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Books > Science & Mathematics > Physics > Thermodynamics & statistical physics > Statistical physics
With a foreword by Freeman Dyson, the handbook brings together
leading mathematicians and physicists to offer a comprehensive
overview of random matrix theory, including a guide to new
developments and the diverse range of applications of this
approach.
After a short introduction to the fundamentals, this book provides a detailed account of major advances in applying fractional calculus to dynamical systems. Fractional order dynamical systems currently continue to gain further importance in many areas of science and engineering. As with many other approaches to mathematical modeling, the first issue to be addressed is the need to couple a definition of the fractional differentiation or integration operator with the types of dynamical systems that are analyzed. As such, for the fundamentals the focus is on basic aspects of fractional calculus, in particular stability analysis, which is required to tackle synchronization in coupled fractional order systems, to understand the essence of estimators for related integer order systems, and to keep track of the interplay between synchronization and parameter observation. This serves as the common basis for the more advanced topics and applications presented in the subsequent chapters, which include an introduction to the 'Immersion and Invariance' (I&I) methodology, the masterslave synchronization scheme for partially known nonlinear fractional order systems, Fractional Algebraic Observability (FAO) and Fractional Generalized quasi-Synchronization (FGqS) to name but a few. This book is intended not only for applied mathematicians and theoretical physicists, but also for anyone in applied science dealing with complex nonlinear systems.
Learn classical thermodynamics alongside statistical mechanics with this fresh approach to the subjects. Molecular and macroscopic principles are explained in an integrated, side-by-side manner to give students a deep, intuitive understanding of thermodynamics and equip them to tackle future research topics that focus on the nanoscale. Entropy is introduced from the get-go, providing a clear explanation of how the classical laws connect to the molecular principles, and closing the gap between the atomic world and thermodynamics. Notation is streamlined throughout, with a focus on general concepts and simple models, for building basic physical intuition and gaining confidence in problem analysis and model development. Well over 400 guided end-of-chapter problems are included, addressing conceptual, fundamental, and applied skill sets. Numerous worked examples are also provided together with handy shaded boxes to emphasize key concepts, making this the complete teaching package for students in chemical engineering and the chemical sciences.
The Ising model provides a detailed mathematical description of ferromagnetism and is widely used in statistical physics and condensed matter physics. In this Student's Guide, the author demystifies the mathematical framework of the Ising model and provides students with a clear understanding of both its physical significance, and how to apply it successfully in their calculations. Key topics related to the Ising model are covered, including exact solutions of both finite and infinite systems, series expansions about high and low temperatures, mean-field approximation methods, and renormalization-group calculations. The book also incorporates plots, figures, and tables to highlight the significance of the results. Designed as a supplementary resource for undergraduate and graduate students, each chapter includes a selection of exercises intended to reinforce and extend important concepts, and solutions are also available for all exercises.
Predicting thermodynamic quantities for chemically realistic systems on the basis of atomistic calculations is still, even today, a nontrivial task. Nonetheless, accurate treatment of inter-particle interactions, in terms of quantum chemical first principles methods, is a prerequisite for many applications, because of the complexity of both reactants and solvents in modern molecular sciences. Currently, a straightforward calculation of thermodynamic properties from these methods is only possible for high-temperature and low- density systems. Although the enthalpy of a system can often be predicted to a good level of precision with this ideal gas approach, calculating the entropy contribution to the free energy is problematic, especially as the density of the system increases. This thesis contains a compact and coherent introduction of basic theoretical features. The foundations are then laid for the development of approaches suitable for calculation of condensed phase entropies on the basis of well-established quantum chemical methods. The main emphasis of this work is on realistic systems in solution, which is the most important environment for chemical synthesis. The presented results demonstrate how isolated molecular concepts typically employed in modern quantum chemistry can be extended for the accurate determination of thermodynamic properties by means of scale- transferring approaches.
