Scientific research involving neutrons or synchrotron radiation is performed in large experimental installations at a few sites around the world. Taking full advantage of such techniques requires a wide range of specialized expertise not found in any university course. Therefore, there is a need for reference books and training courses to introduce young scientists to the underlying principles and methods.

Neutron and X-Ray Spectroscopy delivers an up-to-date account of the principles and practice of inelastic and spectroscopic methods available at neutron and synchrotron sources, including recent developments. The chapters are based on a course of lectures and practicals (the HERCULES course at the European Synchrotron Radiation Facility) delivered to young scientists who require these methods in their professional careers. Each chapter, written by a leading specialist in the field, introduces the basic concepts of the technique and provides an overview of recent work. This volume, which focuses on spectroscopic techniques in synchrotron radiation and inelastic neutron scattering, will be a primary source of information for physicists, chemists and materials scientists who wish to acquire a basic understanding of these techniques and to discover the possibilities offered by them. Emphasizing the complementarity of the neutron and X-ray methods, this tutorial will also be invaluable to scientists already working in neighboring fields who seek to extend their knowledge.

Scanning tunneling microscopy has achieved remarkable progress and become the key technology for surface science. This book predicts the future development for all of scanning probe microscopy (SPM). Such forecasts may help to determine the course ultimately taken and may accelerate research and development on nanotechnology and nanoscience, as well as all in SPM-related fields in the future.

For all practical purposes the basic physical equations governing the behaviour of a system at the molecular level can only be solved approximately. The key issue in any reliable and accurate computational study in molecular physics and quantum chemistry is the adoption of a suitable model which contains the essential physics and chemistry, is computationally tractable, and preferably amenable to systematic refinement. The provision of advice on the choice of an appropriate model for a specific problem has so far received scant attention. This issue is becoming acute as standard' software packages are becoming widely available and are being increasingly heavily used in both the academic and industrial sectors by researchers who have received no special training in the theoretical physics and chemistry that underpins them. This volume provides researchers whose background may not be in the computational molecular sciences with the necessary background to make intelligent use of the methods available by performing reliable calculations of appropriate accuracy and making a considered interpretation of the data so obtained.

In this book the characteristics of synchrotron radiation, including insertion device radiation, are described and derived from first principles. The reader is first introduced to the subject in an intuitive way in order to gain familiarity with the underlying physical processes. A rigorous mathematical derivation of the theory follows. Since the characteristics of synchrotron radiation are intimately connected with the parameters of the electron beam and its accelerator, a basic introduction to electron beam dynamics and accelerator design is included. The book is aimed at graduate students and scientists working with synchrotron radiation.

This book provides a comprehensive introduction to the growing field of nuclear solid state physics with synchrotron radiation, a technique that is finding a number of unique applications in fields such as magnetism, surface science, and lattice dynamics. Due to the remarkable brilliance of modern synchrotron radiation sources, the method is particularly suited for the study of thin films, nanoparticles and clusters. Its high isotopic specificity can be employed to measure magnetic or vibrational properties with very high spatial resolution. The book is written on an introductory level and is thus suited for newcomers to the field. Many examples are presented to illustrate the unique experimental possibilities.

The purpose of this book is to provide a broad, comprehensive, up-to-date coverage of current beneficiation techniques and processes that are used for both metallic and nonmetallic minerals; and for other materials, such as household and industrial solid wastes, that are also processed by conventional beneficiation methods in their standard methods of recycling and reclamation. Conservation of natural resources is an adjunct of beneficiation in that we have used up once-available deposits of high-grade ores, leaving only the low-grade deposits that must be beneficiated to upgrade them to sufficiently high levels for processing and metal recovery by current extractive technology. Conservation is also important in the reclamation and recycling of indestructible, noncorrosive materials, so that they may be recovered and reused many times over. The mainly physical, relatively uncomplicated, beneficiation treatments also save large quantities of energy, as these comparatively simple operations are all relatively low energy consumers, when compared with the later separation operations of pyro and electrical nature, which are very high energy consumers. Environmentally, both air and water pollution from beneficiation treatments are either quite low or can easily be controlled, and are gas-free and operated at ambient temperature, to make them one of the cleaner and lower polluting processes used in material treatments.

