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Books > Science & Mathematics > Physics > Thermodynamics & statistical physics > Statistical physics
The dielectric properties especially of glassy materials are nowadays explored at widely varying temperatures and pressures without any gap in the spectral range from Hz up to the Infrared, thus covering typically 20 decades or more. This extraordinary span enables to trace the scaling and the mutual interactions of relaxation processes in detail, e.g. the dynamic glass transition and secondary relaxations, but as well far infrared vibrations, like the Boson peak. Additionally the evolution of intra-molecular interactions in the course of the dynamic glass transition is also well explored by (Fourier Transform) Infrared Spectroscopy. This volume within 'Advances in Dielectrics' summarizes this knowledge and discusses it with respect to the existing and often competing theoretical concepts.
This book is the productof my research at the EndowedChair of Corporate Finance and Capital Markets at the European Business School. Many people devoted their inspiration, time, and knowledge in order to support me with my interdisciplinary research. Thank you all for your support. Especially, I thank my academic supervisor Prof. Ulrich Hommel, Ph.D., who provided me with the freedom to pursue my research interests and who always s- ported me generously. In addition, I am very grateful to my co-supervisor Prof. Dr. Susanne Strahringer (TU Dresden), who graciously accepted the task of refer- ing my book. Also, I thank Prof. Dr. Matthias Krause of the Chair for Theoretical Computer Science in Mannheim for the technical and computer scienti?c support. During my research visits I received generous support from Prof. Yaneer Bar- Yam (NECSI and Harvard) and Prof. John D. Sterman (MIT), who introduced me to the ?eld of System Dynamics and Complex Systems, as well as from Prof. Victor Mossotti (U.S. Geological Survey), Prof. Hiroki Sayama (NECSI and Bingh- ton), Prof. Markus de Aguiar (Universidade Estadual de Campinas), Prof. Michel Baranger (MIT), Prof. Jay W. Forrester (MIT), and Prof. Brian D. Josephson (Cambridge). Thank you very much for numerous inspiring discussions.
Humans engage in a seemingly endless variety of different behaviors, of which some are found across species, while others are conceived of as typically human. Most generally, behavior comes about through the interplay of various constraints - informational, mechanical, neural, metabolic, and so on - operating at multiple scales in space and time. Over the years, consensus has grown in the research community that, rather than investigating behavior only from bottom up, it may be also well understood in terms of concepts and laws on the phenomenological level. Such top down approach is rooted in theories of synergetics and self-organization using tools from nonlinear dynamics. The present compendium brings together scientists from all over the world that have contributed to the development of their respective fields departing from this background. It provides an introduction to deterministic as well as stochastic dynamical systems and contains applications to motor control and coordination, visual perception and illusion, as well as auditory perception in the context of speech and music.
The European Conference on Complex Systems, held under the patronage of the Complex Systems Society, is an annual event that has become the leading European conference devoted to complexity science. ECCS'12, its ninth edition, took place in Brussels, during the first week of September 2012. It gathered about 650 scholars representing a wide range of topics relating to complex systems research, with emphasis on interdisciplinary approaches. More specifically, the following tracks were covered: 1. Foundations of Complex Systems 2. Complexity, Information and Computation 3. Prediction, Policy and Planning, Environment 4. Biological Complexity 5. Interacting Populations, Collective Behavior 6. Social Systems, Economics and Finance This book contains a selection of the contributions presented at the conference and its satellite meetings. Its contents reflect the extent, diversity and richness of research areas in the field, both fundamental and applied. "
Complex Nonlinearity: Chaos, Phase Transitions, Topology Change and Path Integrals is a book about prediction & control of general nonlinear and chaotic dynamics of high-dimensional complex systems of various physical and non-physical nature and their underpinning geometro-topological change. The book starts with a textbook-like expose on nonlinear dynamics, attractors and chaos, both temporal and spatio-temporal, including modern techniques of chaos-control. Chapter 2 turns to the edge of chaos, in the form of phase transitions (equilibrium and non-equilibrium, oscillatory, fractal and noise-induced), as well as the related field of synergetics. While the natural stage for linear dynamics comprises of flat, Euclidean geometry (with the corresponding calculation tools from linear algebra and analysis), the natural stage for nonlinear dynamics is curved, Riemannian geometry (with the corresponding tools from nonlinear, tensor algebra and analysis). The extreme nonlinearity - chaos - corresponds to the topology change of this curved geometrical stage, usually called configuration manifold. Chapter 3 elaborates on geometry and topology change in relation with complex nonlinearity and chaos. Chapter 4 develops general nonlinear dynamics, continuous and discrete, deterministic and stochastic, in the unique form of path integrals and their action-amplitude formalism. This most natural framework for representing both phase transitions and topology change starts with Feynman's sum over histories, to be quickly generalized into the sum over geometries and topologies. The last Chapter puts all the previously developed techniques together and presents the unified form of complex nonlinearity. Here we have chaos, phase transitions, geometrical dynamics and topology change, all working together in the form of path integrals. The objective of this book is to provide a serious reader with a serious scientific tool that will enable them to actually perform a competitive research in modern complex nonlinearity. It includes a comprehensive bibliography on the subject and a detailed index. Target readership includes all researchers and students of complex nonlinear systems (in physics, mathematics, engineering, chemistry, biology, psychology, sociology, economics, medicine, etc.), working both in industry/clinics and academia.
