From the basics of thermodynamics to solutions for modern dynamical problems —the complete beginner's guide to statistical mechanics.

Unlike most books on statistical mechanics, this one is written for advanced students in chemistry, chemical engineering, biophysics, and related fields. It targets readers with no prior exposure to statistical mechanics and provides a complete introduction to all the important principles, concepts, and equations, while maintaining a level of mathematical sophistication that most advanced chemistry students will find manageable. The emphasis is on finding solutions to common problems in chemistry. Topics covered include:

• The Maxwell-Boltzmann velocity distribution for molecules in a gas, partition functions, and calculation of thermodynamic properties
• Ensembles (including the grand canonical ensemble), independent particles, and thermodynamic properties of atoms and molecules
• Practical introductions to quantum statistical mechanics and classical statistical mechanics
• Applications to electrons in metals and semiconductors; bosons and fermions; imperfect gases; transport properties; dipole moments in electric and magnetic fields; and distribution functions and correlation functions in fluids
• Time-dependent techniques for handling both simple and modern dynamical problems —the Liouville equation, time-correlation functions, and the Langevin equation.

Clearly written, and with a minimum of theory, Statistical Mechanics for Chemists takes you step by step through mathematical manipulations and explains the physical and chemical bases for each procedure. It is a valuable resource for advanced students in chemistry, chemical engineering, biophysics, and related fields.

This text provides an overview of important theory, principles, and concepts in the field of thermodynamics, making this abstract and complex subject easy to comprehend while building practical skills in the process. It enhances understanding of heat transfer, steam tables, energy concepts, power generation, psychrometry, refrigeration cycles, and more. Practical, easily accessible case studies illustrate various thermodynamics principles. Each chapter concludes with a list of questions or problems, with answers at the back of the book.

The science of statistical mechanics is concerned with defining the thermodynamic properties of a macroscopic sample in terms of the properties of the microscopic systems of which it is composed. The aim of this book is to provide a clear, logical, and self-contained treatment of equilibrium statistical mechanics starting from Boltzmann's two statistical assumptions, and to present a wide variety of applications to diverse physical assemblies. The coverage is enhanced and extended through an extensive set of accessible problems. An appendix provides an introduction to non-equilibrium statistical mechanics through the Boltzmann equation and its extensions. The book assumes introductory courses in classical and quantum mechanics, as well as familiarity with multi-variable calculus and the essentials of complex analysis. Some knowledge of thermodynamics is assumed, although the book starts with an appropriate review of that topic. The targeted audience is first-year graduate students, and advanced undergraduates, in physics, chemistry, and the related physical sciences. The goal of this text is to help the reader obtain a clear working knowledge of the very useful and powerful methods of equilibrium statistical mechanics and to enhance the understanding and appreciation of the more advanced texts.

In this new textbook, a number of unusual applications are discussed in addition to the usual topics covered in a course on Statistical Physics. Examples are: statistical mechanics of powders, Peierls instability, graphene, Bose-Einstein condensates in a trap, Casimir effect and the quantum Hall effect. Superfluidity and super-conductivity (including the physics of high-temperature superconductors) have also been discussed extensively.The emphasis on the treatment of these topics is pedagogic, introducing the basic tenets of statistical mechanics, with extensive and thorough discussion of the postulates, ensembles, and the relevant statistics. Many standard examples illustrate the microcanonical, canonical and grand canonical ensembles, as well as the Bose-Einstein and Fermi-Dirac statistics.A special feature of this text is the detailed presentation of the theory of second-order phase transitions and the renormalization group, emphasizing the role of disorder. Non-equilibrium statistical physics is introduced via the Boltzmann transport equation. Additional topics covered here include metastability, glassy systems, the Langevin equation, Brownian motion, and the Fokker-Planck equation.Graduate students will find the presentation readily accessible, since the topics have been treated with great deal of care and attention to detail.