An introductory textbook exploring the subject of Lagrangian and Hamiltonian dynamics, with a relaxed and self-contained setting. Lagrangian and Hamiltonian dynamics is the continuation of Newton's classical physics into new formalisms, each highlighting novel aspects of mechanics that gradually build in complexity to form the basis for almost all of theoretical physics. Lagrangian and Hamiltonian dynamics also acts as a gateway to more abstract concepts routed in differential geometry and field theories and can be used to introduce these subject areas to newcomers. Journeying in a self-contained manner from the very basics, through the fundamentals and onwards to the cutting edge of the subject, along the way the reader is supported by all the necessary background mathematics, fully worked examples, thoughtful and vibrant illustrations as well as an informal narrative and numerous fresh, modern and inter-disciplinary applications. The book contains some unusual topics for a classical mechanics textbook. Most notable examples include the 'classical wavefunction', Koopman-von Neumann theory, classical density functional theories, the 'vakonomic' variational principle for non-holonomic constraints, the Gibbs-Appell equations, classical path integrals, Nambu brackets and the full framing of mechanics in the language of differential geometry.
This book presents a careful selection of the most important developments of the \phi^4 model, offering a judicious summary of this model with a view to future prospects and the challenges ahead. Over the past four decades, the \phi^4 model has been the basis for a broad array of developments in the physics and mathematics of nonlinear waves. From kinks to breathers, from continuum media to discrete lattices, from collisions of solitary waves to spectral properties, and from deterministic to stochastic models of \phi^4 (and \phi^6, \phi^8, \phi^12 variants more recently), this dynamical model has served as an excellent test bed for formulating and testing the ideas of nonlinear science and solitary waves.
Instantons, or pseudoparticles, are solutions to the equations of motion in classical field theories on a Euclidean spacetime. Instantons are found everywhere in quantum theories as they have many applications in quantum tunnelling. Diverse physical phenomena may be described through quantum tunnelling, for example: the Josephson effect, the decay of meta-stable nuclear states, band formation in tight binding models of crystalline solids, the structure of the gauge theory vacuum, confinement in 2+1 dimensions, and the decay of superheated or supercooled phases. Drawing inspiration from Sidney Coleman's Erice lectures, this volume provides an accessible, detailed introduction to instanton methods, with many applications, making it a valuable resource for graduate students in many areas of physics, from condensed matter, particle and nuclear physics, to string theory. This title, first published in 2017, has been reissued as an Open Access publication on Cambridge Core.
Instantons, or pseudoparticles, are solutions to the equations of motion in classical field theories on a Euclidean spacetime. Instantons are found everywhere in quantum theories as they have many applications in quantum tunnelling. Diverse physical phenomena may be described through quantum tunnelling, for example: the Josephson effect, the decay of meta-stable nuclear states, band formation in tight binding models of crystalline solids, the structure of the gauge theory vacuum, confinement in 2+1 dimensions, and the decay of superheated or supercooled phases. Drawing inspiration from Sidney Coleman's Erice lectures, this volume provides an accessible, detailed introduction to instanton methods, with many applications, making it a valuable resource for graduate students in many areas of physics, from condensed matter, particle and nuclear physics, to string theory. This title, first published in 2017, has been reissued as an Open Access publication on Cambridge Core.
This book focuses on theoretical thermotics, the theory of transformation thermotics and its extended theories for the active control of macroscopic thermal phenomena of artificial systems, which is in sharp contrast to classical thermodynamics comprising the four thermodynamic laws for the passive description of macroscopic thermal phenomena of natural systems. The book covers the basic concepts and mathematical methods, which are necessary to understand thermal problems extensively investigated in physics, but also in other disciplines of engineering and materials. The analyses rely on models solved by analytical techniques accompanied with computer simulations and laboratory experiments. This book serves both as a reference work for senior researchers and a study text for zero beginners.
