This volume, written by a range of international experts, covers a wide range of topics involving organic fluorine compounds. Each chapter is preceded by a summary and includes extensive illustrations and references. The chapters cover atmospheric chemistry, application of 19F NMR, partition, degradation and transformation, naturally occurring organic fluorine compounds, toxicology of perfluoroalkanes and phosphorofluoridates, and application of aromatic compounds to the elucidation of the mechanism of cytochrome P450.

Bewitched is an odd word with which to begin a chemical textbook. Yet that is a fair description of how I reacted on first leaming of ion exchange and imagining what might be done with it. That initial fascination has not left me these many years later, and it has provided much ofthe motivation for writing this book. The perceived need for a text on the fundamentals of ion chromatography provided the rest. Many readers will have a general idea of what ion chromatography is and what it does. Briefly, for those who do not, it is an umbrella term for a variety of chromatographie methods for the rapid and sensitive analysis of mixtures of ionic species. It has become highly developed in the last decade, and while it is now routinely used for the determination of organic as weH as inorganic ions, its initial impact was greatest in the area of inorganic analysis. In the past the determination of inorganic ions, particularly anions, meant laborious, time-con suming, and often not very sensitive "wet chemieal" methods. In the last ten years that has changed radically as ion chromatography has supplanted these older methods."

In this book, the author theoretically studies two aspects of topological states. First, novel states arising from hybridizing surface states of topological insulators are theoretically introduced. As a remarkable example, the author shows the existence of gapless interface states at the interface between two different topological insulators, which belong to the same topological phase. While such interface states are usually gapped due to hybridization, the author proves that the interface states are in fact gapless when the two topological insulators have opposite chiralities. This is the first time that gapless topological novel interface states protected by mirror symmetry have been proposed. Second, the author studies the Weyl semimetal phase in thin topological insulators subjected to a magnetic field. This Weyl semimetal phase possesses edge states showing abnormal dispersion, which is not observed without mirror symmetry. The author explains that the edge states gain a finite velocity by a particular form of inversion symmetry breaking, which makes it possible to observe the phenomenon by means of electric conductivity.

This book introduces the basic theoretical concepts required for the analysis of the optical response of semiconductor systems in the coherent regime. It is the most instructive textbook on the theory and optical effects of semiconductors. The entire presentation is based on a one-dimensional tight-binding model. Starting with discrete-level systems, increasing complexity is added gradually to the model by including band-structure and many-particle interaction. Various linear and nonlinear optical spectra and temporal phenomena are studied. The analysis of many-body effects in nonlinear optical phenomena covers a major part of the book.

Volume 7 continues the tradition of previous volumes in this series by presenting cutting-edge and current advances in atomic spectroscopy. This volume focuses on the application of atomic spectroscopy particularly ICPMS, with an emphasis in the area of clinical and biological samples
New techniques such as double focusing and field-flow fractionation ICP-MS are presented. Other areas such as laser induced breakdown spectrometry and new applications of graphite furnace AAS are included. A major theme of many of the chapters is speciation, which is the hottest topic in elemental determination at present.
.Focuses on cutting-edge advances in atomic spectroscopy
.Contributors are leaders in their fields
.Can be used in conjunction with the other books in the series or as a stand-alone title

Following the long-standing tradition of the Seeheim-Workshops on M ssbauer Spectroscopy, 1978, 1983, 1988, 1994 always held in the same traditional place of the Lufthansa Training Center in Seeheim/Germany, the 5th workshop took place in 2002. The main topics covered are:
-new technical developments such as the techniques of Nuclear Inelastic Scattering (NIS) and Nuclear Forward Scattering (NFS) of Synchrotron Radiation and their applications in studying lattice dynamics, magnetism and surface phenomena;
-investigations of molecular structural and bonding properties in biomolecules and coordination compounds;
-problems related to geochemistry and earth sciences;
-applications of M ssbauer spectroscopy in molecular magnetism and photomagnetism.
The book will serve as a source of great actuality to physicists, chemists and geoscientists employing the M ssbauer effect and other hyperfine interaction techniques to explore solid state properties of bulk materials as well as surface phenomena.

