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Books > Science & Mathematics > Chemistry > Inorganic chemistry > General
The book provides an in-depth discussion regarding inorganic ion exchangers for students, teachers, and researchers engaged in conducting research in chemical technology and related areas. Analytical chemists seeking simple and novel means of using easy-to-prepare chromatographic materials will find this book extremely informative. Inorganic Ion Exchangers in Chemical Analysis is unique in its discussion of column and planar chromatographic applications of amorphous synthetic inorganic ion exchangers. The book also covers the historical background of iorganic ion exchangers, their classification and present status, and the analytical aspects of these materials.
The creation of molecular materials that have desired electrical conductance and magnetic properties demands the precise arrangement of molecules in the solid state. Such controlled arrangement has been achieved very elegantly by supramolecular chemists, especially those practising crystal engineering. This book, which presents articles by foremost experts in crystal engineering, molecular conductors and magnetic magnetism, reveals the results of an interdisciplinary union that may well have a profound influence on the future of materials science. Theoretical studies reveal potential areas of interest for those investigating molecular conductors and magnets, as well as materials that exhibit both properties. A unique survey of the state of the art appealing to all those doing research in supramolecular chemistry and materials science.
This volume contains the proceedings of the NATO Advanced Research Workshop on "Atomic and Molecular Wires". It was sponsored by the Ministry of Scientific Affairs Division special program on Nanoscale Science with the support of the CNRS and the Max Planck Institute. Scientists working or interested in the properties of wires at a subnanoscale were brought together in Les Houches (France) from 6 to 10 May 1996. Subnanoscale wires can be fabricated either by surface physicists (atomic wires) or by synthetic chemists (molecular wires). Both communities present their foremost advances using, for example, STM to assemble atomic lines atom for atom, to fabricate a mask for such a line or using the wide range of chemical synthesis techniques to obtain long, rigid and conjugated oligomers. Interconnecting such tiny wires to sources (voltage, current) continues to demand a great technological effort. But nanolithography associated with microfabrication or STM are now clearly identified paths for measuring the electrical resistance of an atomic or a molecular wire. The first measurements have been reported on Xe , benzene, C ' di(phenylene-ethynylene) showing 2 60 the need for a deeper understanding of transport phenomena through subnanowires. Such transport phenomena like tunnel (off-resonance) transport and Coulomb blockade have been discussed by theorists with an emphasis on the exponential decrease of the tunnel current with the wire length versus the ballistic regime of transport.
Organic LEDs (OLEDs) in mobile displays have been in large-scale production for over a decade, and OLED-based televisions are rapidly gaining traction in the marketplace. OLEDs are on the verge of entering the solid-state lighting market in a big way. The OLED technology gives higher color purity and is more efficient than any of the competing technologies. When produced at scale, OLEDs are also economical. A key limitation in the development of OLEDs was the efficient conversion of all of the electrical energy put into the device into light. Until the late 1990s, the maximum efficiency of OLEDs was limited to 25% (photons/electrons), but this limitation was removed and OLEDs with 100% efficiency were reported in the early 2000s. This advance in OLED technology was driven by the author of this book. He and his collaborators developed electrophosphorescence, which is essential in reaching the 100% efficiency that is now commonplace in commercial devices.
Boasting numerous industrial applications, inorganic chemistry forms the basis for research into new materials and bioinorganic compounds such as calcium that act as biological catalysts. Now complete, this highly acclaimed series presents current knowledge in all areas of inorganic chemistry, including chemistry of the elements; organometallic, polymeric and solid-state materials; and compounds relevant to bioinorganic chemistry.
This first International Workshop on Auger Spectroscopy and Electronic Struc ture - IWASES 1, held in Giardini-Naxos, Sicily, Italy, grew out of a number of longstanding collaborations between the various Institutes of Physics of the University of Messina, namely the Institute of the Structure of Matter, the In stitute of Theoretical Physics and the Institute of General Physics, and groups in other European countries at the University of Liverpool, England, the Insti tute of Physical Chemistry, University of Munich, and the Fritz Haber Institute of the Max Planck Society, Berlin, FRG. This workshop was the first to be devoted solely to Auger electron spectroscopy. This initiative was motivated by the enormous evolution of the field within the last decade to a point where it now extends far beyond the mere application of this spectroscopy as an analytical tool to determine surface cleanliness and surface composition. In fact, the Auger process, which is a multi-electron process, and which leaves the sample in a doubly (or higher) ionized state, is an invaluable probe for investigating excited states and, in particular, electron (or hole) correlation effects. These correlation effects play an important role for many physical prop erties of matter such as magnetism, screening processes, and electron stimulated desorption (ESD), to name but a few."