A completely revised edition that combines a comprehensive coverage of statistical and thermal physics with enhanced computational tools, accessibility, and active learning activities to meet the needs of today's students and educators This revised and expanded edition of Statistical and Thermal Physics introduces students to the essential ideas and techniques used in many areas of contemporary physics. Ready-to-run programs help make the many abstract concepts concrete. The text requires only a background in introductory mechanics and some basic ideas of quantum theory, discussing material typically found in undergraduate texts as well as topics such as fluids, critical phenomena, and computational techniques, which serve as a natural bridge to graduate study. Completely revised to be more accessible to students Encourages active reading with guided problems tied to the text Updated open source programs available in Java, Python, and JavaScript Integrates Monte Carlo and molecular dynamics simulations and other numerical techniques Self-contained introductions to thermodynamics and probability, including Bayes' theorem A fuller discussion of magnetism and the Ising model than other undergraduate texts Treats ideal classical and quantum gases within a uniform framework Features a new chapter on transport coefficients and linear response theory Draws on findings from contemporary research Solutions manual (available only to instructors)
Continuum Models for Phase Transitions and Twinning in Crystals presents the fundamentals of a remarkably successful approach to crystal thermomechanics. Developed over the last two decades, it is based on the mathematical theory of nonlinear thermoelasticity, in which a new viewpoint on material symmetry, motivated by molecular theories, plays a central role.
Networks are convenient mathematical models to represent the structure of complex systems, from cells to societies. In the last decade, multilayer network science - the branch of the field dealing with units interacting in multiple distinct ways, simultaneously - was demonstrated to be an effective modeling and analytical framework for a wide spectrum of empirical systems, from biopolymers networks (such as interactome and metabolomes) to neuronal networks (such as connectomes), from social networks to urban and transportation networks. In this Element, a decade after one of the most seminal papers on this topic, the authors review the most salient features of multilayer network science, covering both theoretical aspects and direct applications to real-world coupled/interdependent systems, from the point of view of multilayer structure, dynamics and function. The authors discuss potential frontiers for this topic and the corresponding challenges in the field for the next future.
This book provides a comprehensive and self-contained overview of recent progress in nonequilibrium statistical mechanics, in particular, the discovery of fluctuation relations and other time-reversal symmetry relations. The significance of these advances is that nonequilibrium statistical physics is no longer restricted to the linear regimes close to equilibrium, but extends to fully nonlinear regimes. These important new results have inspired the development of a unifying framework for describing both the microscopic dynamics of collections of particles, and the macroscopic hydrodynamics and thermodynamics of matter itself. The book discusses the significance of this theoretical framework in relation to a broad range of nonequilibrium processes, from the nanoscale to the macroscale, and is essential reading for researchers and graduate students in statistical physics, theoretical chemistry and biological physics.
Our original objective in writing this book was to demonstrate how the concept of the equation of motion of a Brownian particle - the Langevin equation or Newtonian-like evolution equation of the random phase space variables describing the motion - first formulated by Langevin in 1908 - so making him inter alia the founder of the subject of stochastic differential equations, may be extended to solve the nonlinear problems arising from the Brownian motion in a potential. Such problems appear under various guises in many diverse applications in physics, chemistry, biology, electrical engineering, etc. However, they have been invariably treated (following the original approach of Einstein and Smoluchowski) via the Fokker-Planck equation for the evolution of the probability density function in phase space. Thus the more simple direct dynamical approach of Langevin which we use and extend here, has been virtually ignored as far as the Brownian motion in a potential is concerned. In addition two other considerations have driven us to write this new edition of The Langevin Equation. First, more than five years have elapsed since the publication of the third edition and following many suggestions and comments of our colleagues and other interested readers, it became increasingly evident to us that the book should be revised in order to give a better presentation of the contents. In particular, several chapters appearing in the third edition have been rewritten so as to provide a more direct appeal to the particular community involved and at the same time to emphasize via a synergetic approach how seemingly unrelated physical problems all involving random noise may be described using virtually identical mathematical methods. Secondly, in that period many new and exciting developments have occurred in the application of the Langevin equation to Brownian motion. Consequently, in order to accommodate all these, a very large amount of new material has been added so as to present a comprehensive overview of the subject.
