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Highly Luminescent Lanthanide Complexes with Specific Coordination Structures (Hardcover, 2014 ed.)
Loot Price: R2,765
Discovery Miles 27 650
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Highly Luminescent Lanthanide Complexes with Specific Coordination Structures (Hardcover, 2014 ed.)
Series: Springer Theses
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This thesis deals with strongly luminescent lanthanide complexes
having novel coordination structures. Luminescent lanthanide
complexes are promising candidates as active materials for EL
devices, lasers, and bio-sensing applications. The organic ligands
in lanthanide complexes control geometrical and vibrational
frequency structures that are closely related to the luminescent
properties. In most of the previous work, however, lanthanide
complexes have high-vibrational frequency C-H units close to the
metal center for radiationless transition. In this thesis, the
luminescent properties of lanthanide complexes with low-vibrational
frequency C-F and P=O units are elucidated in terms of geometrical,
vibrational, and chemical structures. The author also describes
lanthanide coordination polymers with both high thermal stability
(decomposition point > 300 DegreesC) and strong-luminescent
properties (emission quantum yield > 80%). The author believes
that novel studies on the characteristic structures and
photophysical properties of lanthanide complexes may open up a
frontier field in photophysical, coordination and material
chemistry.
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