Discusses the laboratory and industrial synthesis of nonionic surfactants. Furnishes exhaustive coverage of the most recent advances in nonionic surfactant organic chemistry. Analyzes a novel class of catalysts for the production of surfactants with highly narrow distributions.

The discovery and evolution of oranometallic cluster chemistry is a major event in the development of inorganic chemistry. This is the second volume in the series 'The Chemistry of Metal Clusters' edited by Du Shriver, Herb Kaesz, and Richard Adams.
This volume focuses on the chemistry of the early transition elements in their lower and middle oxidation states, i.e., halide, sulfide, oxide, phosphate, alkoxide, and related o-donor ligands. The key feature linking all these complexes in metal-metal bonding is the presence of pi-donor ligands.

Emphasizing the utility of copper-related compounds, this text illustrates the numerous current and potential uses from agricultural bactericides and wood preservatives to colourants and solar cells. It discusses the properties and behaviour of the copper ion, copper compounds' employment in organic polymerization and isomerization reactions, the enhancement of feed efficiencies and additives in plant and animal nutrition, and more.

This book presents recent advances in selected topics on the chemistry, structure, and bonding of Zintl phases and Zintl ions. A number of different research areas are presented, including the use of Zintl phases as precursors to novel solid state compounds, electrochemical synthesis of novel Zintl phases, Zintl phases at the metal-insulator border, reactivity of Zintl phases, structure and bonding of novel Zintl compounds.
Representing the current research of a number of the world's greatest experts in Zintl science, this book presents a balance between the solution chemistry and solid state chemistry related to Zintl phases and ions.

Electrochemistry no longer is a specialist discipline, but has become a technique of major importance for most inorganic and organometallic chemists. Similarly, electron-transfer activation has led to great progress in transition-metal mediated organic and inorganic syntheses. This book provides a unique introduction and overview of the structure and reactions of transition-metal radicals, of transition-metal electrochemistry, and of electron-transfer activation, with emphasis on catalytic processes. Each chapter of this book includes numerous citations of the chemical literature, lots of examples and illustrations and the book is written in an extremely readable style. It will serve as a useful tutorial for a wide spectrum of students, chemists, and chemical engineers involved in organic, inorganic, and organometallic chemistry.

Inorganic membrane science and technology is a new field of membrane separation technology which until recently was dominated by the earlier field of polymer membranes. Currently the subject is undergoing rapid development and innovation.

The present book describes the fundamental principles of both synthesis of inorganic membranes and membrane supports and also the associated phenomena of transport and separation in a semi-quantitative form.

Features of this book:

- Examples are given which illustrate the state-of-the-art in the synthesis of membranes with controlled properties

- Future possibilities and limitations are discussed

- The reader is provided with references to more extended treatments in the literature

- Potential areas for future innovation are indicated.

By combining aspects of both the science and technology of inorganic membranes this book serves as a useful source of information for scientists and engineers working in this field. It also provides some observations of important investigators who have contributed to the development of this subject.

For the first time the discipline of modern inorganic chemistry has been systematized according to a plan constructed by a council of editorial advisors and consultants, among them three Nobel laureates (E.O. Fischer, H. Taube and G. Wilkinson).
Rather than producing a collection of unrelated review articles, the series creates a framework which reflects the creative potential of this scientific discipline. Thus, it stimulates future development by identifying areas which are fruitful for further research.
The work is indexed in a unique way by a structured system which maximizes its usefulness to the reader. It augments the organization of the work by providing additional routes of access for specific compounds, reactions and other topics.

Over the last decade, increased attention to reaction dynamics, combined with the intensive application of computers in chemical studies, mathematical modeling of chemical processes, and mechanistic studies has brought graph theory to the forefront of research. It offers an advanced and powerful formalism for the description of chemical reactions and their intrinsic reaction mechanisms. Chemical Reaction Networks: A Graph-Theoretical Approach elegantly reviews and expands upon graph theory as applied to mechanistic theory, chemical kinetics, and catalysis. The authors explore various graph-theoretical approaches to canonical representation, numbering, and coding of elementary steps and chemical reaction mechanisms, the analysis of their topological structure, the complexity estimation, and classification of reaction mechanisms. They discuss topologically distinctive features of multiroute catalytic and noncatalytic and chain reactions involving metal complexes. With it's careful balance of clear language and mathematical rigor, the presentation of the authors' significant original work, and emphasis on practical applications and examples, Chemical Reaction Networks: A Graph Theoretical Approach is both an outstanding reference and valuable tool for chemical research.