P.J. van der Put offers students an original introduction to materials chemistry that integrates the full range of inorganic chemistry. Technologists who need specific chemical facts to manipulate matter will also find this work invaluable as an easy-to-use reference. The text includes practical subjects of immediate use for materials such as bonding, morphogenesis, and design that more orthodox materials science volumes often leave out.
The book emphasizes various aspects of processing secondary sources for recovery of uranium. The field of secondary resource processing is gaining ground over the last few years as it is eco-friendly, economical and in tune with the philosophy of sustainable development. The book is the first one of its type in the area and includes a succint and comprehensive description of related areas of ore mineralogy, resource classification, processing principles involved in uranium solubilisation followed by separation and safety aspects. The clear organisation and the carefully selected figures and tables makes the treatment invaluable for practising engineers, research workers and academic institutions.
The book covers the chronological development of synthetic approaches to make carbon nanotube mimics. It starts with the breakthrough syntheses reported in 2008 to the most recent methods to make nanobelts and short nanotubes.
Wetting Theory discusses the numerous practical applications of wetting, such as preparing self-cleaning surfaces, manufacturing artificial blood vessels, and developing new lubricants and nonadhesive dishes. As part of Wetting: Theory and Experiments, Two-Volume Set, thisvolume provides new, critical insights into the theory of wetting. Chapters are arranged to allow readers to follow the development of a suggested approach (static and dynamic properties of wetting) and how these tools are applied to specific problems. Main attention is given to nanoscale wetting (nanodrops on solid surfaces, liquid in the nanoslit) on the basis of microscopic density functional theory and fluid dynamics on solid surfaces on the basis of hydrodynamic equations. Aimed at engineers, physical scientists, and materials scientists, this volume addresses the key areas of wetting, providing invaluable insights to the field.
Wetting Experiments contains experimental wetting studies related to biological problems, polymers, and catalysts. An understanding of wetting is important for numerous practical applications, such as preparing self-cleaning surfaces, manufacturing artificial blood vessels, and developing new lubricants and nonadhesive dishes. As part of Wetting: Theory and Experiments, Two-Volume Set, thisvolume provides new insights into wetting experiments and fills a need not addressed by other books. Biology-related studies are devoted to the problem synthetic materials selection for use in biological media. Polymers are examined to estimate various surface characteristics, such as the ability of polymeric solids to alter their surface structures between different environments to minimize their interfacial free energy. Aimed at engineers, physical scientists, and materials scientists, this volume addresses the key areas of wetting, providing insights valuable to the field.
This series presents critical reviews of the present and future trends in polymer and biopolymer science including chemistry, physical chemistry, physics and materials science. It is addressed to all scientists at universities and in industry who wish to keep abreast of advances in the topics covered. Impact Factor Ranking: Always number one in Polymer Science. More information as well as the electronic version of the whole content available at: www.springerlink.com
SELECTED AS ONE OF THE BEST BOOKS OF 2018 BY THE DAILY MAIL 'A hugely entertaining tour of the periodic table and the 118 elements that are the basic building blocks of everything' Daily Mail In 2016, with the addition of four final elements - nihonium, moscovium, tennessine and oganesson - to make a total of 118 elements, the periodic table was finally complete, rendering any pre-existing books on the subject obsolete. Tim James, the science YouTuber and secondary-school teacher we all wish we'd had, provides an accessible and wonderfully entertaining 'biography of chemistry' that uses stories to explain the positions and patterns of elements in the periodic table. Many popular science titles tend to tell the history of scientific developments, leaving the actual science largely unexplained; James, however, makes use of stories to explain the principles of chemistry within the table, showing its relevance to everyday life. Quirkily illustrated and filled with humour, this is the perfect book for students wanting to learn chemistry or for parents wanting to help, but it is also for anyone who wants to understand how our world works at a fundamental level. The periodic table, that abstract and seemingly jumbled graphic, holds (nearly) all the answers. As James puts it, elements are 'the building blocks nature uses for cosmic cookery: the purest substances making up everything from beetroot to bicycles.' Whether you're studying the periodic table for the first time or are simply interested in the fundamental building blocks of the universe - from the core of the sun to the networks in our brains - Elemental is the perfect guide. Website: timjamesscience.com YouTube: timjamesScience Twitter: @tjamesScience
This book will help chemists and non-chemists alike understand the fundamentals of surface chemistry and precursor design, and how these precursors drive the processes of atomic layer deposition, and how the surface-precursor interaction governs atomic layer deposition processes. The underlying principles in atomic layer deposition rely on the chemistry of a precursor with a surface.
