Starting at the dawn of science, History of Industrial Gases traces the development of gas theory from its Aristotelian roots to its modern achievements as a global industry. Dr. Almqvist explores how environmental protection, geographical areas, and the drive for higher purity and efficiency affected development in the nineteenth and twentieth centuries, and how they will influence the future of this rapidly expanding industry. The roles of major contributing companies are also discussed to provide an informative and thought-provoking treatise valuable to anyone who studies or works in this fascinating field.

Mixed valency is one of various names used to describe compounds which contain ions of the same element in two different formal states of oxidation. The existence of mixed valency systems goes far back into the geological evolutionary history of the earth and other planets, while a plethora of mixed valency minerals has attracted attention since antiquity. Indeed, control of the oxidation states of Fe in its oxides (FeO, Fe304' Fe203) was elegantly used in vase painting by the ancient Greeks to produce the characteristic black and red Attic ceramics (Z. Goffer, "Archaeological Chemistry," Wiley, New York, 1980). It was, however, only 25 years ago that two reviews of mixed valency appeared in the literature almost simultaneously, signalling the first attempt to treat mixed valency systems as a separate class of compounds whose properties can be correlated with the molecular and the electronic structure of their members. Then mixed valency phenomena attracted the interest of disparate classes of scientists, ranging from synthetic chemists to solid state physicists and from biologists to geologists. This activity culminated with the NATO ASI meeting in Oxford in 1979. The 1980's saw again a continuing upsurge of interest in mixed valency. Its presence is a necessary factor in the search for highly conducting materials, including molecular metals and superconductors. The highly celebrated high T c ceramic superconducting oxides are indeed mixed valency compounds.

In recent years, the technology of cryogenic comminution has been widely applied in the field of chemical engineering, food making, medicine production, and particularly in recycling of waste materials. Because of the increasing pollution of waste tires and the shortage of raw rubber resource, the recycling process for waste rubber products has become important and commercially viable. This technology has shown a great number of advantages such as causing no environmental pollution, requiring low energy consumption and producing high quality products. Hence, the normal crusher which was used to reclaim materials, such as waste tires, nylon, plastic and many polymer materials at atmospheric 12 temperature is being replaced by a cryogenic crusher. * In the cryogenic crusher, the property of the milled material is usually very sensitive to temperature change. When a crusher is in operation, it will generate a great deal of heat that causes the material temperature increased. Once the temperature increases over the vitrification temperature, the material property will change and lose the brittle behavior causing the energy consumption to rise sharply. Consequently, the comminution process cannot be continued. Therefore, it is believed that the cryogenic crusher is the most critical component in the cryogenic comminution system. The research on the temperature increase and energy consumption in the cryogenic crusher is not only to reduce the energy consumption of the crasher, but also to reduce the energy consumption of the cryogenic system.

One of the most spectacular consequences of the description of the superfluid condensate in superfluid He or in superconductors as a single macroscopic quantum state is the quantization of circulation, resulting in quantized vortex lines. This book draws no distinction between superfluid He3 and He4 and superconductors. The reader will find the essential introductory chapters and the most recent theoretical and experimental progress in our understanding of the vortex state in both superconductors and superfluids, from lectures given by leading experts in the field, both experimentalists and theoreticians, who gathered in Cargese for a NATO ASI. The peculiar features related to short coherence lengths, 2D geometry, high temperatures, disorder, and pinning are thoroughly discussed. "

This volume includes 11 contributions to the 23rd Conference of the European Colloid and Interface Society which took in Antalya, Turkey between September 6th and 11th, 2009. The contributions from leading scientists cover a broad spectrum of topics concerning* Self Assembly* Interfacial Phenomena* Colloidal Dispersions and Colloidal Stability* Polymer Solution, Gels and Phase Behaviour* Nanostructured Materials* Biomaterials and Medical AspectsDue to the increasing significance of Colloid and Interface Science for both scientific and technical applications where scientific principles also contribute to new technologies in fast improving Nanotechnology and Medical Science, this book will be an essential source of information with respect to recent developments and results related to this field.

