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Books > Science & Mathematics > Physics > Thermodynamics & statistical physics > Statistical physics
Thermal and statistical physics has established the principles and procedures needed to understand and explain the properties of systems consisting of macroscopically large numbers of particles. By developing microscopic statistical physics and macroscopic classical thermodynamic descriptions in tandem, Statistical and Thermal Physics: An Introduction provides insight into basic concepts and relationships at an advanced undergraduate level. This second edition is updated throughout, providing a highly detailed, profoundly thorough, and comprehensive introduction to the subject and features exercises within the text as well as end-of-chapter problems. Part I of this book consists of nine chapters, the first three of which deal with the basics of equilibrium thermodynamics, including the fundamental relation. The following three chapters introduce microstates and lead to the Boltzmann definition of the entropy using the microcanonical ensemble approach. In developing the subject, the ideal gas and the ideal spin system are introduced as models for discussion. The laws of thermodynamics are compactly stated. The final three chapters in Part I introduce the thermodynamic potentials and the Maxwell relations. Applications of thermodynamics to gases, condensed matter, and phase transitions and critical phenomena are dealt with in detail. Initial chapters in Part II present the elements of probability theory and establish the thermodynamic equivalence of the three statistical ensembles that are used in determining probabilities. The canonical and the grand canonical distributions are obtained and discussed. Chapters 12-15 are concerned with quantum distributions. By making use of the grand canonical distribution, the Fermi-Dirac and Bose-Einstein quantum distribution functions are derived and then used to explain the properties of ideal Fermi and Bose gases. The Planck distribution is introduced and applied to photons in radiation and to phonons on solids. The last five chapters cover a variety of topics: the ideal gas revisited, nonideal systems, the density matrix, reactions, and irreversible thermodynamics. A flowchart is provided to assist instructors on planning a course. Key Features: Fully updated throughout, with new content on exciting topics, including black hole thermodynamics, Heisenberg antiferromagnetic chains, entropy and information theory, renewable and nonrenewable energy sources, and the mean field theory of antiferromagnetic systems Additional problem exercises with solutions provide further learning opportunities Suitable for advanced undergraduate students in physics or applied physics. Michael J.R. Hoch spent many years as a visiting scientist at the National High Magnetic Field Laboratory at Florida State University, USA. Prior to this, he was a professor of physics and the director of the Condensed Matter Physics Research Unit at the University of the Witwatersrand, Johannesburg, where he is currently professor emeritus in the School of Physics.
Nonadiabatic transition is a highly multidisciplinary concept and phenomenon, constituting a fundamental mechanism of state and phase changes in various dynamical processes of physics, chemistry and biology, such as molecular dynamics, energy relaxation, chemical reaction, and electron and proton transfer. Control of molecular processes by laser fields is also an example of time-dependent nonadiabatic transition.In this new edition, the original chapters are updated to facilitate enhanced understanding of the concept and applications. Three new chapters - comprehension of nonadiabatic chemical dynamics, control of chemical dynamics, and manifestation of molecular functions - are also added.
The availability of large data sets has allowed researchers to uncover complex properties such as large-scale fluctuations and heterogeneities in many networks, leading to the breakdown of standard theoretical frameworks and models. Until recently these systems were considered as haphazard sets of points and connections. Recent advances have generated a vigorous research effort in understanding the effect of complex connectivity patterns on dynamical phenomena. This book presents a comprehensive account of these effects. A vast number of systems, from the brain to ecosystems, power grids and the internet, can be represented as large complex networks. This book will interest graduate students and researchers in many disciplines, from physics and statistical mechanics to mathematical biology and information science. Its modular approach allows readers to readily access the sections of most interest to them, and complicated maths is avoided so the text can be easily followed by non-experts in the subject.
This book is a collection of papers contributed by some of the greatest names in the areas of chaos and nonlinear dynamics. Each paper examines a research topic at the frontier of the area of dynamical systems. As well as reviewing recent results, each paper also discusses the future perspectives of each topic. The result is an invaluable snapshot of the state of the ?eld by some of the most important researchers in the area. The ?rst contribution in this book (the section entitled "How did you get into Chaos?") is actually not a paper, but a collection of personal accounts by a number of participants of the conference held in Aberdeen in September 2007 to honour Celso Grebogi's 60th birthday. At the instigation of James Yorke, many of the most well-known scientists in the area agreed to share their tales on how they got involved in chaos during a celebratory dinner in Celso's honour during the conference. This was recorded in video, we felt that these accounts were a valuable historic document for the ?eld. So we decided to transcribe it and include it here as the ?rst section of the book.