This monographdeals with metastable states in amorphoussemiconductors- ma- rials which lack long-range periodicity in the atoms' positions, which are in th- modynamic nonequilibrium and which, in addition, have several metastable states. Thesestates giverise tovariouspropertiesandeffects- namelya widerangeofp- toinduced changes and high photosensitivity and X-ray sensitivity - that are unique among solid-state semiconductors.Historically, amorphousselenium and seleni- based materials have played an important role in physics and technology, and they continue to do so. In these materials there exist inherent intermediate (metastable) states, structural and electronic in origin, which lead to interesting properties and effects different from those of their crystalline counterparts. In this volume, the metastable states and related effects are investigated in depth against the background of a detailed consideration of local atomic and electronic structure, and taking into account a wide range of light-induced effects. Although the rst publications on amorphous semiconductors date back to the early 1970s, studies of metastable states in these materials had not been analyzed systematically up to now, which led to erroneous ideas, even among specialists. In the present book, experimental investigations of metastable states are reported in detail for elemental selenium and selenium-based materials.

This book is intended to present for the first time experimental methods to measure equilibria states of pure and mixed gases being adsorbed on the surface of solid materials. It has been written for engineers and scientists from industry and academia who are interested in adsorption based gas separation processes and/or in using gas adsorption for characterization of the porosity of solid materials. This book is the result of a fruitful collaboration of a theoretician (JUK) and an experimentalist (RS) over more than twelve years in the field of gas adsorption systems at the Institute of Fluid- and Thermodynamics (IFT) at the University of Siegen, Siegen, Germany. This collaboration resulted in the development of several new methods to measure not only pure gas adsorption, but gas mixture or coadsorption equilibria on inert porous solids. Also several new theoretical results could be achieved leading to new types of so-called adsorption isotherms based on the concepts of molecular association and - phenomenologically speaking - on that of thermodynamic phases of fractal dimension. Naturally, results of international collaboration of the authors over the years (1980-2000) also are included.

Despite a long history of almost 180 years stretching back to the times of Carnot and, later, Clausius and Lord Kelvin, amongst others following him, the subject of thermodynamics has not as yet seen its full maturity, in the sense that the theory of irreversible processes has remained incomplete. The works of L. Onsager, J. Meixner, I. Prigogine on the thermodyn- ics of linear irreversible processes are, in effect, the early efforts toward the desired goal of giving an adequate description of irreversible processes, but their theory is confined to near-equilibrium phenomena. The works in recent years by various research workers on the extension of the aforem- tioned thermodynamic theory of linear irreversible processes are further efforts toward the goal mentioned. The present work is another of such efforts and a contribution to the subject of generalizing the thermodyn- ics of reversible processes, namely, equilibrium thermodynamics, to that of irreversible processes-non-equilibrium thermodynamics, without being restricted to linear irreversible processes. In this context the terms 'far - moved from equilibrium' is often used in the literature, and such states of macroscopic systems and non-linear irreversible phenomena in them are the objects of interest in this work. The thermodynamics of processes, either reversible or irreversible, is a continuum mechanical theory of matter and energy and their exchange between different parts of the system, and as such it makes no direct r- erence to the molecules constituting the substance under consideration.

The phenomenon of localization of the electronic wave function in a random medium can be regarded as the key manifestation of quantum coherence in a condensed matter system. As one of the most remarkable phenomena in condensed matter physics discovered in the 20th century, the localization problem is an indispensable part of the theory of the quantum Hall effects and rivals superconductivity in its significance as a manifestation of quantum coherence at a macroscopic scale. The present volume, written by some of the leading experts in the field, is intended to highlight some of the recent progress in the field of localization, with particular emphasis on the effect of interactions on quantum coherence. The chapters are written in textbook style and should serve as a reliable and thorough introduction for advanced students or researchers already working in the field of mesoscopic physics.

