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Molecular Orbitals of Transition Metal Complexes (Hardcover)
Loot Price: R2,701
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Molecular Orbitals of Transition Metal Complexes (Hardcover)
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This book starts with the most elementary ideas of molecular
orbital theory and leads the reader progressively to an
understanding of the electronic structure, geometry and, in some
cases, reactivity of transition metal complexes. The qualitative
orbital approach, based on simple notions such as symmetry, overlap
and electronegativity, is the focus of the presentation and a
substantial part of the book is associated with the mechanics of
the assembly of molecular orbital diagrams. The first chapter
recalls the basis for electron counting in transition metal
complexes. The main ligand fields (octahedral, square planar,
tetrahedral, etc.) are studied in the second chapter (sigma
interactions) and the structure of the "d block" is used to trace
the relationships between the electronic structure and the geometry
of the complexes. The third chapter studies the change in analysis
when the ligands have pi-type interactions with the metal. All
these ideas are then used in the fourth chapter to study a series
of selected applications of varying complexity (structure,
reactivity). The fifth chapter deals with the "isolobal analogy"
which points out the resemblance between the molecular orbitals of
inorganic and organic species and provides a bridge between these
two subfields of chemistry. The last chapter is devoted to a
presentation of basic Group Theory with applications to some of the
complexes studied in the earlier chapters.
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