The almost universal presence of water in our everyday lives and the very common' nature of its presence and properties possibly deflects attention from the fact that it has a number of very unusual characteristics which, furthermore, are found to be extremely sensitive to physical parameters, chemical environment and other influences. Hydrogen-bonding effects, too, are not restricted to water, so it is necessary to investigate other systems as well, in order to understand the characteristics in a wider context. Hydrogen Bond Networks reflects the diversity and relevance of water in subjects ranging from the fundamentals of condensed matter physics, through aspects of chemical reactivity to structure and function in biological systems.

Springer-Verlag 2003 This issue is dedicated to Doctor Shuji Saito on the occasion of the 50th anniversary of his ?rst paper published in the Journal of German Colloid Society. The paper entitled ''Die Solubilisation von Polyvinylazetat'' by N. Sata and S. Saito appeared in the Kolloid Zeitschrift (1952) 128: 154. According to the title, the paper dealt with the solubilization of poly(vinyl acetate) (PVAc) in aqueous sodium dodecyl sulfate (SDS) solutions. The authors observed that PVAc, a water-insoluble polymer, is c- pletely dissolved by micellar SDS solutions, a result that mostly intrigued them. One has to recall that at that time, the micellar solubilization was the only available theory to explain the dissolution of hydrophobic compounds in micellar systems. The theory worked well in the case of low molecular weight compounds like hydrocarbons, oleophilic dyes, etc., which are solubilized in the inner core of the micelle, but how can a small micelle accommodate a giant polymer molecule? To solve this problem Sata and Saito originally proposed a model consisting of surfactant aggregates formed along the polymer backbone. The model based on simple viscometric measurements was later in the eighties con?rmed by the advent of the more sophisticated neutron scattering technique and is nowadays called the ''necklace model''. During his career, Dr.

It has been more than 80 years since Valasek first recognized the existence of a dielectric analogue to ferromagnetism, ferroelectricity, in Rochelle salt. Much as with semiconductor research, the initial studies of ferroelectric materials focused on homogeneous materials. Unlike semiconductor research, however, which rapidly expanded into n- homogeneous structures and devices, investigations of compositionally graded and layered ferroelectrics have been relatively recent endeavors. Indeed, many of the most significant results and analysis pertaining to polarization-graded ferroelectrics have only appeared in publication within the last ten years. Further extensions of these concepts to the general class of order-parameter graded ferroic materials, as depicted on the cover of this book, have (with one exception) been totally lacking. It was thus with a great deal of excitement that we assembled the manuscript for this book. The primary focus of this study is directed toward polarization-graded ferroelectrics and their active components, transpacitors; however, the findings presented here are quite general. The theory of graded 2 and 5; whereas, much of the ferroics is put on a solid foundation in chapters introductory material relies more heavily upon analogy. This was done so as to provide the reader with an intuitive approach to graded ferroics, thereby enabling them to see heterogeneous ferroics as clearly logical extensions of passive semiconductor junction devices such as p-n and n-p diodes and their active manifestations, transistors, to: transpacitors, transductors, translastics, and ultimately to the general active ferroic elements, transponents.

Segregation is a pervasive phenomenon whereby a flowing granular mass consisting of particles with diverse physical properties becomes spatially inhomogeneous. In the industrial sector that deals with the handling and processing of bulk solids, this non-uniformity is highly undesirable since blend homogeneity is generally a stringent requirement of most products. In the arena of geophysical flows, segregation can enhance the destructive capabilities of natural events such as avalanches and landslides. During the last 15 years, these issues have provided motivation and fostered collaborations between the communities of mathematicians, engineers, industrial researchers, and physicists to develop predictive models of segregation by integrating the perspectives and approaches of each. The collection of unique papers brings to light many of the perplexing scientific and technical issues in our current understanding of this complex phenomenon. It addresses advances in experiment, computational modeling and theory. This volume is one of the very few books devoted entirely to problems of segregation of particulate solids.

