From the basics of thermodynamics to solutions for modern dynamical problems —the complete beginner's guide to statistical mechanics.

Unlike most books on statistical mechanics, this one is written for advanced students in chemistry, chemical engineering, biophysics, and related fields. It targets readers with no prior exposure to statistical mechanics and provides a complete introduction to all the important principles, concepts, and equations, while maintaining a level of mathematical sophistication that most advanced chemistry students will find manageable. The emphasis is on finding solutions to common problems in chemistry. Topics covered include:

• The Maxwell-Boltzmann velocity distribution for molecules in a gas, partition functions, and calculation of thermodynamic properties
• Ensembles (including the grand canonical ensemble), independent particles, and thermodynamic properties of atoms and molecules
• Practical introductions to quantum statistical mechanics and classical statistical mechanics
• Applications to electrons in metals and semiconductors; bosons and fermions; imperfect gases; transport properties; dipole moments in electric and magnetic fields; and distribution functions and correlation functions in fluids
• Time-dependent techniques for handling both simple and modern dynamical problems —the Liouville equation, time-correlation functions, and the Langevin equation.

Clearly written, and with a minimum of theory, Statistical Mechanics for Chemists takes you step by step through mathematical manipulations and explains the physical and chemical bases for each procedure. It is a valuable resource for advanced students in chemistry, chemical engineering, biophysics, and related fields.

This book gives the definitive mathematical answer to what thermodynamics really is: a variational calculus applied to probability distributions. Extending Gibbs's notion of ensemble, the Author imagines the ensemble of all possible probability distributions and assigns probabilities to them by selection rules that are fairly general. The calculus of the most probable distribution in the ensemble produces the entire network of mathematical relationships we recognize as thermodynamics. The first part of the book develops the theory for discrete and continuous distributions while the second part applies this thermodynamic calculus to problems in population balance theory and shows how the emergence of a giant component in aggregation, and the shattering transition in fragmentation may be treated as formal phase transitions. While the book is intended as a research monograph, the material is self-contained and the style sufficiently tutorial to be accessible for self-paced study by an advanced graduate student in such fields as physics, chemistry, and engineering.

This book pays tribute to two pioneers in the field of Mathematical physics, Jiri Patera and Pavel Winternitz of the CRM. Each has contributed more than forty years to the subject of mathematical physics, particularly to the study of algebraic methods.

The aim of this Book is to give an overview, based on the results of nearly three decades of intensive research, of transient chaos. One belief that motivates us to write this book is that, transient chaos may not have been appreciated even within the nonlinear-science community, let alone other scientific disciplines.

With a foreword by Freeman Dyson, the handbook brings together leading mathematicians and physicists to offer a comprehensive overview of random matrix theory, including a guide to new developments and the diverse range of applications of this approach.
In part one, all modern and classical techniques of solving random matrix models are explored, including orthogonal polynomials, exact replicas or supersymmetry. Further, all main extensions of the classical Gaussian ensembles of Wigner and Dyson are introduced including sparse, heavy tailed, non-Hermitian or multi-matrix models. In the second and larger part, all major applications are covered, in disciplines ranging from physics and mathematics to biology and engineering. This includes standard fields such as number theory, quantum chaos or quantum chromodynamics, as well as recent developments such as partitions, growth models, knot theory, wireless communication or bio-polymer folding.
The handbook is suitable both for introducing novices to this area of research and as a main source of reference for active researchers in mathematics, physics and engineering.

After a short introduction to the fundamentals, this book provides a detailed account of major advances in applying fractional calculus to dynamical systems. Fractional order dynamical systems currently continue to gain further importance in many areas of science and engineering. As with many other approaches to mathematical modeling, the first issue to be addressed is the need to couple a definition of the fractional differentiation or integration operator with the types of dynamical systems that are analyzed. As such, for the fundamentals the focus is on basic aspects of fractional calculus, in particular stability analysis, which is required to tackle synchronization in coupled fractional order systems, to understand the essence of estimators for related integer order systems, and to keep track of the interplay between synchronization and parameter observation. This serves as the common basis for the more advanced topics and applications presented in the subsequent chapters, which include an introduction to the 'Immersion and Invariance' (I&I) methodology, the masterslave synchronization scheme for partially known nonlinear fractional order systems, Fractional Algebraic Observability (FAO) and Fractional Generalized quasi-Synchronization (FGqS) to name but a few. This book is intended not only for applied mathematicians and theoretical physicists, but also for anyone in applied science dealing with complex nonlinear systems.

