Thermodynamics and information touch theory every facet of chemistry. However, the physical chemistry curriculum digested by students worldwide is still heavily skewed toward heat/work principles established more than a century ago. Rectifying this situation, Chemical Thermodynamics and Information Theory with Applications explores applications drawn from the intersection of thermodynamics and information theory-two mature and far-reaching fields. In an approach that intertwines information science and chemistry, this book covers: The informational aspects of thermodynamic state equations The algorithmic aspects of transformations-compression, expansion, cyclic, and more The principles of best-practice programming How molecules transmit and modify information via collisions and chemical reactions Using examples from physical and organic chemistry, this book demonstrates how the disciplines of thermodynamics and information theory are intertwined. Accessible to curiosity-driven chemists with knowledge of basic calculus, probability, and statistics, the book provides a fresh perspective on time-honored subjects such as state transformations, heat and work exchanges, and chemical reactions.

This monograph introduces an exact model for a critical spin chain with arbitrary spin S, which includes the Haldane--Shastry model as the special case S=1/2. While spinons in the Haldane-Shastry model obey abelian half-fermi statistics, the spinons in the general model introduced here obey non-abelian statistics. This manifests itself through topological choices for the fractional momentum spacings. The general model is derived by mapping exact models of quantized Hall states onto spin chains. The book begins with pedagogical review of all the relevant models including the non-abelian statistics in the Pfaffian Hall state, and is understandable to every student with a graduate course in quantum mechanics.

Over 130 years ago, James Clerk Maxwell introduced his hypothetical "demon" as a challenge to the scope of the second law of thermodynamics. Fascination with the demon persisted throughout the development of statistical and quantum physics, information theory, and computer science, and links have been established between Maxwell's demon and each of these disciplines. The demon's seductive quality makes it appealing to physical scientists, engineers, computer scientists, biologists, psychologists, and historians and philosophers of science. Since the publication of Maxwell's Demon: Entropy, Information, Computing in 1990, Maxwell's demon has been the subject of renewed and increased interest by numerous researchers in the fields mentioned above. Updated and expanded, Maxwell's Demon 2: Entropy, Classical and Quantum Information, Computing retains many of the seminal papers that appeared in the first edition, including the original thoughts of James Clerk Maxwell and William Thomson; a historical review by Martin Klein; and key articles by Leo Szilard, Leon Brillouin, Rolf Landauer, and Charles Bennett that led to new branches of research on the demon. This second edition contains newer articles by Landauer, Bennett, and others, related to Landauer's principle; connections with quantum mechanics; algorithmic information; and the thermodynamics and limits of computation. The book also includes two separate bibliographies: an alphabetical listing by author and a chronological bibliography that is annotated by the editors and contains selected quotes from the books and articles listed. The bibliography has more than doubled in size since publication of the first edition and now contains over 570 entries.

The aim of this book is to provide the fundamentals of statistical physics and its application to condensed matter. The combination of statistical mechanics and quantum mechanics has provided an understanding of properties of matter leading to spectacular technological innovations and discoveries in condensed matter which have radically changed our daily life.The book gives the steps to follow to understand fundamental theories and to apply these to real materials.

* Physical chemists will find this book comprehensive. Topical reviews on all aspects of colloidal ordering and related phase transitions will be covered. It provides a good blend of experimental and theoretical investigations.
* Useful to materials scientists and chemical engineers, the book includes a discussion of stability, important from the point of view of applications of colloidal crystals.
* Physicists will be interested in the book, because it highlights the controversy over effective interparticle interaction in charged colloids.

This edited volume collects six surveys that present state-of-the-art results on modeling, qualitative analysis, and simulation of active matter, focusing on specific applications in the natural sciences. Following the previously published Active Particles volumes, these chapters are written by leading experts in the field and reflect the diversity of subject matter in theory and applications within an interdisciplinary framework. Topics covered include: Variability and heterogeneity in natural swarms Multiscale aspects of the dynamics of human crowds Mathematical modeling of cell collective motion triggered by self-generated gradients Clustering dynamics on graphs Random Batch Methods for classical and quantum interacting particle systems The consensus-based global optimization algorithm and its recent variants Mathematicians and other members of the scientific community interested in active matter and its many applications will find this volume to be a timely, authoritative, and valuable resource.