Electronic structure and physical properties of strongly correlated materials containing elements with partially filled 3d, 4d, 4f and 5f electronic shells is analyzed by Dynamical Mean-Field Theory (DMFT). DMFT is the most universal and effective tool used for the theoretical investigation of electronic states with strong correlation effects. In the present book the basics of the method are given and its application to various material classes is shown. The book is aimed at a broad readership: theoretical physicists and experimentalists studying strongly correlated systems. It also serves as a handbook for students and all those who want to be acquainted with fast developing filed of condensed matter physics.

Semiconducting and Insulating Crystals details how absorption spectroscopy provides information on the nature, concentration, charge state and configuration of impurities in crystals and also on their kinetics and transformations under annealing. After an introduction of the bulk optical properties of semiconductors and insulators and of impurities in crystals, this book presents the physical bases necessary for the understanding of impurity spectra. The description of various set-ups and accessories used in absorption spectroscopy is followed by a presentation of experimental results on specific impurities and classes of impurities and their relation with those obtained by various computation and by other experimental techniques.

The area of macromolecular and supramolecular science and engineering has gained substantial interest and importance during the last decade and many applications can be envisioned in the future. The rapid developments in this interdisciplinary area justify a snapshot of the state-of-the-art in the research of materials and processes that is given in this monograph. This monograph is based primarily on synthetic architectures and systems covered by the contents of selected plenary and invited lectures delivered at the 1st International Symposium on Macro- and Supramolecular Architectures and Materials (MAM-01): Biological and Synthetic Systems, which was held from 11-14 April 2001 on the international campus of the Kwangju Institute of Science and Technology (K-JIST) in Kwangju, South Korea. In addition, it contains several complementing contributions in this novel field of science dealing with synthetic architectures and represents a unique compilation of reviewed research accounts of the in-depth knowledge of macromolecular and supramolecular materials and processes. It comprises 22 pioneering chapters written by 64 renowned experts from 13 different countries.

Pneumatic conveying is one of the most popular methods of handling bulk powdered and granular materials in mining, chemical and agricultural industries. This 3rd edition of this successful book covers both theoretical and practical aspects of the subject. It is unique in its blending of academic materials and good industrial design techniques. Each topic is covered in depth, with emphasis placed on the latest techniques, hardware systems and design and research methodology. Its comprehensive worked examples and table ensure that the reader need not consult any other reference material. In this 3rdedition new sections on simulation and modelling have been added, while the use of tomography as a tool for monitoring pneumatic conveying is also covered."

A revolution similar to that brought by CCDs to visible astronomy is still ahead in IR and submillimeter astronomy. There is certainly no wavelength range which has, over the past several years, seen such impressive advances in technology: large-scale detector arrays, new designs for cooling in space, lightweight mirror technologies. Scientific cases for observing the cold universe are outstanding. Observations in the FIR/Submm range will provide answers to such fundamental questions as: What is the spectrum of the primordial fluctuations? How do primeval galaxies look? What are the first stages of star formation? Most of the international space missions that have been triggered by these questions are presented in detail here. Technological issues raised by these missions are reviewed, as are the most recent achievements in cooling and detector technologies.

This sixth Volume of the International Workshop on Instabilities and Nonequilibrium Structures is dedicated to the memory of my friend Walter Zeller, Professor of the Universidad C'at6lica df' Valparaiso and Vice-Director of the Workshop. Walter Zeller was much more than an organizer of this meeting: his enthusiasm, dedication and critical views were many times the essential ingredients to continue with a task which in occasions faced difficulties and incomprehensiolls. It is in great part due to him that the workshop has adquired to-day tradition. maturity and international recognition. This Volume should have been coedited by Walter and it is with df'ep emotion that I learned that his disciples Javier Martinez and Rolando Tiemann wanted as a last hommage to their Professor and friend to coedit tfus book. No me seria posible terminal' estas lineas sin pensar en la senora Adriana Gamonal de Zelln. qUf' ella encuentre en este libro la admiraci6n y reconocimiento hacia su marido de quiPIlf's [l\Prall sus discipulos, colegas y amigos.