Learn classical thermodynamics alongside statistical mechanics with this fresh approach to the subjects. Molecular and macroscopic principles are explained in an integrated, side-by-side manner to give students a deep, intuitive understanding of thermodynamics and equip them to tackle future research topics that focus on the nanoscale. Entropy is introduced from the get-go, providing a clear explanation of how the classical laws connect to the molecular principles, and closing the gap between the atomic world and thermodynamics. Notation is streamlined throughout, with a focus on general concepts and simple models, for building basic physical intuition and gaining confidence in problem analysis and model development. Well over 400 guided end-of-chapter problems are included, addressing conceptual, fundamental, and applied skill sets. Numerous worked examples are also provided together with handy shaded boxes to emphasize key concepts, making this the complete teaching package for students in chemical engineering and the chemical sciences.

The Ising model provides a detailed mathematical description of ferromagnetism and is widely used in statistical physics and condensed matter physics. In this Student's Guide, the author demystifies the mathematical framework of the Ising model and provides students with a clear understanding of both its physical significance, and how to apply it successfully in their calculations. Key topics related to the Ising model are covered, including exact solutions of both finite and infinite systems, series expansions about high and low temperatures, mean-field approximation methods, and renormalization-group calculations. The book also incorporates plots, figures, and tables to highlight the significance of the results. Designed as a supplementary resource for undergraduate and graduate students, each chapter includes a selection of exercises intended to reinforce and extend important concepts, and solutions are also available for all exercises.

Predicting thermodynamic quantities for chemically realistic systems on the basis of atomistic calculations is still, even today, a nontrivial task. Nonetheless, accurate treatment of inter-particle interactions, in terms of quantum chemical first principles methods, is a prerequisite for many applications, because of the complexity of both reactants and solvents in modern molecular sciences. Currently, a straightforward calculation of thermodynamic properties from these methods is only possible for high-temperature and low- density systems. Although the enthalpy of a system can often be predicted to a good level of precision with this ideal gas approach, calculating the entropy contribution to the free energy is problematic, especially as the density of the system increases. This thesis contains a compact and coherent introduction of basic theoretical features. The foundations are then laid for the development of approaches suitable for calculation of condensed phase entropies on the basis of well-established quantum chemical methods. The main emphasis of this work is on realistic systems in solution, which is the most important environment for chemical synthesis. The presented results demonstrate how isolated molecular concepts typically employed in modern quantum chemistry can be extended for the accurate determination of thermodynamic properties by means of scale- transferring approaches.

An introductory textbook exploring the subject of Lagrangian and Hamiltonian dynamics, with a relaxed and self-contained setting. Lagrangian and Hamiltonian dynamics is the continuation of Newton's classical physics into new formalisms, each highlighting novel aspects of mechanics that gradually build in complexity to form the basis for almost all of theoretical physics. Lagrangian and Hamiltonian dynamics also acts as a gateway to more abstract concepts routed in differential geometry and field theories and can be used to introduce these subject areas to newcomers. Journeying in a self-contained manner from the very basics, through the fundamentals and onwards to the cutting edge of the subject, along the way the reader is supported by all the necessary background mathematics, fully worked examples, thoughtful and vibrant illustrations as well as an informal narrative and numerous fresh, modern and inter-disciplinary applications. The book contains some unusual topics for a classical mechanics textbook. Most notable examples include the 'classical wavefunction', Koopman-von Neumann theory, classical density functional theories, the 'vakonomic' variational principle for non-holonomic constraints, the Gibbs-Appell equations, classical path integrals, Nambu brackets and the full framing of mechanics in the language of differential geometry.

