On-surface synthesis is appearing as an extremely promising strategy to create organic nanoarchitectures with atomic precision. Molecular building blocks holding adequate functional groups are dosed onto surfaces that support or even drive their covalent linkage. The surface confinement and the frequent lack of solvents (most commonly being performed under vacuum conditions) create a completely new scenario fully complementary to conventional chemistry. In a pedagogical way and based on the most recent developments, this volume presents our current understanding in the field, addressing fundamental reaction mechanisms, synthetic strategies to influence the reactions according to our needs, as well as the ultimate growth and characterization of functional materials. Verging on chemistry, physics and materials science, the book is aimed at students and researchers interested in nanochemistry, surface science, supramolecular materials and molecular devices. Chapters "Mechanistic insights into surface-supported chemical reactions", "Reactivity on and of Graphene Layers: Scanning Probe Microscopy Reviels" and "Bottom-up fabrication of atomically precise graphene nanoribbons" of this book are available open access under a CC BY 4.0 license at link.springer.com

This thesis describes improvements to and control of the electrical conductance in single-molecule junctions (SMJs), which have potential applications in molecular electronics, with a focus on the bonding between the metal and molecule. In order to improve the electrical conductance, the orbital of the molecule is directly bonded to the metal orbital, because anchoring groups, which were typically used in other studies to bind molecule with metal electrodes, became resistive spacers. Using this direct -binding, the author has successfully demonstrated highly conductive SMJs involving benzene, endohedral metallofullerene Ce@C82, and nitrogen. Subsequently, the author investigated control of the electrical conductance of SMJs using pyrazine. The nitrogen atom in the -conjugated system of pyrazine was expected to function as an anchoring point, and two bonding states were expected. One originates primarily from the orbital, while the other originates primarily from an n state of the nitrogen. Measurements of conductance and dI/dV spectra coupled with theoretical calculations revealed that the pyrazine SMJ has bistable conductance states, in which the pyrazine axis is either tilted or parallel with respect to the junction axis. The bistable states were switched by changing the gap size between the metal electrodes using an external force. Notably, it is difficult to change the electrical properties of bulk-state materials using mechanical force. The findings reveal that the electron transport properties of a SMJ can be controlled by designing a proper metal-molecule interface, which has considerable potential for molecular electronics. Moreover, this thesis will serve as a guideline for every step of SMJ research: design, fabrication, evaluation, and control.

Humans first used carbon as chars from firewood in ritual paintings and primitive metallurgical processes. Natural forms of carbon have been known since antiquity, yet the knowledge of the carbon element in chemistry and its technical applications on a larger scale are a relatively recent development. The industrial revolution in Europe two centuries ago led the way to the numerous applications of these graphitic forms that are still used today. Graphite and Precursors features short tutorial articles on different topics related to the science and technology of carbons intended for engineers, students of Materials Science and scientists who are seeking a fundamental understanding without "reinventing the wheel." This first volume of the World of Carbon book series focuses on graphite and its precursors, including its origin and various implications. The basic properties of hexagonal graphite are developed, and several theoretical and experimental approaches explain why this crystalline solid is fascinating in solid state physics. Also featured are the numerous applications connected to thermal, mechanical and chemical graphites, as well as their various industrial uses in polycrystalline form. Finally, carbon precursors are introduced.

Ammonia is one of the 10 largest commodity chemicals produced. The editor, Anders Nielsen, is research director with one of the largest industrial catalyst producers. He has compiled a complete reference on all aspects of catalytical ammonia production in industry, from thermodynamics and kinetics to reactor and plant design. One chapter deals with safety aspects of ammonia handling and storage.

Corinna Reisinger has developed a new organocatalytic asymmetric epoxidation of cyclic and acyclic , -unsaturated ketones. In this thesis, Corinna documents her methodology, using primary amine salts as catalysts, and hydrogen peroxide as an inexpensive and environmentally benign oxidant. She describes the unprecedented and powerful catalytic asymmetric hydro peroxi dation of , -enones, a process which produces optically active five-membered cyclic peroxyhemiketals in a single operation. She also proves the versatility and synthetic value of the cyclic peroxyhemiketals by converting them into highly enantioenriched acyclic and cyclic aldol products. Currently, these cyclic aldol products are inaccessible by any other synthetic means. Furthermore, cyclic peroxyhemiketals are precursors to optically active 1,2-dioxolanes which are of biological relevance. This work is a breakthrough in the field of asymmetric epoxidation chemistry and outlines the most efficient method in the literature for generating highly enantioselective cyclic epoxyketones known to date.

