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Books > Science & Mathematics > Physics > States of matter > General
Among various branches of polymer physics an important position is occupied by that vast area, which deals with the thermal behav ior and thermal properties of polymers and which is normally called the thermal physics of polymers. Historically it began when the un usual thermo-mechanical behavior of natural rubber under stretch ing, which had been discovered by Gough at the very beginning of the last century, was studied 50 years later experimentally by Joule and theoretically by Lord Kelvin. This made it possible even at that time to distinguish polymers from other subjects of physical investigations. These investigation laid down the basic principles of solving the key problem of polymer physics - rubberlike elasticity - which was solved in the middle of our century by means of the statistical thermodynamics applied to chain molecules. At approx imately the same time it was demonstrated, by using the methods of solid state physics, that the low temperature dependence of heat capacity and thermal expansivity of linear polymers should fol low dependencies different from that characteristic of nonpolymeric solids. Finally, new ideas about the structure and morphology of polymers arised at the end of the 1950s stimulated the development of new thermal methods (differential scanning calorimetry, defor mation calorimetry), which have become very powerful instruments for studying the nature of various states of polymers and the struc tural heterogeneity."
-Effects of Electric Fields on Block Copolymer Nanostructures By H. G. Schoberth, V. Olszowka, K. Schmidt, and A. Boeker -Nanopattern Evolution in Block Copolymer Films: Experiment, Simulations and Challenges By L. Tsarkova, G.J. Agur Sevink, and G. Krausch -Controlled Wrinkling as a Novel Method for the Fabrication of Patterned Surfaces By A. Schweikart, A. Horn, A. Boeker, and A. Fery -Layered Systems Under Shear Flow By D. Svensek and H. R. Brand -Thermal Diffusion in Polymer Blends: Criticality and Pattern Formation By W. Koehler, A. Krekhov, and W. Zimmermann -Foaming of Microstructured and Nanostructured Polymer Blends By H. Ruckdaschel, P. Gutmann, V. Altstadt, H. Schmalz, and A.H.E. Muller
There have been many recent and important developments based on effective field theory and the renormalization group in atomic, condensed matter, nuclear and high-energy physics. These powerful and versatile methods provide novel approaches to study complex and strongly interacting many-body systems in a controlled manner. The six extensive lectures gathered in this volume combine selected introductory and interdisciplinary presentations focused on recent applications of effective field theory and the renormalization group to many-body problems in such diverse fields as BEC, DFT, extreme matter, Fermi-liquid theory and gauge theories. Primarily aimed at graduate students and junior researchers, they offer an opportunity to explore fundamental physics across subfield boundaries at an early stage in their careers.
Critical regimes of two-phase flows with a polydisperse solid phase form the basis of such widespread industrial processes as separation of various powdery materials and minerals dressing. It is impossible to describe such complicated flows analytically. Therefore, this study concentrates on invariants experimentally revealed and theoretically grounded for such flows. This approach can be compared with the situation in gases, where in order to determine principal parameters of their state, one does not need to measure the kinetic energy and velocity of each molecule and find its contribution to the temperature and pressure. These parameters are determined in a simple way for the system on the whole. A novel conception of two-phase flows allowing the formulation of their statistical parameters is physically substantiated. On the basis of the invariants and these parameters, a comprehensive method of estimating and predicting mass transfer in such flows is developed. It is noteworthy that the presented results are mostly phenomenological. Such an approach can be successfully extended to the separation of liquids, gases and isotopes. The book is intended for students and specialists engaged in chemical technology, mineral dressing, ceramics, microelectronics, pharmacology, power generation, thermal engineering and other fields in which flows carrying solid particles are used in the technological process.
This comprehensive treatise reviews, for the first time, all the essential work over the past 160 years on the photoelastic and the closely related linear and quadratic electro-optic effects in isotropic and crystalline mate rials. Emphasis is placed on the phenomenal growth of the subject during the past decade and a half with the advent of the laser, with the use of high-frequency acousto-optic and electro-optic techniques, and with the discovery of new piezoelectric materials, all of which have offered a feedback to the wide interest in these two areas of solid-state physics. The first of these subjects, the photoelastic effect, was discovered by Sir David Brewster in 1815. He first found the effect in gels and subsequently found it in glasses and crystals. While the effect remained of academic interest for nearly a hundred years, it became of practical value when Coker and Filon applied it to measuring stresses in machine parts. With one photograph and subsequent analysis, the stress in any planar model can be determined. By taking sections of a three-dimensional model, complete three-dimensional stresses can be found. Hence this effect is widely applied in industry."