This open access book offers a concise overview of how data from large scale experiments are analyzed and how technological tools are used in practice, as in the search for new elementary particles. It focuses on interconnects between physics and detector technology in experimental particle physics, and includes descriptions of mathematical approaches. Readers find all the important steps in analysis, including reconstruction of the momentum and energy of particles from detector information, particle identification, and also the general concept of simulating particle production from collisions and detector responses. As the scale of scientific experiments becomes larger and data-intensive science emerges, the techniques used in the data analysis become ever more complicated, making it difficult for beginners to grasp the overall picture. The book provides an explanation of the idea and concepts behind the methods, helping readers understand journal articles on high energy physics. This book is engaging as it does not overemphasize mathematical formalism and it gives a lively example of how such methods have been applied to the Higgs particle discovery in the Large Hadron Collider (LHC) experiments, which led to Englert and Higgs being awarded the Nobel Prize in Physics for 2013. Graduate students and young researchers can easily obtain the required knowledge on how to start data analyses from these notes, without having to spend time in consulting many experts or digesting huge amounts of literature.

This book offers a didactic and a self-contained treatment of the physics of liquid and flowing matter with a statistical mechanics approach. Experimental and theoretical methods that were developed to study fluids are now frequently applied to a number of more complex systems generically referred to as soft matter. As for simple liquids, also for complex fluids it is important to understand how their macroscopic behavior is determined by the interactions between the component units. Moreover, in recent years new and relevant insights have emerged from the study of anomalous phases and metastable states of matter. In addition to the traditional topics concerning fluids in normal conditions, the authors of this book discuss recent developments in the field of disordered systems in condensed and soft matter. In particular they emphasize computer simulation techniques that are used in the study of soft matter and the theories and study of slow glassy dynamics. For these reasons the book includes a specific chapter about metastability, supercooled liquids and glass transition. The book is written for graduate students and active researchers in the field.

Simulating for a crisis is far more than creating a simulation of a crisis situation. In order for a simulation to be useful during a crisis, it should be created within the space of a few days to allow decision makers to use it as quickly as possible. Furthermore, during a crisis the aim is not to optimize just one factor, but to balance various, interdependent aspects of life. In the COVID-19 crisis, decisions had to be made concerning e.g. whether to close schools and restaurants, and the (economic) consequences of a 3 or 4-week lock-down had to be considered. As such, rather than one simulation focusing on a very limited aspect, a framework allowing the simulation of several different scenarios focusing on different aspects of the crisis was required. Moreover, the results of the simulations needed to be easily understandable and explainable: if a simulation indicates that closing schools has no effect, this can only be used if the decision makers can explain why this is the case. This book describes how a simulation framework was created for the COVID-19 crisis, and demonstrates how it was used to simulate a wide range of scenarios that were relevant for decision makers at the time. It also discusses the usefulness of the approach, and explains the decisions that had to be made along the way as well as the trade-offs. Lastly, the book examines the lessons learned and the directions for the further development of social simulation frameworks to make them better suited to crisis situations, and to foster a more resilient society.

This monograph is a comprehensive and cohesive exposition of power-law statistics. Following a bottom-up construction from a foundational bedrock - the power Poisson process - this monograph presents a unified study of an assortment of power-law statistics including: Pareto laws, Zipf laws, Weibull and Frechet laws, power Lorenz curves, Levy laws, power Newcomb-Benford laws, sub-diffusion and super-diffusion, and 1/f and flicker noises. The bedrock power Poisson process, as well as the assortment of power-law statistics, are investigated via diverse perspectives: structural, stochastic, fractal, dynamical, and socioeconomic. This monograph is poised to serve researchers and practitioners - from various fields of science and engineering - that are engaged in analyses of power-law statistics.

This book presents sensemaking strategies to support security planning and design. Threats to security are becoming complex and multifaceted and increasingly challenging traditional notions of security. The security landscape is characterized as 'messes' and 'wicked problems' that proliferate in this age of complexity. Designing security solutions in the face of interconnectedness, volatility and uncertainty, we run the risk of providing the right answer to the wrong problem thereby resulting in unintended consequences. Sensemaking is the activity that enables us to turn the ongoing complexity of the world into a "situation that is comprehended explicitly in words and that serves as a springboard into action" (Weick, Sutcliffe, Obstfeld, 2005). It is about creating an emerging picture of our world through data collection, analysis, action, and reflection. The importance of sensemaking to security is that it enables us to plan, design and act when the world as we knew it seems to have shifted. Leveraging the relevant theoretical grounding and thought leadership in sensemaking, key examples are provided, thereby illustrating how sensemaking strategies can support security planning and design. This is a critical analytical and leadership requirement in this age of volatility, uncertainty, complexity and ambiguity that characterizes the security landscape. This book is useful for academics, graduate students in global security, and government and security planning practitioners.