Mass spectrometry (MS) offers unmatched capabilities for the detection, characterization, and identification of a broad range of analytes. Mass spectrometry imaging (MSI) integrates MS data with information on the spatial distributions of the analytes, further enhancing the applicability of MS. In Mass Spectrometry Imaging: Principles and Protocols, expert practitioners from academia, industry, and the clinic contribute cutting-edge protocols describing the application of MSI to investigations of analyte localization in a variety of specimens, from microorganisms to plant and animal tissues. Divided into three sections, this volume presents the principles of MS, current and future trends of MSI, and qualitative and quantitative protocols to measure and identify endogenous metabolites and xenobiotics. An array of MSI approaches and technologies for characterizing peptide and protein distributions are described in detail. Written in the highly successful Methods in Molecular Biology (TM) series format, protocol chapters include introductions to their respective topics, lists of the necessary materials and reagents, and step-by-step, readily reproducible laboratory procedures. Also included are notes providing tips to avoid experimental pitfalls and helpful suggestions for method troubleshooting. Comprehensive and up-to-date, Mass Spectrometry Imaging: Principles and Protocols is written for scientists, biological and chemical engineers, and clinicians who are interested in applying MSI in their work and those who would benefit from having detailed experimental guidelines available in a single, convenient source.

This book is an up-to-date survey of the major optical characterization techniques for thin solid films. Emphasis is placed on practicability of the various approaches. Relevant fundamentals are briefly reviewed before demonstrating the application of these techniques to practically relevant research and development topics. The book is written by international top experts, all of whom are involved in industrial research and development projects.

The book deals with various consequences of major nuclear accidents, such as in 1986 in Chernobyl and in 2011 in Fukushima. The public is extremely interested in learning more about the movements and risks posed by radiation in the environment related to food supply and food safety. Radionuclides are found in air, water, soil and even in us not only after nuclear accidents because they occur also in nature. Every day, we ingest and inhale radionuclides in our air and food and the water. This book provides a solid underpinning of the basic physical-chemistry and biogeochemistry of naturally occurring and anthrop radioactivity. The mechanisms of radioactive element transfer in the atmosphere, tropospheric and stratospheric diffusion of radioactivity, environmental contamination from accidents and the impact of atmospheric pollution on the food chain, soil and plants, are analyzed and the analytical methods are illustrated. The question of natural radioactivity concentration in building materials is addressed too. While the book contains many case studies and data for Greece, it is of general value. It contributes to the development of international environmentally safe standards and economically reasonable standard regulations based on justified radiological, social and economical legislation concepts.

The development of linear-scaling density functional theory (LS-DFT) has made ab initio calculations on systems containing thousands of atoms possible. These systems range from nanostructures to biomolecules. These methods rely on the use of localized basis sets, which are optimised for the representation of occupied Kohn-Sham states but do not guarantee an accurate representation of the unoccupied states. This is problematic if one wishes to combine the power of LS-DFT with that of theoretical spectroscopy, which provides a direct link between simulation and experiment. In this work a new method is presented for optimizing localized functions to accurately represent the unoccupied states, thus allowing theoretical spectroscopy of large systems. Results are presented for optical absorption spectra calculated using the ONETEP code, but the method is equally applicable to other spectroscopies and LS formulations. Other topics covered include a study of some simple one dimensional basis sets and the presentation of two methods for band structure calculation using localized basis sets, both of which have important implications for the use of localized basis sets within LS-DFT.