The Environmental Chemistry of Aluminum provides a comprehensive, fundamental account of the aqueous chemistry of aluminum within an environmental context. An excellent reference for environmental chemists and scientific administrators of environmental programs, this book contains material reflecting the many recent changes in this rapidly developing discipline.
The first three chapters discuss the most fundamental aspects of aluminum chemistry: its quantitation in soils and natural waters, including speciation measurements, and its stable chemical forms, both as a dissolved solute and in a solid phase. These chapters emphasize both critical assessments of and definitive recommendations for laboratory methodologies and measured thermodynamic properties relating to aluminum chemistry.
The next four chapters in The Environmental Chemistry of Aluminum build on this foundation to provide details of the polymeric chemistry of aluminum: its polynuclear and colloidal hydrolytic species in aqueous solution, its complexes with natural organic ligands, including humic substances, and its role as an adsorptive and adsorbent in surface reactions. These chapters are grounded in experimental results rather than conceptual modeling.
The final three chapters describe the chemistry of aluminum in soils, waters, and watersheds. These chapters illustrate the problems of spatial and temporal variability, metastability, and scale that continue to make aluminum geochemistry one of the great challenges in modern environmental science.

This book is devoted to general questions of the chemistry of metal alkoxides - including physiochemical properties, structure, specific features of single groups of alkoxides, theoretical principles of their use, and major applications of this method in the preparation of functional materials.

Buckminsterfullerenes Edited by W. Edward Billups Marco A. Ciufolini "The authors ... have done an excellent job of summarizing the current state of knowledge of this new class of nanoscale materials, and have captured much of the sense of excitement." -R. E. Smalley Few areas of chemical research have attracted the attention of the scientific community as have the fullerenes. The interest has crossed disciplines of physics, chemistry, and materials science. Buckminsterfullerene itself has been named the Molecule of the Year by Science (December 20, 1991). This monograph brings together the work of leading investigators. It is organized into four sections: (1) The main events leading to the discovery and preliminary studies of the fullerenes. (2) Theoretical studies of fulleroid cages. (3) Super-conductivity properties. (4) Exo- and endohedral complexes and some chemical properties of these new materials.

More than a one-volume listing of synthetic methods, Compendium of Organic Synthetic Methods offers chemists a highly focused and selective look at several thousand functional group transformations. Used by more professionals than any comparable reference on the market, this valuable desktop resource provides quick access to the recipes of the newest, most useful reactions and transformations. It also affords professionals an unparalleled opportunity to browse the vast body of recent literature for new reactions and transformations that may be of interest.

Featuring 1,200 more entries than its predecessor, Volume 8 covers functional group transformations and carbon-carbon bond forming reactions appearing in the literature from 1990 through 1992. It presents approximately 1,400 examples of published reactions for the preparation of monofunctional compounds and approximately 1,640 examples of reactions that prepare difunctional compounds with various functional groups. It also features 60 more reviews than Volume 7.

As in all the previous Compendium volumes, the classification schemes used allow for quick and easy reference and information retrieval. Chemical transformations are classified first by the reacting functional group of the starting material and then by the functional group formed. The transformation, major reagents that effect the transformation, yield percentage, and stereochemistry are all clearly shown. The Compendium also includes indices for both monofunctional and difunctional compounds as an efficient means of guiding you to specific classes of transformations.

Compendium of Organic Synthetic Methods, Volume 8 provides professional chemists and students unparalleled access to the wealth of methods, reactions, and transformations in contemporary organic chemistry.

"This new book is by two knowledgeable and expert popularizers of chemistry and deals exclusively with molecules and compounds rather than with the simpler atoms and elements. It is based on the very successful Molecule of the Month website that was begun by Paul May fifteen years ago and to which his co-author Simon Cotton has been a frequent contributor. The authors strike an excellent balance between introducing the novice to the world of molecules while also keeping the expert chemist interested. I highly recommend this book to all readers. It will vastly expand your knowledge and horizons of chemistry and the human ingenuity that surrounds it." From the Foreword by Dr. Eric Scerri, UCLA, Los Angeles, website: www.ericscerri.com, Author of The Periodic Table, Its Story and Its Significance and several other books on the elements and the periodic table. The world is composed of molecules. Some are synthetic while many others are products of nature. Molecules That Amaze Us presents the stories behind many of the most famous and infamous molecules that make up our modern world. Examples include the molecule responsible for the spicy heat in chilies (capsaicin), the world s first synthetic painkiller (aspirin), the pigment responsible for the color of autumn leaves (carotene), the explosive in dynamite (nitroglycerine), the antimalarial drug (quinine), the drug known as "speed" (methamphetamine), and many others. Other molecules discussed include caffeine, adrenaline, cholesterol, cocaine, digitalis, dopamine, glucose, insulin, methane, nicotine, oxytocin, penicillin, carbon dioxide, limonene, and testosterone. In all, the book includes 67 sections, each describing a different molecule, what it does, how it is made, and why it is so interesting. Written by experts in the field, the book is accessible and easy to read. It includes amusing anecdotes