The focus of this thesis is the interplay of synchrony and adaptivity in complex networks. Synchronization is a ubiquitous phenomenon observed in different contexts in physics, chemistry, biology, neuroscience, medicine, socioeconomic systems, and engineering. Most prominently, synchronization takes place in the brain, where it is associated with cognitive capacities like learning and memory, but is also a characteristic of neurological diseases like Parkinson and epilepsy. Adaptivity is common in many networks in nature and technology, where the connectivity changes in time, i.e., the strength of the coupling is continuously adjusted depending upon the dynamic state of the system, for instance synaptic neuronal plasticity in the brain. This research contributes to a fundamental understanding of various synchronization patterns, including hierarchical multifrequency clusters, chimeras and other partial synchronization states. After a concise survey of the fundamentals of adaptive and complex dynamical networks and synaptic plasticity, in the first part of the thesis the existence and stability of cluster synchronization in globally coupled adaptive networks is discussed for simple paradigmatic phase oscillators as well as for a more realistic neuronal oscillator model with spike-timing dependent plasticity. In the second part of the thesis the interplay of adaptivity and connectivity is investigated for more complex network structures like nonlocally coupled rings, random networks, and multilayer systems. Besides presenting a plethora of novel, sometimes intriguing patterns of synchrony, the thesis makes a number of pioneering methodological advances, where rigorous mathematical proofs are given in the Appendices. These results are of interest not only from a fundamental point of view, but also with respect to challenging applications in neuroscience and technological systems.

Modern structural applications of crystallography make extensive use of statistical methods, in particular the probability density function (pdf) of the magnitude of the structure factor. Similarly, direct methods of phase determination have been responsible for much of the success of crystallography - methods based on properties of joint pdfs. This monograph, from two authorities in the field of structure factor statics, presents a survey of techniques and theories in this field of research in a self-contained and consistent way, with an emphasis on the probabilistic principles involved.

This book describes fundamental physical principles, together with their mathematical formulations, for modelling the propagation of signals in nerve fibres. Above all, it focuses on the complex electro-mechano-thermal process that produces an ensemble of waves composed of several components, besides the action potential. These components include mechanical waves in the biomembrane and axoplasm, together with the temperature change. Pursuing a step-by-step approach, the content moves from physics and mathematics, to describing the physiological effects, and finally to modelling the coupling effects. The assumptions and hypotheses used for modelling, as well as selected helpful concepts from continuum mechanics, are systematically explained, and the modelling is illustrated using the outcomes of numerical simulation. The book is chiefly intended for researchers and graduate students, providing them with a detailed description of how to model the complex physiological processes in nerve fibres.

This book presents a careful selection of the most important developments of the \phi^4 model, offering a judicious summary of this model with a view to future prospects and the challenges ahead. Over the past four decades, the \phi^4 model has been the basis for a broad array of developments in the physics and mathematics of nonlinear waves. From kinks to breathers, from continuum media to discrete lattices, from collisions of solitary waves to spectral properties, and from deterministic to stochastic models of \phi^4 (and \phi^6, \phi^8, \phi^12 variants more recently), this dynamical model has served as an excellent test bed for formulating and testing the ideas of nonlinear science and solitary waves.

This book is useful to engineers, researchers, entrepreneurs, and students in different branches of production, engineering, and systems sciences. The polytopic roadmaps are the guidelines inspired by the development stages of cognitive-intelligent systems, and expected to become powerful instruments releasing an abundance of new capabilities and structures for complex engineering systems implementation. The 4D approach developed in previous monographs and correlated with industry 4.0and Fourth Industrial Revolution is continued here toward higher dimensions approaches correlated with polytopic operations, equipment, technologies, industries, and societies. Methodology emphasizes the role of doubling, iteration, dimensionality, and cyclicality around the center, of periodic tables and of conservative and exploratory strategies. Partitions, permutations, classifications, and complexification, as polytopic chemistry, are the elementary operations analyzed. Multi-scale transfer, cyclic operations, conveyors, and assembly lines are the practical examples of operations and equipment. Polytopic flow sheets, online analytical processing, polytopic engineering designs, and reality-inspired engineering are presented. Innovative concepts such as Industry 5.0, polytopic industry, Society 5.0, polytopic society, cyber physical social systems, industrial Internet, and digital twins have been discussed. The general polytopic roadmaps, (GPTR), are proposed as universal guidelines and as common methodologies to synthesize the systemic thinking and capabilities for growing complexity projects implementation.

