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A First Example of a Lyotropic Smectic C* Analog Phase - Design, Properties and Chirality Effects (Hardcover, 1st ed. 2016)
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A First Example of a Lyotropic Smectic C* Analog Phase - Design, Properties and Chirality Effects (Hardcover, 1st ed. 2016)
Series: Springer Theses
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In this thesis Johanna Bruckner reports the discovery of the
lyotropic counterpart of the thermotropic SmC* phase, which has
become famous as the only spontaneously polarized, ferroelectric
fluid in nature. By means of polarizing optical microscopy, X-ray
diffraction and electro-optic experiments she firmly establishes
aspects of the structure of the novel lyotropic liquid crystalline
phase and elucidates its fascinating properties, among them a
pronounced polar electro-optic effect, analogous to the
ferroelectric switching of its thermotropic counterpart. The
helical ground state of the mesophase raises the fundamental
question of how chiral interactions are "communicated" across
layers of more or less disordered and achiral solvent molecules
which are located between adjacent bi-layers of the chiral
amphiphile molecules. This thesis bridges an important gap between
thermotropic and lyotropic liquid crystals and pioneers a new field
of liquid crystal research.
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