MWW-Type Titanosilicate - Synthesis, Structural Modification and Catalytic Applications to Green Oxidations (Paperback, 2013 ed.)

This book provides a comprehensive review of a new generation of selective oxidation titanosilicate catalysts with the MWW topology (Ti-MWW) based on the research achievements of the past 12 years. It gives an overview of the synthesis, structure modification and catalytic properties of Ti-MWW. Ti-MWW can readily be prepared by means of direct hydrothermal synthesis with crystallization-supporting agents, using dual-structure-directing agents and a dry-gel conversion technique. It also can be post-synthesized through unique reversible structure transformation and liquid-phase isomorphous substitution. The structural conversion of Ti-MWW into the materials usable for processing large molecules is summarized. Taking advantage of the structure diversity of the lamellar precursor of Ti-MWW, it can be fully or partially delaminated, and undergo interlayer silylation to obtain a novel structure with larger porosity. In the selective oxidation (alkene epoxidation and ketone/aldehyde ammoximation) with hydrogen peroxide or organic peroxide as an oxidant, the unique catalytic properties of Ti-MWW are described in comparison to conventional titanosilicates such as TS-1 and Ti-Beta.

General

Imprint:	Springer-Verlag
Country of origin:	Germany
Series:	SpringerBriefs in Green Chemistry for Sustainability
Release date:	August 2013
First published:	2013
Authors:	Peng Wu • Hao Xu • Le Xu • Yueming Liu • Mingyuan He
Dimensions:	235 x 155 x 8mm (L x W x T)
Format:	Paperback
Pages:	125
Edition:	2013 ed.
ISBN-13:	978-3-642-39114-9
Categories:	Books > Science & Mathematics > Chemistry > Physical chemistry > Catalysis Books > Earth & environment > The environment > Pollution & threats to the environment > General Books > Professional & Technical > Industrial chemistry & manufacturing technologies > Industrial chemistry > General
LSN:	3-642-39114-1
Barcode:	9783642391149

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