This book develops analytical methods for studying the dynamical chaos, synchronization, and dynamics of structures in various models of coupled rotators. Rotators and their systems are defined in a cylindrical phase space, and, unlike oscillators, which are defined in Rn, they have a wider "range" of motion: There are vibrational and rotational types for cyclic variables, as well as their combinations (rotational-vibrational) if the number of cyclic variables is more than one. The specificity of rotator phase space poses serious challenges in terms of selecting methods for studying the dynamics of related systems. The book chiefly focuses on developing a modified form of the method of averaging, which can be used to study the dynamics of rotators. In general, the book uses the "language" of the qualitative theory of differential equations, point mappings, and the theory of bifurcations, which helps authors to obtain new results on dynamical chaos in systems with few degrees of freedom. In addition, a special section is devoted to the study and classification of dynamic structures that can occur in systems with a large number of interconnected objects, i.e. in lattices of rotators and/or oscillators. Given its scope and format, the book can be used both in lectures and courses on nonlinear dynamics, and in specialized courses on the development and operation of relevant systems that can be represented by a large number of various practical systems: interconnected grids of various mechanical systems, various types of networks including not only mechanical but also biological systems, etc.
From the basics of thermodynamics to solutions for modern dynamical problems —the complete beginner's guide to statistical mechanics. Unlike most books on statistical mechanics, this one is written for advanced students in chemistry, chemical engineering, biophysics, and related fields. It targets readers with no prior exposure to statistical mechanics and provides a complete introduction to all the important principles, concepts, and equations, while maintaining a level of mathematical sophistication that most advanced chemistry students will find manageable. The emphasis is on finding solutions to common problems in chemistry. Topics covered include:
Clearly written, and with a minimum of theory, Statistical Mechanics for Chemists takes you step by step through mathematical manipulations and explains the physical and chemical bases for each procedure. It is a valuable resource for advanced students in chemistry, chemical engineering, biophysics, and related fields.
This book contains a selection of the latest research in the field of Computational Social Science (CSS) methods, uses, and results, as presented at the 2018 annual conference of the CSSSA. This conference was held in Santa Fe, New Mexico, October 25 - 28, 2018, at the Drury Plaza Hotel. CSS investigates social and behavioral dynamics in both nature and society, through computer simulation, network analysis, and the science of complex systems. The Computational Social Science Society of the Americas (CSSSA) is a professional society that aims to advance the field of CSS in all its areas, from fundamental principles to real-world applications, by holding conferences and workshops, promoting standards of scientific excellence in research and teaching, and publishing novel research findings. What follows is a diverse representation of new approaches and research findings, using the tools of CSS and Agent-Based Modeling (ABM) in exploring complex phenomena across many different domains. Readers will not only have the methods and results of these specific projects on which to build, but will also gain a greater appreciation for the broad scope of CSS, and have a wealth of case-study examples that can serve as meaningful exemplars for new research projects and activities. This book, we hope, will appeal to any researchers and students working in the social sciences, broadly defined, who aim to better understand and apply the concepts of Complex Adaptive Systems to their work.