The science of statistical mechanics is concerned with defining the thermodynamic properties of a macroscopic sample in terms of the properties of the microscopic systems of which it is composed. The aim of this book is to provide a clear, logical, and self-contained treatment of equilibrium statistical mechanics starting from Boltzmann's two statistical assumptions, and to present a wide variety of applications to diverse physical assemblies. The coverage is enhanced and extended through an extensive set of accessible problems. An appendix provides an introduction to non-equilibrium statistical mechanics through the Boltzmann equation and its extensions. The book assumes introductory courses in classical and quantum mechanics, as well as familiarity with multi-variable calculus and the essentials of complex analysis. Some knowledge of thermodynamics is assumed, although the book starts with an appropriate review of that topic. The targeted audience is first-year graduate students, and advanced undergraduates, in physics, chemistry, and the related physical sciences. The goal of this text is to help the reader obtain a clear working knowledge of the very useful and powerful methods of equilibrium statistical mechanics and to enhance the understanding and appreciation of the more advanced texts.
The science of statistical mechanics is concerned with defining the thermodynamic properties of a macroscopic sample in terms of the properties of the microscopic systems of which it is composed. The aim of this book is to provide a clear, logical, and self-contained treatment of equilibrium statistical mechanics starting from Boltzmann's two statistical assumptions, and to present a wide variety of applications to diverse physical assemblies. The coverage is enhanced and extended through an extensive set of accessible problems. An appendix provides an introduction to non-equilibrium statistical mechanics through the Boltzmann equation and its extensions. The book assumes introductory courses in classical and quantum mechanics, as well as familiarity with multi-variable calculus and the essentials of complex analysis. Some knowledge of thermodynamics is assumed, although the book starts with an appropriate review of that topic. The targeted audience is first-year graduate students, and advanced undergraduates, in physics, chemistry, and the related physical sciences. The goal of this text is to help the reader obtain a clear working knowledge of the very useful and powerful methods of equilibrium statistical mechanics and to enhance the understanding and appreciation of the more advanced texts.
This is one of the very few books focusing on relativistic statistical mechanics, and is written by a leading expert in this special field. It started from the notion of relativistic kinetic theory, half a century ago, exploding into relativistic statistical mechanics. This will interest specialists of various fields, especially the (classical and quantum) plasma physics. However, quantum physics - to which a major part is devoted - will be of more interest since, not only it applies to quantum plasma physics, but also to nuclear matter and to strong magnetic field, cosmology, etc. Although the domain of gauge theory is not covered in this book, the topic is not completely forgotten, in particular in the domain of plasma physics. This book is particularly readable for graduate students and a fortiori to young researchers for whom it offers methods and also appropriate schemes to deal with the current problems encountered in astrophysics, in strong magnetic, in nuclear or even in high energy physics.
The wide application of technologies in new mechanical, electronic and biomedical systems calls for materials and structures with non-conventional properties (e.g materials with 'memory'). Of equal importance is the understanding of the physical behaviour of these materials and consequently developing mathematical modelling techniques for prediction. This self contained text discusses the mathematical modelling used with these types of electromagnetic materials. It provides a carefully structured, coherent, and comprehensive treatment of electromagnetism of continuous media. The authors provide a systematic review of known subjects along with original results about thermodynamics of electromagnetic materials, well-posedness of initial boundary-value problems, variational settings, and wave propagation. Models of non-linear materials, non-local materials (superconductors), and hysteretic (magnetic) materials are also developed in detail.
This book covers in great detail the Rouse-segment-based molecular theories in polymer viscoelasticity -- the Rouse theory and the extended reptation theory (based on the framework of the Doi-Edwards theory) -- that have been shown to explain experimental results in a consistently quantitative way. The explanation for the 3.4 power law of viscosity, quantitative line-shape analyses of viscoelastic responses and agreements between different sorts of viscoelastic responses, the consistency between the viscoelasticity and diffusion results, the clarification of the onset of entangelement, the discovery of the number of entanglement strands per cubed entanglement distance being a universal constant and the basic mechanism of the glass transition-related thermorheological complexity are discussed or shown in great detail. The mystery behind the success of the Rouse-segment-based molecular theories over the entropic region of a viscoelastic response is revealed by the Monte Carlo simulations on the Fraenkel chains. Specifically, the simulation studies give a natural explanation for the coexistence of the energy-driven and entropy-driven modes in a viscoelastic response and provide a theoretical basis resolving the paradox that the experimentally determined sizes of Rouse and Kuhn segments are nearly the same. This book starts from a very fundamental level; each chapter is built upon the contents of the previous chapters. Thus, the readers may use the book as a textbook and eventually reach an advanced research level. This book is also a useful source of reference for physicists, chemists and material scientists.
