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Electrified Interfaces in Physics, Chemistry and Biology (Paperback, Softcover reprint of the original 1st ed. 1992)
Loot Price: R1,564
Discovery Miles 15 640
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Electrified Interfaces in Physics, Chemistry and Biology (Paperback, Softcover reprint of the original 1st ed. 1992)
Series: NATO Science Series C, 355
Expected to ship within 10 - 15 working days
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Electrified interfaces span from metaVsemiconductor and
metaVelectrolyte interfaces to disperse systems and biological
membranes, and are notably important in so many physical, chemical
and biological systems that their study has been tackled by
researchers with different scientific backgrounds using different
methodological approaches. The various electrified interfaces have
several common features. The equilibrium distribution of positive
and negative ions in an electrolytic solution is governed by the
same Poisson-Boltzmann equation independent of whether the solution
comes into contact with a metal, a colloidal particle or a
biomembrane, and the same is true for the equilibrium distribution
of free electrons and holes of a semiconductor in contact with a
different conducting phase. Evaluation of electric potential
differences across biomembranes is based on the same identity of
electrochemical potentials which holds for a glass electrode and
which yields the Nernst equation when applied to a metal/solution
interface. The theory of thermally activated electron tunneling,
which was developed by Marcus, Levich, Dogonadze and others to
account for electron transfer across metaVelectrolyte interfaces,
is also applied to light induced charge separation and proton
translocation reactions across intercellular membranes. From an
experimental viewpoint, the same electrochemical and in situ
spectroscopic techniques can equally well be employed for the study
of apparently quite different electrified interfaces.
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