"A Modern Course in Statistical Physics" is a textbook that illustrates the foundations of equilibrium and non-equilibrium statistical physics, and the universal nature of thermodynamic processes, from the point of view of contemporary research problems. The book treats such diverse topics as the microscopic theory of critical phenomena, superfluid dynamics, quantum conductance, light scattering, transport processes, and dissipative structures, all in the framework of the foundations of statistical physics and thermodynamics. It shows the quantum origins of problems in classical statistical physics. One focus of the book is fluctuations that occur due to the discrete nature of matter, a topic of growing importance for nanometer scale physics and biophysics. Another focus concerns classical and quantum phase transitions, in both monatomic and mixed particle systems. This fourth edition extends the range of topics considered to include, for example, entropic forces, electrochemical processes in biological systems and batteries, adsorption processes in biological systems, diamagnetism, the theory of Bose-Einstein condensation, memory effects in Brownian motion, the hydrodynamics of binary mixtures. A set of exercises and problems is to be found at the end of each chapter and, in addition, solutions to a subset of the problems is provided. The appendices cover Exact Differentials, Ergodicity, Number Representation, Scattering Theory, and also a short course on Probability.
Providing a systematic introduction to the techniques which are fundamental to quantum field theory, this book pays special attention to the use of these techniques in a wide variety of areas, including ordinary quantum mechanics, quantum mechanics in the second-quantized formulation, relativistic quantum field theory, Euclidean field theory, quantum statistics at finite temperature, and the classical statistics of nonideal gas and spin systems. The extended chapter on variational methods and functional Legendre transformations contains completely original material.
Presenting in a coherent and accessible fashion current results in nanomagnetism, this book constitutes a comprehensive, rigorous and readable account, from first principles of the classical and quantum theories underlying the dynamics of magnetic nanoparticles subject to thermal fluctuations.Starting with the Larmor-like equation for a giant spin, both the stochastic (Langevin) equation of motion of the magnetization and the associated evolution (Fokker-Planck) equation for the distribution function of the magnetization orientations of ferromagnetic nanoparticles (classical spins) in a heat bath are developed along with their solution (using angular momentum theory) for arbitrary magnetocrystalline-Zeeman energy. Thus, observables such as the magnetization reversal time, relaxation functions, dynamic susceptibilities, etc. are calculated and compared with the predictions of classical escape rate theory including in the most general case spin-torque-transfer. Regarding quantum effects, which are based on the reduced spin density matrix evolution equation in Hilbert space as is described at length, they are comprehensively treated via the Wigner-Stratonovich formulation of the quantum mechanics of spins via their orientational quasi-probability distributions on a classically meaningful representation space. Here, as suggested by the relevant Weyl symbols, the latter is the configuration space of the polar angles. Hence, one is led, by mapping the reduced density matrix equation onto that space, to a master equation for the quasi-probability evolution akin to the Fokker-Planck equation which may be solved in a similar way. Thus, one may study in a classical-like manner the evolution of observables with spin number ranging from an elementary spin to molecular clusters to the classical limit, viz. a nanoparticle. The entire discussion hinges on the one-to-one correspondence between polarization operators in Hilbert space and the spherical harmonics allied to concepts of spin coherent states long familiar in quantum optics.Catering for the reader with only a passing knowledge of statistical and quantum mechanics, the book serves as an introductory text on a complicated subject where the literature is remarkably sparse.
In this resource, acknowledged leaders in the field examine current state-of-the-art and recent developments in technology, of flow boiling systems which are affected by convective flows. This important volume consists of expanded and revised peer-reviewed papers presented at the Engineering Foundations's Convective Flow Boiling: An International Conference held in 1995.
Il testo si configura come un' introduzione alla fisica statistica rivolto in primo luogo a quei corsi di studio in ingegneria che piu hanno a che fare con le proprieta fisiche dei materiali, ed ha lo scopo di fornire le basi microscopiche del comportamento termodinamico di cui si fa uso sia in molti corsi tradizionali, quali quelli di termofluidica d'interesse per l'ingegneria chimica e nucleare, che in corsi rivolti ad applicazioni avanzate nella scienza dei materiali e nelle nanotecnologie. Particolare attenzione viene quindi dedicata all'impiego di metodi di fisica statistica nella scienza dei materiali, approfondendo tematiche relative alle vibrazioni nei solidi, ai processi di nucleazione liquido/vapore, alla struttura dello stato fluido e vetroso, ai plasmi, ai materiali magnetici, al gas di Fermi e alla superfluidita. Per il suo carattere generale, e per l'accento posto sui fondamenti della meccanica quantistica, il volume si presta comunque a costituire anche un testo introduttivo alla meccanica statistica per studenti dei corsi di laurea in fisica."