This book presents a careful selection of the most important developments of the \phi^4 model, offering a judicious summary of this model with a view to future prospects and the challenges ahead. Over the past four decades, the \phi^4 model has been the basis for a broad array of developments in the physics and mathematics of nonlinear waves. From kinks to breathers, from continuum media to discrete lattices, from collisions of solitary waves to spectral properties, and from deterministic to stochastic models of \phi^4 (and \phi^6, \phi^8, \phi^12 variants more recently), this dynamical model has served as an excellent test bed for formulating and testing the ideas of nonlinear science and solitary waves.

Instantons, or pseudoparticles, are solutions to the equations of motion in classical field theories on a Euclidean spacetime. Instantons are found everywhere in quantum theories as they have many applications in quantum tunnelling. Diverse physical phenomena may be described through quantum tunnelling, for example: the Josephson effect, the decay of meta-stable nuclear states, band formation in tight binding models of crystalline solids, the structure of the gauge theory vacuum, confinement in 2+1 dimensions, and the decay of superheated or supercooled phases. Drawing inspiration from Sidney Coleman's Erice lectures, this volume provides an accessible, detailed introduction to instanton methods, with many applications, making it a valuable resource for graduate students in many areas of physics, from condensed matter, particle and nuclear physics, to string theory. This title, first published in 2017, has been reissued as an Open Access publication on Cambridge Core.

Instantons, or pseudoparticles, are solutions to the equations of motion in classical field theories on a Euclidean spacetime. Instantons are found everywhere in quantum theories as they have many applications in quantum tunnelling. Diverse physical phenomena may be described through quantum tunnelling, for example: the Josephson effect, the decay of meta-stable nuclear states, band formation in tight binding models of crystalline solids, the structure of the gauge theory vacuum, confinement in 2+1 dimensions, and the decay of superheated or supercooled phases. Drawing inspiration from Sidney Coleman's Erice lectures, this volume provides an accessible, detailed introduction to instanton methods, with many applications, making it a valuable resource for graduate students in many areas of physics, from condensed matter, particle and nuclear physics, to string theory. This title, first published in 2017, has been reissued as an Open Access publication on Cambridge Core.

This book focuses on theoretical thermotics, the theory of transformation thermotics and its extended theories for the active control of macroscopic thermal phenomena of artificial systems, which is in sharp contrast to classical thermodynamics comprising the four thermodynamic laws for the passive description of macroscopic thermal phenomena of natural systems. The book covers the basic concepts and mathematical methods, which are necessary to understand thermal problems extensively investigated in physics, but also in other disciplines of engineering and materials. The analyses rely on models solved by analytical techniques accompanied with computer simulations and laboratory experiments. This book serves both as a reference work for senior researchers and a study text for zero beginners.

Networks are convenient mathematical models to represent the structure of complex systems, from cells to societies. In the last decade, multilayer network science - the branch of the field dealing with units interacting in multiple distinct ways, simultaneously - was demonstrated to be an effective modeling and analytical framework for a wide spectrum of empirical systems, from biopolymers networks (such as interactome and metabolomes) to neuronal networks (such as connectomes), from social networks to urban and transportation networks. In this Element, a decade after one of the most seminal papers on this topic, the authors review the most salient features of multilayer network science, covering both theoretical aspects and direct applications to real-world coupled/interdependent systems, from the point of view of multilayer structure, dynamics and function. The authors discuss potential frontiers for this topic and the corresponding challenges in the field for the next future.

This book provides a comprehensive and self-contained overview of recent progress in nonequilibrium statistical mechanics, in particular, the discovery of fluctuation relations and other time-reversal symmetry relations. The significance of these advances is that nonequilibrium statistical physics is no longer restricted to the linear regimes close to equilibrium, but extends to fully nonlinear regimes. These important new results have inspired the development of a unifying framework for describing both the microscopic dynamics of collections of particles, and the macroscopic hydrodynamics and thermodynamics of matter itself. The book discusses the significance of this theoretical framework in relation to a broad range of nonequilibrium processes, from the nanoscale to the macroscale, and is essential reading for researchers and graduate students in statistical physics, theoretical chemistry and biological physics.

