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Books > Science & Mathematics > Physics > States of matter > General
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The liquid crystalline state may be identified as a distinct and unique state of matter which is characterised by properties which resemble those of both solids and liquids. It was first recognised in the middle of the last century through the study of nerve myelin and derivatives of cholesterol. The research in the area really gathered momentum, however, when as a result of the pioneering work of Gray in the early 1970's organic compounds exhibiting liquid crystalline properties were shown to be suitable to form the basis of display devices in the electronic products. The study of liquid crystals is truly multidisciplinary and has attached the attention of physicists, biologists, chemists, mathematicians and electronics engineers. It is therefore impossible to cover all these aspects fully in two small volumes and therefore it was decided in view of the overall title of the series to concentrate on the structural and bonding aspects of the subject. The Chapters presented in these two volumes have been organised to cover the following fundamental aspects of the subiect. The calculation of the structures of liquid crystals, an account of their dynamical properties and a discussion of computer simulations of liquid crystalline phases formed by Gay Berne mesogens. The relationships between molecular conformation and packing are analysed in some detail. The crystal structures of liquid crystal mesogens and the importance of their X ray scattering properties for characterisational purposes are discussed.
This book provides tools well suited for the quantitative
investigation of semiconductor electron microscopy. These tools
allow for the accurate determination of the composition of ternary
semiconductor nanostructures with a spatial resolution at near
atomic scales. The book focuses on new methods including strain
state analysis as well as evaluation of the composition via the
lattice fringe analysis (CELFA) technique. The basics of these
procedures as well as their advantages, drawbacks and sources of
error are all discussed. The techniques are applied to quantum
wells and dots in order to give insight into kinetic growth effects
such as segregation and migration. In the first part of the book
the fundamentals of transmission electron microscopy are provided.
These are needed for an understanding of the digital image analysis
techniques described in the second part of the book. There the
reader will find information on different methods of
have advances in of The last few seen our understanding revolutionary years heterostructures. An amount the electronic of enormous properties quantum undertaken both the and the theoretical of research has been on experimental in nanostructures. The field vast of electronic now covers a aspects transport and extensive number of review of an books, articles, spectrum topics, papers and conference continue to be in this area. published Complete proceedings of this and field is the of this book. beyond exciting evolving scope coverage We refer the interested reader to of the excellent and some comprehensive books and conference on this proceedings subject. Much has been made in our of confined understanding quantum progress A's is well it is to construct heterostruc known, possible quantum systems. tures which well as one dimensional are approximated quasi two dimensional, zero dimensional Our interest here is in the of or properties particles systems. We brief andfields in two dimensional a intro quasi (2 D) systems. provide duction to the of 2 D in to motion in 2 D systems, particular systems physics the confined within finite For we will assume that a area. simplicity, generally Such confined is defined an infinite hard wall a by potential. system boundary We will 2 D will be referred to as a or as a wire.
This comprehensive series covers the science and technology of zeolites and all related microporous and mesoporous materials. Authored by renowned experts, volume 3 deals with the most widely employed techniques for the post-synthesis modification of molecular sieves.
I welcome the opportunity to have my book translated, because of the great emphasis on two-phase flow and heat transfer in the English-speaking world, as related to research, university education, and industrial practice. The 1988 Springer-Verlag edition of "Warmeiibergang beim Kondensieren und beim Sieden" has been enlarged to include additional material on falling film evaporation (Chapter 12) and pressure drop in two-phase flow (Chapter 13). Minor errors in the original text have also been corrected. I would like to express my sincere appreciation to Professor Green, Asso ciate Professor of German at Rensselaer, for his excellent translation and co operation. My thanks go also to Professor Bergles for his close attention to technical and linguistic details. He carefully read the typescript and made many comments and suggestions that helped to improve the manuscript. I hope that the English edition will meet with' a favorable reception and contribute to better understanding and to progress in the field of heat transfer in condensation and boiling. February 1992 K. Stephan Preface to the German-Language Edition This book is a continuation of the series "Heat and Mass Transfer" edited by U. Grigull, in which three volumes have already been published. Its aim is to acquaint students and practicing engineers with heat transfer during condensa tion and boiling, and is intended primarily for students and engineers in mechanical, chemical, electrical, and industrial processing engineering."