With their similarity to the organs of the most advanced creatures that inhabit the Earth, sensors are regarded as being the "senses of electronics": arti?cial eyes and ears that are capable of seeing and hearing beyond the range of - man perception; electronic noses and tongues that can recognise odours and ?avours without a lifetime training; touch that is able not only to feel the texture and temperature of the materials but even to discern their chemical compo- tion. Among the world of chemical sensors, optical devices (sometimes termed "optodes", from the Greek "the optical way") have reached a prominent place in those areas where the features of light and of the light-matter interaction show their advantage: contactless or long-distance interrogation, detection sensitivity, analyte selectivity, absence of electrical interference or risks, and lack of analyte consumption, to name just a few. The introduction of optical ?bres and integrated optics has added more value to such sensing since now light can be con?ned and readily carried to dif?cult-to-reach locations, higher information density can be transported, indicator dyes can be immobilised at the distal end or the evanescent ?eld for unique chemical and biochemical sensing (including multiplexed and distributed measurements), optical s- sors can now be subject to mass production and novel sensing schemes have been established (interferometric, surface plasmon resonance, ?uorescence energy transfer, supramolecular recognition . . . ).

This book brings together a number of studies which examine the ways in which the retention and selectivity of separations in high-performance liquid chromatography are dependent on the chemical structure of the analytes and the properties of the stationary and mobile phases. Although previous authors have described the optimisation of separations by alteration of the mobile phase, little emphasis has previously been reported of the influence of the structure and properties of the analyte.

The initial chapters describe methods based on retention index group increments and log P increments for the prediction of the retention of analytes and the ways in which these factors are influenced by mobile phases and intramolecular interactions. The values of a wide range of group increments in different eluents are tabulated.

Different scales of retention indices in liquid chromatography are described for the comparison of separations, the identification of analytes and the comparison of stationary phases. Applications of these methods in the pharmaceutical, toxicology, forensic, metabolism, environmental, food and other fields are reviewed. The effects of different mobile phases on the selectivity of the retention indices are reported. A compilation of sources of reported retention index values are given.

Methods for the comparison of stationary phases based on the interactions of different analytes are covered, including lipophilic and polar indices, shape selectivity comparisons, their application to novel stationary phases, and chemometric methods for column comparisons.

As a spectroscopic method, Nuclear Magnetic Resonance (NMR) has seen spectacular growth over the past two decades, both as a technique and in its applications. Today the applications of NMR span a wide range of scientific disciplines, from physics to biology to medicine. Each volume of Nuclear Magnetic Resonance comprises a combination of annual and biennial reports which together provide comprehensive of the literature on this topic. This Specialist Periodical Report reflects the growing volume of published work involving NMR techniques and applications, in particular NMR of natural macromolecules which is covered in two reports: "NMR of Proteins and Acids" and "NMR of Carbohydrates, Lipids and Membranes." For those wanting to become rapidly acquainted with specific areas of NMR, this title provides unrivalled scope of coverage. Seasoned practitioners of NMR will find this an in valuable source of current methods and applications. Specialist Periodical Reports provide systematic and detailed review coverage in major areas of chemical research. Compiled by teams of leading authorities in the relevant subject areas, the series creates a unique service for the active research chemist, with regular, in-depth accounts of progress in particular fields of chemistry. Subject coverage within different volumes of a given title is similar and publication is on an annual or biennial basis.

Conference Overview and the Role of Chemistry in High-Temperature Materials Science and Technology LEO BREWER Department of ChemistIy, University of California, and Materials and Chemical Sciences Division, Lawrence Berkeley Laboratory, 1 Cyclotron Road, Berkeley, CA 94720 I don't want to compete with the fascinating historic account that John Drowart gave us, but I would like to go through the history of high don't get the reaction that I get from temperature symposia. I hope I some of my classes when I say, "Remember when such-and-such hap pened during the War?" And I get this blank look, and one of the students will say, "I wasn't born until after the Korean War. " Neverthe less, during World War II, many people in the high-temperature field had their first initiation. But there was one handicap. Owing to security measures, they were not able to interact with one another. Following the War, it was recognized that the high-temperature field was going to expand to meet the demands for materials with unique properties. To meet the demands for new fabrication techniques, it was important to establish better communications among various people. High-tempera ture symposia were established at that time and have continued very frequently, and I'd like to point out why they are especially important for this field. One problem is that it is not easy to work at high temperatures."