Time-Resolved Light-Scattering from Excitons investigates exciton
states in semiconductors and their relaxation processes by
time-resolved light-scattering.
This volume, the proceedings of a 1998 international workshop, provides experimental evidence of the effects of correlation on the physical, chemical, and mechanical properties of materials, as well as the theoretical/computational methodology that has been developed for their study.
This accessible text presents a unified approach of treating the microstructure and effective properties of heterogeneous media. Part I deals with the quantitative characterization of the microstructure of heterogeneous via theoretical methods; Part II treats a wide variety of effective properties of heterogeneous materials and how they are linked to the microstructure, accomplished by using rigorous methods.
Universality is one of the fascinating features of condensed matter physies: it is the property whereby systems of radieally different composition and structure ex- hibit similar behavior. In the mid-1960s the word entered usage to express the fact that the equations of state of several substances could be mapped onto one another near the critical point: critieal universality. Renormalization group theory in the early 1970s provided both an explanation and a sharper definition of universality. Systems with similar behavior - universality classes - correspond to the same fixed point of a renormalization group transformation. A number of brilliant con- tributions showed how the same concepts could be applied to non-thermodynamie systems, such as the statisties of self-avoiding walks or of connected clusters on a lattice. A few years later it was realized that chaotie dynamieal systems mayaiso exhibit some degree of universality, the paradigmatic example being the period doubling cascade in the iterated maps of the unit interval into itself.
Low-temperature X-ray diffraction (LTXRD) investigations offer many challenges to the diffractionist, not all of which are technical or scientific in nature. LTXRD studies can be frustrating: There are at least two reports of investigations ruined by the loss of crystals (grown with extreme difficulty) because of the widespread power failure and blackout in the northeastern United States in late 1965. LTXRD studies can cause discomfort: In several instances, "low temperatures" have been attained by opening all the windows in the X-ray laboratory. LTXRD studies can be dangerous: It was once reported that a crys tal was lost because a laboratory assistant fell down a flight of stairs and lay unconscious for about an hour on his way to refilling a liquid-nitrogen (LN2 ) dewar. This last report indicated the disposition of the crystal but not that of the laboratory assistant. However, in general, the results of low-temperature X-ray diffraction investigations cannot be obtained in any other manner, and one is well compensated for the effort expended in constructing and maintaining a low-temperature system. Crystal-structure analyses of solidified liquids and gases, phase transformation investigations, accurate crystal-structure analy ses and electron-density maps, thermal expansion measurements, and defect structure studies are a few of the many important applications of LTXRD."
On first acquaintance the electric arc discharge appears to be both visually attractive and a relatively simple phenomena to understand. To those of us engaged in prolonged study of this discharge, it remains a constantly exciting phenomena but we become only too aware of its complex nature and the difficulties in interpreting its bulk properties. This is particu larly true when the arc exists in a practical device and is subjected therefore to extreme conditions. In recent years the possibilities for the beginning of a fuller understanding of the complexities of the arc has arisen out of the excellent research and development work of scientists and engineers throughout the world. Much of this work has been stimulated not only by the need for the development of practical devices but also by the interest in thermonuclear fusion, mag netohydrodynamic generation and space exploration. In much of this work, the arc discharge has been a common feature as a source of study of high temperature plasma. As a result of this increased interest in the arc, the expert and would-be expert is now faced with the problem of assessing extensive newly published information on arc properties. Thus there is the need for texts which present to the engineer and researcher a review and summary of the present situation. This book is a valuable contribution to this task."