This monograph discusses the essential principles of the evaporationprocess by looking at it at the molecular and atomic level. In the first part methods of statistical physics, physical kinetics andnumerical modeling are outlined including the Maxwell's distributionfunction, the Boltzmann kinetic equation, the Vlasov approach, and theCUDA technique. The distribution functions of evaporating particles are then defined.Experimental results on the evaporation coefficient and the temperaturejump on the evaporation surface are critically reviewed and compared tothe theory and numerical results presented in previous chapters. The book ends with a chapter devoted to evaporation in differentprocesses, such as boiling and cavitation.This monograph addressesgraduate students and researchers working on phase transitions andrelated fields.
This book gives the definitive mathematical answer to what thermodynamics really is: a variational calculus applied to probability distributions. Extending Gibbs's notion of ensemble, the Author imagines the ensemble of all possible probability distributions and assigns probabilities to them by selection rules that are fairly general. The calculus of the most probable distribution in the ensemble produces the entire network of mathematical relationships we recognize as thermodynamics. The first part of the book develops the theory for discrete and continuous distributions while the second part applies this thermodynamic calculus to problems in population balance theory and shows how the emergence of a giant component in aggregation, and the shattering transition in fragmentation may be treated as formal phase transitions. While the book is intended as a research monograph, the material is self-contained and the style sufficiently tutorial to be accessible for self-paced study by an advanced graduate student in such fields as physics, chemistry, and engineering.
This book pays tribute to two pioneers in the field of Mathematical physics, Jiri Patera and Pavel Winternitz of the CRM. Each has contributed more than forty years to the subject of mathematical physics, particularly to the study of algebraic methods.
The aim of this Book is to give an overview, based on the results of nearly three decades of intensive research, of transient chaos. One belief that motivates us to write this book is that, transient chaos may not have been appreciated even within the nonlinear-science community, let alone other scientific disciplines.
After a short introduction to the fundamentals, this book provides a detailed account of major advances in applying fractional calculus to dynamical systems. Fractional order dynamical systems currently continue to gain further importance in many areas of science and engineering. As with many other approaches to mathematical modeling, the first issue to be addressed is the need to couple a definition of the fractional differentiation or integration operator with the types of dynamical systems that are analyzed. As such, for the fundamentals the focus is on basic aspects of fractional calculus, in particular stability analysis, which is required to tackle synchronization in coupled fractional order systems, to understand the essence of estimators for related integer order systems, and to keep track of the interplay between synchronization and parameter observation. This serves as the common basis for the more advanced topics and applications presented in the subsequent chapters, which include an introduction to the 'Immersion and Invariance' (I&I) methodology, the masterslave synchronization scheme for partially known nonlinear fractional order systems, Fractional Algebraic Observability (FAO) and Fractional Generalized quasi-Synchronization (FGqS) to name but a few. This book is intended not only for applied mathematicians and theoretical physicists, but also for anyone in applied science dealing with complex nonlinear systems.
Learn classical thermodynamics alongside statistical mechanics with this fresh approach to the subjects. Molecular and macroscopic principles are explained in an integrated, side-by-side manner to give students a deep, intuitive understanding of thermodynamics and equip them to tackle future research topics that focus on the nanoscale. Entropy is introduced from the get-go, providing a clear explanation of how the classical laws connect to the molecular principles, and closing the gap between the atomic world and thermodynamics. Notation is streamlined throughout, with a focus on general concepts and simple models, for building basic physical intuition and gaining confidence in problem analysis and model development. Well over 400 guided end-of-chapter problems are included, addressing conceptual, fundamental, and applied skill sets. Numerous worked examples are also provided together with handy shaded boxes to emphasize key concepts, making this the complete teaching package for students in chemical engineering and the chemical sciences.
