aspects, representative sampling procedures, inter-element relationships, the physiological function of elements and uptake mechanisms. The book further explores the concept Stoichiometric Network Analysis (SNA) to analyze the biological roles of chemical species. Also discussed is the idea of ecotoxicological identity cards which give a first-hand description of properties relevant for biological and toxicological features of a certain chemical element and its geo biochemically plausible speciation form. The focus of this book goes beyond both classical bioinorganic chemistry and toxicology.

This book brings together contributions from groundwater researchers and scientists on underground water resources in Egypt's deserts. The aquifers' quantity and quality are evaluated in many regions of the Egyptian deserts using established methods that can be effectively employed to investigate the potential for sustainable development in Egypt and similarly arid countries. The water resources in Egypt's deserts are subject to deterioration, mainly by land salinization and water deficiency. This book presents the best management practices, water quantity and quality, and optimal and sustainable usage of available groundwater. The book offers a unique guide for all readers interested in groundwater, modeling, and assessment for sustainable development in Egypt and countries with similar weather and water conditions.

This book presents an overview of recent advances in our understanding of the genesis of diamonds and the associated phases. It is divided into three main parts, starting with an introduction to the analysis of diamond inclusions to infer the formation processes. In turn, the second part of the book presents high-pressure experimental studies in mantle diamond-parental mineral systems with representative multicomponent boundary compositions. The experimental syngenesis phase diagrams provided reveal the physicochemical mechanisms of diamond nucleation and substantiate the mantle-carbonatite concept of the genesis of diamonds and associated phases. Lastly, the book describes the genetic classification of diamond-hosted mineral inclusions and experimentally determined RE "mineral-parental melt" partition coefficients. The physicochemical experimental evidence presented shows the driving forces behind the fractional evolution of the mantle magmas and diamond-parental melts. Given the depth and breadth of its coverage, the book offers researchers essential new insights into the ways diamonds and associated minerals and rocks are naturally created.

Most of the world s mountains are rich in water and, as such, play a pivotal role in the global water cycle. They provide water for diverse human uses and ecosystems. Growing water demands as well as climate change will lead to ever-increasing pressure on mountain waters. Overcoming water-use conflicts and maintaining the ecological functioning of mountain waters presents a highly challenging task and is indispensable for sustainable development.
This book extensively portrays the highly diverse attributes of mountain waters and demonstrates their paramount importance for ecological and societal development. The extensive summaries on the scientific basics of mountain waters are supplemented with considerations on the diverse water uses, needs for management actions, and challenges regarding sustainable water management. This overview concerns not only the mountain areas themselves but also downriver reaches and their surrounding lowlands, and, therefore, the relationship between mountain and lowland water issues."

"Distribution and Transformation of Nutrients and Eutrophication in Large-scale Lakes and Reservoirs: The Three Gorges Reservoir" presents key findings on early eutrophication in large-scale lakes and reservoirs, providing readers with an overview of lake management problems and the tools that can be applied to solve them. The broad spectrum of available tools is presented in detail, including environmental technological methods, ecotechnological methods and the application of models to determine the best management strategy.

The book is intended for environmental engineers and researchers in the fields of environmental science and ecological chemistry.

Professor Zhenyao Shen, Professor Junfeng Niu and Associate Professor Ying Wang work at the School of Environment, Beijing Normal University, China. Dr. Hongyuan Wang works at Chinese Academy of Agricultural Sciences, China. Dr. Xin Zhao works at Changjiang River Scientific Research Institute, China.

The first volume in this new text book series covers comprehensively relevant aspects related to the appearance and characterisation of fossil matter in the geosphere such as kerogen, oil, shales and coals. As organic geochemistry is a modern scientific subject characterized by a high transdisciplinarity and located at the edge of chemistry, environmental sciences, geology and biology, there clearly is a need for a flexible offer of appropriate academic teaching material on an undergraduat level addressed to the variety of students coming originally from different study disciplines. For such a flexible usage this textbook series' consists of different volumes with clear defined aspects and with manageable length.

This book provides an overview of the fundamentals and reference values for Ca stable isotope research, as well as current analytical methodologies including detailed instructions for sample preparation and isotope analysis. As such, it introduces readers to the different fields of application, including low-temperature mineral precipitation and biomineralisation, Earth surface processes and global cycling, high-temperature processes and cosmochemistry, and lastly human studies and biomedical applications. The current state of the art in these major areas is discussed, and open questions and possible future directions are identified. In terms of its depth and coverage, the current work extends and complements the previous reviews of Ca stable isotope geochemistry, addressing the needs of graduate students and advanced researchers who want to familiarize themselves with Ca stable isotope research.

This book is both a review and a look to the future, highlighting challenges for better predicting quantitatively the impact of diagenesis on reservoir rocks. Classical diagenesis studies make use of a wide range of descriptive analytical techniques to explain specific, relatively time-framed fluid-rock interaction processes, and deduce their impacts on reservoir rocks. Future operational workflows will consist of constructing a conceptual diagenesis model, quantifying the related diagenetic phases, and modelling the diagenetic processes. Innovative approaches are emerging for applied quantitative diagenesis, providing numerical data that can be used by reservoir engineers as entry (input) data, and for validating results of numerical simulations. Geometry-based, geostatistical and geochemical modelling do not necessarily mimic natural processes, they rather provide reasonable solutions to specific problems.