Quantum and chaos, key concepts in contemporary science, are incompatible by nature. This volume presents an investigation into quantum transport in mesoscopic or nanoscale systems which are classically chaotic and shows the success and failure of quantal, semiclassical, and random matrix theories in dealing with questions emerging from the mesoscopic cosmos. These traditional theories are critically analysed, and this leads to a new direction. To reconcile quantum with chaos and to restore genuine temporal chaos in quantum systems, a time-discrete variant of quantum dynamics is proposed. Audience: This book will be of interest to graduate students and researchers in physics, chemistry and mathematics, whose work involves fundamental questions of quantum mechanics in chaotic systems.

To push MOSFETs to their scaling limits and to explore devices that may complement or even replace them at molecular scale, a clear understanding of device physics at nanometer scale is necessary. Nanoscale Transistors provides a description on the recent development of theory, modeling, and simulation of nanotransistors for electrical engineers, physicists, and chemists working on nanoscale devices. Simple physical pictures and semi-analytical models, which were validated by detailed numerical simulations, are provided for both evolutionary and revolutionary nanotransistors. After basic concepts are reviewed, the text summarizes the essentials of traditional semiconductor devices, digital circuits, and systems to supply a baseline against which new devices can be assessed. A nontraditional view of the MOSFET using concepts that are valid at nanoscale is developed and then applied to nanotube FET as an example of how to extend the concepts to revolutionary nanotransistors. This practical guide then explore the limits of devices by discussing conduction in single molecules

This book describes semiconductors from a materials science perspective rather than from condensed matter physics or electrical engineering viewpoints. It includes discussion of current approaches to organic materials for electronic devices. It further describes the fundamental aspects of thin film nucleation and growth, and the most common physical and chemical vapor deposition techniques. Examples of the application of the concepts in each chapter to specific problems or situations are included, along with recommended readings and homework problems.

This book focuses on the investigation of the basic properties of magnetic nanostructures, and the fundamental physics of novel nanostructures for submicron devices. It provides a broad overview of the latest developments in this emerging and fascinating field of nano-sized materials, with emphasis on the practical understanding and operation of devices using or based on nanostructured magnetic materials. The topics also include submicron technologies, nanoscale characterization, new techniques for the synthesis of nanoparticles as well as an in-depth treatment of their characterization and chemical and physical properties. Potential industrial applications of these advanced materials are also discussed.

This volume contains a peer reviewed selection of the papers presented at the highly successful sixteenth meeting of the European Colloid and Interface Society which was held in Paris, France in September 2002 and highlights some of the important advances in this area. The topics covered include: Molecular self assemblies; Colloids and interfaces; Long range and/or weak interactions in interfacial systems; Original ways to probe colloidal systems; Colloids in biology.

The volume is of interest to both academic and industrial scientists working with colloidal and interfacial systems in chemistry, physics and biology.

With an emphasis on aircraft materials, this book describes techniques for the material characterization to detect and quantify degradation processes such as corrosion and fatigue. It introduces readers to these techniques based on x-ray, ultrasonic, optical and thermal principles and demonstrates the potential of the techniques for a wide variety of applications concerning aircraft materials, especially aluminum and titanium alloys. The advantages and disadvantages of various techniques are evaluated.

The new edition includes additional analytical methods in the classical theory of viscoelasticity. This leads to a new theory of finite linear viscoelasticity of incompressible isotropic materials. Anisotropic viscoplasticity is completely reformulated and extended to a general constitutive theory that covers crystal plasticity as a special case.