The knowledge about crystal structure and its correlation with physical properties is the prerequisite for designing new materials with taylored properties. This work provides for researchers and graduates a valuable resource on various techniques for crystal structure determinations. By discussing a broad range of different materials and tools the authors enable the understanding of why a material might be suitable for a particular application.
The book includes several topics as per Universities curriculum of M.Sc. and M.Phil. course work in Chemistry. This covers different Physiological aspects of Bioinorganic Chemistry in terms of 4 Chapters with in-depth and up-to-date coverage. The book symmetrically presents (i) Coordination chemistry of chlorophylls/bacteriochlophylls and its functional aspects in photosynthesis, (ii) Complexes containing nitric oxide: Synthesis, reactivity, structure, bonding, and therapeutic aspects of nitric oxide releasing molecules (NORMS) in human beings and plants, (iv) Complexes containing carbon monoxide: Synthesis, reactivity, structure, bonding, and therapeutic aspects of carbon monoxide releasing molecules (CORMS) in human beings and plants, and (iv) Advantageous role of gaseous signaling molecule, H2S: Hydrogen sulphide and their respective donors, in ophthalmic diseases and physiological implications in plants. At the end, three relevant topics are included as appendices for updating students and faculty members.
This book is essential reading for scientists and students interested in both organic and inorganic chemical technology. The authors cover the production of chemical reagents as well as trends from adjacent fields including biotechnology and process simulation. Chemical Technologies and Processes is of interest to chemical engineers, materials scientists, as well as chemists in both academia and industry.
This book summarizes some recent developments in the area of high-energy high-density (HEDM) materials. Rather than being comprehensive in scope, emphasis is given to structural and bonding features of highly energetic - terials with possible applications as high explosives (secondary explosives) or propellants. In this book we do not focus on primary explosives (e.g. lead azidereplacements)sincebyde?nitiontheexplosiveperformance(detonation velocity and detonation pressure) of such materials - although very sensitive -are much less energetic than secondary (high) explosives. Modern HEDMs derive most of their energy (i) from oxidation of the c- bon backbone, as in traditional energetic materials, (ii) from ring or cage strain, or (iii) from their very high positive heat of formation. Examples of the?rstclassare traditionalexplosives, suchasTNT, RDXand HMX.Modern nitro-compounds, such as CL-20 or the recently reported hepta- and octa- trocubanes, belong to the second group of explosives and possess very high densities and enhance the energies utilizing substantial cage strain. Members of the third class of compounds are high-nitrogen compounds (up to 85% - trogencontent), such as aminotetrazole and nitrotetrazolederivatives, which show the desired remarkable insensitivity to electrostatic discharge, friction and impact, while having very high positive heats of formation and therefore very high explosive powers. The synthesis of energetic, non-nuclear materials for military application has been a long-term goal in various academic and military research groups worldwide. Some of the current challenges that face HEDMscientists are: Demandforenvironmentallycompatibleandtoxicologicallyacceptable- plosives and propellants. Examples are replacements for TNT, RDX and HMXsince nitro-explosivesper se, aswellastheir environmental transf- mation products, are toxic."
Zeitschrift fur Kristallographie. Supplement Volume 41 presents the complete Abstracts of all contributions to the 29th Annual Conference of the German Crystallographic Society in Hamburg (Germany) 2021: - Plenary Talks - Microsymposia - Poster Session Supplement Series of Zeitschrift fur Kristallographie publishes Abstracts of international conferences on the interdisciplinary field of crystallography.
This book provides an in-depth introduction to the sol to gel transition in inorganic and hybrid organic-inorganic systems, one of the most important chemical-physical transitions and the basis of the sol-gel process. Familiarity with the fundamental chemistry and physics of this transition is essential for students in chemistry and materials science through academic and industry researchers working on sol-gel-related applications. The book features a didactic approach, using simple and clear language to explain the sol to gel transition and the accompanying processes. The text is also suitable for use in short courses and workshops for graduate students as well as professionals.This fully revised and updated new edition contains a wealth of new content. In particular, it includes a detailed discussion of the chemistry of transition metal alkoxides and organosilanes, and an extended discussion of the sol to gel transition models.