Pendulum is the simplest nonlinear system, which, however, provides the means for the description of different phenomena in Nature that occur in physics, chemistry, biology, medicine, communications, economics and sociology. The chaotic behavior of pendulum is usually associated with the random force acting on a pendulum (Brownian motion). Another type of chaotic motion (deterministic chaos) occurs in nonlinear systems with only few degrees of freedom. This book presents a comprehensive description of these phenomena going on in underdamped and overdamped pendula subject to additive and multiplicative periodic and random forces. No preliminary knowledge, such as complex mathematical or numerical methods, is required from a reader other than undergraduate courses in mathematical physics. A wide group of researchers, along with students and teachers will, thus, benefit from this definitive book on nonlinear dynamics.
This book provides a comprehensive introduction to the theory of phase transitions and critical phenomena. The content covers a period of more than 100 years of theoretical research of condensed matter phases and phase transitions providing a clear interrelationship with experimental problems. It starts from certain basic University knowledge of thermodynamics, statistical physics and quantum mechanics. The text is illustrated with classic examples of phase transitions. Various types of phase transition and (multi)critical points are introduced and explained. The classic aspects of the theory are naturally related with the modern developments. This interrelationship and the field-theoretical renormalization group method are presented in details. The main applications of the renormalization group methods are presented. Special attention is paid to the description of quantum phase transitions. This edition contains a more detailed presentation of the renormalization group method and its applications to particular systems.
This book provides a comprehensive introduction to the theory of phase transitions and critical phenomena. The content covers a period of more than 100 years of theoretical research of condensed matter phases and phase transitions providing a clear interrelationship with experimental problems. It starts from certain basic University knowledge of thermodynamics, statistical physics and quantum mechanics. The text is illustrated with classic examples of phase transitions. Various types of phase transition and (multi)critical points are introduced and explained. The classic aspects of the theory are naturally related with the modern developments. This interrelationship and the field-theoretical renormalization group method are presented in details. The main applications of the renormalization group methods are presented. Special attention is paid to the description of quantum phase transitions. This edition contains a more detailed presentation of the renormalization group method and its applications to particular systems.
This textbook is for undergraduate students on a basic course in Statistical Mechanics. The prerequisite is thermodynamics. It begins with a study of three situations -- the closed system and the systems in thermal contact with a reservoir -- in order to formulate the important fundamentals: entropy from Boltzmann formula, partition function and grand partition function. Through the presentation of quantum statistics, Bose statistics and Fermi-Dirac statistics are established, including as a special case the classical situation of Maxell-Boltzmann statistics. A series of examples ensue it: the harmonic oscillator, the polymer chain, the two level system, bosons (photons, phonons, and the Bose-Einstein condensation) and fermions (electrons in metals and in semiconductors). A compact historical note on influential scientists forms the concluding chapter. The unique presentation starts off with the principles, elucidating the well-developed theory, and only thereafter the application of theory. Calculations on the main steps are detailed, leaving behind minimal gap. The author emphasizes with theory the link between the macroscopic world (thermodynamics) and the microscopic world.
This textbook is for undergraduate students on a basic course in Statistical Mechanics. The prerequisite is thermodynamics. It begins with a study of three situations -- the closed system and the systems in thermal contact with a reservoir -- in order to formulate the important fundamentals: entropy from Boltzmann formula, partition function and grand partition function. Through the presentation of quantum statistics, Bose statistics and Fermi-Dirac statistics are established, including as a special case the classical situation of Maxell-Boltzmann statistics. A series of examples ensue it: the harmonic oscillator, the polymer chain, the two level system, bosons (photons, phonons, and the Bose-Einstein condensation) and fermions (electrons in metals and in semiconductors). A compact historical note on influential scientists forms the concluding chapter. The unique presentation starts off with the principles, elucidating the well-developed theory, and only thereafter the application of theory. Calculations on the main steps are detailed, leaving behind minimal gap. The author emphasizes with theory the link between the macroscopic world (thermodynamics) and the microscopic world.
