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Dispersion Stability, Microstructure and Phase Transition of Anisotropic Nanodiscs (Hardcover, 2014 ed.)
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Dispersion Stability, Microstructure and Phase Transition of Anisotropic Nanodiscs (Hardcover, 2014 ed.)
Series: Springer Theses
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This thesis explores the dispersion stability, microstructure and
phase transitions involved in the nanoclay system. It describes the
recently discovered formation of colloidal gels via two routes: the
first is through phase separation and second is by equilibrium
gelation and includes the first reported experimental observation
of a system with high aspect ratio nanodiscs. The phase behavior of
anisotropic nanodiscs of different aspect ratio in their individual
and mixed states in aqueous and hydrophobic media is investigated.
Distinct phase separation, equilibrium fluid and equilibrium gel
phases are observed in nanoclay dispersions with extensive aging.
The work then explores solution behavior, gelation kinetics, aging
dynamics and temperature-induced ordering in the individual and
mixed states of these discotic colloids. Anisotropic ordering
dynamics induced by a water-air interface, waiting time and
temperature in these dispersions were studied in great detail along
with aggregation behavior of nanoplatelets in hydrophobic
environment of alcohol solutions.
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