Understanding the structural organization of materials at the atomic scale is a lo- standing challenge of condensed matter physics and chemistry. By reducing the size of synthesized systems down to the nanometer, or by constructing them as collection of nanoscale size constitutive units, researchers are faced with the task of going beyond models and interpretations based on bulk behavior. Among the wealth of new materials having in common a "nanoscale" ngerprint, one can encounter systems intrinsically extending to a few nanometers (clusters of various compo- tions), systems featuring at least one spatial dimension not repeated periodically in space and assemblies of nanoscale grains forming extended compounds. For all these cases, there is a compelling need of an atomic-scale information combining knowledge of the topology of the system and of its bonding behavior, based on the electronic structure and its interplay with the atomic con gurations. Recent dev- opments in computer architectures and progresses in available computational power have made possible the practical realization of a paradygma that appeared totally unrealistic at the outset of computer simulations in materials science. This consists inbeing able to parallel (at least inprinciple) any experimental effort by asimulation counterpart, this occurring at the scale most appropriate to complement and enrich the experiment.
Although the subject of wave propagation in solids has a long history, the classical theory of elastic waves having been developed in the nine- teenth century by STOKES, POISSON, RAYLEIGH and KELVIN, the last two decades have seen a remarkable revival of interest in this subject among both theoreticians and experimenters. There' are a number of reasons for this; first, experimental methods for the generation and detection of high frequency mechanical waves have become available only with the advent of electronic techniques and of high speed photo- graphic recording apparatus. Secondly, the appearan
In recent years several improvements have been made in the manufacturing of resistive, superconducting and hybrid mag nets. Condensed matter physicists are nowadays doing ex periments in steady magnetic fields of up to 30 Tesla. But the field homogenity {/B}, required in a volume of the order of a 3 few cm is usually several orders of magnitude less severe than the one which is needed for high resolution NMR. Over the last 30 years, with each generation of new high resolution NMR spectrometers, from 100 MHz up to 600 MHz, taking advan tage of the increase in sensitivity and resolution, new areas of research have been opened in chemistry, physical chemistry and biochemistry. The generation of the 20 Tesla supercon ducting magnets is coming. Thus one may seriously start to consider high resolution NMR at 1 GHz. The purpose of this volume is to examine some of the advantages which can be obtained at such high frequencies and some of the problems we shall be facing. An important aspect of NMR at high field which is not presented in this volume concerns the design of the magnet. The building of a superconducting magnet, producing a field 10 3 higher than 20 T, with a field homogeneity IlB/B 10-, in a cm volume still remains today in 1990 a major challenge. Grenoble, France J. B. Robert Guest-Editor Professor J. B. Robert Service National des Champs Intenses B. P."
Cryogenics, a term commonly used to refer to very low temperatures, had its beginning in the latter half of the last century when man learned, for the first time, how to cool objects to a temperature lower than had ever existed na tu rally on the face of the earth. The air we breathe was first liquefied in 1883 by a Polish scientist named Olszewski. Ten years later he and a British scientist, Sir James Dewar, liquefied hydrogen. Helium, the last of the so-caBed permanent gases, was finally liquefied by the Dutch physicist Kamerlingh Onnes in 1908. Thus, by the beginning of the twentieth century the door had been opened to astrange new world of experimentation in which aB substances, except liquid helium, are solids and where the absolute temperature is only a few microdegrees away. However, the point on the temperature scale at which refrigeration in the ordinary sense of the term ends and cryogenics begins has ne ver been weB defined. Most workers in the field have chosen to restrict cryogenics to a tem perature range below -150 DegreesC (123 K). This is a reasonable dividing line since the normal boiling points of the more permanent gases, such as helium, hydrogen, neon, nitrogen, oxygen, and air, lie below this temperature, while the more common refrigerants have boiling points that are above this temperature. Cryogenic engineering is concerned with the design and development of low-temperature systems and components.
Noise in physical systems - as a consequence of the corpuscular nature of matter - conveys information about microscopic mechanisms determining the macroscopic behavior of the system. Besides being a source of information, noise also represents a source of annoying disturbances which affect information transMission along a physical system. Therefore, noise analysis can promote our insight into the behavior of a physical system, as well as our knowledge of the natural constraints imposed upon physical-information transmission channels and devices. In recent years the continuous scientific and technical interest in noise problems has led to a remarkable progress in the understanding of noise phenomena. This progress is reflected by the rich material presented at the Fifth International Conference on Noise in Physical Systems. The conference papers originally published in these proceedings cover the various aspects of today's noise research in the fields of solid-state devices, l/f-noise, magnetic and superconducting materials, measuring methods, and theory of fluctuations. Each session of the conference was introduced by one or two invited review lectures which are included in these proceedings in full length. The 12 invited papers and more than 40 contributed papers on specific topics (only three of them have been omitted from the proceedings since they will be published elsewhere) provide a comprehensive survey of the current state-of-the-art and recent advances of noise analysis.
