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Books > Professional & Technical > Industrial chemistry & manufacturing technologies > Industrial chemistry
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Organotrifluoroborate Preparation, Coupling and Hydrolysis (Hardcover, 2013 ed.)
Loot Price: R3,520
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Organotrifluoroborate Preparation, Coupling and Hydrolysis (Hardcover, 2013 ed.)
Series: Springer Theses
Expected to ship within 12 - 17 working days
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Total price: R3,540
Discovery Miles: 35 400
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Alistair Lennox's thesis reports on the reactivity of
organotrifluoroborates, which are becoming increasingly important
reagents in synthesis. The thesis is divided into three sections.
The first section describes a method for preparing
organotrifluoroborates. The second section reports on a mechanistic
investigation into the main application of RBF3K reagents as
coupling partners in Suzuki-Miyaura coupling, phenomena identified
as arising from organotrifluoroborate hydrolysis and fluoride
release. The final section reports on a detailed investigation into
the hydrolysis mechanism, a prerequisite for their Suzuki-Miyaura
coupling, and how it may be predicted and controlled. This research
has uncovered many interesting and useful details and shows how
problems associated with Suzuki-Miyaura coupling can best be
addressed. There has already been wide industrial uptake of the new
procedures and insights. The broad nature and clear and succinct
style will make the thesis a valuable resource for anyone working
in synthesis, organometallic chemistry, or in homogeneous
catalysis.
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