While books have been written on many topics of Polymer Science, no compre hensive treatise on long chain branching has ever been composed. This series of reviews in Volume 142 and 143 of Advances in Polymer Science tries to fill this gap by highlighting active areas of research on branched polymers. Long chain branching is a phenomenon observed in synthetic polymers and in some natural polysaccharides. It has long been recognized as a major mole cular parameter of macromolecules. Its presence was first surmised by H. Stau dinger and G. V. Schuh (Ber. 68, 2320, 1935). Interestingly, their method of iden tification by means of the abnormal relation between intrinsic viscosity and molecular weight has survived to this day. Indeed, the most sophisticated method for analysis of long chain branching uses size exclusion fractionation with the simultaneous recording of mass, molecular weight and intrinsic visco sity of the fractions. In the 1940s and 1950s, random branching in polymers and its effect on their properties was studied by Stockmayer, Flory, Zimm and many others. Their work remains a milestone on the subject to this day. Flory dedicated several chapters of his "Principles of Polymer Chemistry" to non linear polymers. Especially important at that time was the view that randomly branched polymers are inter mediates to polymeric networks. Further developments in randomly branched polymers came from the introduction of percolation theory. The modern aspec ts of this topic are elaborated here in the chapter by W. Burchard.
With contributions by: R.H. Boyd; B.G. Sumpter, D.W. Noid, G.L. Liang, B. Wunderlich; M.D. Ediger, D.B. Adolf; R.-J. Roe; I. Bahar, B. Erman, L. Monnerie; A.A. Gusev, F. Muller-Plathe, W.F. van Gunsteren, U.W. Suter; L.R. Dodd, D.N. Theodorou; E. Leontidis, J.J. de Pablo, M. Laso, U.W. Suter; K.S. Schweizer."
The aesthetically pleasing molecular architectures of fullerenes and nanotubes are appealing not only because of their beauty but also because they are responsible for the many unprecedented chemical and physical properties of this compound class. Although succession of exciting new discoveries continues unabated fullerene research has become a mature science. It is now possible to predict fullerene chemistry, to design new structure variations like open fullerene clusters, heterofullerenes and endohedral fullerenes, and to develop fullerene materials and modified nanotubes with high potential for technological applications. This volume represents the state-of-the-art of fullerene research, focussing on areas showing high potential for future growth and practical applications. The authors are leading scientists whose groups are making major contributions in the field.
This book reviews recent advances in polymer swelling resulting from the use of novel microporous composite films. It offers a new approach to understanding sorption processes in polymer-liquid systems based on the molecular structures of the sorbed molecules and the repeat unit of the sorbent polymer. It is shown how the adsorption parameters obtained in these studies relate meaningfully with the Flory-Huggins interaction parameters. This implies that these adsorption parameters have relevance not only for swelling and drying of polymers, but also for other phenomena in which molecular sorption plays an important role, such as in chromatography and in membrane permeation.
This series presents critical reviews of the present and future trends in polymer and biopolymer science including chemistry, physical chemistry, physics and materials science. It is addressed to all scientists at universities and in industry who wish to keep abreast of advances in the topics covered. Impact Factor Ranking: Always number one in Polymer Science. More information as well as the electronic version of the whole content available at: www.springerlink.com
This Cumulative Index of Structure Reports contains all the structures for the years 1913-1980 (Volumes 1 to 46B) and the authors for the latest 10-year period, 1971- 1980 (Volumes 37B to 46B). The arrangement in the classified structure index is as outlined on pages VII-VIII. University of Guelph, G. FERGUSON Guelph, Ontario, Canada [VI] VII ARRANGEMENT Classified Organic Index (Page 1) Each entry gives the formula, name, and Strukturbericht and Structure Reports references. The entries are arranged in accordance with the classification scheme based on chemical structure of the Cambridge Crystallographic Data Centre; within each class the order is by formula. The formula index will help to locate a compound for which the classification is doubtful. The classification is: (0) Aliphatic hydrocarbons and derivatives 1 Aliphatic carboxylic acid derivatives 2 Aliphatic carboxylic acid salts (&JmOnium, IA, IIA . . tals) 3 Aliphatic lllllines 4 Aliphatic (N and S) COIIIJ>OWids 7 Nitriles (aliphatic and aroutic) 8 Urea compounds (aliphatic and aromatic) 9 Nitrogen-nitrogen c0111pounds (aliphatic and aromatic) 10 Nitrogen-oxygen compoWids (aliphatic and aroutic) 11 Sulphur and selenium COIIIpounds 12 Carbonium ions, carbanions, radicals 13 Benz.