The acquisition and interpretation of images is a central capability in almost all scientific and technological domains. In particular, the acquisition of electromagnetic radiation, in the form of visible light, UV, infrared, X-ray, etc. is of enormous practical importance. The ultimate sensitivity in electronic imaging is the detection of individual photons. With this book, the first comprehensive review of all aspects of single-photon electronic imaging has been created. Topics include theoretical basics, semiconductor fabrication, single-photon detection principles, imager design and applications of different spectral domains. Today, the solid-state fabrication capabilities for several types of image sensors has advanced to a point, where uncoooled single-photon electronic imaging will soon become a consumer product. This book is giving a specialists view from different domains to the forthcoming "single-photon imaging" revolution. The various aspects of single-photon imaging are treated by internationally renowned, leading scientists and technologists who have all pioneered their respective fields.

This volume provides a comprehensive overview of environmental aspects of the Sava River, which is the greatest tributary to the Danube River and the major drainage river system of South Eastern Europe. Hydroelectric power plants, river traffic, intensive agricultural activities, heavy industry and floods have considerable influence on the environment and biota in the basin. Summarizing the results that were gathered in the course of EU, bilateral and national projects, the book highlights the most important stressors and helps readers to better understand the impact of anthropogenic activities on the function of river basins. Topics include: transboundary water cooperation between the riparian countries; climate change projection, including its impact on flood hazards; evaluation of anthropogenic pollution sources; pollution of sediments, metal bioavailability and ecotoxicological and microbiological characterization of the river. The biological part also addresses quality aspects related to wildlife in river aquatic ecosystems (algae, macrophytes, zooplankton, macroinvertebrates and fish) and riparian ecosystems (amphibians, reptiles, birds and mammals). The general state of biodiversity and pressures caused by invasive aquatic species are also discussed.

Environmental chemistry is a fast developing science aimed at deciphering fundamental mechanisms ruling the behaviour of pollutants in ecosystems. Applying this knowledge to current environmental issues leads to the remediation of environmental media, and to new, low energy, low emission, sustainable processes. Nanotechnology applications for alternative energies such as solar power, fuel cells, hydrogen and lithium batteries are reviewed in the first section. Recent investigations on carbon nanotubes, nanocatalysts and cyclodextrins disclose unprecedented techniques to monitor and clean pollutants such as greenhouse gases, heavy metals, pesticides, pathogens occurring in water, air and soil. The second section reviews the risks for human health of critical pollutants such as endocrine disruptors, dioxins and heavy metals contaminating seafood and sediments. An exhaustive review of DDT isomers reveals unexpected mechanisms of DDT transfer to fishes. A chapter on pollutant geochronology using river sedimentary archives provides novel insights on pollution history since the beginning of the anthropocene.

This book will be a valuable source of information for engineers and students developing novel applied techniques to monitor and clean pollutants in air, wastewater, soils and sediments.

"

What drives a scientist to edit a book on a speci c scienti c subject such as chiral mechanisms in separation methods? Until December 2005, the journal Analytical Chemistry of the American Chemical Society (Washington, DC) had an A-page section that was dedicated to simple and clear presentations of the most recent te- niques or the state of the art in a particular eld or topic. The "A-page" section was prepared for a broad audience of chemists including industrial professionals, s- dents as well as academics looking for information outside their eld of expertise. 1 Daniel W. Armstrong, one of the editors of this journal and a twenty-year+ long friend, invited me to present my view on chiral recognition mechanisms in a simple and clear way in an "A-page" article. In 2006, the "A-page" section was maintained as the rst articles at the beginning of each rst bi-monthly issue but the pagination was no longer page distinguished from the regular research articles published by the journal. During the time between the invitation and the submission, the A-page section was integrated into the rest of the journal and the article appeared as (2006) Anal Chem (78):2093-2099.

