This book is intended to present for the first time experimental methods to measure equilibria states of pure and mixed gases being adsorbed on the surface of solid materials. It has been written for engineers and scientists from industry and academia who are interested in adsorption based gas separation processes and/or in using gas adsorption for characterization of the porosity of solid materials. This book is the result of a fruitful collaboration of a theoretician (JUK) and an experimentalist (RS) over more than twelve years in the field of gas adsorption systems at the Institute of Fluid- and Thermodynamics (IFT) at the University of Siegen, Siegen, Germany. This collaboration resulted in the development of several new methods to measure not only pure gas adsorption, but gas mixture or coadsorption equilibria on inert porous solids. Also several new theoretical results could be achieved leading to new types of so-called adsorption isotherms based on the concepts of molecular association and - phenomenologically speaking - on that of thermodynamic phases of fractal dimension. Naturally, results of international collaboration of the authors over the years (1980-2000) also are included.

This book describes semiconductors from a materials science perspective rather than from condensed matter physics or electrical engineering viewpoints. It includes discussion of current approaches to organic materials for electronic devices. It further describes the fundamental aspects of thin film nucleation and growth, and the most common physical and chemical vapor deposition techniques. Examples of the application of the concepts in each chapter to specific problems or situations are included, along with recommended readings and homework problems.

Raman scattering is now being applied with increasing success to a wide range of practical problems at the cutting edge of materials science. The purpose of this book is to make Raman spectroscopy understandable to the non-specialist and thus to bring it into the mainstream of routine materials characterization. The book is pedagogical in approach and focuses on technologically important condensed-matter systems in which the specific use of Raman spectroscopy yields new and useful information. Included are chapters on instrumentation, bulk semiconductors and alloys, heterostructures, high-Tc superconductors, catalysts, carbon-based materials, wide-gap and super-hard materials, and polymers.

The study of sliding friction is one of the oldest problems in physics, and certainly one of the most important from a practical point of view. Low-friction surfaces are in increasingly high demand for high-tech components such as computer storage systems, miniature motors, and aerospace devices. It has been estimated that about 5% of the gross national product in the developed countries is "wasted" on friction and the related wear. In spite of this, remarkable little is understood about the fundamental, microscopic processes responsible for friction and wear. The topic of interfacial sliding has experienced a major burst of in terest and activity since 1987, much of which has developed quite independently and spontaneously. This volume contains contributions from leading scientists on fundamental aspects of sliding friction. Some problems considered are: What is the origin of stick-and-slip motion? What is the origin of the rapid processes taking place within a lub at low sliding velocities? On a metallic surface, is the rication layer electronic or phononic friction the dominating energy dissipation pro cess? What is the role (if any) of self-organized criticality in sliding friction? How thick is the water layer during sliding on ice and snow? These and other questions raised in this book are of course only part ly answered: the topic of sliding friction is still in an early state of development."

Experiments with rubber balloons and rubber sheets have led to surprising observations, some of them hitherto unknown or not previously described in the literature. In balloons, these phenomena are due to the non-monotonic pressure-radius characteristic which makes balloons a subject of interest to physicists engaged in stability studies. Here is a situation in which symmetry breaking and hysteresis may be studied analytically, because the stress-stretch relations of rubber - and its non-convex free energy - can be determined explicitly from the kinetic theory of rubber and from non-linear elasticity. Since rubber elasticity and the elasticity of gases are both entropy-induced, a rubber balloon represents a compromise between the entropic tendency of a gas to expand and the entropic tendency of rubber to contract. Thus rubber and rubber balloons furnish instructive paradigms of thermodynamics. This monograph treats the subject at a level appropriate for post-graduate studies.

Success in the fabrication of structures at the nanometer length scale has opened up a new horizon to condensed matter physics: the study of quantum phenomena in confined boxes, wires, rings, etc. A new class of electronic devices based on this physics has been proposed, with the promise of a new functionality for ultrafast and/or ultradense electronic circuits. Such applications demand highly sophisticated fabrication techniques, the crucial one being lithography. Nanolithography contains updated reviews by major experts on the well established techniques -- electron beam lithography (EBL), X-ray lithography (XRL), ion beam lithography (IBL) -- as well as on emergent techniques, such as scanning tunnelling lithography (STL).

This book consists of ten chapters which outline a wide range of technologies from first-principle calculations to continuum mechanics, with applications to materials design and development. Written with a clear exposition, this book will be invaluable for engineers who want to learn about the modern technologies and techniques utilized in materials design.