Significant experimental work is devoted to the preparation of one and zero dimensional semiconductor structures in view of future electronic and optical devices which involve quantum effects. The aim is good control in the realisation of nanometer structures both in vertical and lateral direction. Conventional processing techniques based on lithography face inherent problems such as limited resolution and surface defects caused by reactive ion etching. During the last few years several research groups started working on direct syntheses of semiconductor nanostructures by combining epitaxial growth techniques such as molecular beam epitaxy and chemical vapour deposition with pre patterning of the substrate wafers. Another idea is based on island formation in strained layer heteroepitaxy. Zero and one dimensional structures with dimensions down to a few atomic distances have been realised this way. An important point is that the size of the quantum structures is controlled within the epitaxial deposition in a self-adjusting process. The main subjects of the book are: Theoretical aspects of epitaxial growth, selfassembling nanostructures and cluster formation, epitaxial growth in tilted and non-(001) surfaces, cleaved edge overgrowth, nanostructure growth on patterned silicon substrates, nanostructures prepared by selective area epitaxy or growth on patterned substrates, in-situ etching and device applications based on epitaxial regrowth on patterned substrates. The experimental work mainly concentrated on GaAs/A1GaAs, GaAs/InGaAs, InGaP/InP and Si/SiGe based semiconductor heterostructures. Growth related problems received special attention. The different concepts for preparation of low dimensional structures are presented to allow direct comparison and to identify new concepts for future research work.
This Briefs volume describes the properties and structure of elementary excitations in isotope low-dimensional structures. Without assuming prior knowledge of quantum physics, the present book provides the basic knowledge needed to understand the recent developments in the sub-disciplines of nanoscience isotopetronics, novel device concepts and materials for nanotechnology. It is the first and comprehensive interdisciplinary account of the newly developed scientific discipline isotopetronics.
The first part is devoted to colloidal particles and stochastic dynamics, mainly concerned with recent authoritative results in the study of interactions between colloidal particles and transport properties in colloids and ferrocolloids. Recent advances in non-equilibrium statistical physics, such as stochastic resonance, Brownian motors, ratchets and noise-induced transport are also reported. The second part deals with biological systems and polymers. Here, standard simulation methodology to treat diffusional dynamics of multi-protein systems and proton transport in macromolecules is presented. Results of nervous system, spectroscopy of biological membrane models, and Monte Carlo simulations of polymers chains are also discussed. The third part is concerned with granular materials and quantum systems, in particular an effective-medium theory for a random system is reported. Additionally, a comprehensive treatment of spin and charge order in the vortex lattice of the cuprates, both theoretical and experimental, is included. Thermodynamics analogies between Bose-Einstein condensation and black-body radiation are also presented.The last part of the book contains recent developments of certain topics of liquid crystals and molecular fluids, including nonequilibrium thermal light scattering from nematic liquid crystals, relaxation in the kinetic Ising model on the periodic in homogeneous chain, models for thermotropic liquid-crystals, thermodynamic properties of fluids with discrete potentials as well as of fluids determined from the speed of sound effective potentials, and second viral coefficient for polar fluids.
We present here the transcripts of lectures and talks which were delivered at the NATO ADVANCED STUDY INSTITUTE "Electrons in Disordered Hetals and at ~~etallic Surfaces" held at the State University of Ghent, Belgium between August 28 and September 9, 1978. The aim of these lectures was to highlight some of the current progress in our understanding of the degenerate electron 'liquid' in an external field which is neither uniform nor periodic. This theme brought together such topics as the electronic structure at metallic surfaces and in random metallic alloys, liquid metals and metallic glasses. As is the case in connection with infinite order ed crystals, the central issues to be discussed were the nature of the electronic spectra, the stability of the various phases and the occurrence of such phenomena as magnetism and supercon ductivity. In the theoretical lectures the emphasis was on detailed rea listic calculations based, more or less, on the density functional approach to the problem of the inhomogeneous electron liquid. How ever, where such calculations were not available, as in the case of magnetism in random alloys and that of metallic glasses, sim pler phenomenological models were used. The theoretical discussions were balanced by reviews of the most promising experimental techniques. Here the stress was on results and their relevance to the fundamental theory. lforeover, the attention had centered on those experiments which probe the electronic structure in the greatest detail.