This book is designed for use in an introductory course in thermodynamics. It is aimed at students of Physics, Chemistry, Materials Science, and Engineering. As an undergraduate text, it gives a clear description of the theoretical framework of thermodynamics, while providing specific examples of its use in a wide variety of problems. These examples include topics that are atypical of undergraduate texts, such as biological systems, atmospheric phenomena, and polymers. The narrative is infused with historical notes on the characters who make up the story of thermodynamics, enlivening the material while keeping the reader engaged.
This volume presents a collection of original and peer-reviewed articles related with the applications of Statistical Physics dedicated to Professor Dr Leopoldo Garcia-Colin, in commemoration of his 80th birthday in 2010. Professor Garcia-Colin has worked in many different fields of statistical physics, and has applied it to biological physics, solid state physics, relativity and cosmology. These are pioneering works of Prof Garcia-Colin involved in all various fields which have their roots in Mexico. His influence is found in each of these works that cover a wide range of topics including thermodynamics, statistical mechanics and kinetic theory applied to biological systems, cosmology and condensed matter, among others.Papers contributed by important experts in the field, such as J Lebowitz, as well as the latest classical applications of statistical physics can be found in this volume.
This book is devoted to analysis of Monte Carlo methods developed in rarefied gas dynamics. Presented is the short history of the development of such methods, described are their main properties, their advantages and deficiencies. It is shown that the contemporary stage in the progress of computational methods cannot be regarded without a complex approach to the preparation of algorithms taking into account all the peculiarities of the problem under consideration, that is, of the physical nature of a process, the mathematical model and the theoretical aspects of computational mathematics and stochastic processes. Thoroughly investigated is the possibility of application of Monte Carlo methods in some kindred areas of science which are non-traditional for the use of statistical modeling (continuous media, turbulence). Considered are the possible directions of development of statistical modeling.
Gauge/gravity duality creates new links between quantum theory and gravity. It has led to new concepts in mathematics and physics, and provides new tools to solve problems in many areas of theoretical physics. This book is the first textbook on this important topic, enabling graduate students and researchers in string theory and particle, nuclear and condensed matter physics to get acquainted with the subject. Focusing on the fundamental aspects as well as on the applications, this textbook guides readers through a thorough explanation of the central concepts of gauge/gravity duality. For the AdS/CFT correspondence, it explains in detail how string theory provides the conjectured map. Generalisations to less symmetric cases of gauge/gravity duality and their applications are then presented, in particular to finite temperature and density, hydrodynamics, QCD-like theories, the quark-gluon plasma and condensed matter systems. The textbook features a large number of exercises, with solutions available online at www.cambridge.org/9781107010345.
This is a masters/graduate level textbook on statistical physics. The basics of the discipline and its application in the current topics of interest like BoseEinstein condensate, statistical astrophysics and phase transitions have been discussed with thoroughness. This is a systematic introduction and development of a course material tried successful over a number of years. Feedback from the students tells that it has immensely helped them in their later research.
How can one construct dynamical systems obeying the first and second laws of thermodynamics: mean energy is conserved and entropy increases with time? This book answers the question for classical probability (Part I) and quantum probability (Part II). A novel feature is the introduction of heat particles which supply thermal noise and represent the kinetic energy of the molecules. When applied to chemical reactions, the theory leads to the usual nonlinear reaction-diffusion equations as well as modifications of them. These can exhibit oscillations, or can converge to equilibrium. In this second edition, the text is simplified in parts and the bibliography has been expanded. The main difference is the addition of two new chapters; in the first, classical fluid dynamics is introduced. A lattice model is developed, which in the continuum limit gives us the Euler equations. The five Navier???Stokes equations are also presented, modified by a diffusion term in the continuity equation. The second addition is in the last chapter, which now includes estimation theory, both classical and quantum, using information geometry.
