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Metal-Oxygen Clusters - The Surface and Catalytic Properties of Heteropoly Oxometalates (Paperback, Softcover reprint of the original 1st ed. 2001)
Loot Price: R4,238
Discovery Miles 42 380
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Metal-Oxygen Clusters - The Surface and Catalytic Properties of Heteropoly Oxometalates (Paperback, Softcover reprint of the original 1st ed. 2001)
Series: Fundamental and Applied Catalysis
Expected to ship within 10 - 15 working days
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Metal-Oxygen Clusters is the first book, providing an overview of
the surface chemistry and catalytic properties of heteropoly
oxometalates. After a brief look at the early knowledge of
heteropoly oxometalates, the book discusses the synthesis,
characterization, structure, bulk properties and stability of these
materials. The remainder and the largest portion of the book
explores the properties of these solids as catalysts in
acid-catalyzed and oxidation processes in supported or unsupported
forms. The book provides an up-to-date review of the methods for
synthesizing heteropoly oxometalates of Keggin structure,
techniques from spectroscopic through electrochemical to elemental
analysis for their characterization and the current information on
their structure, bulk properties and their stabilities at high
temperatures and under acid and alkaline conditions. The book
discusses the materials employed as supports for the title solid
and the results of the examination of the supported materials.
Methods for the identification of the nature and source of the two
catalytic functions, the acidic and oxidative properties, of the
heteropoly oxometalates are reviewed and discussed. The use of both
the supported and unsupported heteropoly oxometalates as catalysts
in acidity-requisite processes ranging from methanol conversion to
hydrocarbons to ring-expansion and contraction processes and in
oxidation processes from methane cyclohexane are described and
related to the aforementioned properties.
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