This 24th volume continues in the tradition of its predecessors, presenting authoritative, interdisciplinary coverage of contemporary topics in the field of carbon chemistry and physics. With contributions by leading international experts, this volume: describes pitch polymerization kinetics during mesophase formation and the constitution of coexisting phases in mesophase pitch during heat treatment; elucidates the mechanism of mesophase formation and pitch polymerization kinetics after mesophase formation; examines the importance of physical, solid-state, electro- and analytical chemistry in the study of carbon surfaces; discusses the theoretical background for the thermal conductivity of diamonds, single crystal diamonds and chemically-vapour-deposited diamond films; and explains the chemistry involved in the commercial fabrication and use of needle coke.

Internationally renowned authors review recent advances in the understanding of the structure and reactivity of transition metal hydrides. This up-to-date analysis of transition metal hydrides examines the recent upsurge of experimental studies devoted to transition metal hydrides in both gas phase and solution. It also explores the recent emergence of new refinements in the methodologies and techniques used to delineate reaction mechanisms in solution.

For the first time the discipline of modern inorganic chemistry has been systematized according to a plan constructed by a council of editorial advisors and consultants, among them three Nobel laureates (E.O. Fischer, H. Taube and G. Wilkinson). Rather than producing a collection of unrelated review articles, the series creates a framework which reflects the creative potential of this scientific discipline. Thus, it stimulates future development by identifying areas which are fruitful for further research. The work is indexed in a unique way by a structured system which maximizes its usefulness to the reader. It augments the organization of the work by providing additional routes of access for specific compounds, reactions and other topics.

For the first time the discipline of modern inorganic chemistry has been systematized according to a plan constructed by a council of editorial advisors and consultants, among them three Nobel laureates (E.O. Fischer, H. Taube and G. Wilkinson).
Rather than producing a collection of unrelated review articles, the series creates a framework which reflects the creative potential of this scientific discipline. Thus, it stimulates future development by identifying areas which are fruitful for further research.
The work is indexed in a unique way by a structured system which maximizes its usefulness to the reader. It augments the organization of the work by providing additional routes of access for specific compounds, reactions and other topics.

Both the early use of artificial lighting and current manufacturing methods concerning incandescent and fluorescent lamps are covered in this book. The protocols for manufacture of fluorescent lamp phosphors and those used in cathode ray tubes are also treated in some detail. This text surveys the amazing, vast array of artificial lighting devices known to date in terms of how they arose and are, or have been used by mankind.

A complete description of the formulations and methodology for manufacturing all known phosphors is given. The book will serve as a repository of such phosphor manufacturing methods, including that of cathode ray tube phosphors. Methods of manufacture of lamp parts are also presented, including that of tungsten wire. The original approaches used are described as well as improvements in technology. These will serve as comparative methods for present day manufacture of these components. A history of the lamp industry is presented. Several methods are given which may serve as a source for further work in the lamp industry. Some of the earliest work has been applied in the laser industry to develop new types of discharge lasers. These include nitrogen-gas lasers and the rare gas (excimer) lasers. Previous work on lamps may also be applied in the development of new types of lasers.

While the boundaries between the areas of chemistry traditionally labeled as inorganic, organic and physical are gradually diffusing, the practical techniques adopted by workers in each of these areas are often radically different. The breadth and variety of research classed as "inorganic chemistry" is readily apparent from an inspection of some of the leading international journals, and can be quite daunting for newcomers to this domain who are likely to have only limited experience of the methodologies involved. This book has therefore been written to provide guidance for those unfamiliar with the techniques most often encountered in synthetic inorganic / metalorganic chemistry, with an emphasis on procedures for handling air-sensitive compounds. One chapter is devoted to more specialized techniques such as metal vapor synthesis, and a review of preparative methods for a selection of starting materials is included as an aid to those planning research projects. While this book is aimed primarily at postgraduate and advanced undergraduate students involved in inorganic research projects, synthetic organic chemists and industrial chemists will also find much useful information within its pages. Similarly, it serves as a useful reference source for materials and polymer scientists who wish to take advantage of recent progress in precursor synthesis and catalyst development.

This volume is devoted to the research area regarding the biological properties of metal alkyl derivatives, offering an authoritative account of this subject by 16 scientists. In 11 chapters, Biological Properties of Metal Alkyl Derivatives highlights, in detail, derivatives of germanium, tin, lead, arsenic, antimony, selenium, tellurium, cobalt (vitamin B12 derivatives) and nickel (coenzyme F430), including the role of (mainly) micro-organisms in their formation. The derivatives of indium, thallium, bismuth, various transition metals and mercury are also covered to some extent, as are those of the non-metals silicon, phosphorus and sulfur, and the haloperoxidase route of the biogenesis of halomethanes by fungi and plants. The properties of these alkyl derivatives, their biosynthesis, including mechanistic aspects, their appearance in waters (rivers, lakes, oceans) and sediments, and their physiological and toxic effects are summarized.