The aim of this book is to provide the fundamentals of statistical physics and its application to condensed matter. The combination of statistical mechanics and quantum mechanics has provided an understanding of properties of matter leading to spectacular technological innovations and discoveries in condensed matter which have radically changed our daily life.The book gives the steps to follow to understand fundamental theories and to apply these to real materials.

Instantons, or pseudoparticles, are solutions to the equations of motion in classical field theories on a Euclidean spacetime. Instantons are found everywhere in quantum theories as they have many applications in quantum tunnelling. Diverse physical phenomena may be described through quantum tunnelling, for example: the Josephson effect, the decay of meta-stable nuclear states, band formation in tight binding models of crystalline solids, the structure of the gauge theory vacuum, confinement in 2+1 dimensions, and the decay of superheated or supercooled phases. Drawing inspiration from Sidney Coleman's Erice lectures, this volume provides an accessible, detailed introduction to instanton methods, with many applications, making it a valuable resource for graduate students in many areas of physics, from condensed matter, particle and nuclear physics, to string theory. This title, first published in 2017, has been reissued as an Open Access publication on Cambridge Core.

Predicting thermodynamic quantities for chemically realistic systems on the basis of atomistic calculations is still, even today, a nontrivial task. Nonetheless, accurate treatment of inter-particle interactions, in terms of quantum chemical first principles methods, is a prerequisite for many applications, because of the complexity of both reactants and solvents in modern molecular sciences. Currently, a straightforward calculation of thermodynamic properties from these methods is only possible for high-temperature and low- density systems. Although the enthalpy of a system can often be predicted to a good level of precision with this ideal gas approach, calculating the entropy contribution to the free energy is problematic, especially as the density of the system increases. This thesis contains a compact and coherent introduction of basic theoretical features. The foundations are then laid for the development of approaches suitable for calculation of condensed phase entropies on the basis of well-established quantum chemical methods. The main emphasis of this work is on realistic systems in solution, which is the most important environment for chemical synthesis. The presented results demonstrate how isolated molecular concepts typically employed in modern quantum chemistry can be extended for the accurate determination of thermodynamic properties by means of scale- transferring approaches.

This book presents the state of the art in social simulation as presented at the Social Simulation Conference 2019 in Mainz, Germany. It covers the developments in applications and methods of social simulation, addressing societal issues such as socio-ecological systems and policymaking. Methodological issues discussed include large-scale empirical calibration, model sharing and interdisciplinary research, as well as decision-making models, validation and the use of qualitative data in simulation modeling. Research areas covered include archaeology, cognitive science, economics, organization science and social simulation education. This book gives readers insight into the increasing use of social simulation in both its theoretical development and in practical applications such as policymaking whereby modeling and the behavior of complex systems is key. The book appeals to students, researchers and professionals in the various fields.

Based on courses given at the universities of Texas and California, this book treats an active field of research that touches upon the foundations of physics and chemistry. It presents, in as simple a manner as possible, the basic mechanisms that determine the dynamical evolution of both classical and quantum systems in sufficient generality to include quantum phenomena. The book begins with a discussion of Noether's theorem, integrability, KAM theory, and a definition of chaotic behavior; continues with a detailed discussion of area-preserving maps, integrable quantum systems, spectral properties, path integrals, and periodically driven systems; and concludes by showing how to apply the ideas to stochastic systems. The presentation is complete and self-contained; appendices provide much of the needed mathematical background, and there are extensive references to the current literature; while problems at the ends of chapters help students clarify their understanding. This new edition has an updated presentation throughout, and a new chapter on open quantum systems.

This book shows how neural networks are applied to computational mechanics. Part I presents the fundamentals of neural networks and other machine learning method in computational mechanics. Part II highlights the applications of neural networks to a variety of problems of computational mechanics. The final chapter gives perspectives to the applications of the deep learning to computational mechanics.