Recent years have seen an explosion in the volume of work carried out using supersonic jets of molecules following the discovery that the technique could provide information on structure and dynamics of a very high quality otherwise impossible to obtain. Written and edited by a first class team of authors, acknowledged world leaders in their subjects, this book describes applications in detail along with analysis of data recorded and background theory. Physical chemists and chemical physicists will find this unique book an essential concentrated source of information and reference.

"Offers a comprehensive treatment of surface chemistry and its applications to chemical engineering, biology, and medicine. Focuses on the chmical and physical structure of oil-water interfaces and membrane surfaces. Details interfacial potentials, ion solvation, and electrostatic instabilities in double layers."

The breadth of scientific and technological interests in the general topic of photochemistry is truly enormous and includes, for example, such diverse areas as microelectronics, atmospheric chemistry, organic synthesis, non-conventional photoimaging, photosynthesis, solar energy conversion, polymer technologies, and spectroscopy. This Specialist Periodical Report on Photochemistry aims to provide an annual review of photo-induced processes that have relevance to the above wide-ranging academic and commercial disciplines, and interests in chemistry, physics, biology and technology. In order to provide easy access to this vast and varied literature, each volume of Photochemistry comprises sections concerned with photophysical processes in condensed phases, organic aspects which are sub-divided by chromophore type, polymer photochemistry, and photochemical aspects of solar energy conversion. Volume 34 covers literature published from July 2001 to June 2002. Specialist Periodical Reports provide systematic and detailed review coverage in major areas of chemical research. Compiled by teams of leading authorities in the relevant subject areas, the series creates a unique service for the active research chemist, with regular, in-depth accounts of progress in particular fields of chemistry. Subject coverage within different volumes of a given title is similar and publication is on an annual or biennial basis.

"Discusses the most recent advances in the correlations of structure and reactivity relationships of micelles, liposomes, microemulsions, and emulsions by thermal behavior measurements, as well as the options, scope, and limitations of the thermal behavior of dispersed systems. Highlights current studies on heterogeneous colloidal (dispersed) systems."

Nanocomposite structures and dispersions is concerned with the chemistry of the reaction approaches by which polymer and metal particles are synthesized. Although, the scope of this volume is focused on metal particles, the basic knowledge of polymer colloids preparation is presented. Therefore, this book would serve as a general introduction to people just entering the field and for the experts seeking for the information in other sub-fields.
Dealing with nanoscience and nanotechnology from the viewpoint of a chemist, therefore the book describes in detail terms, definitions, theories, experiments, and techniques dealing with synthesis of polymer and metal particles.
Nanocomposite structures and dispersions is focused on both the organic (synthetic and natural) and inorganic materials, and their hybrids. The aim is to summarize the fundamentals and mechanistic approaches in preparation and characterization of colloidal nanoparticles and dispersions so as to provide the readers a systematic and coherent picture of the field. The book introduces the reader the interesting field of nanoscience based on polymer and metal colloidal nanoparticles. Placing a special emphasis on polymer, inorganic and metal nanomaterials classified as nanoparticles, nanocrystals, nanorods, nanotubes, nanobelts, etc.
* Serves as a general introduction for those just entering the field and experts seeking information in other sub-fields
* Variety of synthetic approaches is described including emulsion, miniemulsion and microemulsion approaches, hogeneous and heterogeneous nucleation approaches under mild and high temperatures.
* Focused on both the organic (synthetic and natural) and inorganic materials, and their hybrids.

This volume of Modern Aspects contains seven chapters. The major topics covered in the first six chapters of this volume include fundamentals of solid state electrochemistry; kinetics of electrochemical hydrogen entry into metals and alloys; oxidation of organics; fuel cells; electrode kinetics of trace-anion catalysis; nano structural analysis. The last chapter is a corrected version of chapter four from Volume 35. Faisal M. AI-faqeer and Howard W. Pickering begin the first chapter by going back to 1864 and Cailletet who found that some hydrogen evolved and was absorbed by iron when it was immersed in dilute sulfuric acid. The absorption of hydrogen into metals and alloys can lead to catastrophic failures of structures. They discuss the kinetics of electrochemical hydrogen entry into metals and alloys. In chapter three, Clyde L. Briant reviews the electrochemistry, corrosion and hydrogen embrittlement of unalloyed titanium. He begins by reviewing the basic electrochemistry and general corrosion of titanium. He also discusses pitting and galvanostatic corrosion followed by a review of hydrogen embrittlement emphasizing the formation of hydrides and the effect of these on titanium's mechanical properties. Christos Comninellis and Gy6rgy F6ti discuss the oxidative electrochemical processes of organics in chapter three. They begin by defining direct and indirect electrochemical oxidation of organics. They introduce a model that allows them to distinguish between active (strong) and non-active (weak) anodes. Different classes of organic compounds are used for kinetic models of organic oxidation at active and non-active type anodes.