For the first time the discipline of modern inorganic chemistry has been systematized according to a plan constructed by a council of editorial advisors and consultants, among them three Nobel laureates (E.O. Fischer, H. Taube and G. Wilkinson).
Rather than producing a collection of unrelated review articles, the series creates a framework which reflects the creative potential of this scientific discipline. Thus, it stimulates future development by identifying areas which are fruitful for further research.
The work is indexed in a unique way by a structured system which maximizes its usefulness to the reader. It augments the organization of the work by providing additional routes of access for specific compounds, reactions and other topics.

Volume 17, entitled Lead: Its Effects on Environment and Health of the series Metal Ions in Life Sciences centers on the interrelations between biosystems and lead. The book provides an up-to-date review of the bioinorganic chemistry of this metal and its ions; it covers the biogeochemistry of lead, its use (not only as gasoline additive) and anthropogenic release into the environment, its cycling and speciation in the atmosphere, in waters, soils, and sediments, and also in mammalian organs. The analytical tools to determine and to quantify this toxic element in blood, saliva, urine, hair, etc. are described. The properties of lead(II) complexes formed with amino acids, peptides, proteins (including metallothioneins), nucleobases, nucleotides, nucleic acids, and other ligands of biological relevance are summarized for the solid state and for aqueous solutions as well. All this is important for obtaining a coherent picture on the properties of lead, its effects on plants and toxic actions on mammalian organs. This and more is treated in an authoritative and timely manner in the 16 stimulating chapters of Volume 17, which are written by 36 internationally recognized experts from 13 nations. The impact of this recently again vibrant research area is manifested in nearly 2000 references, over 50 tables and more than 100 illustrations (half in color). Lead: Its Effects on Environment and Health is an essential resource for scientists working in the wide range from material sciences, inorganic biochemistry all the way through to medicine including the clinic ... not forgetting that it also provides excellent information for teaching.

Powder diffraction is a widely used scientific technique in the characterization of materials with broad application in materials science, chemistry, physics, geology, pharmacology and archaeology. Powder Diffraction: Theory and Practice provides an advanced introductory text about modern methods and applications of powder diffraction in research and industry. The authors begin with a brief overview of the basic theory of diffraction from crystals and powders. Data collection strategies are described including x-ray, neutron and electron diffraction setups using modern day apparatus including synchrotron sources. Data corrections, essential for quantitative analysis are covered before the authors conclude with a discussion of the analysis methods themselves. The information is presented in a way that facilitates understanding the information content of the data, as well as best practices for collecting and analyzing data for quantitative analysis. This long awaited book condenses the knowledge of renowned experts in the field into a single, authoritative, overview of the application of powder diffraction in modern materials research. The book contains essential theory and introductory material for students and researchers wishing to learn how to apply the frontier methods of powder diffraction

Continuing to explore the relationship between the chemistry of metals and life processes, this volume in the Metal Ions in Biological Systems series examines the degradation of environmental pollutants by micro-organisms. It covers the action of micro-organisms and metalloenzymes on lignin, tannins, hemicelluloses, cellulose and aromatic compounds, as well as on halogenated aromatics and aliphatics; analyzes mechanistic aspects; considers the role of metalloproteases in biotechnology and wastewater sludge treatment; and describes the metal-dependent conversion of inorganic nitrogen and sulfur compounds.

This book focuses on inorganic nanosheets, including various oxides, chalcogenides, and graphenes, that provide two-dimensional (2D) media to develop materials chemistry in broad fields such as electronics, photonics, environmental science, and biology. The application area of nanosheets and nanosheet-based materials covers the analytical, photochemical, optical, biological, energetic, and environmental research fields. All of these applications come from the low dimensionality of the nanosheets, which anisotropically regulate structures of solids, microspaces, and fluids. Understanding nanosheets from chemical, structural, and application aspects in relation to their "fully nanoscopic" characters will help materials scientists to develop novel advanced materials. This is the first book that accurately and concisely summarizes this field including exfoliation and intercalation chemistries of layered crystals. The book provides perspective on the materials chemistry of inorganic nanosheets. The first section describes fundamental aspects of nanosheets common to diverse applications: how unique structures and properties are obtained from nanosheets based on low dimensionality. The second section presents state-of-the-art descriptions of how the 2D nature of nanosheets is utilized in each application of the materials that are developed.