In this volume we aim to introduce recent progress in the study of aperiodic materials, which include icosahedral clusters, amorphous metals, quasicrys- tals, glasses, and liquids. Quasicrystals, discovered in 1984, correspond to a kind of revolution in our understanding of crystallography, wherein the five-fold rotational symmetry was prohibited in long-range ordered systems. Various interesting physicochemical properties of these materials strongly depend on structural inhomogeneity at the microscopic level, and the small angle X-ray scattering method is widely used to analyze such structures. These new materials provide fundamental improvements to materials prop- erties, and are not only scientifically interesting but also industrially impor- tant for applications such as ultrafine magnetic recording media and future electronic devices. This book contains three chapters. The first chapter, written by H. Tanaka and T. Fujiwara, deals with 'Electronic Structure in Aperiodic Materials', and reviews the application of theoretical methods to determine the elec- tronic structures and resulting properties of amorphous metals, quasicrys- tals, and liquids. The second chapter, written by Y. Waseda, K. Sugiyama, and A. H. Shinohara, covers the recent topic of 'Anomalous Small Angle X- ray Scattering for Structural Inhomogeneity of Materials', starting with its fundamentals. The third chapter, 'Icosahedral Clusters in RE(TM - Al h3 1 x x Amorphous Alloys', by K. Fukamichi, A. Fujita, T. H. Chang, E. Matsubara, and Y.

It has been almost thirty years since the publication of a book that is entirely dedicated to the theory, description, characterization and measurement of the thermal conductivity of solids. The recent discovery of new materials which possess more complex crystal structures and thus more complicated phonon scattering mechanisms have brought innovative challenges to the theory and experimental understanding of these new materials. With the development of new and novel solid materials and new measurement techniques, this book will serve as a current and extensive resource to the next generation researchers in the field of thermal conductivity. This book is a valuable resource for research groups and special topics courses (8-10 students), for 1st or 2nd year graduate level courses in Thermal Properties of Solids, special topics courses in Thermal Conductivity, Superconductors and Magnetic Materials, and to researchers in Thermoelectrics, Thermal Barrier Materials and Solid State Physics.

Semiconductor spintronics is expected to lead to a new generation of transistors, lasers and integrated magnetic sensors that can be used to create ultra-low power, high speed memory, logic and photonic devices. Useful spintronic devices will need materials with practical magnetic ordering temperatures and current research points to gallium and aluminium nitride magnetic superconductors as having great potential.

This book details current research into the properties of III-nitride semiconductors and their usefulness in novel devices such as spin-polarized light emitters, spin field effect transistors, integrated sensors and high temperature electronics.

Written by three leading researchers in nitride semiconductors, the book provides an excellent introduction to gallium nitride technology and will be of interest to all reseachers and industrial practitioners wishing to keep up to date with developments that may lead to the next generation of transistors, lasers and integrated magnetic sensors.

The monograph "Shaped Crystal Growth" by V. A. Tatarchenko is the first systematic of the macroscopic crystallization theory. The theory is based on the stable statement growth conception, which means that self-stabilization is present in the system, with growth parameter deviations occurring under the action of external perturbations attenuating with time. The crystallization rate is one of the parameters responsible for crystal defect formation. Steady-state crystal growth means that crystallization rate internal stabilization is present, thus allowing more perfect crystals to grow. Most important is the fact that the crystal shape (an easily observed parameter) is one of the stable-growth characteristics when growing crystals without any contact with the crucible walls. This means that constant-cross-section crystal growth is to a certain extent evidence of crystallization process stability. The principles of the stable crystal growth theory were developed by the author of the monograph in the early 1970s. Due to the efforts over the past 20 years of V. A. Tatarchenko, his disciples (V. A. Borodin, S. K. Brantov, E. A. Brener, G. I. Romanova, G. A. Satunkin et al) and his followers (B. L. Timan, 0. V. Kolotiy et al) the theory has been completed, which is demonstrated by this monograph. The characteristic feature of the theory is its trend towards solving practical problems that occur in the process of crystal growth."