"Heterocycles from Transition Metal Catalysis: Formation and Functionalization" provides a concise summary of the prominent role of late transition metal (palladium, nickel, copper) catalysed processes in the synthesis and functionalization of heterocyclic systems. It gives an introduction to catalytic transformations, an overview of the most important reaction types, and presents synthetically useful catalytic processes classified by the target system and the type of transformation.

The book provides a representative selection of transition metal catalysed reactions transformations that are relevant in heterocyclic chemistry. In this way, the authors present a useful resource for members of the academic community looking for a textbook as well as industrial chemists in search of a reference book. This book will be an invaluable resource for synthetic chemists, medicinal chemists, and those more generally interested in applied catalysis.

This volume provides the latest developments in the field of surface science and technology based on diazonium coupling agents as well as their precursors (e.g. aromatic amines). It presents new concepts of surface chemistry of diazonium salts and discusses their novel and challenging applications. The latest advances on surface modification with diazonium salts are discussed and various promising alternative surface modifiers such as iodonium salts are examined. This book demonstrates the universality of diazonium salts in the surface treatment of classical and emergent materials and it will be a great tool for researcher and graduates working in this field.

This book introduces readers to the preparation of two-dimensional metal sulfide/oxide for CO2 photoreduction. Based on two-dimensional metal sulfide/oxide materials, this book establishes the structure-to-property relationships of photocatalyst for CO2 photoreduction, and reveals the intrinsic mechanism of the CO2 photoreduction by virtue of the in situ characterization techniques and the density functional theory calculations. It is anticipated that this book will help to identify empirical guidelines for designing and fabricating high-performance catalysts of solar-driven CO2 reduction.

Provides understanding of the device architecture, electrode design, and pros-cons of classical supercapacitors Explains material design in the context of electrochemical energy storage Covers state-of-the-art quantum supercapacitor and technological challenges Describes advanced version of supercapacitor devices describing macro-to-micro scale devices and applications at different scales Include details of challenges and outline of future designs

The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of organometallic compounds and reactions tailored to the needs of such diverse areas as organic synthesis, medical research, biology and materials science. Thus the scope of coverage includes a broad range of topics of pure and applied organometallic chemistry, where new breakthroughs are being achieved that are of significance to a larger scientific audience. The individual volumes of Topics in Organometallic Chemistry are thematic. Review articles are generally invited by the volume editors. All chapters from Topics in Organometallic Chemistry are published OnlineFirst with an individual DOI. In references, Topics in Organometallic Chemistry is abbreviated as Top Organomet Chem and cited as a journal.

Jonathan Scragg documents his work on a very promising material suitable for use in solar cells. Copper Zinc Tin Sulfide (CZTS) is a low cost, earth-abundant material suitable for large scale deployment in photovoltaics. Jonathan pioneered and optimized a low cost route to this material involving electroplating of the three metals concerned, followed by rapid thermal processing (RTP) in sulfur vapour. His beautifully detailed RTP studies - combined with techniques such as XRD, EDX and Raman - reveal the complex relationships between composition, processing and photovoltaic performance. This exceptional thesis contributes to the development of clean, sustainable and alternative sources of energy

There is an increasing challenge for chemical industry and research institutions to find cost-efficient and environmentally sound methods of converting natural resources into fuels chemicals and energy. Catalysts are essential to these processes and the Catalysis Specialist Periodical Report series serves to highlight major developments in this area. This series provides systematic and detailed reviews of topics of interest to scientists and engineers in the catalysis field. The coverage includes all major areas of heterogeneous and homogeneous catalysis and also specific applications of catalysis such as NOx control kinetics and experimental techniques such as microcalorimetry. Each chapter is compiled by recognised experts within their specialist fields and provides a summary of the current literature. This series will be of interest to all those in academia and industry who need an up-to-date critical analysis and summary of catalysis research and applications. Catalysis will be of interest to anyone working in academia and industry that needs an up-to-date critical analysis and summary of catalysis research and applications. Specialist Periodical Reports provide systematic and detailed review coverage in major areas of chemical research. Compiled by teams of leading experts in their specialist fields, this series is designed to help the chemistry community keep current with the latest developments in their field. Each volume in the series is published either annually or biennially and is a superb reference point for researchers. www.rsc.org/spr

Corrosion due to water is one of the most significant and complex causes of damage to metallic products. Written from the viewpoint of physical chemistry, this authoritative and established text deals with the aqueous corrosion of metals. Available for the first time in English, Corrosion of Metal addressing engineers, metallurgists, physicists and chemists. This self-contained, valuable reference comprehensively organizes and makes readily accessible the accumulated wealth of fundamental and applied knowledge. The concentration is on the underlying essentials of corrosion and failure, and the material is consistently presented in relation to practical applications to corrosion protection. The first chapters introducing the physicochemical principles are ideal for students. The following chapters provide an overview of the state of research for those familiar with the fundamentals. An exhaustive bibliography and appendices conclude the volume.