Framework Science.- Polymers for Multifunctional Applications: Some General Considerations.- An Objective for Polymers with Unusual Properties: Polymers with Delocalized Electronic States.- Ceramics from Organometallic Polymers: Industrial Perspectives.- The Current State of the Art in the Synthesis of Inorganic and Organometallic Polymers.- Polymer Synthesis.- Polymerization of Liquid Crystalline Monomers.- Electrosynthesis, A New Route to Disilanes, Polysilanes and Polycarbosilanes.- Catalytic Dehydro-and Dehydrosilyl-coupling: New Routes to Inorganic and Hybrid Organic/Inorganic Polymers.- Synthesis of Penta-alkoxy-and Penta-aryloxy Silicates Directly from SiO2.- Magnetic Materials.- Molecular Composites of the MPS3 Layered Inorganic Polymers: Chemistry, Magnetic, and Dielectric Properties.- Chemistry, Structures and Magnetic Properties of Mn(II)Cu(II) Molecular Compounds: Heterobinuclear Species, Ferrimagnetic Chains and Molecular-Based Ferromagnets..- Magnetic Molecular Materials.- Conducting And Electronic Materials.- Molecular Solids with Organic Conducting Chains and Inorganic Magnetic Chains: The (Per)2(mnt)2 Family. (M = Ni, Cu, Pd, Pt, Au, Fe and Co)..- Selective Synthesis and Some Electroconductive Properties of Organosilicon Polymers Containing Aromatic Units.- Crystal and Electronic Structure of Cobaltacene Intercalates of the Host Lattices SnS2-xSex (x=O, 0.3, 0.5, 1.3, 1.85, 2).- Approaches to Stacked, Semi-conducting Organometallics.- Supramolecular Organization of Phthalocyanines. Design and Synthesis of Low Dimensional Conductors.- Preceramic Materials.- Synthesis and Pyrolysis Chemistry of Polymeric Precursors to SiC and Si3N4.- A Catalytic Preparation of a New Preceramic Polymer: Transformation into SiC.- Transition Metal Oxo Polymers Synthesized via Sol-Gel Chemistry.- Organically Modified Silicates as Inorganic-Organic Polymers.- Nonlinear Optical Materials.- Resonant Nonlinear Optical Excitations in Glassy Polymers.- Rigid-Rod Transition Metal Acetylide Complexes, Oligomers, and Polymers for Nonlinear Optics.- Characterization.- Spectroscopic Characterization of the Pyrolysis Process of Pre-Ceramics Polymers.- Characterisation of Metallophthalocyanine Polymers for Application as Semiconductor Gas Sensor Material.- Aspects of Polyphosphazene Photochemistry.- Characterizing the Microstructures of New Polymers.- Report To Nato.- Inorganic and Organometallic Polymer with Special Properties. Progress, Potential and Problems.
This concise, easy-to-read book outlines the basic principles needed to understand the chemical mechanisms of explosion. Written for students with no previous knowledge of explosives but some understanding of chemical reactions in mind, it takes the reader through the history of explosives and introduces the concepts of high explosives, propellants and pyrotechnics. Covering combustion, deflagration, and detonation; ignition, initiation, and thermal decomposition; thermochemistry, thermodynamics and kinetics, the text includes detailed formulations and reactions presented with thermochemical calculations to aid understanding. This edition includes environmental legislation and its impact on explosives, together with a section on safety hazard tests. It also contains the latest developments in synthesis and manufacturing of explosives. Covering all aspects of the properties of explosives, The Chemistry of Explosives is a unique text which introduces difficult subjects in a readable manner. Ideal for A-level students and new graduates with no previous knowledge of explosive materials, it will also be useful to anyone needing succinct information on the subject, such as the more experienced chemist in the explosives sector.
The book presents, in a unified manner, various crystallization design methods. It discusses in detail the geometric framework for representing complex phase behavior involving multiple solutes, enantiomers, hydrates, compounds, polymorphs, and solid solutions through visualization of high-dimensional phase diagrams. It also describes how the impact of transport processes is accounted for using kinetically controlled process paths. |
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