Modern physics is confronted with a large variety of complex spatial patterns. Although both spatial statisticians and statistical physicists study random geometrical structures, there has been only little interaction between the two up to now because of different traditions and languages.
This volume aims to change this situation by presenting in a clear way fundamental concepts of spatial statistics which are of great potential value for condensed matter physics and materials sciences in general, and for porous media, percolation and Gibbs processes in particular. Geometric aspects, in particular ideas of stochastic and integral geometry, play a central role throughout. With nonspecialist researchers and graduate students also in mind, prominent physicists give an excellent introduction here to modern ideas of statistical physics pertinent to this exciting field of research.

The need to predict, understand, and optimize complex physical and c- mical processes occurring in and around the earth, such as groundwater c- tamination, oil reservoir production, discovering new oil reserves, and ocean hydrodynamics, has been increasingly recognized. Despite their seemingly disparate natures, these geoscience problems have many common mathe- tical and computational characteristics. The techniques used to describe and study them are applicable across a broad range of areas. The study of the above problems through physical experiments, mat- matical theory, and computational techniques requires interdisciplinary col- boration between engineers, mathematicians, computational scientists, and other researchers working in industry, government laboratories, and univ- sities. By bringing together such researchers, meaningful progress can be made in predicting, understanding, and optimizing physical and chemical processes. The International Workshop on Fluid Flow and Transport in Porous - dia was successfully held in Beijing, China, August 2{6, 1999. The aim of this workshop was to bring together applied mathematicians, computational scientists, and engineers working actively in the mathematical and nume- cal treatment of ?uid ?ow and transport in porous media. A broad range of researchers presented papers and discussed both problems and current, state-of-the-art techniques.

Biopolymers from Renewable Resources is a compilation of information on the diverse and useful polymers derived from agricultural, animal, and microbial sources. The volume provides insight into the diversity of polymers obtained directly from, or derived from, renewable resources. The beneficial aspects of utilizing polymers from renewable resources, when considering synthesis, pro cessing, disposal, biodegradability, and overall material life-cycle issues, suggests that this will continue to be an important and growing area of interest. The individual chapters provide information on synthesis, processing and properties for a variety of polyamides, polysaccharides, polyesters and polyphenols. The reader will have a single volume that provides a resource from which to gain initial insights into this diverse field and from which key references and contacts can be drawn. Aspects of biology, biotechnology, polymer synthesis, polymer processing and engineering, mechanical properties and biophysics are addressed to varying degrees for the specific biopolymers. The volume can be used as a reference book or as a teaching text. At the more practical level, the range of important materials derived from renewable resources is both extensive and impressive. Gels, additives, fibers, coatings and films are generated from a variety of the biopolymers reviewed in this volume. These polymers are used in commodity materials in our everyday lives, as well as in specialty products."

Most descriptions of polymers start at room temperature and end at the melting point. This textbook starts at very low temperatures and ends at room temperature. At low temperatures, may processes and relaxations are frozen which allows singular processes or separate relaxations to be studied. At room temperatures, or at the main glass transitions, many processes overlap and the properties are determined by relaxations. At low temperatures, there are temperature ranges with negligible influences by glass transitions. They can be used for investigating so-called basic properties which arise from principles of solid state physics. The chain structure of polymers, however, requires stringent modifications for establishing solid state physics of polymers. Several processes which are specific of polymers, occur only at low temperatures. There are also technological aspects for considering polymers at low temperatures. More and more applications of polymeric materials in low temperature technology appear. Some examples are thermal and electrical insulations, support elements for cryogenic devices, low-loss materials for high frequency equipments. It is hoped that, in addition to the scientific part, a data collection in the appendix may help to apply polymers more intensively in low temperature technology. The author greatly appreciates the contributions by his coworkers of the Kernforschungszentrum Karlsruhe in measurement and discussion of many data presented in the textbook and its appendix. Fruitful disccussions with the colleagues Prof. H. Baur, Prof. S. Hunklinger, Prof. D. Munz and Prof. R."

This book provides an attempt to convey the colorful facets of condensed matter systems with reduced dimensionality. Some of the specific features predicted for interacting one-dimensional electron systems, such as charge- and spin-density waves, have been observed in many quasi-one-dimensional materials. The two-dimensional world is even richer: besides d-wave superconductivity and the Quantum Hall Effect - perhaps the most spectacular phases explored during the last two decades - many collective charge and spin states have captured the interest of researchers, such as charge stripes or spontaneously generated circulating currents.