The rapidly-developing field of confined polymers is reviewed in this volume. Special emphasis is given to polymer aspects of this interdisciplinary problem. Taken together, the contributions offer ample evidence of how the field of polymer science continues to evolve with the passage of time. The topics revolve around the tendency of surfaces to impede chain relaxation and to stimulate new sorts of chain organization. These have been implicated in a variety of spectacular phenomena. Here is a listing of authors and affiliations: K. Binder (Johannes Gutenberg-Universit t Mainz, Germany); P.-G. de Gennes (College de France, France); E.P. Giannelis, R. Krishnamoorti, and E. Manias (Cornell University and University of Houston, USA); G.S. Grest (Exxon Research and Engineering Co., USA); L. Leger, E. Raphael, and H. Hervet (College de France, France); S.-Q. Wang (Case Western Reserve University, USA).

A totally new concept for clean surface processing of Si wafers is introduced in this book. Some fifty distinguished researchers and engineers from the leading Japanese semiconductor companies, such as NEC, Hitachi, Toshiba, Sony and Panasonic as well as from several universities reveal to us for the first time the secrets of these highly productive institutions. They describe the techniques and equipment necessary for the preparation of clean high-quality semiconductor surfaces as a first step in high-yield/high-quality device production. This book thus opens the door to the manufacturing of reliable nanoscale devices and will be extremely useful for every engineer, physicist and technician involved in the production of silicon semiconductor devices.

here, Herbert Baur provides a simple description of the theory of thermophysics of polymers. In order to illustrate the theoretical skeleton, he only treats the simple, easily comprehensible problems of polymer physics, yet, in detail. The main points covered are: thermally excited conformation isomery of polymers; phonon gas of ideal polymer crystals; the dissipative thermo-mechanical behaviour of polymers, new aspects of viscoelastic behavior, glass transistion, and crystallization.

This volume is devoted to the topic of "Monolayer and Sub monolayer Helium Films," which was the subject of a symposium held at Stevens Institute of Technology, June 7th and 8th, 1973. All the papers in this volume were presented at this symposium. The symposium was sponsored by Stevens Institute of Technology with support from the National Science Foundation and the Office of Naval Research, and had as Organizing Committee: Professor D. F. Brewer (University of Sussex), Professor J. G. Dash (University of Washington), Professor J. G. 'Daunt (Stevens Institute of Technology), Doctor V. J. Emery (Brookhaven National Laboratory), Professor E. Lerner (Stevens Institute of Technology), Doctor F. J. Milford (Battelle Memorial Institute), Doctor A. D. Novaco (Brookhaven National Laboratory), Professor F. Pollock (Stevens Institute of Technology), and Professor W. A. Steele (Pennsylvania State University). The symposium was largely devoted to papers on the topic of thin (unsaturated) helium films at low temperatures, many of which were of a review character. In addition some papers of a more general character were included in order to review some powerful techniques used for investigating surfaces at higher temperatures. The Editors wish to thank all the authors of these papers for their enthusiastic cooperation in the preparation of this volume."

Structural organization or disorganization in macromolecular systems has been an important subject of polymer physical chemistry during the last one or two decades. This volume summarizes the main lectures presented at the Osaka University Macromolecular Symposium OUMS '98 on Molecular Interactions and Time-Space Organization in Macromolecular Systems, where the following topics were discussed:crystallization kinetics, liquid crystals, phase separation, gelation, adhesion, complex formation, and self-organization, with emphasis on molecular interactions. Both these topics are hot issues at present and frequently are taken up as a main theme at a particular symposium. The present symposium invited leading theorists and experimentalists in these fields as guest speakers and is expected to attract the interest of a significant range of readers.

In recent years, with the advent of ?ne line lithographical methods, molecular beam epitaxy, organometallic vapour phase epitaxy and other experimental techniques, low dimensional structures having quantum con?nement in one, two and three dimensions (such as inversion layers, ultrathin ?lms, nipi's, quantum well superlattices, quantum wires, quantum wire superlattices, and quantum dots together with quantum con?ned structures aided by various other ?elds) have attracted much attention, not only for their potential in uncovering new phenomena in nanoscience, but also for their interesting applications in the realm of quantum e?ect devices. In ultrathin ?lms, due to the reduction of symmetry in the wave-vector space, the motion of the carriers in the direction normal to the ?lm becomes quantized leading to the quantum size e?ect. Such systems ?nd extensive applications in quantum well lasers, ?eld e?ect transistors, high speed digital networks and also in other low dimensional systems. In quantum wires, the carriers are quantized in two transverse directions and only one-dimensional motion of the carriers is allowed. The transport properties of charge carriers in quantum wires, which may be studied by utilizing the similarities with optical and microwave waveguides, are currently being investigated. Knowledge regarding these quantized structures may be gained from original research contributions in scienti?c journals, proceedings of international conferences and various - view articles.