This book provides a comprehensive summary of research to date in the field of stable iron isotope geochemistry. Since research began in this field 20 years ago, the field has grown to become one of the major research fields in "non-traditional" stable isotope geochemistry. This book reviews all aspects of the field, from low-temperature to high-temperature processes, biological processes, and cosmochemical processes. It provides a detailed history and state-of-the art summary about analytical methods to determine Fe-isotope ratios and discusses analytical and sample prospects.

South America is a unique place where a number of past climate archives are ava- able from tropical to high latitude regions. It thus offers a unique opportunity to explore past climate variability along a latitudinal transect from the Equator to Polar regions and to study climate teleconnections. Most climate records from tropical and subtropical South America for the past 20,000 years have been interpreted as local responses to shift in the mean position and intensity of the InterTropical Conv- gence Zone due to tropical and extratropical forcings or to changes in the South American Summer Monsoon. Further South, the role of the Southern Hemisphere westerly winds on global climate has been highly investigated with both paleodata and coupled climate models. However the regional response over South America during the last 20,000 years is much more variable from place to place than pre- ously thought. The factors that govern the spatial patterns of variability on millennial scale resolution are still to be understood. The question of past natural rates and ranges of climate conditions over South America is therefore of special relevance in this context since today millions of people live under climates where any changes in monsoon rainfall can lead to catastrophic consequences.

Written by two of the best US researchers in the field, this text investigates issues of astrobiological relevance in the context of cold aqueous planetary geochemistry. At the core of the technical chapters is the FREZCHEM model, initially developed over many years by one of the authors to quantify aqueous electrolyte properties and chemical thermodynamics at subzero temperatures. FREZCHEM is of huge relevance to scientists in a number of fields, including biogeochemists.

Following release to the environment, synthetic chemicals may be degraded by biotic and abiotic processes. The degradation of the chemical can follow a plethora of pathways and a range of other substances can be formed via thesedifferentpathways(e.g.[1]).Anumberoftermshavebeenusedforthese substances including metabolites, degradates and transformation products - in this book we use the term transformation products. While we often know a lot about the environmental properties and effects of the parent synthetic chemical, we know much less about the transformationproducts. Transformationproductscanbehave very differently fromtheparent c- pound (e.g. [2]). For example, selected transformation products are much more persistent than their associated parent compound in soils, waters and sediments andsomemaybetransported aroundthelocal,regionalandglobal environmentstoadifferentextentthantheparentcompound.Transformation products can also have very different toxicities than the parent compound (e.g. [3]) and in some cases transformation products can be orders of mag- tude more toxic than their parent compound; although this situation is rare. The environmental risks of transformation products can therefore be very different than the risks of the parent compound. Thepotentialenvironmentalimpactsoftransformationproductsarerec- nised by many regulatory assessment schemes. For example, in the EU, pes- cideproducersarenotonlyrequiredtoassessthefateandeffectsoftheparent pesticide but are also required to assess the potential adverse effects of major metabolitesandminor metabolitesthat aredeemed tobeofconcern[4]. S- ilar requirements also exist for new human and veterinary pharmaceuticals and biocides (e.g. [5]). However, for many older substances and many other substance classes (e.g. industrial chemicals), data on the environmental risks of transformationproductscan be limited or non-existent.

The shock waves produced by meteorite impacts give rise not only to the obvious craters seen on planets and their satellites but also to subtle effects seen only with chemical and petrographic examination of the shocked material. Shock waves in the interplanetary and interstellar medium play an important role in the formation of stars and planets, including the solar system. They also produce important chemical effects in interstellar clouds of dust and gas, --- including the production of rather complex organic molecules. This volume is concerned primarily with the chemical and physical effects of shock waves on typical Earth and planetary solid materials. The emphasis is on comparing naturally occurring materials with similar materials produced by shock compression in the laboratory. Such comparisons can provide clues about the environment and events that produced the natural materials. The chapters in the book deal with three main topics: * methods used to investigate the effects of shock on recovered minerals and rocks * effects of shock on carbon and hydrocarbons * subtle effects of shocks on geochemistry, such as shock induced redistribution of lead isotopes, the effect of the great impact at the end of the Cretaceous on atmospheric SO2 and CO2, and effect of shocks on ices.

This book presents recent research into developing and applying computational tools to estimate the performance and safety of hydraulic structures from the planning and construction stage to the service period. Based on the results of a close collaboration between the author and his colleagues, friends, students and field engineers, it shows how to achieve a good correlation between numerical computation and the actual in situ behavior of hydraulic structures. The book's heuristic and visualized style disseminates the philosophy and road map as well as the findings of the research. The chapters reflect the various aspects of the three typical and practical methods (the finite element method, the block element method, the composite element method) that the author has been working on and made essential contributions to since the 1980s. This book is an advanced continuation of Hydraulic Structures by the same author, published by Springer in 2015.