Non-Linear Optical Properties of Matter: From Molecules to Condensed Phases attempts to draw together both theory and application in this field. As such it will be of interest to both experimentalists and theoreticians alike. Divided into two parts, Part 1 is concerned with the theory and computing of non-linear optical (NLO) properties while Part 2 reviews the latest developments in experimentation.

Part 1: Surveys the current advances in the computation of the NLO properties of molecules, crystalline solids and nano-particles. It examines the methods employed to compute the properties of both microscopic and macroscopic forms of matter.

Part 2: Covers the recent advances on the NLO properties of organometallic compounds, rotaxanes, glasses, Langmuir-Blodget films, gold and silver nano-particles etc. Strategies to develop novel NLO materials are also discussed along with the Hyper-Rayleigh scattering technique.

In a ?rst approximation, certainly rough, one can de?ne as non-crystalline materials those which are neither single-crystals nor poly-crystals. Within this category, we canincludedisorderedsolids, softcondensed matter, andlivesystemsamong others. Contrary to crystals, non-crystalline materials have in common that their intrinsic structures cannot be exclusively described by a discrete and periodical function but by a continuous function with short range of order. Structurally these systems have in common the relevance of length scales between those de?ned by the atomic and the macroscopic scale. In a simple ?uid, for example, mobile molecules may freely exchange their positions, so that their new positions are permutations of their old ones. By contrast, in a complex ?uid large groups of molecules may be interc- nected so that the permutation freedom within the group is lost, while the p- mutation between the groups is possible. In this case, the dominant characteristic length, which may de?ne the properties of the system, is not the molecular size but that of the groups. A central aspect of some non-crystalline materials is that they may self-organize. This is of particular importance for Soft-matter materials. Self-organization is characterized by the spontaneous creation of regular structures at different length scales which may exhibit a certain hierarchy that controls the properties of the system. X-ray scattering and diffraction have been for more than a hundred years an essential technique to characterize the structure of materials. Quite often scattering anddiffractionphenomenaexhibitedbynon-crystallinematerialshavebeenreferred to as non-crystalline diffractio

This book includes a numerical investigation of shear localization in granular materials within micro-polar hypoplasticity, which was carried out during my long research stay at the Institute of Soil and Rock Mechanics at Karlsruhe University from 1985 to 1996. I dedicate my book to Prof. Gerd Gudehus from Germany, the former head of the Institute of Rock and Soil Mechanics at Karlsruhe University and the supervisor of my scientific research during my stay in Karlsruhe, who encouraged me to deal with shear localization in granular bodies within micro-polar hypoplasticity. I greatly - preciate his profound knowledge, kind help constructive discussions, and collegial attitude to his co-workers. I am thankful to the both series editors: Prof. Wei Wu from Universitat fur Bodenkultur in Austria and Prof. Ronaldo Borja from Stanford University in USA for their helpful suggestions with respect to the contents and structure of the book. I am also grateful to Dr. Thomas Ditzinger and Mrs. Heather King from the Springer Publishing Company and SPS data processing team for their help in editing this book. Gdansk, Jacek Tejchman June 2008 Contents 1 Introduction......................................................................... 1 2 Literature Overview on Experiments........................................... 11 3 Theoretical Model.................................................................. 47 3.1 Hypoplastic Constitutive Model............................................. 47 3.2 Calibration of Hypoplastic Material Parameters........................... 60 3.3 Micro-polar Continuum........................................................ 67 3.4 Micro-polar Hypoplastic Constitutive Model.............................. 72 3.5 Finite Element Implementation................................................ 75 4 Finite Element Calculations: Preliminary Results............................"

Oxides form a broad subject area of research and technology development which encompasses different disciplines such as materials science, solid state chemistry, physics etc. The aim of this book is to demonstrate the interplay of these fields and to provide an introduction to the techniques and methodologies involving film growth, characterization and device processing. The literature in this field is thus fairly scattered in different research journals covering one or the other aspect of the specific activity. This situation calls for a book that will consolidate this information and thus enable a beginner as well as an expert to get an overall perspective of the field, its foundations, and its projected progress.