This book is suitable to be used as a text in introducing graduate courses or advanced undergraduate courses on the equilibrium statistical mechanics of bulk phases, interfaces, thin films and associations colloids. Emphasis is placed on exactly solvable models or physically motivated approximate theories that offer revealing insights into the molecular origins of the behaviour of materials in equilibrium. Also emphasized are theoretically motivated semiempirical models that can be used in quantitative predictions of phase and interfacial behavior. The book is unique in its unified approach to the theory of phases and their interfaces and on the density functional theory that unification is based on.

Our original objective in writing this book was to demonstrate how the concept of the equation of motion of a Brownian particle - the Langevin equation or Newtonian-like evolution equation of the random phase space variables describing the motion - first formulated by Langevin in 1908 - so making him inter alia the founder of the subject of stochastic differential equations, may be extended to solve the nonlinear problems arising from the Brownian motion in a potential. Such problems appear under various guises in many diverse applications in physics, chemistry, biology, electrical engineering, etc. However, they have been invariably treated (following the original approach of Einstein and Smoluchowski) via the Fokker-Planck equation for the evolution of the probability density function in phase space. Thus the more simple direct dynamical approach of Langevin which we use and extend here, has been virtually ignored as far as the Brownian motion in a potential is concerned. In addition two other considerations have driven us to write this new edition of The Langevin Equation. First, more than five years have elapsed since the publication of the third edition and following many suggestions and comments of our colleagues and other interested readers, it became increasingly evident to us that the book should be revised in order to give a better presentation of the contents. In particular, several chapters appearing in the third edition have been rewritten so as to provide a more direct appeal to the particular community involved and at the same time to emphasize via a synergetic approach how seemingly unrelated physical problems all involving random noise may be described using virtually identical mathematical methods. Secondly, in that period many new and exciting developments have occurred in the application of the Langevin equation to Brownian motion. Consequently, in order to accommodate all these, a very large amount of new material has been added so as to present a comprehensive overview of the subject.

Bringing together the key ideas from nonequilibrium statistical mechanics and powerful methodology from quantum field theory, this book captures the essence of nonequilibrium quantum field theory. Beginning with the foundational aspects of the theory, the book presents important concepts and useful techniques, discusses issues of basic interest, and shows how thermal field, linear response, kinetic theories and hydrodynamics emerge. It also illustrates how these concepts and methodology are applied to current research topics including nonequilibrium phase transitions, thermalization in relativistic heavy ion collisions, the nonequilibrium dynamics of Bose-Einstein condensation, and the generation of structures from quantum fluctuations in the early Universe. Divided into five parts, with each part addressing a particular stage in the conceptual and technical development of the subject, this self-contained book is a valuable reference for graduate students and researchers in particle physics, gravitation, cosmology, atomic-optical and condensed matter physics.

This is the first unified treatment of the properties of thermodynamically open and closed systems. It provides the theory and methodology that are necessary to understand nonlinear processes. The section on Classical Systems covers topics ranging from the evolution of probability to open and closed systems and non-Hamiltonian systems. The concluding section on Quantum Systems is equally detailed, treating the evolution of quantum systems, c-number fluctuations and operator fluctuations.
The material covered is applicable to weather systems, ocean currents, dye lasers and many other nonequilibrium systems. The text is also suitable for students in graduate course. Numerous physical chemical examples facilitate self-study.

Statistics links microscopic and macroscopic phenomena, and requires for this reason a large number of microscopic elements like atoms. The results are values of maximum probability or of averaging. This introduction to statistical physics concentrates on the basic principles and attempts to explain these in simple terms, supplemented by numerous examples. These basic principles include the difference between classical and quantum statistics, a priori probabilities as related to degeneracies, the vital aspect of indistinguishability as compared with distinguishability in classical physics, the differences between conserved and non-conserved elements, the different ways of counting arrangements in the three statistics (Maxwell-Boltzmann, Fermi-Dirac, Bose-Einstein), the difference between maximization of the number of arrangements of elements, and averaging in the Darwin-Fowler method. Significant applications to solids, radiation and electrons in metals are treated in separate chapters, as well as Bose-Einstein condensation. In this latest edition, apart from a general revision, the topic of thermal radiation has been expanded with a new section on black bodies and an additional chapter on black holes. Other additions are more examples with applications of statistical mechanics in solid state physics and superconductivity. Throughout the presentation, the introduction carries almost all details for calculations.