Recent years have witnessed important progress in material preparation, measurement techniques and theoretical methods. Today larger and better samples, higher flux for neutron beams, advanced light sources, better resolution in electron spectroscopy, new computational algorithms, and the development of field-theoretical approaches allow an in-depth analysis of the complex many-body behaviour of low-dimensional materials. The epoch when simple mean-field arguments were sufficient for describing the gross features observed experimentally is definitely over.

The Editors' aim is to thoroughly explain a number of selected topics: the application of dynamical probes, such as neutron scattering, optical absorption and photoemission, as well as transport studies, both electrical and thermal. Some of the more theoretical chapters are directly relevant for experiments, such as optical spectroscopy, transport in one-dimensional models, and the phenomenology of charge inhomogeneities in layered materials, while others discuss more general topics and methods, for example the concept of a Luttinger liquid and bosonization, or duality transformations, both promising tools for treating strongly interacting many-body systems.

The monograph "Shaped Crystal Growth" by V. A. Tatarchenko is the first systematic of the macroscopic crystallization theory. The theory is based on the stable statement growth conception, which means that self-stabilization is present in the system, with growth parameter deviations occurring under the action of external perturbations attenuating with time. The crystallization rate is one of the parameters responsible for crystal defect formation. Steady-state crystal growth means that crystallization rate internal stabilization is present, thus allowing more perfect crystals to grow. Most important is the fact that the crystal shape (an easily observed parameter) is one of the stable-growth characteristics when growing crystals without any contact with the crucible walls. This means that constant-cross-section crystal growth is to a certain extent evidence of crystallization process stability. The principles of the stable crystal growth theory were developed by the author of the monograph in the early 1970s. Due to the efforts over the past 20 years of V. A. Tatarchenko, his disciples (V. A. Borodin, S. K. Brantov, E. A. Brener, G. I. Romanova, G. A. Satunkin et al) and his followers (B. L. Timan, 0. V. Kolotiy et al) the theory has been completed, which is demonstrated by this monograph. The characteristic feature of the theory is its trend towards solving practical problems that occur in the process of crystal growth."

This book includes a numerical investigation of shear localization in granular materials within micro-polar hypoplasticity, which was carried out during my long research stay at the Institute of Soil and Rock Mechanics at Karlsruhe University from 1985 to 1996. I dedicate my book to Prof. Gerd Gudehus from Germany, the former head of the Institute of Rock and Soil Mechanics at Karlsruhe University and the supervisor of my scientific research during my stay in Karlsruhe, who encouraged me to deal with shear localization in granular bodies within micro-polar hypoplasticity. I greatly - preciate his profound knowledge, kind help constructive discussions, and collegial attitude to his co-workers. I am thankful to the both series editors: Prof. Wei Wu from Universitat fur Bodenkultur in Austria and Prof. Ronaldo Borja from Stanford University in USA for their helpful suggestions with respect to the contents and structure of the book. I am also grateful to Dr. Thomas Ditzinger and Mrs. Heather King from the Springer Publishing Company and SPS data processing team for their help in editing this book. Gdansk, Jacek Tejchman June 2008 Contents 1 Introduction......................................................................... 1 2 Literature Overview on Experiments........................................... 11 3 Theoretical Model.................................................................. 47 3.1 Hypoplastic Constitutive Model............................................. 47 3.2 Calibration of Hypoplastic Material Parameters........................... 60 3.3 Micro-polar Continuum........................................................ 67 3.4 Micro-polar Hypoplastic Constitutive Model.............................. 72 3.5 Finite Element Implementation................................................ 75 4 Finite Element Calculations: Preliminary Results............................"

In a ?rst approximation, certainly rough, one can de?ne as non-crystalline materials those which are neither single-crystals nor poly-crystals. Within this category, we canincludedisorderedsolids, softcondensed matter, andlivesystemsamong others. Contrary to crystals, non-crystalline materials have in common that their intrinsic structures cannot be exclusively described by a discrete and periodical function but by a continuous function with short range of order. Structurally these systems have in common the relevance of length scales between those de?ned by the atomic and the macroscopic scale. In a simple ?uid, for example, mobile molecules may freely exchange their positions, so that their new positions are permutations of their old ones. By contrast, in a complex ?uid large groups of molecules may be interc- nected so that the permutation freedom within the group is lost, while the p- mutation between the groups is possible. In this case, the dominant characteristic length, which may de?ne the properties of the system, is not the molecular size but that of the groups. A central aspect of some non-crystalline materials is that they may self-organize. This is of particular importance for Soft-matter materials. Self-organization is characterized by the spontaneous creation of regular structures at different length scales which may exhibit a certain hierarchy that controls the properties of the system. X-ray scattering and diffraction have been for more than a hundred years an essential technique to characterize the structure of materials. Quite often scattering anddiffractionphenomenaexhibitedbynon-crystallinematerialshavebeenreferred to as non-crystalline diffractio

physics

Non-Linear Optical Properties of Matter: From Molecules to Condensed Phases attempts to draw together both theory and application in this field. As such it will be of interest to both experimentalists and theoreticians alike. Divided into two parts, Part 1 is concerned with the theory and computing of non-linear optical (NLO) properties while Part 2 reviews the latest developments in experimentation.