This book presents mathematical models that arise in current photographic science. The book contains seventeen chapters, each dealing with one area of photographic science, and a final chapter containing exercises. Each chapter, except the two introductory chapters, begin with general background information at a level understandable by graduate and undergraduate students. It then proceeds to develop a mathematical model, using mathematical tools such as ordinary differential equations, partial differential equations, and stochastic processes. Next, some mathematical results are mentioned, often providing a partial solution to problems raised by the model. Finally, most chapters include open problems. The last chapter of the book contains "Modeling and Applied Mathematics" exercises based on the material presented in the earlier chapters. These exercises are intended primarily for graduate students and advanced undergraduates.

Magnetism encompasses a wide range of systems and physical phenomena, and its study has posed and exposed both important fundamental problems and many practical applications. Recently, several entirely new phenomena have thus been discovered, generated through cooperative behaviour which could not have been predicted from a knowledge of `one-spin' states. At the same time, advances in sample preparation, experimental technique, apparatus and radiation sources, have led to increasing precision in the investigation and exposure of greater subtleties in magnetic thin films, multilayers and other systems. Examples of unexpected and conceptually new phenomena occur in strongly correlated and fluctuating quantum systems, producing effects such as Haldane and spin-Peierls gaps, solitons, quantum spin glasses and spin liquids. The discovery and elucidation of these `emerging properties' is a central theme in modern condensed matter physics. The present book comprises a series of chapters by world experts, covering both theoretical and experimental aspects. The approach is pedagogical and tutorial, but fully up to date, covering the latest research. The level is appropriate to graduate researchers who may either be just moving into the field or who are already active in condensed matter physics.

An extensive body of research is involved in pushing miniaturisation to its physical limit, encompassing the miniaturisation of electronic devices, the manipulation of single atoms by scanning tunnelling microscopy, bio-engineering, the chemical synthesis of complex molecules, microsensor technology, and information storage and retrieval. In parallel to these practical aspects of miniaturisation there is also the necessity to understand the physics of small structures. Ultimate Limits of Fabrication and Measurement brings together a number of leading articles from a variety of fields with the common aim of ultimate miniaturisation and measurement.

Observation, Prediction and Simulation of Phase Transitions in Complex Fluids presents an overview of the phase transitions that occur in a variety of soft-matter systems: colloidal suspensions of spherical or rod-like particles and their mixtures, directed polymers and polymer blends, colloid--polymer mixtures, and liquid-forming mesogens. This modern and fascinating branch of condensed matter physics is presented from three complementary viewpoints. The first section, written by experimentalists, emphasises the observation of basic phenomena (by light scattering, for example). The second section, written by theoreticians, focuses on the necessary theoretical tools (density functional theory, path integrals, free energy expansions). The third section is devoted to the results of modern simulation techniques (Gibbs ensemble, free energy calculations, configurational bias Monte Carlo). The interplay between the disciplines is clearly illustrated. For all those interested in modern research in equilibrium statistical mechanics.

The last decade has witnessed significant advances in the ability to generate short light pulses throughout the optical spectrum. These developments have had a tremendous impact on the field of chemical dynamics. Fundamental questions concerning chemical reactions, once thought to be unaddressable, are now easily studied in real-time experiments. Ultrafast spectroscopies are currently being used to study a variety of fundamental chemical phenomena. This book focuses on some of the experimental and associated theoretical studies of reactions in clusters, liquid and solid media. Many of the advances in our understanding of the fundamental details of chemical reactivity result from the interplay of experiment and theory. This theme is present in many of the chapters, indicating the pervasiveness of a combined approach for eludicating molecular models of chemical reactions. With parallel developments in computer simulation, complex chemical sys tems are being studied at a molecular level. The discussions presented in this book recount many areas at the forefront of "ultrafast chemistry". They serve the purpose of both bringing the expert up to date with the work being done in many laboratories as well as introducing those not directly involved in this field to the diverse set of problems that can be studied. I hope that this book conveys the excitement that both I and the other authors in this volume feel about the field of ultrafast chemistry. John D. Simon 1993 1.D. Simon (ed.), Ultrafast Dynamics of Chemical Systems, vii.