How can one construct dynamical systems obeying the first and second laws of thermodynamics: mean energy is conserved and entropy increases with time? This book answers the question for classical probability (Part I) and quantum probability (Part II). A novel feature is the introduction of heat particles which supply thermal noise and represent the kinetic energy of the molecules. When applied to chemical reactions, the theory leads to the usual nonlinear reaction-diffusion equations as well as modifications of them. These can exhibit oscillations, or can converge to equilibrium. In this second edition, the text is simplified in parts and the bibliography has been expanded. The main difference is the addition of two new chapters; in the first, classical fluid dynamics is introduced. A lattice model is developed, which in the continuum limit gives us the Euler equations. The five Navier???Stokes equations are also presented, modified by a diffusion term in the continuity equation. The second addition is in the last chapter, which now includes estimation theory, both classical and quantum, using information geometry.
The principal message of this book is that thermodynamics and statistical mechanics will benefit from replacing the unfortunate, misleading and mysterious term "entropy" with a more familiar, meaningful and appropriate term such as information, missing information or uncertainty. This replacement would facilitate the interpretation of the "driving force" of many processes in terms of informational changes and dispel the mystery that has always enshrouded entropy.It has been 140 years since Clausius coined the term "entropy"; almost 50 years since Shannon developed the mathematical theory of "information" - subsequently renamed "entropy". In this book, the author advocates replacing "entropy" by "information", a term that has become widely used in many branches of science.The author also takes a new and bold approach to thermodynamics and statistical mechanics. Information is used not only as a tool for predicting distributions but as the fundamental cornerstone concept of thermodynamics, held until now by the term "entropy".The topics covered include the fundamentals of probability and information theory; the general concept of information as well as the particular concept of information as applied in thermodynamics; the re-derivation of the Sackur-Tetrode equation for the entropy of an ideal gas from purely informational arguments; the fundamental formalism of statistical mechanics; and many examples of simple processes the "driving force" for which is analyzed in terms of information.
The principal message of this book is that thermodynamics and statistical mechanics will benefit from replacing the unfortunate, misleading and mysterious term "entropy" with a more familiar, meaningful and appropriate term such as information, missing information or uncertainty. This replacement would facilitate the interpretation of the "driving force" of many processes in terms of informational changes and dispel the mystery that has always enshrouded entropy.It has been 140 years since Clausius coined the term "entropy"; almost 50 years since Shannon developed the mathematical theory of "information" - subsequently renamed "entropy". In this book, the author advocates replacing "entropy" by "information", a term that has become widely used in many branches of science.The author also takes a new and bold approach to thermodynamics and statistical mechanics. Information is used not only as a tool for predicting distributions but as the fundamental cornerstone concept of thermodynamics, held until now by the term "entropy".The topics covered include the fundamentals of probability and information theory; the general concept of information as well as the particular concept of information as applied in thermodynamics; the re-derivation of the Sackur-Tetrode equation for the entropy of an ideal gas from purely informational arguments; the fundamental formalism of statistical mechanics; and many examples of simple processes the "driving force" for which is analyzed in terms of information.
This third edition of one of the most important and best selling textbooks in statistical physics, is a graduate level text suitable for students in physics, chemistry, and materials science.The discussion of strongly interacting condensed matter systems has been expanded. A chapter on stochastic processes has also been added with emphasis on applications of the Fokker-Planck equation.The modern theory of phase transitions occupies a central place. The chapter devoted to the renormalization group approach is largely rewritten and includes a detailed discussion of the basic concepts and examples of both exact and approximate calculations. The development of the basic tools includes a chapter on computer simulations in which both Monte Carlo method and molecular dynamics are introduced, and a section on Brownian dynamics added.The theories are applied to a number of important systems such as liquids, liquid crystals, polymers, membranes, Bose condensation, superfluidity and superconductivity. There is also an extensive treatment of interacting Fermi and Bose systems, percolation theory and disordered systems in general.
This third edition of one of the most important and best selling textbooks in statistical physics, is a graduate level text suitable for students in physics, chemistry, and materials science.The discussion of strongly interacting condensed matter systems has been expanded. A chapter on stochastic processes has also been added with emphasis on applications of the Fokker-Planck equation.The modern theory of phase transitions occupies a central place. The chapter devoted to the renormalization group approach is largely rewritten and includes a detailed discussion of the basic concepts and examples of both exact and approximate calculations. The development of the basic tools includes a chapter on computer simulations in which both Monte Carlo method and molecular dynamics are introduced, and a section on Brownian dynamics added.The theories are applied to a number of important systems such as liquids, liquid crystals, polymers, membranes, Bose condensation, superfluidity and superconductivity. There is also an extensive treatment of interacting Fermi and Bose systems, percolation theory and disordered systems in general. |
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