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Energetics of Organometallic Species (Paperback, Softcover reprint of the original 1st ed. 1992)
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Energetics of Organometallic Species (Paperback, Softcover reprint of the original 1st ed. 1992)
Series: NATO Science Series C, 367
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An overview of modern organometallic thermochemistry, made by some
of the most active scientists in the area, is offered in this book.
The contents correspond to the seventeen lectures delivered at the
NATO ASI Energetics of Organometallic Species (Curia, Portugal,
September 1991), plus three other invited contributions from
participants of that summer school. These papers reflect a variety
of research interests, and discuss results obtained with several
techniques. It is therefore considered appropriate to add a few
preliminary words, attempting to bring some unity out of that
diversity. In the first three chapters, results obtained by
classical calorimetric methods are described. Modern organometallic
thermochemistry started in Manchester, with Henry Skinner, and his
pioneering work is briefly surveyed in the first chapter. The
historical perspective is followed by a discussion of a very actual
issue: the trends of stepwise bond dissociation enthalpies. Geoff
Pilcher, another Manchester thermochemist, makes, in chapter 2, a
comprehensive and authoritative survey of problems found in the
most classical of thermochemical techniques - combustion
calorimetr- applied to organometallic compounds. Finally, results
from another classical technique, reaction-solution calorimetry,
are reviewed in the third chapter, by Tobin Marks and coworkers.
More than anybody else, Tobin Marks has used thermochemical values
to define synthetic strategies for organometallic compounds, thus
indicating an application of thermochemical data of which too
little use has been made so far.
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