Predicting thermodynamic quantities for chemically realistic systems on the basis of atomistic calculations is still, even today, a nontrivial task. Nonetheless, accurate treatment of inter-particle interactions, in terms of quantum chemical first principles methods, is a prerequisite for many applications, because of the complexity of both reactants and solvents in modern molecular sciences. Currently, a straightforward calculation of thermodynamic properties from these methods is only possible for high-temperature and low- density systems. Although the enthalpy of a system can often be predicted to a good level of precision with this ideal gas approach, calculating the entropy contribution to the free energy is problematic, especially as the density of the system increases. This thesis contains a compact and coherent introduction of basic theoretical features. The foundations are then laid for the development of approaches suitable for calculation of condensed phase entropies on the basis of well-established quantum chemical methods. The main emphasis of this work is on realistic systems in solution, which is the most important environment for chemical synthesis. The presented results demonstrate how isolated molecular concepts typically employed in modern quantum chemistry can be extended for the accurate determination of thermodynamic properties by means of scale- transferring approaches.
An introductory textbook exploring the subject of Lagrangian and Hamiltonian dynamics, with a relaxed and self-contained setting. Lagrangian and Hamiltonian dynamics is the continuation of Newton's classical physics into new formalisms, each highlighting novel aspects of mechanics that gradually build in complexity to form the basis for almost all of theoretical physics. Lagrangian and Hamiltonian dynamics also acts as a gateway to more abstract concepts routed in differential geometry and field theories and can be used to introduce these subject areas to newcomers. Journeying in a self-contained manner from the very basics, through the fundamentals and onwards to the cutting edge of the subject, along the way the reader is supported by all the necessary background mathematics, fully worked examples, thoughtful and vibrant illustrations as well as an informal narrative and numerous fresh, modern and inter-disciplinary applications. The book contains some unusual topics for a classical mechanics textbook. Most notable examples include the 'classical wavefunction', Koopman-von Neumann theory, classical density functional theories, the 'vakonomic' variational principle for non-holonomic constraints, the Gibbs-Appell equations, classical path integrals, Nambu brackets and the full framing of mechanics in the language of differential geometry.
This book presents a careful selection of the most important developments of the \phi^4 model, offering a judicious summary of this model with a view to future prospects and the challenges ahead. Over the past four decades, the \phi^4 model has been the basis for a broad array of developments in the physics and mathematics of nonlinear waves. From kinks to breathers, from continuum media to discrete lattices, from collisions of solitary waves to spectral properties, and from deterministic to stochastic models of \phi^4 (and \phi^6, \phi^8, \phi^12 variants more recently), this dynamical model has served as an excellent test bed for formulating and testing the ideas of nonlinear science and solitary waves.
The Ising model provides a detailed mathematical description of ferromagnetism and is widely used in statistical physics and condensed matter physics. In this Student's Guide, the author demystifies the mathematical framework of the Ising model and provides students with a clear understanding of both its physical significance, and how to apply it successfully in their calculations. Key topics related to the Ising model are covered, including exact solutions of both finite and infinite systems, series expansions about high and low temperatures, mean-field approximation methods, and renormalization-group calculations. The book also incorporates plots, figures, and tables to highlight the significance of the results. Designed as a supplementary resource for undergraduate and graduate students, each chapter includes a selection of exercises intended to reinforce and extend important concepts, and solutions are also available for all exercises.
This book focuses on theoretical thermotics, the theory of transformation thermotics and its extended theories for the active control of macroscopic thermal phenomena of artificial systems, which is in sharp contrast to classical thermodynamics comprising the four thermodynamic laws for the passive description of macroscopic thermal phenomena of natural systems. The book covers the basic concepts and mathematical methods, which are necessary to understand thermal problems extensively investigated in physics, but also in other disciplines of engineering and materials. The analyses rely on models solved by analytical techniques accompanied with computer simulations and laboratory experiments. This book serves both as a reference work for senior researchers and a study text for zero beginners.