This volume is an outgrowth of the Second International Workshop on Macroscopic Quantum Coherence and Computing held in Napoli, Italy, in June 2000. This workshop gathered a number of experts from the major Universities and Research Institutions of several countries. The choice of the location, which recognizes the role and the traditions of Naples in this field, guaranteed the participants a stimulating atmosphere. The aim of the workshop has been to report on the recent theoretical and experimental results on the macroscopic quantum coherence of macroscopic systems. Particular attention was devoted to Josephson devices. The correlation with other atomic and molecular systems, exhibiting a macroscopic quantum behaviour, was also discussed. The seminars provided both historical overview and recent theoretical ground on the topic, as well as information on new experimental results relative to the quantum computing area. The first workshop on this topic, held in Napoli in 1998, has been ennobled by important reports on observations of Macroscopic Quantum Coherence in mesoscopic systems. The current workshop proposed, among many stimulating results, the first observations of Macroscopic Quantum Coherence between macroscopically distinct fluxoid states in rf SQUIDs, 20 years after the Leggett's proposal to experimentally test the quantum behavior of macroscopic systems. Reports on observations of quantum behaviour in molecular and magnetic systems, small Josephson devices, quantum dots have also been particularly stimulating in view of the realization of several possible q-bits.

Deng Feng Wang was born February 8, 1965 in Chongqing City, China and died August 15, 1999 while swimming with friends in the Atlantic Ocean off Island Beach State Park, New Jersey. In his brief life, he was to have an influence far beyond his years. On August 12th 2000, The Deng Feng Wang Memorial Conference was held at his alma mater, Princeton University, during which Deng Feng's mentors, collaborators and friends presented scientific talks in a testimonial to his tremendous influence on their work and careers. The first part of this volume contains proceedings contributions from the conference, with plenary talks by Nobel Laureate Professor Phil Anderson of Princeton University and leading Condensed Matter Theorists Professor Piers Coleman of Rutgers University and Professor Christian Gruber of the University of Lausanne. Other talks, given by collaborators, friends and classmates testify to the great breadth of Deng Feng Wang's influence, with remarkable connections shown between seemingly unrelated areas in physics such as Condensed Matter Physics, Superconductivity, One-Dimensional Models, Statistical Physics, Mathematical Physics, Quantum Field Theory, High Energy Theory, Nuclear Magnetic Resonance, Supersymmetry, M-Theory and String Theory, in addition to such varied fields outside of physics such as Oil Drilling, Mixed Signal Circuits and Neurology. The second part of the volume consists of reprints of some of Deng Feng Wang's most important papers in the areas of Condensed Matter Physics, Statistical Physics, Magnetism, Mathematical Physics and Mathematical Finance. This volume represents a fascinating synthesis of a wide variety of topics, and ultimately points to the universality of physics and of science as a whole. As such, it represents a fitting tribute to a remarkable individual, whose tragic death will never erase his enduring influence.

Polymers are substances made of macromolecules formed by thousands of atoms organized in one (homopolymers) or more (copolymers) groups that repeat themselves to form linear or branched chains, or lattice structures. The concept of polymer traces back to the years 1920's and is one of the most significant ideas of last century. It has given great impulse to indus try but also to fundamental research, including life sciences. Macromolecules are made of sm all molecules known as monomers. The process that brings monomers into polymers is known as polymerization. A fundamental contri bution to the industrial production of polymers, particularly polypropylene and polyethylene, is due to the Nobel prize winners Giulio Natta and Karl Ziegler. The ideas of Ziegler and Natta date back to 1954, and the process has been improved continuously over the years, particularly concerning the design and shaping of the catalysts. Chapter 1 (due to A. Fasano ) is devoted to a review of some results concerning the modelling of the Ziegler- Natta polymerization. The specific ex am pie is the production of polypropilene. The process is extremely complex and all studies with relevant mathematical contents are fairly recent, and several problems are still open.

