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Adsorption on Mesoporous Metal-Organic Frameworks in Solution for Clean Energy, Environment and Healthcare (Paperback)
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Adsorption on Mesoporous Metal-Organic Frameworks in Solution for Clean Energy, Environment and Healthcare (Paperback)
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Adsorption and desorption in solution play significant roles in
separations, detoxification of waste streams, in purification,
chromatography, heterogeneous catalysis, metabolism of medicinal
drugs, and beyond. Metal-Organic Frameworks (MOFs) are well-ordered
3-dimensional hybrid organic-inorganic polymers which contain metal
cations and the structure-building organic "linker" units.
Mesoporous MOFs with pore sizes 2-50 nm are particularly suitable
for adsorption and adsorption-based separations of large molecules
of organic and bio-organic compounds. Thousands of organic
compounds and, in particular, aromatic and heterocyclic compounds
are widely used as feedstock for industrial chemical synthesis, as
fine chemicals, major components of liquid fossil fuels, dyestuffs,
industrial solvents, agricultural chemicals, medicinal drugs,
pharmaceuticals and personal care products (PPCPs), and active
pharmaceutical ingredients (APIs). There is a strong interest
towards synthesis, characterization and studies of both known and
newly synthesized mesoporous MOFs for adsorption in solution to
achieve the high adsorption capacity, selectivity, and the
possibility of multiple regeneration of "spent" sorbent. This book
covers experimental fundamental research on using mesoporous MOFs
in emerging applications of major industrial, environmental and
academic importance, especially purification of water and liquid
fossil fuels and in advanced biomedical technologies.
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