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Construction and Reactivity of Pt-Based Bi-component Catalytic Systems (Hardcover, 1st ed. 2017)
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Construction and Reactivity of Pt-Based Bi-component Catalytic Systems (Hardcover, 1st ed. 2017)
Series: Springer Theses
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In this thesis, the author outlines the construction of active
structure and modulation of catalytic reactivity of Pt-based
bi-component catalysts, from the model systems to real supported
catalysts. The thesis investigates the promotion effect of the
second components on catalytic performance of Pt catalysts, and
presents the reversible generation of the "sandwich-like" structure
of Pt-Ni catalysts, containing both surface NiO1-X and subsurface
Ni by alternating redox treatments at medium temperature. With the
aid of single layer graphene, the dynamic process of chemical
reactions occurring on the Pt(111) surface can be visualized using
in-situ LEEM and DUV-PEEM techniques, the results of which are
included here. The author reveals that the graphene layer exhibits
a strong confinement effect on the chemistry of molecules
underneath and the intercalated CO can desorb from the Pt surface
around room temperature and in UHV, which may promote the CO
oxidation confined under graphene.
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