This book is intended as a supplementary text to the standard course books on theoretical physics and astrophysics, addressing applications and selected problems in theoretical physics and astrophysics, most of which are to a greater or lesser extent associated with electrodynamics.

This book includes seminal papers on technical subjects-transport theory, invariant imbedding, and integral equations-presented as contributions to honour George Milt Wing in celebration of his 65th birth anniversary in 1988.

This thesis make significant contributions to both the numerical and analytical aspects of particle physics, reducing the noise associated with matrix calculations in quantum chromodynamics (QCD) and modeling multi-quark mesonic matters that could be used to investigate particles previously unseen in nature. Several methods are developed that can reduce the statistical uncertainty in the extraction of hard-to-detect lattice QCD signals from disconnected diagrams. The most promising technique beats competing methods by 1700 percent, leading to a potential decrease in the computation time of quark loop quantities by an order of magnitude. This not only increases efficiency but also works for QCD matrices with almost-zero eigenvalues, a region where most QCD algorithms break down. This thesis also develops analytical solutions used to investigate exotic particles, specifically the Thomas-Fermi quark model, giving insight into possible new states formed from mesonic matter. The main benefit of this model is that it can work for a large number of quarks which is currently almost impossible with lattice QCD. Patterns of single-quark energies are observed which give the first a priori indication that stable octa-quark and hexadeca-quark versions of the charmed and bottom Z-meson exist.

Physics underlies all complexity, including our own existence: how is this possible? How can our own lives emerge from interactions of electrons, protons, and neutrons? This book considers the interaction of physical and non-physical causation in complex systems such as living beings, and in particular in the human brain, relating this to the emergence of higher levels of complexity with real causal powers. In particular it explores the idea of top-down causation, which is the key effect allowing the emergence of true complexity and also enables the causal efficacy of non-physical entities, including the value of money, social conventions, and ethical choices.

This book presents a new approach to learning the dynamics of particles and rigid bodies at an intermediate to advanced level. There are three distinguishing features of this approach. First, the primary emphasis is to obtain the equations of motion of dynamical systems and to solve them numerically. As a consequence, most of the analytical exercises and homework found in traditional dynamics texts written at this level are replaced by MATLAB (R)-based simulations. Second, extensive use is made of matrices. Matrices are essential to define the important role that constraints have on the behavior of dynamical systems. Matrices are also key elements in many of the software tools that engineers use to solve more complex and practical dynamics problems, such as in the multi-body codes used for analyzing mechanical, aerospace, and biomechanics systems. The third and feature is the use of a combination of Newton-Euler and Lagrangian (analytical mechanics) treatments for solving dynamics problems. Rather than discussing these two treatments separately, Engineering Dynamics 2.0 uses a geometrical approach that ties these two treatments together, leading to a more transparent description of difficult concepts such as "virtual" displacements. Some important highlights of the book include: Extensive discussion of the role of constraints in formulating and solving dynamics problems. Implementation of a highly unified approach to dynamics in a simple context suitable for a second-level course. Descriptions of non-linear phenomena such as parametric resonances and chaotic behavior. A treatment of both dynamic and static stability. Overviews of the numerical methods (ordinary differential equation solvers, Newton-Raphson method) needed to solve dynamics problems. An introduction to the dynamics of deformable bodies and the use of finite difference and finite element methods. Engineering Dynamics 2.0 provides a unique, modern treatment of dynamics problems that is directly useful in advanced engineering applications. It is a valuable resource for undergraduate and graduate students and for practicing engineers.

Probability theory has been extraordinarily successful at describing a variety of phenomena, from the behaviour of gases to the transmission of messages, and is, besides, a powerful tool with applications throughout mathematics. At its heart are a number of concepts familiar in one guise or another to many: Gauss' bell-shaped curve, the law of averages, and so on, concepts that crop up in so many settings they are in some sense universal. This universality is predicted by probability theory to a remarkable degree. This book explains that theory and investigates its ramifications. Assuming a good working knowledge of basic analysis, real and complex, the author maps out a route from basic probability, via random walks, Brownian motion, the law of large numbers and the central limit theorem, to aspects of ergodic theorems, equilibrium and nonequilibrium statistical mechanics, communication over a noisy channel, and random matrices. Numerous examples and exercises enrich the text.