An innovative, unified, and comprehensive treatment of the geometric and electronic structure of surfaces. The book emphasizes fundamental aspects, such as the principles of surface crystallography and thermodynamics, the forces driving the rearrangement of the atoms, and the relationship between bonding and electronic structure. It especially illuminates the relationship between surface orientation, chemistry, energetics, and the resulting properties. Principles of Surface Physics develops general physical arguments and methods that enable readers to analyse novel surfaces and interfaces of new materials. This makes the book an indispensable reference to all those studying growth, surface-molecule interactions, self-assembled structures, and materials engineering.

Some twenty-three years after the discovery of pulsars and their identification as rotating neutron stars, neutron star physics may be regarded as comingofage. Pul sars and accreting neutron stars have now been studied at every wavelength, from the initial radio observations, through optical, X-, and "{-ray, up to the very recent observations in the TeV region, while theorists have studied in some detail relevant physical processes both outside and inside neutron stars. As a result, comparisonof theory with observation provides a test ofour theoretical ideas in fields as diverse as neutron and nuclear matter, superfluidity and superconductivity, the acceleration of high energy particles, and the generation and maintenance of intense magnetic fields. For example, through observations of glitches and post glitch behavior of pulsars, it has become possible to establish the presence ofsuperfluid neutron mat ter in the inner crust of neutron stars, and to determine some of its properties, while neutron stars in compact binary systems offer one ofthe most efficient energy generation mechanisms known. It is in fact the interactive interpretation of these ,diverse pieces of information that can lead to major advances in our understanding of the physics of these exotic objects, and justifies the characterization of neutron stars as hadron physics laboratories.

The importance of safety in any scientific endeavor is never in question. However, when cryogenic temperatures are involved, safety is especially important. In addition to observing the normal precautions, one must also take into account the variations of physical properties that occur at low temperatures. At these tempera tures, some properties not only exhibit large differences from their normal values but also can vary widely over a small temperature range. Before any cryogenic project is started, a thorough knowledge of the possible hazards is necessary. Only in this way can the safest operation be attained. Over the hundred-year history of cryogenic research, this has been shown to be the case. Keeping this requirement in mind is an essential ingredient in the quest for accident-free work. The past four or five decades have seen a great expansion of cryogenic technology. Cryogenic liquids, such as oxygen, nitrogen, hydrogen, and helium, have become commonly used in a number of different applications and are easily available in any part of the United States and, indeed, almost anywhere in the world. Not only are these liquids available, they have become less expensive and also available in ever larger quantities. As quantities increase, so also do the conse quences of mishaps. The future seems to hold promise of ever larger and more widespread use of the common cryogens. Thus, the importance of safety also increases as time progresses.

This monograph describes mathematical models that enable prediction of phase compositions for various technological processes, as developed on the base of a complex physico-chemical analysis of reaction. It studies thermodynamics and kinetics of specific stages of complex pyrometallurgical processes involving boron, carbon, sulfur, tungsten, phosphorus, and many more, as well as their exposure to all sorts of factors.

First and foremost, this enables to optimize processes and technologies at the stage of design, while traditional empirical means of development of new technologies are basically incapable of providing an optimal solution. Simulation results of metals and alloys production, welding and coating technologies allow obtaining materials with pre-given composition, structure and properties in a cost-saving and conscious manner. Moreover, a so-called "inverse problem," i.e., selecting source materials which would ensure the required results, cannot be solved by any other means.

The contents of this book correspond to Sessions VII and VIII of the International Workshop on Instabilities and Nonequilibrium Structures which took place in Vifia del Mar, Chile, in December 1997 and December 1999, respectively. We were not able to publish this book before and we apologize for this fact to the authors and participants of the meeting. We have made an effort to actualize the courses and articles which have been reviewed by the authors. Both Workshops were organized by Facultad de Ciencias Fisicas y Matematicas, Universidad de Chile, Instituto de Fisica of Universidad Cat61ica de Valparaiso and Centro de Fisica No Lineal y Sistemas Complejos de Santiago. We are glad to acknowledge here the support of the Facultad de Ingenieria of Universidad de los Andes of Santiago which also be from now on one of the organizing Institutions of future Workshops. Enrique Tirapegui PREFACE This book is divided in two parts. In Part I we have collected the courses given in Sessions VII and VIII of the Workshop and in Part II we include a selection of the invited Conferences and Seminars presented at both meetings.