This introductory level text addresses the broad range of nonequilibrium phenomena observed at short time scales. It focuses on the important questions of correlations and memory effects in dense interacting systems. Experiments on very short time scales are characterized, in particular, by strong correlations far from equilibrium, by nonlinear dynamics, and by the related phenomena of turbulence and chaos. The impressive successes of experiments using pulsed lasers to study the properties of matter and of the new methods of analysis of the early phases of heavy ion reactions have necessitated a review of the available many-body theoretical methods. The aim of this book is thus to provide an introduction to the experimental and theoretical methods that help us to understand the behaviour of such systems when disturbed on very short time scales.

"Nanotechnology" isa broad term that includes aspects of materials science, mesoscopicphysics, organicandinorganicchemistry, na- electronics, atmosphericchemistry, airpollution, and other?elds. The technology is very muchincurrent focus-at the beginning of the Third Millennium-and raises hopes for environmentally benign, resource-lean manufacturing of products of manykinds. One precursor to present-day nanotechnology used porous coatings, comprised of "ultra?ne" particles withdimensions inthe nanometer range, for absorption of thermal radiation on thermocouples, bolometers, and the like. These particles were prepared by gas-phase syntheses, speci?cally using species formed by nucleation andgrowth from a metalvapor - dergoing coolingby collisions withinert gas molecules. Such "inert gas evaporation" was explored inthe 1920s and 1930s see, for example, A.H. Pfund, Phys. Rev. 35 (1930) 1434]andwas investigated in moredetail in the 1960s and 1970s see, for example, K. Kimoto et al., Jpn. J. Appl. Phys. 2 (1963) 702; C.G. Granqvist and R.A. Buhrman, J. Appl. Phys.47 (1976) 2200]. Improved analytical capabilities(electron microscopy)as well as new applications (selective absorption of solar energy) were twoofthe r- sons for the renewed interest. Today, gas-phase synthesis of nanoparticles constitutesthe foundation for a pro?table butstill small industry. Aerosols, i.e., dispersions or suspensions of particles ina gas, form the background ?eld for contemporaryefforts in gas-phase nanotechnology. Interest inaerosol researchhistorically arose from the issues of atmospheric chemistry and physics, human health protection, and airpollution. Today, aerosol researchengagesa vast array of efforts inthese and related ?elds, andelsewherein work identi?ed as nanotechnology.

Critical phenomena arise in a wide variety of physical systems. Classi cal examples are the liquid-vapour critical point or the paramagnetic ferromagnetic transition. Further examples include multicomponent fluids and alloys, superfluids, superconductors, polymers and fully developed tur bulence and may even extend to the quark-gluon plasma and the early uni verse as a whole. Early theoretical investigators tried to reduce the problem to a very small number of degrees of freedom, such as the van der Waals equation and mean field approximations, culminating in Landau's general theory of critical phenomena. Nowadays, it is understood that the common ground for all these phenomena lies in the presence of strong fluctuations of infinitely many coupled variables. This was made explicit first through the exact solution of the two-dimensional Ising model by Onsager. Systematic subsequent developments have been leading to the scaling theories of critical phenomena and the renormalization group which allow a precise description of the close neighborhood of the critical point, often in good agreement with experiments. In contrast to the general understanding a century ago, the presence of fluctuations on all length scales at a critical point is emphasized today. This can be briefly summarized by saying that at a critical point a system is scale invariant. In addition, conformal invaTiance permits also a non-uniform, local rescal ing, provided only that angles remain unchanged."