Most of the untreated surfaces of polymers used in industry are not hydrophilic but hydrophobic. It is, therefore, difficult to bond these nonpolar polymer sur faces directly to other substances like adhesives, printing inks, and paints because they generally consist of polar compounds. On the other hand, polymer surfaces generally adsorb proteins when brought into direct contact with a bio logical system, resulting in cell attachment or platelet aggregation. The protein adsorption and attachment of biological components trigger a subsequent series of mostly adverse biological reactions toward the polymeric materials. Therefore, the technologies for surface modification of polymers or regulation of the polymer surface interaction with other substances have been of prime importance in polymer applications from the advent of polymer industries. Some of the technologies have been directed to introduction of new function alities onto polymer surfaces. The new functionalities introduced include improved surface hydrophilicity, hydrophobicity, bio compatibility, conductivi ty, anti-fogging, anti-fouling, grazing, surface hardness, surface roughness, adhesion, lubrication, and antistatic property. Theoretically, there is a large dif ference in properties between the surface and the bulk of a material and only the outermost surface is enough to be taken into consideration when the sur face properties are concerned. However, this is not the case for polymer surfaces, as the physical structure of the outermost polymer surface is generally not fixed but continuously changing with time due to the microscopic Brownian motion of polymer segments."
Self-assembly is undoubtedly a topic of special interest in current chemistry and is related to very wide scientific areas. Recent progress in this field seems to be featured by the construction of well-defined discrete systems exploiting complementary hydrogen bonding as well as coordination bonding. Seven leading international experts introduce the current topics in this very interesting field, focusing on two major subjects: organic assemblies and inorganic assemblies. All researchers who are interested in molecular recognition, material science, nanotechnology, and supramolecular chemistry will welcome this book as an inspiring source for creative research ideas.
The IUTAM Symposium on Mechanical and Electromagnetic Waves in Structured Media took place at the University of Sydney from January 18- 22, 1999. It brought together leading researchers from eleven countries for a week-long meeting, with the aim of providing cross-links between the com- nities studying related problems involving elastic and electromagnetic waves in structured materials. After the meeting, participants were invited to submit articles based on their presentations, which were refereed and assembled to constitute these Proceedings. The topics covered here represent areas at the forefront of research intoelastic and electromagnetic waves. They include effect of nonlinearity, diffusion and multiple scattering on waves, as well as asymptotic and numerical techniques. Composite materials are discussed in depth, with example systems ranging fromdusty plasmas to a magneto-elastic microstructured system. Also included are studies of homogenisation, that field which seeks to determine equivalent homogeneous systems which can give equivalent wave properties to structured materials, and inverse problems, in which waves are used as a probe to infer structural details concerning scattering systems. There are also strong groups of papers on the localization of waves by random systems, and photonic and phononic band gap materials. These are being developed by analogue with semiconductors for electrons, and hold out the promise of enabling designers to control the propagation of waves through materials in novel ways. We would like to thank the other members of the Scientific Committee (A.
Viscoelasticandtransportpropertiesofpolymersintheliquid(solution,melt)or liquid-like (rubber) state determine their processing and application to a large extent and are of basic physical interest [1-3]. An understanding of these dynamic properties at a molecular level, therefore, is of great importance. However,thisunderstandingiscomplicatedbythefactsthatdi?erentmotional processes may occur on di?erent length scales and that the dynamics are governed by universal chain properties as well as by the special chemical structure of the monomer units [4,5]. The earliest and simplest approach in this direction starts from Langevin equations with solutions comprising a spectrum of relaxation modes [1-4]. Special features are the incorporation of entropic forces (Rouse model, [6]) which relax uctuations of reduced entropy, and of hydrodynamic interactions (Zimm model, [7]) which couple segmental motions via long-range back ow elds in polymer solutions, and the inclusion of topological constraints or entanglements (reptation or tube model, [8-10]) which are mutually imposed within a dense ensemble of chains. Another approach, neglecting the details of the chemical structure and concentratingontheuniversalelementsofchainrelaxation,isbasedondynamic scalingconsiderations[4,11].Inparticularinpolymersolutions,thisapproach o?ers an elegant tool to specify the general trends of polymer dynamics, although it su?ers from the lack of a molecular interpretation. A real test of these theoretical approaches requires microscopic methods, which simultaneously give direct access to the space and time evolution of the segmental di?usion. Here, quasi-elastic scattering methods play a crucial role sincetheyallowthemeasurementofthecorrespondingcorrelationfunctions.In particular,thehigh-resolutionneutronspinecho(NSE)spectroscopy[12-15]is very suitable for such investigations since this method covers an appropriate range in time (0.005)t/ns)40) and space (r/nm [15). Furthermore, the possibilityoflabellingbyhydrogen-deuteriumexchangeallowstheobservation of single-chain behavior even in the melt.