Volume 3, like the preceding volumes, focuses on the diversity of surfactants, both in terms of chemical structure and physico-chemical / surface active properties. These properties may be predictable for simple molecules but, for most commercial surfactants (which may be regarded as multi-component blends), this is not so easy. Yet it is important to develop a greater understanding of the interactions within a multi-component mixture, in order to select the most appropriate product for a particular application in which a combination of surface active properties is required.

A special feature of this volume is the initial chapter, in which the end uses of surface active agents are classified by industrial sector and the surfactant properties required for each application are presented in detail. The result is a unique guide to the influence of chemical structure on performance in end use, highlighting the benefits of particular surfactants and illustrating how some of the newer classes of surfactant may overcome the deficiencies of previously used products.

"Progresses from theoretical issues to applications. Contains a historical overview, in-depth considerations of various scenarios of silica adsorption, and results from the latest research. Invaluable for broad coverage of the expanding field of silica research."

Industrial products that are made from, or contain, nitrogen are described in parts of some encyclopedias and standard reference works. However it is not always simple to determine from these varied sources the present status of the technology and markets for various nitrogen products. We therefore perceived a need for a text that provides a comprehensive description of: 1) products that are made from or that contain nitrogen; 2) the processes that produce these products; and 3) the markets that consume these products. I have attempted to present the material in a standardized format that should make this book easy to use and helpful to the readers. The standard format for each product is: Introduction, Process, Production, and Uses, with some variations in different chapters. This book provides information that could be used by a wide range of readers: Fertilizer companies to evaluate different production processes and review general trends in the market. Basic chemical companies to evaluate different production processes and review general trends in the market. Specialty chemical companies to investigate new chemical production and/or sales opportunities and the processes that could make those sales a possibility. Chemical distributors to obtain a feel for the general market size for some chemicals and the basic handling and distribution procedures for various chemicals. Engineering Companies to evaluate different production processes and review general trends in the market. Engineering and Chemistry Students to learn more about practical applications of the principals that they have experienced in their classrooms and laboratories."

This book provides a collection of contributed chapters, delivering a comprehensive overview of topics related to the synthesis and crystal growth of nitride compounds under supercritical ammonia conditions. Focusing on key chemical and technological aspects of ammonothermal synthesis and growth of functional nitride compounds, the book also describes many innovative techniques for in-situ observation and presents new data fundamental for materials synthesis under ammonothermal conditions. With its detailed coverage of many thermodynamic and kinetics aspects, which are necessary for understanding and controlling crystal growth, this contributed volume is the ideal companion to materials chemists and engineers at any point in their journey in this rich and exciting field.

This hands-on reference tool provides the most up-to-date information needed to synthesize molecules by solid-phase synthesis (SPS)-employing polymeric support (resins), anchoring linkages (handles), coupling reagents (activators), and protection schemes. The volume presents new strategies for creating a wide variety of compounds invaluable for drug discovery in coming years. Thoroughly analyzes peptides, DNA, carbohydrates, conjugates of biomolecules, and small molecules. Written by 35 internationally recognized authorities, Solid-Phase Synthesis provides experimental procedures and a literature review for peptides, DNA, PNA, carbohydrates, peptidomimetics, and small molecule assembly describes the preparation of solid supports and handles (linkers) as well as their appropriate incorporation into a synthetic strategy discusses methods for the construction of more complex peptides: cyclic (lactam and disulfide), glyco-, phospho-, sulfo- and nucleopeptides explains the protocols for the preparation of side-chain and N-alpha protecting groups for amino acids surveys the various coupling reagents and methods for peptide chain elongation considers convergent peptide synthesis (fragment condensations) examines engineering designs for automation details techniques for the purification and analysis of peptides and combination libraries and more Containing over 2400 references and more than 300 tables, drawings, and equations, Solid-Phase Synthesis is an eminently practical and quick-reference guide for organic, combinatorial, and medicinal chemists and biochemists; pharmacists, pharmacologists, and pharmaceutical researchers; molecular and cell biologists; enzymologists; immunologists; neurobiologists; and graduate and medical school students in these disciplines.

This book describes the forcefields/interatomic potentials that are used in the atomistic-scale and molecular dynamics simulations. It covers mechanisms, salient features, formulations, important aspects and case studies of various forcefields utilized for characterizing various materials (such as nuclear materials and nanomaterials) and applications. This book gives many help to students and researchers who are studying the forcefield potentials and introduces various applications of atomistic-scale simulations to professors who are researching molecular dynamics.