This is an approachable introduction to the important topics and recent developments in the field of condensed matter physics. First, the general language of quantum field theory is developed in a way appropriate for dealing with systems having a large number of degrees of freedom. This paves the way for a description of the basic processes in such systems. Applications include various aspects of superfluidity and superconductivity, as well as a detailed description of the fractional quantum Hall liquid.

Biomaterials repair, reinforce or replace damaged functional parts of the (human) body. All mechanical and biological interactions between an implant and the body occur across the interface, which has to correspond as nearly as possible to its particular function. Much of the progress in adapting polymer materials for use in a biological environment has been obtained through irradiation techniques. For this reason the most recent developments in four key areas are reviewed in this special volume: (1) the analysis of the topology and the elemental composition of a functional surface, (2) the chemical modification of the surface which results in highly pure, sterile and versatile surfaces, (3) the sterilisation of implantable devices via ionising radiation and its possible effects on the structural mechanical properties of polymers, and (4) the radiation effects on living cells and tissues which are of particular importance for radiation protection and radiotherapy.

The application to Biology of the methodologies developed in Physics is attracting an increasing interest from the scientific community. It has led to the emergence of a new interdisciplinary field, called Physical Biology, with the aim of reaching a better understanding of the biological mechanisms at molecular and cellular levels. Statistical Mechanics in particular plays an important role in the development of this new field.

For this reason, the XXth session of the famous Sitges Conference on Statistical Physics was dedicated to "Physical Biology: from Molecular Interactions to Cellular Behavior." As is by now tradition, a number of lectures were subsequently selected, expanded and updated for publication as lecture notes, so as to provide both a state-of-the-art introduction and overview to a number of subjects of broader interest and to favor the interchange and cross-fertilization of ideas between biologists and physicists.

The present volume focuses on three main subtopics (biological water, protein solutions as well as transport and replication), presenting for each of them the on-going debates on recent results. The role of water in biological processes, the mechanisms of protein folding, the phases and cooperative effects in biological solutions, the thermodynamic description of replication, transport and neural activity, all are subjects that are revised in this volume, based on new experiments and new theoretical interpretations.

Timely information on scientific and engineering developments occurring in laboratories around the world provides critical input to maintaining the economic and technological strength of the United States. Moreover, sharing this information quickly with other countries can greatly enhance the productivity of scientists and engineers. These are some of the reasons why the National Science Foundation (NSF) has been involved in funding science and technology assessments comparing the United States and foreign countries since the early 1980s. A substantial number of these studies have been conducted by the World Technology Evaluation Center (WTEC) managed by Loyola College through a cooperative agreement with NSF. The National Science and Technology Council (NSTC), Committee on Technology's Interagency Working Group on NanoScience, Engineering and Technology (CT/IWGN) worked with WTEC to develop the scope of this Nanostucture Science and Technology report in an effort to develop a baseline of understanding for how to strategically make Federal nanoscale R&D investments in the coming years. The purpose of the NSTC/WTEC activity is to assess R&D efforts in other countries in specific areas of technology, to compare these efforts and their results to U. S. research in the same areas, and to identify opportunities for international collaboration in precompetitive research. Many U. S. organizations support substantial data gathering and analysis efforts focusing on nations such as Japan. But often the results of these studies are not widely available. At the same time, government and privately sponsored studies that are in the public domain tend to be "input" studies.

This book, featuring the most comprehensive treatment of Josephson junctions ever published, describes superconductor/two-dimensional-electron-gas (2DEG) structures, providing a better understanding of their transport properties. It also discusses the control of junctions using gate electrodes or injection currents, and the physical effects observed in these junctions.

Providing in a single volume all essential information on the physical properties of alkali halides, this book will be a valuable reference for solid-state physicists and materials scientists.