The renewed and increasing interest in lipid self-assembly, phase behaviour and interfacial properties can be related to both a much improved insight in biological systems and the applications of lipids in food and pharmaceutical industry; in the latter, the development of drug delivery systems based on lipids has become in focus. Amphiphilic systems comprise lipids, surfactants as well as different types of polymers, including block and graft copolymers. Research on biological amphiphiles has often been conducted separate from research on synthetic ones. However, in recent years a very fruitful convergence between the two fields has evolved. These new perspectives on fundamental research and applications of lipids are discussed in these proceedings from an international symposium on "Lipid and Polymer Lipid-systems," October 2000 in Chia Laguna in Italy - a joint undertaking of Prof. Maura Monduzzi at Cagliari University, Italy and Camurus Lipid Research Foundation, Lund, Sweden.
The incessantly interest in aqueous polymer dispersions (APD)
since more than 90 years can be related to the almost unlimited
possibilities to tailor APD to specific needs.
The modeling of minerals and silicated materials is a. difficult challenge faced by Solid StatePhysics, Quantum Chemistry and Molecular Dynamics communities. The difficulty of such a modeling is due to the wide diversity of elements, including heavy atoms, and types of bonding involved in such systems. Moreover, one has to consider infinite systems: either perfect cr- tals or glasses and melts. In the solid state a given chemical composition gives rise to numerous polymorphs, geometricallycloselyrelated. These polymorphs have very similar energies and related thermodynamical pr- erties which explain the complexity of their phase diagrams. The modeling of silicates and minerals covers a wide field of applications ranging from basic research to technology, from Solid State Physics to Earth and Planetary science. The use of modeling techniques yields information of different nature. In the case of chemical studies, we can mention inv- tigations on catalytic processes occurring on surfaces and in zeolite cages. These calculations find possible applications in chemical engineering, in particular in the oil industry
The two volumes "New Developments in Polymer Analytics" deal with recent progress in the characterization of polymers, mostly in solution but also at s- faces. Despite the fact that almost all of the described techniques are getting on in years, the contributions are expected to meet the readers interest because either the methods are newly applied to polymers or the instrumentation has achieved a major breakthrough leading to an enhanced utilizaton by polymer scientists. The first volume concentrates on separation techniques. H. Pasch summarizes the recent successes of multi-dimensional chromatography in the characteri- tion of copolymers. Both, chain length distribution and the compositional h- erogeneity of copolymers are accessible. Capillary electrophoresis is widely and successfully utilized for the characterization of biopolymers, particular of DNA. It is only recently that the technique has been applied to the characterization of water soluble synthetic macromolecules. This contributrion of Grosche and Engelhardt focuses on the analysis of polyelectrolytes by capillary electopho- sis. The last contribution of the first volume by Coelfen and Antonietti sum- rizes the achievements and pitfalls of field flow fractionation techniques. The major drawbacks in the instrumentation have been overcome in recent years and the"triple F techniques" are currently advancing to a powerful competitor to size exclusion chromatography.
Photonic band gap crystals offer unique ways to tailor light and the propagation of electromagnetic waves. In analogy to electrons in a crystal, EM waves propagating in a structure with a periodically-modulated dielectric constant are organized into photonic bands separated by gaps in which propagating states are forbidden. Proposed applications of such photonic band gap crystals, operating at frequencies from microwave to optical, include zero- threshold lasers, low-loss resonators and cavities, and efficient microwave antennas. Spontaneous emission is suppressed for photons in the photonic band gap, offering novel approaches to manipulating the EM field and creating high-efficiency light-emitting structures. Photonic Band Gap Materials identifies three most promising areas of research. The first is materials fabrication, involving the creation of high quality, low loss, periodic dielectric structures. The smallest photonic crystals yet fabricated have been made by machining Si wafers along (110), and some have lattice constants as small as 500 microns. The second area is in applications. Possible applications presented are microwave mirrors, directional antennas, resonators (especially in the 2 GHz region), filters, waveguides, Y splitters, and resonant microcavities. The third area covers fundamentally new physical phenomena in condensed matter physics and quantum optics. An excellent review of recent development, covering theoretical, experimental and applied aspects. Interesting and stimulating reading for active researchers, as well as a useful reference for non-specialists.
This volume includes 58 contributions to the 11th International Conference on Surface and Colloid Science, a highly successful conference sponsored by the International Association of Colloid and Interface Scientists and held in Iguassu Falls, Brazil, in September 2003. Topics covered are the following: Biocolloids and Biological Applications, Charged Particles and Interfaces, Colloid Stability, Colloidal Dispersions, Environmental Colloidal Science, Interfaces and Adsorption, Nanostructures and Nanotechnology, Self-Assembly and Structured Fluids, Surfactants and Polymers, Technology and Applications, Colloids and Surfaces in Oil Production. Surface and colloid science has acquired great momentum during the past twenty years and this volume is a good display of new results and new directions in this important area.
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