Our original objective in writing this book was to demonstrate how the concept of the equation of motion of a Brownian particle - the Langevin equation or Newtonian-like evolution equation of the random phase space variables describing the motion - first formulated by Langevin in 1908 - so making him inter alia the founder of the subject of stochastic differential equations, may be extended to solve the nonlinear problems arising from the Brownian motion in a potential. Such problems appear under various guises in many diverse applications in physics, chemistry, biology, electrical engineering, etc. However, they have been invariably treated (following the original approach of Einstein and Smoluchowski) via the Fokker-Planck equation for the evolution of the probability density function in phase space. Thus the more simple direct dynamical approach of Langevin which we use and extend here, has been virtually ignored as far as the Brownian motion in a potential is concerned. In addition two other considerations have driven us to write this new edition of The Langevin Equation. First, more than five years have elapsed since the publication of the third edition and following many suggestions and comments of our colleagues and other interested readers, it became increasingly evident to us that the book should be revised in order to give a better presentation of the contents. In particular, several chapters appearing in the third edition have been rewritten so as to provide a more direct appeal to the particular community involved and at the same time to emphasize via a synergetic approach how seemingly unrelated physical problems all involving random noise may be described using virtually identical mathematical methods. Secondly, in that period many new and exciting developments have occurred in the application of the Langevin equation to Brownian motion. Consequently, in order to accommodate all these, a very large amount of new material has been added so as to present a comprehensive overview of the subject.

Providing a systematic introduction to the techniques which are fundamental to quantum field theory, this book pays special attention to the use of these techniques in a wide variety of areas, including ordinary quantum mechanics, quantum mechanics in the second-quantized formulation, relativistic quantum field theory, Euclidean field theory, quantum statistics at finite temperature, and the classical statistics of nonideal gas and spin systems. The extended chapter on variational methods and functional Legendre transformations contains completely original material.

Presenting in a coherent and accessible fashion current results in nanomagnetism, this book constitutes a comprehensive, rigorous and readable account, from first principles of the classical and quantum theories underlying the dynamics of magnetic nanoparticles subject to thermal fluctuations.Starting with the Larmor-like equation for a giant spin, both the stochastic (Langevin) equation of motion of the magnetization and the associated evolution (Fokker-Planck) equation for the distribution function of the magnetization orientations of ferromagnetic nanoparticles (classical spins) in a heat bath are developed along with their solution (using angular momentum theory) for arbitrary magnetocrystalline-Zeeman energy. Thus, observables such as the magnetization reversal time, relaxation functions, dynamic susceptibilities, etc. are calculated and compared with the predictions of classical escape rate theory including in the most general case spin-torque-transfer. Regarding quantum effects, which are based on the reduced spin density matrix evolution equation in Hilbert space as is described at length, they are comprehensively treated via the Wigner-Stratonovich formulation of the quantum mechanics of spins via their orientational quasi-probability distributions on a classically meaningful representation space. Here, as suggested by the relevant Weyl symbols, the latter is the configuration space of the polar angles. Hence, one is led, by mapping the reduced density matrix equation onto that space, to a master equation for the quasi-probability evolution akin to the Fokker-Planck equation which may be solved in a similar way. Thus, one may study in a classical-like manner the evolution of observables with spin number ranging from an elementary spin to molecular clusters to the classical limit, viz. a nanoparticle. The entire discussion hinges on the one-to-one correspondence between polarization operators in Hilbert space and the spherical harmonics allied to concepts of spin coherent states long familiar in quantum optics.Catering for the reader with only a passing knowledge of statistical and quantum mechanics, the book serves as an introductory text on a complicated subject where the literature is remarkably sparse.

In this resource, acknowledged leaders in the field examine current state-of-the-art and recent developments in technology, of flow boiling systems which are affected by convective flows. This important volume consists of expanded and revised peer-reviewed papers presented at the Engineering Foundations's Convective Flow Boiling: An International Conference held in 1995.

Il testo si configura come un' introduzione alla fisica statistica rivolto in primo luogo a quei corsi di studio in ingegneria che piu hanno a che fare con le proprieta fisiche dei materiali, ed ha lo scopo di fornire le basi microscopiche del comportamento termodinamico di cui si fa uso sia in molti corsi tradizionali, quali quelli di termofluidica d'interesse per l'ingegneria chimica e nucleare, che in corsi rivolti ad applicazioni avanzate nella scienza dei materiali e nelle nanotecnologie. Particolare attenzione viene quindi dedicata all'impiego di metodi di fisica statistica nella scienza dei materiali, approfondendo tematiche relative alle vibrazioni nei solidi, ai processi di nucleazione liquido/vapore, alla struttura dello stato fluido e vetroso, ai plasmi, ai materiali magnetici, al gas di Fermi e alla superfluidita. Per il suo carattere generale, e per l'accento posto sui fondamenti della meccanica quantistica, il volume si presta comunque a costituire anche un testo introduttivo alla meccanica statistica per studenti dei corsi di laurea in fisica."