The fundamental physics of metallic magnetism is not yet satisfactorily understood and continues to be interesting. For instance, although the detail is yet to be clarified, magnetism is anticipated to be playing a principal role in producing the high Tc superconductivity of the oxides. This book has two major objectives. First, it intends to provide an introduction to magnetism of metals in a broad sense. Besides pursuing the mechanism of metallic magnetism itself, it attempts to fmd and actively analyze magnetic causes hidden hitherto unnoticed behind various physical phenomena. My foremost goal is to expose the fundamental role played by phonons in the mechanism of metallic magnetism. I demonstrate how such a view also helps to elucidate a broad spectrum of other observations. The second objective is to concisely introduce the standard many-body points of view and techniques necessary in studying solid physics in general. The book is intended to be self-contained and starts with Chapter I containing a brief summary on the rudiments of quantum mechanics and statistical mechanics including the method of second quantization. In the same spirit, the foundation of magnetism in general is summarized in Chapter 2 and that for metals in particular, the Stoner theory, in Chapter 3. In Chapter 4, various linear responses of metallic electrons are systematically discussed with emphasis on the role of magnetism in them.

The two volumes 165 and 166 Polyelectrolytes with Defined Molecular Architecture summarize recent progress in the field. The subjects comprise novel polyelectrolyte architectures including planar, cylindrical and spherical polyelectrolyte brushes as well as micelle, complex and membrane formation. Some solution properties such as conformation of flexible polyions, osmotic coefficients and electrophoretic properties are addressed along with recent progress in analytical theory and simulation.

As in other scientific fields, the importance of boundary areas in wood research, such as that between lignin chemistry and hemicellulose chemis- try, continues to increase. Although the utilization of individual wood components has advanced to an appreciable extent, research into oligo- merie or polymerie compounds of two or more different components has made little progress. By contrast, in other fields, glycoproteins and pro te- oglycans have been found to form biochemical active centers in enzymes and microbes. The association between lignin and carbohydrates in lignified plants was first recognized in 1866. However, research has advanced slowly because of difficulty in the isolation and determination of wood glycocon- jugates, whieh likely have an important influence on the formation of wood, pulping behavior, pulp quality and digestibility by ruminants. Most plants contain both hydrophilie polysaccharides and hydrophobie lignins in their tissues. Lignins have been recognized to not only give mechanieal strength or rigidity to a tree or wood, but also to prevent invasion by fungi, and provide cell wall material, especially in the tracheids and vessels that deliver water extracted from the soil to the top of woody plants. How- ever, in trees, lignins have been found to interact with the polysaccharides, partieularly hemicelluloses, with whieh they coexist, leading to the forma- tion of another chemical component, a kind of glycoconjugate. Therefore, it is necessary to inc1ude lignin or p-hydroxycinnamie acids in any discus- sion on wood hemieelluloses.

This second edition has been brought up to date by the inclusion of an extensive new chapter on aspects relevant to high-temperature superconductors. The new edition provides researchers, engineers and other scientists with an introduction to the field and makes useful supplementary reading for graduate students in low-temperature physics.

The history of scientific research and technological development is replete with examples of breakthroughs that have advanced the frontiers of knowledge, but seldom does it record events that constitute paradigm shifts in broad areas of intellectual pursuit. One notable exception, however, is that of spin electronics (also called spintronics, magnetoelectronics or magnetronics), wherein information is carried by electron spin in addition to, or in place of, electron charge. It is now well established in scientific and engineering communities that Moore's Law, having been an excellent predictor of integrated circuit density and computer performance since the 1970s, now faces great challenges as the scale of electronic devices has been reduced to the level where quantum effects become significant factors in device operation. Electron spin is one such effect that offers the opportunity to continue the gains predicted by Moore's Law, by taking advantage of the confluence of magnetics and semiconductor electronics in the newly emerging discipline of spin electronics. From a fundamental viewpoine, spin-polarization transport in a material occurs when there is an imbalance of spin populations at the Fermi energy. In ferromagnetic metals this imbalance results from a shift in the energy states available to spin-up and spin-down electrons. In practical applications, a ferromagnetic metal may be used as a source of spin-polarized electronics to be injected into a semiconductor, a superconductor or a normal metal, or to tunnel through an insulating barrier.

This is the first book that explains how to structure glass for micro- and nanophotonic applications. It deals with various glass compositions and their properties, and the interactions between glass and the electromagnetic waves used to modify it. The book also explores methods for influencing the geometrical microstructure of glass as well as methods to produce actual microdevices. It also details methods for influencing the geometrical microstructure of glasses.