Part 1: Surveys the current advances in the computation of the NLO properties of molecules, crystalline solids and nano-particles. It examines the methods employed to compute the properties of both microscopic and macroscopic forms of matter.

Part 2: Covers the recent advances on the NLO properties of organometallic compounds, rotaxanes, glasses, Langmuir-Blodget films, gold and silver nano-particles etc. Strategies to develop novel NLO materials are also discussed along with the Hyper-Rayleigh scattering technique.

Semiconductor spintronics is expected to lead to a new generation of transistors, lasers and integrated magnetic sensors that can be used to create ultra-low power, high speed memory, logic and photonic devices. Useful spintronic devices will need materials with practical magnetic ordering temperatures and current research points to gallium and aluminium nitride magnetic superconductors as having great potential.

This book details current research into the properties of III-nitride semiconductors and their usefulness in novel devices such as spin-polarized light emitters, spin field effect transistors, integrated sensors and high temperature electronics.

Written by three leading researchers in nitride semiconductors, the book provides an excellent introduction to gallium nitride technology and will be of interest to all reseachers and industrial practitioners wishing to keep up to date with developments that may lead to the next generation of transistors, lasers and integrated magnetic sensors.

This book deals with the formulation of the thermodynamics of chemical and other systems far from equilibrium. It contains applications to non-equilibrium stationary states and approaches to such states, systems with multiple stationary states, stability and equi-stability conditions, reaction diffusion systems, transport properties, and electrochemical systems. The theoretical treatment is complemented by experimental results to substantiate the formulation.

Oxides form a broad subject area of research and technology development which encompasses different disciplines such as materials science, solid state chemistry, physics etc. The aim of this book is to demonstrate the interplay of these fields and to provide an introduction to the techniques and methodologies involving film growth, characterization and device processing. The literature in this field is thus fairly scattered in different research journals covering one or the other aspect of the specific activity. This situation calls for a book that will consolidate this information and thus enable a beginner as well as an expert to get an overall perspective of the field, its foundations, and its projected progress.

In this volume we have collected some of the contributions made to the Twelfth European Workshop on Quantum Systems in Chemistry and Physics (QSCP-XII) in 2007. The workshop was held at Royal Holloway College, the most westerly campusof the University of London, and situated just a stone's throw from Windsor Great Park. The workshop, which ran from 30 August to 5 September, continued the series that was established by Roy McWeeny in April 1996 with a meeting held at San Miniato, near Pisa. The purpose of the QSCP workshops is to bring together, in an informal atmosphere and with the aim of fostering collaboration, those chemists and physicists who share a common ?eld of interest in the theory of the quantum many-body problem. Quantum mechanics provides a theoretical foundation for our understandingof the structure, propertiesanddynamicsof atoms, moleculesandthe solid state, in terms of their component particles: electrons and nuclei. The study of 'Quantum Systems in Chemistry and Physics' therefore underpins many of the emerging?elds in twenty-?rstcenturyscience andtechnology: nanostructure, smart materials, drug design - to name but a few. Members of the workshop were keen to discuss their research and engage in collaboration centred upon the development of fundamental and innovative theory which would lead to the exploration of new concepts. The proceedings of all of the workshops, which have been held annually since 1996, have been published both to disseminate the latest developments within the wider community and to stimulate further collaboration.

This coherent monograph describes and explains quantum phenomena in two-dimensional (2D) electron systems with extremely strong internal interactions, which cannot be described by the conventional Fermi-liquid approach. The central physical objects considered are the 2D Coulomb liquid, of which the average Coulomb interaction energy per electron is much higher than the mean kinetic energy, and the Wigner solid. The text provides a new and comprehensive review of the remarkable properties of Coulomb liquids and solids formed on the free surface of liquid helium and other interfaces. This book is intended for graduate students and researchers in the fields of quantum liquids, electronic properties of 2D systems, and solid-state physics. It includes different levels of sophistication so as to be useful for both theorists and experimentalists. The presentation is largely self-contained, and also describes some instructive examples that will be of general interest to solid-state physicists.