A completely revised edition that combines a comprehensive coverage of statistical and thermal physics with enhanced computational tools, accessibility, and active learning activities to meet the needs of today's students and educators This revised and expanded edition of Statistical and Thermal Physics introduces students to the essential ideas and techniques used in many areas of contemporary physics. Ready-to-run programs help make the many abstract concepts concrete. The text requires only a background in introductory mechanics and some basic ideas of quantum theory, discussing material typically found in undergraduate texts as well as topics such as fluids, critical phenomena, and computational techniques, which serve as a natural bridge to graduate study. Completely revised to be more accessible to students Encourages active reading with guided problems tied to the text Updated open source programs available in Java, Python, and JavaScript Integrates Monte Carlo and molecular dynamics simulations and other numerical techniques Self-contained introductions to thermodynamics and probability, including Bayes' theorem A fuller discussion of magnetism and the Ising model than other undergraduate texts Treats ideal classical and quantum gases within a uniform framework Features a new chapter on transport coefficients and linear response theory Draws on findings from contemporary research Solutions manual (available only to instructors)
Instantons, or pseudoparticles, are solutions to the equations of motion in classical field theories on a Euclidean spacetime. Instantons are found everywhere in quantum theories as they have many applications in quantum tunnelling. Diverse physical phenomena may be described through quantum tunnelling, for example: the Josephson effect, the decay of meta-stable nuclear states, band formation in tight binding models of crystalline solids, the structure of the gauge theory vacuum, confinement in 2+1 dimensions, and the decay of superheated or supercooled phases. Drawing inspiration from Sidney Coleman's Erice lectures, this volume provides an accessible, detailed introduction to instanton methods, with many applications, making it a valuable resource for graduate students in many areas of physics, from condensed matter, particle and nuclear physics, to string theory. This title, first published in 2017, has been reissued as an Open Access publication on Cambridge Core.
Continuum Models for Phase Transitions and Twinning in Crystals presents the fundamentals of a remarkably successful approach to crystal thermomechanics. Developed over the last two decades, it is based on the mathematical theory of nonlinear thermoelasticity, in which a new viewpoint on material symmetry, motivated by molecular theories, plays a central role.
Networks are convenient mathematical models to represent the structure of complex systems, from cells to societies. In the last decade, multilayer network science - the branch of the field dealing with units interacting in multiple distinct ways, simultaneously - was demonstrated to be an effective modeling and analytical framework for a wide spectrum of empirical systems, from biopolymers networks (such as interactome and metabolomes) to neuronal networks (such as connectomes), from social networks to urban and transportation networks. In this Element, a decade after one of the most seminal papers on this topic, the authors review the most salient features of multilayer network science, covering both theoretical aspects and direct applications to real-world coupled/interdependent systems, from the point of view of multilayer structure, dynamics and function. The authors discuss potential frontiers for this topic and the corresponding challenges in the field for the next future.
Our original objective in writing this book was to demonstrate how the concept of the equation of motion of a Brownian particle - the Langevin equation or Newtonian-like evolution equation of the random phase space variables describing the motion - first formulated by Langevin in 1908 - so making him inter alia the founder of the subject of stochastic differential equations, may be extended to solve the nonlinear problems arising from the Brownian motion in a potential. Such problems appear under various guises in many diverse applications in physics, chemistry, biology, electrical engineering, etc. However, they have been invariably treated (following the original approach of Einstein and Smoluchowski) via the Fokker-Planck equation for the evolution of the probability density function in phase space. Thus the more simple direct dynamical approach of Langevin which we use and extend here, has been virtually ignored as far as the Brownian motion in a potential is concerned. In addition two other considerations have driven us to write this new edition of The Langevin Equation. First, more than five years have elapsed since the publication of the third edition and following many suggestions and comments of our colleagues and other interested readers, it became increasingly evident to us that the book should be revised in order to give a better presentation of the contents. In particular, several chapters appearing in the third edition have been rewritten so as to provide a more direct appeal to the particular community involved and at the same time to emphasize via a synergetic approach how seemingly unrelated physical problems all involving random noise may be described using virtually identical mathematical methods. Secondly, in that period many new and exciting developments have occurred in the application of the Langevin equation to Brownian motion. Consequently, in order to accommodate all these, a very large amount of new material has been added so as to present a comprehensive overview of the subject.
Providing a systematic introduction to the techniques which are fundamental to quantum field theory, this book pays special attention to the use of these techniques in a wide variety of areas, including ordinary quantum mechanics, quantum mechanics in the second-quantized formulation, relativistic quantum field theory, Euclidean field theory, quantum statistics at finite temperature, and the classical statistics of nonideal gas and spin systems. The extended chapter on variational methods and functional Legendre transformations contains completely original material. |
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