This book deals with certain important problems in Classical and Quantum Information Theory Quantum Information Theory, A Selection of Matrix Inequalities Stochastic Filtering Theory Applied to Electromagnetic Fields and Strings Wigner-distributions in Quantum Mechanics Quantization of Classical Field Theories Statistical Signal Processing Quantum Field Theory, Quantum Statistics, Gravity, Stochastic Fields and Information Problems in Information Theory It will be very helpful for students of Undergraduate and Postgraduate Courses in Electronics, Communication and Signal Processing. Print edition not for sale in South Asia (India, Sri Lanka, Nepal, Bangladesh, Pakistan or Bhutan).

Statistical Physics (SP) has followed an unusual evolutionary path in science. Originally aiming to provide a fundamental basis for another important branch of Physics, namely Thermodynamics, SP gradually became an independent field of research in its own right. But despite more than a century of steady progress, there are still plenty of challenges and open questions in the SP realm.In fact, the area is still rapidly evolving, in contrast to other branches of science, which already have well defined scopes and borderlines of applicability. This difference is due to the steadily expanding number of applications, as well as ongoing improvements and revisions of concepts and methods in SP. Such particular aspects of SP lend further significance and timeliness to this book about perspectives and trends within the field.Here, the aim is to present the state-of-the-art vision of expert researchers who study SP and Complex Systems. Although a comprehensive treatment is well beyond what can be treated in a single volume, the book provides a snapshot of the field today, as well as a glimpse of where the field may be heading during the next decade.The book is aimed at graduate and advanced undergraduate physics students, as well as researchers who work with SP, Complex Systems, Computational Physics, Biological Physics and related topics. It addresses questions such as: What insights can be gained from recent advances in the study of traditional problems in SP? How can SP help us understand problems that arise in the biological sciences and in the study of complex systems? How can new problems be formulated using the 'language' of SP? In this way, it attempts to document partial progress in answering these and related questions.The book also commemorates the occasion of the 70th anniversary in 2011 of two important physicists and friends who dedicated their lives to the understanding of nature in general and to the development of Statistical Physics and the science of Complexity in particular: Liacir Lucena and H Eugene Stanley.

This book contains contributions presented at the 12th International Conference on Complex Networks (CompleNet), 24-26 May 2021. CompleNet is an international conference on complex networks that brings together researchers and practitioners from diverse disciplines-from sociology, biology, physics, and computer science-who share a passion to better understand the interdependencies within and across systems. CompleNet is a venue to discuss ideas and findings about all types networks, from biological, to technological, to informational and social. It is this interdisciplinary nature of complex networks that CompleNet aims to explore and celebrate.

This book is the fifth volume of papers on advanced problems of phase transitions and critical phenomena, the first four volumes appeared in 2004, 2007, 2012, and 2015. It aims to compile reviews in those aspects of criticality and related subjects that are of current interest. The seven chapters discuss criticality of complex systems, where the new, emergent properties appear via collective behaviour of simple elements. Since all complex systems involve cooperative behaviour between many interconnected components, the field of phase transitions and critical phenomena provides a very natural conceptual and methodological framework for their study.As the first four volumes, this book is based on the review lectures that were given in Lviv (Ukraine) at the 'Ising lectures' - a traditional annual workshop on phase transitions and critical phenomena which aims to bring together scientists working in the field of phase transitions with university students and those who are interested in the subject.

Philosophy in Reality offers a new vision of the relation between science and philosophy in the framework of a non-propositional logic of real processes, grounded in the physics of the real world. This logical system is based on the work of the Franco-Romanian thinker Stephane Lupasco (1900-1988), previously presented by Joseph Brenner in the book Logic in Reality (Springer, 2008). The present book was inspired in part by the ancient Chinese Book of Changes (I Ching) and its scientific-philosophical discussion of change. The emphasis in Philosophy in Reality is on the recovery of dialectics and semantics from reductionist applications and their incorporation into a new synthetic paradigm for knowledge. Through an original re-interpretation of both classical and modern Western thought, this book addresses philosophical issues in scientific fields as well as long-standing conceptual problems such as the origin, nature and role of meaning, the unity of knowledge and the origin of morality. In a rigorous transdisciplinary manner, it discusses foundational and current issues in the physical sciences - mathematics, information, communication and systems theory and their implications for philosophy. The same framework is applied to problems of the origins of society, the transformation of reality by human subjects, and the emergence of a global, sustainable information society. In summary, Philosophy in Reality provides a wealth of new perspectives and references, supporting research by both philosophers and physical and social scientists concerned with the many facets of reality.