In many systems consisting of interacting subsystems, the complex interactions between elements can be represented using multilayer networks. However percolation, key to understanding connectivity and robustness, is not trivially generalised to multiple layers. This Element describes a generalisation of percolation to multilayer networks: weak multiplex percolation. A node belongs to a connected component if at least one of its neighbours in each layer is in this component. The authors fully describe the critical phenomena of this process. In two layers with finite second moments of the degree distributions the authors observe an unusual continuous transition with quadratic growth above the threshold. When the second moments diverge, the singularity is determined by the asymptotics of the degree distributions, creating a rich set of critical behaviours. In three or more layers the authors find a discontinuous hybrid transition which persists even in highly heterogeneous degree distributions, becoming continuous only when the powerlaw exponent reaches $1+1/(M-1)$ for $M$ layers.
Statistical physics examines the collective properties of large ensembles of particles, and is a powerful theoretical tool with important applications across many different scientific disciplines. This book provides a detailed introduction to classical and quantum statistical physics, including links to topics at the frontiers of current research. The first part of the book introduces classical ensembles, provides an extensive review of quantum mechanics, and explains how their combination leads directly to the theory of Bose and Fermi gases. This allows a detailed analysis of the quantum properties of matter, and introduces the exotic features of vacuum fluctuations. The second part discusses more advanced topics such as the two-dimensional Ising model and quantum spin chains. This modern text is ideal for advanced undergraduate and graduate students interested in the role of statistical physics in current research. 140 homework problems reinforce key concepts and further develop readers' understanding of the subject.
Real networks comprise from hundreds to millions of interacting elements and permeate all contexts, from technology to biology to society. All of them display non-trivial connectivity patterns, including the small-world phenomenon, making nodes to be separated by a small number of intermediate links. As a consequence, networks present an apparent lack of metric structure and are difficult to map. Yet, many networks have a hidden geometry that enables meaningful maps in the two-dimensional hyperbolic plane. The discovery of such hidden geometry and the understanding of its role have become fundamental questions in network science giving rise to the field of network geometry. This Element reviews fundamental models and methods for the geometric description of real networks with a focus on applications of real network maps, including decentralized routing protocols, geometric community detection, and the self-similar multiscale unfolding of networks by geometric renormalization.
The general non equilibrium statistical approach, due to Zubarev, is presented briefly in Chapter 1. Chapter 2 is devoted to construction of an application of this approach to a statistical mechanical description of transport processes on a dividing surface between two immiscible fluids when singular densities of mass, and/or momentum, and/or energy are presented. In chapter 3 the shock wave in a gas is considered an interphase boundary of the gas-gas type. Chapters 4 and 5 fluctuations of flows of mass or momentum across the surfaces of sufficiently small liquid or solid particles, respectively, are discussed. Finally, chapter 6 discusses a generalization of the one-particle Brownian motion theory to many-particle situations, where the interparticle hydrodynamic ineraction are essential.
Higher-order networks describe the many-body interactions of a large variety of complex systems, ranging from the the brain to collaboration networks. Simplicial complexes are generalized network structures which allow us to capture the combinatorial properties, the topology and the geometry of higher-order networks. Having been used extensively in quantum gravity to describe discrete or discretized space-time, simplicial complexes have only recently started becoming the representation of choice for capturing the underlying network topology and geometry of complex systems. This Element provides an in-depth introduction to the very hot topic of network theory, covering a wide range of subjects ranging from emergent hyperbolic geometry and topological data analysis to higher-order dynamics. This Elements aims to demonstrate that simplicial complexes provide a very general mathematical framework to reveal how higher-order dynamics depends on simplicial network topology and geometry. |
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