This book highlights cutting-edge topics in contemporary physics, discussing exciting advances and new forms of thinking in evolving fields with emphases both on natural phenomena and applications to modern engineering. It provides material for thought and practice in nanophysics, plasma physics, and electrodynamics. Nanophysics and plasmas are synergic physical areas where the whole is more than the sum of the parts (quantum, atomic and molecular, electrodynamics, photonics, condensed matter, thermodynamics, transport phenomena). The authors emphasize both fundamentals and more complex concepts, making the contents accessible as well challenging. Nanoscale properties and physical phenomena are explained under the umbrella of quantum physics. Advances made in the physical knowledge of the nanoworld, and its metrology are addressed, along with experimental achievements which have furthered studies of extreme weak forces present at nano- or sub-micron scales. The book does not focus in detail on the diversity of applications in nanotechnology and instrumentation, considering that the reader already has basic prior knowledge on that. It also covers an introduction to plasma universe phenomenology, the basics of advanced mathematics applied to the electromagnetic field, longitudinal forces in the vacuum, concepts of helicity and topological torsion, SU(2) representation of Maxwell equations, 2D representation of the electromagnetic field, the use of the fractional derivative, and ergontropic dynamics. The chapters include theory, applications, bibliographic references, and solved exercises. The synergies of the book's topics demonstrate their potential in critical issues, such as relieving humans from barriers imposed by energetic and entropic dependencies and penetrating the realm of weak forces at the nanoscale. The book will boost both post-graduate students and mature scientists to implement new scientific and technological projects.

In many systems consisting of interacting subsystems, the complex interactions between elements can be represented using multilayer networks. However percolation, key to understanding connectivity and robustness, is not trivially generalised to multiple layers. This Element describes a generalisation of percolation to multilayer networks: weak multiplex percolation. A node belongs to a connected component if at least one of its neighbours in each layer is in this component. The authors fully describe the critical phenomena of this process. In two layers with finite second moments of the degree distributions the authors observe an unusual continuous transition with quadratic growth above the threshold. When the second moments diverge, the singularity is determined by the asymptotics of the degree distributions, creating a rich set of critical behaviours. In three or more layers the authors find a discontinuous hybrid transition which persists even in highly heterogeneous degree distributions, becoming continuous only when the powerlaw exponent reaches $1+1/(M-1)$ for $M$ layers.

Statistical physics examines the collective properties of large ensembles of particles, and is a powerful theoretical tool with important applications across many different scientific disciplines. This book provides a detailed introduction to classical and quantum statistical physics, including links to topics at the frontiers of current research. The first part of the book introduces classical ensembles, provides an extensive review of quantum mechanics, and explains how their combination leads directly to the theory of Bose and Fermi gases. This allows a detailed analysis of the quantum properties of matter, and introduces the exotic features of vacuum fluctuations. The second part discusses more advanced topics such as the two-dimensional Ising model and quantum spin chains. This modern text is ideal for advanced undergraduate and graduate students interested in the role of statistical physics in current research. 140 homework problems reinforce key concepts and further develop readers' understanding of the subject.

This book deals with certain important problems in Classical and Quantum Information Theory Quantum Information Theory, A Selection of Matrix Inequalities Stochastic Filtering Theory Applied to Electromagnetic Fields and Strings Wigner-distributions in Quantum Mechanics Quantization of Classical Field Theories Statistical Signal Processing Quantum Field Theory, Quantum Statistics, Gravity, Stochastic Fields and Information Problems in Information Theory It will be very helpful for students of Undergraduate and Postgraduate Courses in Electronics, Communication and Signal Processing. Print edition not for sale in South Asia (India, Sri Lanka, Nepal, Bangladesh, Pakistan or Bhutan).