This book is the productof my research at the EndowedChair of Corporate Finance and Capital Markets at the European Business School. Many people devoted their inspiration, time, and knowledge in order to support me with my interdisciplinary research. Thank you all for your support. Especially, I thank my academic supervisor Prof. Ulrich Hommel, Ph.D., who provided me with the freedom to pursue my research interests and who always s- ported me generously. In addition, I am very grateful to my co-supervisor Prof. Dr. Susanne Strahringer (TU Dresden), who graciously accepted the task of refer- ing my book. Also, I thank Prof. Dr. Matthias Krause of the Chair for Theoretical Computer Science in Mannheim for the technical and computer scienti?c support. During my research visits I received generous support from Prof. Yaneer Bar- Yam (NECSI and Harvard) and Prof. John D. Sterman (MIT), who introduced me to the ?eld of System Dynamics and Complex Systems, as well as from Prof. Victor Mossotti (U.S. Geological Survey), Prof. Hiroki Sayama (NECSI and Bingh- ton), Prof. Markus de Aguiar (Universidade Estadual de Campinas), Prof. Michel Baranger (MIT), Prof. Jay W. Forrester (MIT), and Prof. Brian D. Josephson (Cambridge). Thank you very much for numerous inspiring discussions.

Humans engage in a seemingly endless variety of different behaviors, of which some are found across species, while others are conceived of as typically human. Most generally, behavior comes about through the interplay of various constraints - informational, mechanical, neural, metabolic, and so on - operating at multiple scales in space and time. Over the years, consensus has grown in the research community that, rather than investigating behavior only from bottom up, it may be also well understood in terms of concepts and laws on the phenomenological level. Such top down approach is rooted in theories of synergetics and self-organization using tools from nonlinear dynamics. The present compendium brings together scientists from all over the world that have contributed to the development of their respective fields departing from this background. It provides an introduction to deterministic as well as stochastic dynamical systems and contains applications to motor control and coordination, visual perception and illusion, as well as auditory perception in the context of speech and music.

This is a masters/graduate level textbook on statistical physics. The basics of the discipline and its application in the current topics of interest like BoseEinstein condensate, statistical astrophysics and phase transitions have been discussed with thoroughness.

This is a systematic introduction and development of a course material tried successful over a number of years. Feedback from the students tells that it has immensely helped them in their later research.

This textbook provides an exposition of equilibrium thermodynamics and its applications to several areas of physics with particular attention to phase transitions and critical phenomena. The applications include several areas of condensed matter physics and include also a chapter on thermochemistry. Phase transitions and critical phenomena are treated according to the modern development of the field, based on the ideas of universality and on the Widom scaling theory. For each topic, a mean-field or Landau theory is presented to describe qualitatively the phase transitions. These theories include the van der Waals theory of the liquid-vapor transition, the Hildebrand-Heitler theory of regular mixtures, the Griffiths-Landau theory for multicritical points in multicomponent systems, the Bragg-Williams theory of order-disorder in alloys, the Weiss theory of ferromagnetism, the Neel theory of antiferromagnetism, the Devonshire theory for ferroelectrics and Landau-de Gennes theory of liquid crystals. This new edition presents expanded sections on phase transitions, liquid crystals and magnetic systems, for all problems detailed solutions are provided. It is intended for students in physics and chemistry and provides a unique combination of thorough theoretical explanation and presentation of applications in both areas. Chapter summaries, highlighted essentials and problems with solutions enable a self sustained approach and deepen the knowledge. It is intended for students in physics and chemistry and provides a unique combination of thorough theoretical explanation and presentation of applications in both areas. Chapter summaries, highlighted essentials and problems with solutions enable a self sustained approach and deepen the knowledge.

The European Conference on Complex Systems, held under the patronage of the Complex Systems Society, is an annual event that has become the leading European conference devoted to complexity science. ECCS'12, its ninth edition, took place in Brussels, during the first week of September 2012. It gathered about 650 scholars representing a wide range of topics relating to complex systems research, with emphasis on interdisciplinary approaches. More specifically, the following tracks were covered:

1. Foundations of Complex Systems

2. Complexity, Information and Computation

3. Prediction, Policy and Planning, Environment

4. Biological Complexity

5. Interacting Populations, Collective Behavior

6. Social Systems, Economics and Finance

This book contains a selection of the contributions presented at the conference and its satellite meetings. Its contents reflect the extent, diversity and richness of research areas in the field, both fundamental and applied.