The present volume represents the great majority of the papers presented on Sanibel Island at the first Symposium on Quantum Statistics and Many-Body Problems (January 26-29, 1975). In his Introductory Remarks, Professor Lawdin outlines the history of the original Symposia, and the genesis of the conference whose papers comprise this volume. We join him in his expression of thanks, and note, additionally, our gratitude to him and to Professors N. Y. Ohrn, J. R. Sabin, E. D. Adams, and John Daunt. The papers are grouped somewhat differently from their order of presentation. It seemed convenient to begin with the six papers which deal with sound propagation in one form or another, then have a two-paper diversion into solid Helium. The SHe superf1uid theme is picked up again with four papers on spin dynamics, orbit waves, etc., followed by a selection of five papers on a variety of experimental and theoretical aspects of the SHe superf1uid problem. Work in the areas of films, mono1ayers, and mixtures is presented next, followed by two papers on liquid ~He. We conclude with a selection of six papers on other quantum fluids and general statistical mechanics. We are most grateful to the contributors to this volume for their patience and cooperation; they have had as editors three utter novices! We have learned much, both scientifically and editorially. We hope that this volume will be of at least some help to others as well.
The articles in this book are derived from the Third International Conference of the same name, held June 29-July 3, 1998. Topics include: nonlinear exaltations in condensed systems, evolution of complex systems, dynamics and structure of molecular and biomolecular systems, mathematical models of transfer processes in nonlinear systems and numerical modeling and algorithms.
This is a book describing electronic structure theory and application within the framework of a methodology implemented in the computer code RSPt. In 1986, when the code that was to become RSPt was developed enough to be useful, it was one of the ?rst full-potential, all-electron, relativistic implem- tations of DFT (density functional theory). While RSPt was documented p- asitically in many publications describing the results of its application, it was many years before a publication explicitly describing aspects of the method appeared. In the meantime, several excellent all-electron, full-potential me- ods had been developed, published, and become available. So why a book about RSPt now? The code that became RSPt was initially developed as a personal research tool, rather than a collaborative e?ort or as a product. As such it required some knowledge of its inner workings to use, and as it was meant to be m- imally ?exible, the code required experience to be used e?ectively. These - tributes inhibited, but did not prevent, the spread of RSPt as a research tool. While applicable across the periodic table, the method is particularly useful in describing a wide range of materials, including heavier elements and c- pounds, and its ?exibility provides targeted accuracy and a convenient and accurate framework for implementing and assessing the e?ect of new models.
This volume contains the proceedings of a NATO Advanced Study Institute devoted to the study of dynamical correlation functions of the form (I) J e-lwt 6ft T- is an equilibrium average. In equation (1) it is useful to regard the product AB as the product of two operators in cases in which A and B refer to different spatial points in a condensed matter sys tem and/or in which A and B behave dynamically in a quasiharmonic way. In the second case, one has a two quasiparticle correlation function and CAB;AB(w) gives information about quasiparticle inter actions. Condensed matter physics has increasingly turned its attention to correlation functions of this type during the last 15 years, partly because the two point and/or one-particle correlation functions have by now been very thoroughly studied in many cases. The study of four point and/or two quasiparticle correlations has proceeded somewhat independently in several diverse fields of condensed matter physics and it was one purpose of the institute to bring experts from these different fields together to describe the current state of their art to each other and to advanced students."
Introduction to Thermoelectricity is the latest work by Professor Julian Goldsmid drawing on his 55 years experience in the field. The theory of the thermoelectric and related phenomena is presented in sufficient detail to enable researchers to understand their observations and develop improved thermoelectric materials. The methods for the selection of materials and their improvement are discussed. Thermoelectric materials for use in refrigeration and electrical generation are reviewed. Experimental techniques for the measurement of properties and for the production of thermoelements are described. Special emphasis is placed on nanotechnology which promises to yield great improvements in the efficiency of thermoelectric devices. Chapters are also devoted to transverse thermoelectric effects and thermionic energy conversion, both techniques offering the promise of important applications in the future. |
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