Emerging Mass Spectrometric Tools for Analysis of Polymers and Polymer Additives, by Nina Aminlashgari and Minna Hakkarainen. Analysis of Polymer Additives and Impurities by Liquid Chromatography/Mass Spectrometry and Capillary Electrophoresis/Mass Spectrometry, by Wolfgang Buchberger and Martin Stiftinger. Direct Insertion Probe Mass Spectrometry of Polymers, by Jale Hacaloglu Mass Spectrometric Characterization of Oligo- and Polysaccharides and Their Derivatives, by Petra Mischnick. Electrospray Ionization-Mass Spectrometry for Molecular Level Understanding of Polymer Degradation, by Minna Hakkarainen.

The analysis of solid materials by introducing solid test sampies directly into the graphite furnace of an atomic absorption spectrometer must be regarded as a powerful analytical approach. Even if it is - of course - not the "ultimate method." After three decades of development, the instrumentation and the methodology are available to apply solid sampling successfully for the analysis of almost every material. Moreover, several tasks cannot be solved using other analytical methods as neatly as they can using direct solid sampling. The conventional methods work more or less satisfactorily, so why do we sug gest applying solid sampling much more extensively than it is today? To begin with, the features pointed out time and again should be named: Rapidity of the analytical procedure, low susceptibility to analyte loss or contamination, very smallquantities can be analyzed, and expenditure on instrumentation and per sonell is also low. These properties are examined and the necessary conditions are discussed (Chapter 1) as are the analytical tasks (Chapter 6) for which use of this method is advantageous. Other features that are often overlooked are just as important: The simplicity of the analytical procedures allows the analyst to main tain an intimate relationship with the original scientific task that has to be solved with the analysis. Furthermore, the considerable reduction of working place haz ards and pollution by avoiding the use of chemical reagents must nowadays be assessed as a feature as important as the others."

This thesis provides a comprehensive description of methods used to compute the vibrational spectra of liquid systems by molecular dynamics simulations. The author systematically introduces theoretical basics and discusses the implications of approximating the atomic nuclei as classical particles. The strengths of the methodology are demonstrated through several different examples. Of particular interest are ionic liquids, since their properties are governed by strong and diverse intermolecular interactions in the liquid state. As a novel contribution to the field, the author presents an alternative route toward infrared and Raman intensities on the basis of a Voronoi tessellation of the electron density. This technique is superior to existing approaches regarding the computational resources needed. Moreover, this book presents an innovative approach to obtaining the magnetic moments and vibrational circular dichroism spectra of liquids, and demonstrates its excellent agreement with experimental reference data.

Several hundred nuclear scientists from more than a dozen countries met in Miami Beach, Florida, in September 1989 for a Symposium on Exotic Nuclear Spectroscopy, sponsored by the Division of Nuclear Chemistry and Technology of the Amencan Chemical Society. Braving five days of beckoning beaches, they presented, listened to, and discussed a series spectroscopy-both experimental and of invited papers covering the renaissance of nuclear theoretical-that has occurred during the past decade and which promises to continue well into the decade to come. This book contains the Proceedings of that Symposium on Exotic Nuclear Spectroscopy. But it is much more: During the ensuing six months, most of the pa{>ers were rewritten, polished, and/or expanded; so the resulting book is a much more fimshed, comprehensive, and up-to-date product than a general proceedings. Chapter se~uences follow the original symposium program, which, with a few exceptions, juxtaposes like topics. Each chapter can stand more or less on its own-although, as in any complex, interrelated scientific field, there are many cross-references among chapters. The manuscripts were edited and then uniformly typed in the Department of Chemistry at Michigan State University. I tried to keep the editing to a minimum so as to preserve the flavor of individual styles. A great debt of gratitude goes to those who helped make this volume possible, especially to Vada O'Donnell, who bore the largest burden of typing (and clarifying) the manuscripts.

This book deals with the concept of moments, and how they find application in subsurface hydrologic problems-particularly those dealing with solute transport. Both temporal and spatial moments are dealt with in some detail for a wide variety of problems. Several examples using experimental data, both from laboratory columns and field experiments, are provided to give the readers a clear idea about the scope of this method.