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The science of statistical mechanics is concerned with defining the thermodynamic properties of a macroscopic sample in terms of the properties of the microscopic systems of which it is composed. The aim of this book is to provide a clear, logical, and self-contained treatment of equilibrium statistical mechanics starting from Boltzmann's two statistical assumptions, and to present a wide variety of applications to diverse physical assemblies. The coverage is enhanced and extended through an extensive set of accessible problems. An appendix provides an introduction to non-equilibrium statistical mechanics through the Boltzmann equation and its extensions. The book assumes introductory courses in classical and quantum mechanics, as well as familiarity with multi-variable calculus and the essentials of complex analysis. Some knowledge of thermodynamics is assumed, although the book starts with an appropriate review of that topic. The targeted audience is first-year graduate students, and advanced undergraduates, in physics, chemistry, and the related physical sciences. The goal of this text is to help the reader obtain a clear working knowledge of the very useful and powerful methods of equilibrium statistical mechanics and to enhance the understanding and appreciation of the more advanced texts.

Complex Nonlinearity: Chaos, Phase Transitions, Topology Change and Path Integrals is a book about prediction & control of general nonlinear and chaotic dynamics of high-dimensional complex systems of various physical and non-physical nature and their underpinning geometro-topological change.

The book starts with a textbook-like expose on nonlinear dynamics, attractors and chaos, both temporal and spatio-temporal, including modern techniques of chaos-control. Chapter 2 turns to the edge of chaos, in the form of phase transitions (equilibrium and non-equilibrium, oscillatory, fractal and noise-induced), as well as the related field of synergetics. While the natural stage for linear dynamics comprises of flat, Euclidean geometry (with the corresponding calculation tools from linear algebra and analysis), the natural stage for nonlinear dynamics is curved, Riemannian geometry (with the corresponding tools from nonlinear, tensor algebra and analysis). The extreme nonlinearity - chaos - corresponds to the topology change of this curved geometrical stage, usually called configuration manifold. Chapter 3 elaborates on geometry and topology change in relation with complex nonlinearity and chaos. Chapter 4 develops general nonlinear dynamics, continuous and discrete, deterministic and stochastic, in the unique form of path integrals and their action-amplitude formalism. This most natural framework for representing both phase transitions and topology change starts with Feynman's sum over histories, to be quickly generalized into the sum over geometries and topologies. The last Chapter puts all the previously developed techniques together and presents the unified form of complex nonlinearity. Here we have chaos, phase transitions, geometrical dynamics and topology change, all working together in the form of path integrals.

The objective of this book is to provide a serious reader with a serious scientific tool that will enable them to actually perform a competitive research in modern complex nonlinearity. It includes a comprehensive bibliography on the subject and a detailed index. Target readership includes all researchers and students of complex nonlinear systems (in physics, mathematics, engineering, chemistry, biology, psychology, sociology, economics, medicine, etc.), working both in industry/clinics and academia.

From the basics of thermodynamics to solutions for modern dynamical problems —the complete beginner's guide to statistical mechanics.

Unlike most books on statistical mechanics, this one is written for advanced students in chemistry, chemical engineering, biophysics, and related fields. It targets readers with no prior exposure to statistical mechanics and provides a complete introduction to all the important principles, concepts, and equations, while maintaining a level of mathematical sophistication that most advanced chemistry students will find manageable. The emphasis is on finding solutions to common problems in chemistry. Topics covered include:

• The Maxwell-Boltzmann velocity distribution for molecules in a gas, partition functions, and calculation of thermodynamic properties
• Ensembles (including the grand canonical ensemble), independent particles, and thermodynamic properties of atoms and molecules
• Practical introductions to quantum statistical mechanics and classical statistical mechanics
• Applications to electrons in metals and semiconductors; bosons and fermions; imperfect gases; transport properties; dipole moments in electric and magnetic fields; and distribution functions and correlation functions in fluids
• Time-dependent techniques for handling both simple and modern dynamical problems —the Liouville equation, time-correlation functions, and the Langevin equation.

Clearly written, and with a minimum of theory, Statistical Mechanics for Chemists takes you step by step through mathematical manipulations and explains the physical and chemical bases for each procedure. It is a valuable resource for advanced students in chemistry, chemical engineering, biophysics, and related fields.